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    • 1. 发明授权
    • Process for production of 2-(substituted phenyl)-3,3,3-trifluoropropene compound
    • 2-(取代苯基)-3,3,3-三氟丙烯化合物的制备方法
    • US07964758B2
    • 2011-06-21
    • US12223657
    • 2007-02-13
    • Kazutaka MatobaTakashi MizukoshiYuji Moriyama
    • Kazutaka MatobaTakashi MizukoshiYuji Moriyama
    • C07C17/32
    • C07C17/263C07B37/04C07C41/30C07C231/12C07C25/24C07C22/08C07C233/15C07C43/225
    • There is provided a novel process for production of a 2-(substituted phenyl) -3,3,3-trifluoropropene. Disclosed is a process for production of a 2-(substituted phenyl)-3,3,3-trifluoropropene compound represented by the formula (7) or a salt thereof The process comprises reacting a compound represented by the formula (1) (X is an alkyl group, etc.) with a compound represented by the formula (2) (Y is a halogen atom, etc.) in the presence of a catalyst represented by the formula (3) (M is an ion of a metal belonging to Group 10 on the elementary periodic table which has an oxidation state number of 1 to 8; G is a unidentate or multidentate ligand; L is a phosphine compound represented by the formula (4) which is bound to the center metal M or is a carbene selected from those represented by the formulae (5) and (6), provided that L's may be same as or different from one another when a is 2 to 5; A represents a univalently or multivalently charged anion; b represents an integer of 1 to 3; a represents an integer of 1 to 5·b; c represents 0 or an integer of 1 to 4·b; and n represents an integer of 1 to 6).
    • 提供了一种生产2-(取代的苯基)-3,3,3-三氟丙烯的新方法。 公开了一种由式(7)表示的2-(取代苯基)-3,3,3-三氟丙烯化合物或其盐的制备方法。该方法包括使式(1)表示的化合物(X为 烷基等)与式(2)表示的化合物(Y为卤素原子等)在式(3)表示的催化剂的存在下反应(M为属于 氧原子数为1〜8的元素周期表第10族; G为单齿或多齿配位体; L为与中心金属M结合的式(4)所示的膦化合物或者是卡宾 选自由式(5)和(6)表示的那些,条件是当a为2至5时,L 1可以彼此相同或不同; A表示单价或多价带电的阴离子; b表示1至 3; a表示1〜5·b的整数,c表示0或1〜4·b的整数,n表示i 1到6的整数)。
    • 2. 发明申请
    • Process for Production of 2-(Substituted Phenyl)-3,3,3-Trifluoropropene Compound
    • 2-(取代苯基)-3,3,3-三氟丙烯化合物的制备方法
    • US20100160683A1
    • 2010-06-24
    • US12223657
    • 2007-02-13
    • Kazutaka MatobaTakashi MizukoshiYuji Moriyama
    • Kazutaka MatobaTakashi MizukoshiYuji Moriyama
    • C07C231/12C07C17/32C07C41/30
    • C07C17/263C07B37/04C07C41/30C07C231/12C07C25/24C07C22/08C07C233/15C07C43/225
    • There is provided a novel process for production of a 2-(substituted phenyl)-3,3,3-trifluoropropene. Disclosed is a process for production of a 2-(substituted phenyl)-3,3,3-trifluoropropene compound represented by the formula (7) or a salt thereof The process comprises reacting a compound represented by the formula (1) (X is an alkyl group, etc.) with a compound represented by the formula (2) (Y is a halogen atom, etc.) in the presence of a catalyst represented by the formula (3) (M is an ion of a metal belonging to Group 10 on the elementary periodic table which has an oxidation state number of 1 to 8; G is a unidentate or multidentate ligand; L is a phosphine compound represented by the formula (4) which is bound to the center metal M or is a carbene selected from those represented by the formulae (5) and (6), provided that L's may be same as or different from one another when a is 2 to 5; A represents a univalently or multivalently charged anion; b represents an integer of 1 to 3; a represents an integer of 1 to 5·b; c represents 0 or an integer of 1 to 4·b; and n represents an integer of 1 to 6).
