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1. 发明申请

US20100119969A1 POSITIVE PHOTOSENSITIVE RESIN COMPOSITION AND DPOLYHYDROXYAMIDE RESIN 审中-公开
标题翻译：阳性光敏树脂组合物和DPOLYHYDROXYAMIDE树脂
公开(公告)号：US20100119969A1
公开(公告)日：2010-05-13
申请号：US12451906
申请日：2008-05-27
申请人： Kazuya Ebara , Hideo Suzuki , Takayuki Tamura
发明人： Kazuya Ebara , Hideo Suzuki , Takayuki Tamura
IPC分类号： G03F7/004 , C08G63/00
CPC分类号： C08G69/28 , C08G69/26 , C08G69/265 , C08G69/40 , C08G69/42 , G03F7/0045 , G03F7/0233 , G03F7/0387 , G03F7/0757 , G03F7/40
摘要： There is provided a positive photosensitive resin composition that is excellent in electric insulating properties, heat resistance, mechanical strength and electrical characteristics, and capable of forming a high-resolution circuit pattern. The positive photosensitive resin composition comprises at least one type of a polyhydroxyamide resin containing a repeating unit represented by Formula (1) and having a weight average molecular weight of 3,000 to 100,000, and a compound generating an acid by light irradiation. (where X represents a tetravalent aliphatic group or an aromatic group; R1 and R2 independently represent a hydrogen atom or an alkyl group having 1 to 10 carbon atom(s); Ar1 and Ar2 independently represent an aromatic group; Y represents an organic group containing an aromatic group substituted with at least one OH group; n represents an integer of 1 or more; and l and m independently represent an integer of 0 or 1 or more and satisfy l+m≦2).
摘要翻译：提供了具有优异的电绝缘性，耐热性，机械强度和电特性并且能够形成高分辨率电路图案的正型感光性树脂组合物。正型感光性树脂组合物包含至少一种含有式（1）表示的重均单元，重均分子量为3,000〜100,000的聚羟基酰胺树脂和通过光照射产生酸的化合物。（其中X表示四价脂肪族基团或芳香族基团; R 1和R 2分别表示氢原子或碳原子数1〜10的烷基，Ar 1和Ar 2独立地表示芳香族基，Y表示含有被至少一个OH基团取代的芳基; n表示1以上的整数，l和m分别表示0或1以上的整数，满足l + m＆lt; 1lE; 2）。

2. 发明授权

US08258318B2 Process for production of coumarin dimer compound 有权
标题翻译：生产香豆素二聚体化合物的方法
公开(公告)号：US08258318B2
公开(公告)日：2012-09-04
申请号：US12451213
申请日：2008-04-28
申请人： Hideo Suzuki , Takayuki Tamura
发明人： Hideo Suzuki , Takayuki Tamura
IPC分类号： C07D311/00
CPC分类号： C07D493/04
摘要： There is provided a one-step process for producing a dihydroxy-substituted coumarin dimer compound by a photodimerization reaction of a hydroxy-substituted coumarin compound. The process comprises subjecting a hydroxy-substituted coumarin compound to a photodimerization reaction in a solvent selected from aliphatic ketones having 3 to 10 carbon atoms, aliphatic carboxylic acid esters having 2 to 10 carbon atoms, aliphatic alcohols having 1 to 10 carbon atoms, aliphatic nitriles having 2 to 10 carbon atoms, ethers having 4 to 10 carbon atoms, amides having 3 to 10 carbon atoms, and a mixture thereof to obtain a dihydroxy-substituted coumarin dimer compound.
摘要翻译：提供了通过羟基取代的香豆素化合物的光二聚反应制备二羟基取代的香豆素二聚体化合物的一步法。该方法包括使羟基取代的香豆素化合物在选自具有3至10个碳原子的脂族酮，2至10个碳原子的脂肪族羧酸酯，1至10个碳原子的脂族醇，脂族醇，脂族腈具有2至10个碳原子，具有4至10个碳原子的醚，具有3至10个碳原子的酰胺及其混合物，以获得二羟基取代的香豆素二聚体化合物。

