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    • 1. 发明授权
    • Photosensitizer dye
    • 光敏剂染料
    • US08106198B2
    • 2012-01-31
    • US12223601
    • 2007-02-05
    • Ke-Jian JiangShuji NodaShozo Yanagida
    • Ke-Jian JiangShuji NodaShozo Yanagida
    • C07F15/00H01L31/00
    • C09B57/10C07D213/38C07D409/14H01G9/2031H01G9/2059H01L51/0086H01M14/005Y02E10/542Y02E10/549
    • A theme of the present invention is to provide a new transition metal complex, useful as a photosensitizer dye for a photoelectric conversion element having an excellent durability and a high photoelectric conversion characteristic. The present invention provides a bivalent transition metal complex constituted of (i) a bipyridyl polyacidic ligand, such as a dicarboxybipyridyl (dcbpy) ligand, as an adsorption site for adsorption onto titanium dioxide particle surfaces; (ii) a ligand, selected from the group consisting of an isothiocyanato group, an isocyanato group, and an isoselenocyanato group and enabling absorption and excitation at long wavelengths and charge transfer; and (iii) a bipyridyl (bpy) ligand, having an alkyl group or an alkoxy group, preferably a long-chain alkyl group, and a conjugately bonded thienylvinylene group, aminophenylenevinylene group, etc., and improving an absorbance of a transition metal complex and imparting stability against nucleophile to a sensitizer dye that improves an absorption bathochromic effect.
    • 本发明的主题是提供一种新的过渡金属络合物,其可用作具有优异耐久性和高光电转换特性的光电转换元件的光敏染料。 本发明提供由(i)二吡啶基多酸配体如二羧基联吡啶(dcbpy)配体构成的二价过渡金属络合物作为吸附在二氧化钛颗粒表面上的吸附位点; (ii)选自异硫氰酸酯基,异氰酸基和异硒基异氰酸酯基的配体,并且能够在长波长和电荷转移下进行吸收和激发; 和(iii)具有烷基或烷氧基,优选长链烷基和共轭键合的噻吩基亚乙烯基,氨基亚苯基亚乙烯基等的联吡啶(bpy)配体,并改善过渡金属络合物的吸光度 并赋予敏化剂染料对亲核试剂的稳定性,改善了吸收红细胞色素的作用。
    • 2. 发明申请
    • Photosensitizer Dye
    • 光敏剂染料
    • US20090216021A1
    • 2009-08-27
    • US12223601
    • 2007-02-05
    • Ke-Jian JiangShuji NodaShozo Yanagida
    • Ke-Jian JiangShuji NodaShozo Yanagida
    • C07F15/00
    • C09B57/10C07D213/38C07D409/14H01G9/2031H01G9/2059H01L51/0086H01M14/005Y02E10/542Y02E10/549
    • A theme of the present invention is to provide a new transition metal complex, useful as a photosensitizer dye for a photoelectric conversion element having an excellent durability and a high photoelectric conversion characteristic. The present invention provides a bivalent transition metal complex constituted of (i) a bipyridyl polyacidic ligand, such as a dicarboxybipyridyl (dcbpy) ligand, as an adsorption site for adsorption onto titanium dioxide particle surfaces; (ii) a ligand, selected from the group consisting of an isothiocyanato group, an isocyanato group, and an isoselenocyanato group and enabling absorption and excitation at long wavelengths and charge transfer; and (iii) a bipyridyl (bpy) ligand, having an alkyl group or an alkoxy group, preferably a long-chain alkyl group, and a conjugately bonded thienylvinylene group, aminophenylenevinylene group, et., and improving an absorbance of a transition metal complex and imparting stability against nucleophile to a sensitizer dye that improves an absorption bathochromic effect.
    • 本发明的主题是提供一种新的过渡金属络合物,其可用作具有优异耐久性和高光电转换特性的光电转换元件的光敏染料。 本发明提供由(i)二吡啶基多酸配体如二羧基联吡啶(dcbpy)配体构成的二价过渡金属络合物作为吸附在二氧化钛颗粒表面上的吸附位点; (ii)选自异硫氰酸酯基,异氰酸基和异硒基异氰酸酯基的配体,并且能够在长波长和电荷转移下进行吸收和激发; 和(iii)具有烷基或烷氧基,优选长链烷基和共轭键合的噻吩基亚乙烯基,氨基亚苯基亚乙烯基等的联吡啶(bpy)配体,并改善过渡金属络合物的吸光度 并赋予敏化剂染料对亲核试剂的稳定性,改善了吸收红细胞色素的作用。
    • 7. 发明授权
    • Energy absorbing structure of vehicular door
    • 车门吸能结构
    • US06203096B1
    • 2001-03-20
    • US09313354
    • 1999-05-18
    • Shuji NodaSotaro Kumazawa
    • Shuji NodaSotaro Kumazawa
    • B60J500
    • B60J5/0451B60R21/0428B60R2021/0414
    • An energy absorbing structure of a vehicular door has an energy absorbing member that is disposed on a compartment side of an inner panel, at such a position as to substantially face a hip of an occupant sitting on a seat. The energy absorbing member has a block or container shape. A generally rectangular protruded portion is formed together with the energy absorbing member. The protruded portion is protruded from a front-to-rear middle portion of an upper end portion of a bottom wall of the energy absorbing member that faces the inner panel when the energy absorbing member is mounted. The bottom wall has an increased wall thickness and therefore resists bending deformation. The protruded portion is designed so that the protruded portion is substantially prevented from undergoing compression deformation at the time of impact. In a door assembly, the protruded portion protrudes from a service hole formed in the inner panel toward to an outer panel. A substantially vertically extending windowpane regulator guide is disposed at a side of the protruded portion, the side being opposite from the compartment. The windowpane regulator guide is spaced from the protruded portion by a small clearance.
    • 车门的能量吸收结构具有设置在内板的隔室侧的能量吸收构件,该能量吸收构件基本上面对坐在座椅上的乘员的臀部。 能量吸收构件具有块状或容器形状。 与能量吸收构件一起形成大致矩形的突出部。 当安装能量吸收构件时,突出部分从与能量吸收构件的底壁的上端部的前后中间部分突出。 底壁的壁厚增加,因此抵抗弯曲变形。 突出部被设计成使得突出部基本上防止在冲击时发生压缩变形。 在门组件中,突出部分从形成在内板中的维修孔向外板突出。 大致垂直延伸的窗玻璃调节器引导件设置在突出部分的与隔室相对的一侧。 窗玻璃调节器导向件与突出部分间隔很小的间隙。