3. 发明申请

US20090292103A1 POLYAMIC ACID AND POLYIMIDE 有权
标题翻译：聚氨酯和聚酰亚胺
公开(公告)号：US20090292103A1
公开(公告)日：2009-11-26
申请号：US12373230
申请日：2007-07-09
申请人： Hideo Suzuki , Takayuki Tamura , Yoshikazu Ootsuka
发明人： Hideo Suzuki , Takayuki Tamura , Yoshikazu Ootsuka
IPC分类号： C08G73/10 , C07C61/04 , C07D307/77
CPC分类号： C08G73/1078 , C07D487/04 , C07D493/04 , C08G73/1046 , C08G73/105 , C08G73/1075 , C08L79/08
摘要： A polyamic acid comprising at least 10 mol % repeating units represented by the formula [1] or [2]; and a polyimide represented by the formula [3] or [4] which is obtained from the polyamic acid. A polyimide film having high heat resistance and satisfactory in light-transmitting properties and tensile strength is obtained from the polyamic acid. (In the formulae, R1 and R2 each independently represents hydrogen or C1-10 alkyl; R3 and R4 each independently represents hydrogen, halogeno, C1-10alkyl, or phenyl or the R3 and R4 on adjoining carbon atoms are bonded to each other to form C3-8 cycloalkyl or phenyl; R5 represents a divalent organic group; and n is an integer of 2 or larger.)
摘要翻译：包含由式[1]或[2]表示的至少10摩尔％重复单元的聚酰胺酸; 和由聚酰胺酸得到的由式[3]或[4]表示的聚酰亚胺。从聚酰胺酸得到耐热性高，透光性和拉伸强度良好的聚酰亚胺膜。（式中，R 1和R 2各自独立地表示氢或C 1-10烷基; R 3和R 4各自独立地表示氢，卤素，C 1-10烷基或苯基，或者相邻碳原子上的R 3和R 4彼此键合形成 C3-8环烷基或苯基; R5表示二价有机基团; n为2以上的整数。）

4. 发明授权

US08067527B2 Polyamic acid and polyimide 有权
标题翻译：聚酰胺酸和聚酰亚胺
公开(公告)号：US08067527B2
公开(公告)日：2011-11-29
申请号：US12373230
申请日：2007-07-09
申请人： Hideo Suzuki , Takayuki Tamura , Yoshikazu Ootsuka
发明人： Hideo Suzuki , Takayuki Tamura , Yoshikazu Ootsuka
IPC分类号： C08G73/00
CPC分类号： C08G73/1078 , C07D487/04 , C07D493/04 , C08G73/1046 , C08G73/105 , C08G73/1075 , C08L79/08
摘要： A polyamic acid comprising at least 10 mol % repeating units represented by the formula [1] or [2]; and a polyimide represented by the formula [3] or [4] which is obtained from the polyamic acid. A polyimide film having high heat resistance and satisfactory in light-transmitting properties and tensile strength is obtained from the polyamic acid. (In the formulae, R1 and R2 each independently represents hydrogen or C1-10 alkyl; R3 and R4 each independently represents hydrogen, halogeno, C1-10alkyl, or phenyl or the R3 and R4 on adjoining carbon atoms are bonded to each other to form C3-8 cycloalkyl or phenyl; R5 represents a divalent organic group; and n is an integer of 2 or larger.)
摘要翻译：包含由式[1]或[2]表示的至少10摩尔％重复单元的聚酰胺酸; 和由聚酰胺酸得到的由式[3]或[4]表示的聚酰亚胺。从聚酰胺酸得到耐热性高，透光性和拉伸强度良好的聚酰亚胺膜。（式中，R 1和R 2各自独立地表示氢或C 1-10烷基; R 3和R 4各自独立地表示氢，卤素，C 1-10烷基或苯基，或者相邻碳原子上的R 3和R 4彼此键合形成 C3-8环烷基或苯基; R5表示二价有机基团; n为2以上的整数。）

5. 发明申请

US20110257361A1 ALKYL BENZENE TETRACARBOXYLIC DIANHYDRIDE, MANUFACTURING METHOD THEREOF, POLYIMIDE, AND APPLICATION THEREOF 审中-公开
标题翻译：烷基苯甲酮四羧酸二酐，其制备方法，聚酰亚胺及其应用
公开(公告)号：US20110257361A1
公开(公告)日：2011-10-20
申请号：US13140880
申请日：2009-12-17
申请人： Hideo Suzuki , Takayuki Tamura , Takahiro Noda
发明人： Hideo Suzuki , Takayuki Tamura , Takahiro Noda
IPC分类号： C08G73/10 , C07C51/377 , C07C63/313 , C07D493/04
CPC分类号： C07D493/04 , C07C51/09 , C07C63/313 , C08G73/10 , C08L79/08 , G02F1/133723
摘要： Disclosed is a 5-alkyl-1,2,3,4-benzene tetracarboxylic-1:2,3:4-dianhydride which is represented by the general formula (1) and has excellent solubility with respect to various organic solvents. Depending on the diamine that is used, a polyimide with excellent heat resistance or a polyimide with good workability at a low melting point can be provided, and in addition, a polyimide that exhibits excellent characteristics for electronic materials or the like can be provided. (In the formula, R1 represents an alkyl group with carbon number 1-10.)
摘要翻译：公开了由通式（1）表示的5-烷基-1,2,3,4-苯四羧酸-1,2,3：4-二酐，并且对于各种有机溶剂具有优异的溶解性。根据所使用的二胺，可以提供具有优异耐热性的聚酰亚胺或在低熔点下具有良好加工性的聚酰亚胺，并且还可以提供具有优异的电子材料等特性的聚酰亚胺。（式中，R1表示碳原子数1〜10的烷基）

6. 发明申请

US20090182115A1 POLYAMIC ACID AND POLYIMIDE 有权
标题翻译：聚氨酯和聚酰亚胺
公开(公告)号：US20090182115A1
公开(公告)日：2009-07-16
申请号：US12295705
申请日：2007-02-28
申请人： Hideo Suzuki , Takayuki Tamura , Kentaro Ohmori
发明人： Hideo Suzuki , Takayuki Tamura , Kentaro Ohmori
IPC分类号： C08G73/10 , C08G69/26
CPC分类号： C08G73/10
摘要： Disclosed are a polyamic acid containing not less than 10 mol % of a repeating unit represented by the formula [1] below, and a polyimide represented by the formula [2] below which is obtained from such a polyamic acid. The polyamic acid and polyimide have high heat resistance as shown by a thermal decomposition temperature of not less than 300° C. In addition, the polyamic acid and polyimide have good workability because of their high solubility in solvents, while exhibiting good light transmission. (In the formulae, R1 and R2 independently represent a hydrogen atom or an alkyl group having 1 to 10 carbon atoms; R3 and R4 independently represent a hydrogen atom, a halogen atom, an alkyl group having 1 to 10 carbon atoms or a phenyl group, or alternatively R3 and R4 on adjacent carbon atoms may combine together to form a cycloalkyl group having 3 to 8 carbon atoms or a phenyl group; R5 represents a divalent organic group; and n represents an integer of not less than 2.)
摘要翻译：公开了含有不少于10摩尔％的由下式[1]表示的重复单元的聚酰胺酸和由这种聚酰胺酸获得的由下式[2]表示的聚酰亚胺。聚酰胺酸和聚酰亚胺具有如热分解温度不低于300℃所示的高耐热性。另外，由于聚酰胺酸和聚酰亚胺在溶剂中的溶解性高，同时具有良好的透光性，因此具有良好的加工性。（式中，R 1和R 2分别表示氢原子或碳原子数1〜10的烷基，R 3和R 4分别表示氢原子，卤素原子，碳原子数1〜10的烷基或苯基或者相邻碳原子上的R3和R4可以结合在一起形成具有3〜8个碳原子的环烷基或苯基; R 5表示二价有机基团，n表示不小于2的整数）

7. 发明申请

US20090012318A1 Cage-shaped cyclobutanoic dianhydrides and process for production thereof 有权
标题翻译：笼形环丁酸二酐及其生产方法
公开(公告)号：US20090012318A1
公开(公告)日：2009-01-08
申请号：US11665024
申请日：2005-10-18
申请人： Hideo Suzuki , Takayuki Tamura
发明人： Hideo Suzuki , Takayuki Tamura
IPC分类号： C07D493/08 , C07C67/08 , C07D493/04 , C07C69/74 , C07C61/04 , C07C51/083 , C07C67/333
CPC分类号： C07C67/11 , C07C51/09 , C07C51/56 , C07C67/08 , C07C67/12 , C07C67/333 , C07C69/74 , C07C2601/04 , C07D493/04 , C07D493/08 , C07C61/04
摘要： A process which comprises reacting a 1,2,3,4-cyclobutanetetracarboxylic-1,2:3,4-dianhydride [1] with an alcohol [2] in the presence of an acid catalyst to obtain a compound [3], isomerizing the compound [3] with a base catalyst into a compound [4], reacting the compound [4] with an organic acid to obtain a compound [5], and reacting the compound [5] with a dehydrating agent to obtain a 1,2,3,4-cyclobutanetetracarboxylic-1,3:2,4-dianhydride: wherein R1 and R2 are each independently hydrogen, halogeno, alkyl of 1 to 10 carbon atoms, halogenated alkyl of 1 to 10 carbon atoms, cycloalkyl of 3 to 8 carbon atoms, phenyl, or cyano; and R3 is alkyl of 1 to 10 carbon atoms.
摘要翻译：一种方法包括在酸催化剂存在下使1,2,3,4-环丁烷四羧酸-1,2：3,4-二酐[1]与醇[2]反应，得到化合物[3]，异构化化合物[3]与碱催化剂合成化合物[4]，使化合物[4]与有机酸反应，得到化合物[5]，并使化合物[5]与脱水剂反应，得到1， 2,3,4-环丁烷四羧酸-1,3：2,4-二酐：其中R1和R2各自独立地为氢，卤代，1-10个碳原子的烷基，1-10个碳原子的卤代烷基，3〜 8个碳原子，苯基或氰基; 并且R 3是1至10个碳原子的烷基。

8. 发明授权

US07872148B2 Cage-shaped cyclobutanoic dianhydrides and process for production thereof 有权
标题翻译：笼形环丁酸二酐及其生产方法
公开(公告)号：US07872148B2
公开(公告)日：2011-01-18
申请号：US11665024
申请日：2005-10-18
申请人： Hideo Suzuki , Takayuki Tamura
发明人： Hideo Suzuki , Takayuki Tamura
IPC分类号： C07D493/08
CPC分类号： C07C67/11 , C07C51/09 , C07C51/56 , C07C67/08 , C07C67/12 , C07C67/333 , C07C69/74 , C07C2601/04 , C07D493/04 , C07D493/08 , C07C61/04
摘要： A process which comprises reacting a 1,2,3,4-cyclobutanetetracarboxylic-1,2:3,4-dianhydride [1] with an alcohol [2] in the presence of an acid catalyst to obtain a compound [3], isomerizing the compound [3] with a base catalyst into a compound [4], reacting the compound [4] with an organic acid to obtain a compound [5], and reacting the compound [5] with a dehydrating agent to obtain a 1,2,3,4-cyclobutanetetracarboxylic-1,3:2,4-dianhydride: wherein R1 and R2 are each independently hydrogen, halogeno, alkyl of 1 to 10 carbon atoms, halogenated alkyl of 1 to 10 carbon atoms, cycloalkyl of 3 to 8 carbon atoms, phenyl, or cyano; and R3 is alkyl of 1 to 10 carbon atoms.
摘要翻译：一种方法包括在酸催化剂存在下使1,2,3,4-环丁烷四羧酸-1,2：3,4-二酐[1]与醇[2]反应，得到化合物[3]，异构化化合物[3]与碱催化剂合成化合物[4]，使化合物[4]与有机酸反应，得到化合物[5]，并使化合物[5]与脱水剂反应，得到1， 2,3,4-环丁烷四羧酸-1,3：2,4-二酐：其中R1和R2各自独立地为氢，卤代，1-10个碳原子的烷基，1-10个碳原子的卤代烷基，3〜 8个碳原子，苯基或氰基; 并且R 3是1至10个碳原子的烷基。

9. 发明申请

US20100130755A1 PROCESS FOR PRODUCTION OF COUMARIN DIMER COMPOUND 有权
标题翻译：生产欧司素二聚体化合物的方法
公开(公告)号：US20100130755A1
公开(公告)日：2010-05-27
申请号：US12451213
申请日：2008-04-28
申请人： Hideo Suzuki , Takayuki Tamura
发明人： Hideo Suzuki , Takayuki Tamura
IPC分类号： C07D493/04
CPC分类号： C07D493/04
摘要： There is provided a one-step process for producing a dihydroxy-substituted coumarin dimer compound by a photodimerization reaction of a hydroxy-substituted coumarin compound. The process comprises subjecting a hydroxy-substituted coumarin compound to a photodimerization reaction in a solvent selected from aliphatic ketones having 3 to 10 carbon atoms, aliphatic carboxylic acid esters having 2 to 10 carbon atoms, aliphatic alcohols having 1 to 10 carbon atoms, aliphatic nitriles having 2 to 10 carbon atoms, ethers having 4 to 10 carbon atoms, amides having 3 to 10 carbon atoms, and a mixture thereof to obtain a dihydroxy-substituted coumarin dimer compound.
摘要翻译：提供了通过羟基取代的香豆素化合物的光二聚反应制备二羟基取代的香豆素二聚体化合物的一步法。该方法包括使羟基取代的香豆素化合物在选自具有3至10个碳原子的脂族酮，2至10个碳原子的脂肪族羧酸酯，1至10个碳原子的脂族醇，脂族醇，脂族腈具有2至10个碳原子，具有4至10个碳原子的醚，具有3至10个碳原子的酰胺及其混合物，以获得二羟基取代的香豆素二聚体化合物。

10. 发明授权

US07906611B2 Polyamic acid and polyimide 有权
标题翻译：聚酰胺酸和聚酰亚胺
公开(公告)号：US07906611B2
公开(公告)日：2011-03-15
申请号：US12295705
申请日：2007-02-28
申请人： Hideo Suzuki , Takayuki Tamura , Kentaro Ohmori
发明人： Hideo Suzuki , Takayuki Tamura , Kentaro Ohmori
IPC分类号： C08G73/10
CPC分类号： C08G73/10
摘要： Disclosed are a polyamic acid containing not less than 10 mol % of a repeating unit represented by the formula [1] below, and a polyimide represented by the formula [2] below which is obtained from such a polyamic acid. The polyamic acid and polyimide have high heat resistance as shown by a thermal decomposition temperature of not less than 300° C. In addition, the polyamic acid and polyimide have good workability because of their high solubility in solvents, while exhibiting good light transmission. (In the formula, R1 and R2 independently represent a hydrogen atom or an alkyl group having 1 to 10 carbon atoms; R3 and R4 independently represent a hydrogen atom, a halogen atom, an alkyl group having 1 to 10 carbon atoms or a phenyl group, or alternatively R3 and R4 on adjacent carbon atoms may combine together to form a cycloalkyl group having 3 to 8 carbon atoms or a phenyl group; R5 represents a divalent organic group; and n represents an integer of not less than 2.)
摘要翻译：公开了含有不少于10摩尔％的由下式[1]表示的重复单元的聚酰胺酸和由这种聚酰胺酸获得的由下式[2]表示的聚酰亚胺。聚酰胺酸和聚酰亚胺具有如热分解温度不低于300℃所示的高耐热性。另外，由于聚酰胺酸和聚酰亚胺在溶剂中的溶解性高，同时具有良好的透光性，因此具有良好的加工性。（式中，R 1和R 2分别表示氢原子或碳原子数1〜10的烷基，R 3和R 4分别表示氢原子，卤素原子，碳原子数1〜10的烷基或苯基或者相邻碳原子上的R3和R4可以结合在一起形成具有3〜8个碳原子的环烷基或苯基; R 5表示二价有机基团，n表示不小于2的整数）

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