    • 提供了一种生产2-(取代的苯基)-3,3,3-三氟丙烯的新方法。 公开了一种由式(7)表示的2-(取代苯基)-3,3,3-三氟丙烯化合物或其盐的制备方法。该方法包括使式(1)表示的化合物(X为 烷基等)与式(2)表示的化合物(Y为卤素原子等)在式(3)表示的催化剂的存在下反应(M为属于 氧原子数为1〜8的元素周期表第10族; G为单齿或多齿配位体; L为与中心金属M结合的式(4)所示的膦化合物或者是卡宾 选自由式(5)和(6)表示的那些,条件是当a为2至5时,L 1可以彼此相同或不同; A表示单价或多价带电的阴离子; b表示1至 3; a表示1〜5·b的整数,c表示0或1〜4·b的整数,n表示i 1到6的整数)。
    • 5. 发明授权
    • Production method of isoxazoline-substituted benzoic acid amide compound
    • 异恶唑啉取代苯甲酸酰胺化合物的制备方法
    • US08389738B2
    • 2013-03-05
    • US13002837
    • 2009-07-09
    • Hiroyuki KousakaShunsuke FukuyaYuji MoriyamaManabu YaosakaTakashi Mizukoshi
    • Hiroyuki KousakaShunsuke FukuyaYuji MoriyamaManabu YaosakaTakashi Mizukoshi
    • C07D261/04
    • C07D261/04
    • A production method of an isoxazoline-substituted benzoic acid amide compound of Formula (1) where X is a halogen atom, C1-6 haloalkyl, etc., Y is a halogen atom, C1-6 alkyl, etc., R1 is a C1-6 haloalkyl, etc., R2 and R3 independently of each other are a hydrogen atom, C1-6 alkyl, etc., R4 is C1-6 alkyl, C1-6 haloalkyl, etc., R5 is a hydrogen atom, c1-6 alkyl, etc., m is an integer of 0 to 5, n is an integer of 0 to 4, including: reacting an isoxazoline-substituted benzene compound of Formula (3) where X, Y, R1, m, and n are the same as defined above, L is a chlorine atom, a bromine atom, —C(O)OH, —C(O)J, etc., J is a halogen atom, with a 2-aminoacetic acid amide compound of Formula (2) where R2, R3, R4, and R5 are the same as defined above, or a salt thereof; crystal forms and the production method thereof.
    • 其中X是卤素原子,C 1-6卤代烷基等的式(1)的异恶唑啉取代的苯甲酸酰胺化合物的制备方法,Y是卤素原子,C 1-6烷基等,R 1是C 1 -6卤代烷基等,R2和R3彼此独立地是氢原子,C1-6烷基等,R4是C1-6烷基,C1-6卤代烷基等,R5是氢原子,c1- 6烷基等,m为0〜5的整数,n为0〜4的整数,包括:使式(3)的异恶唑啉取代的苯化合物,其中X,Y,R 1,m和n分别为 与上述相同,L是氯原子,溴原子,-C(O)OH,-C(O)J等,J是卤素原子,与式(2)的2-氨基乙酰胺化合物 2)其中R2,R3,R4和R5与上述定义相同,或其盐; 晶体形式及其制备方法。
    • 6. 发明申请
    • PRODUCTION METHOD OF ISOXAZOLINE-SUBSTITUTED BENZOIC ACID AMIDE COMPOUND
    • ISOXAZOLINE-取代苯甲酸酰胺化合物的生产方法
    • US20110144349A1
    • 2011-06-16
    • US13002837
    • 2009-07-09
    • Hiroyuki KousakaShunsuke FukuyaYuji MoriyamaManabu YaosakaTakashi Mizukoshi
    • Hiroyuki KousakaShunsuke FukuyaYuji MoriyamaManabu YaosakaTakashi Mizukoshi
    • C07D261/04
    • C07D261/04
    • A production method of an isoxazoline-substituted benzoic acid amide compound of Formula (1) where X is a halogen atom, C1-6 haloalkyl, etc., Y is a halogen atom, C1-6 alkyl, etc., R1 is a C1-6 haloalkyl, etc., R2 and R3 independently of each other are a hydrogen atom, C1-6 alkyl, etc., R4 is C1-6 alkyl, C1-6 haloalkyl, etc., R5 is a hydrogen atom, c1-6 alkyl, etc., m is an integer of 0 to 5, n is an integer of 0 to 4, including: reacting an isoxazoline-substituted benzene compound of Formula (3) where X, Y, R1, m, and n are the same as defined above, L is a chlorine atom, a bromine atom, —C(O)OH, —C(O)J, etc., J is a halogen atom, with a 2-aminoacetic acid amide compound of Formula (2) where R2, R3, R4, and R5 are the same as defined above, or a salt thereof; crystal forms and the production method thereof.
    • 其中X是卤素原子,C 1-6卤代烷基等的式(1)的异恶唑啉取代的苯甲酸酰胺化合物的制备方法,Y是卤素原子,C 1-6烷基等,R 1是C 1 -6卤代烷基等,R2和R3彼此独立地是氢原子,C1-6烷基等,R4是C1-6烷基,C1-6卤代烷基等,R5是氢原子,c1- 6烷基等,m为0〜5的整数,n为0〜4的整数,包括:使式(3)的异恶唑啉取代的苯化合物,其中X,Y,R 1,m和n分别为 与上述相同,L是氯原子,溴原子,-C(O)OH,-C(O)J等,J是卤素原子,与式(2)的2-氨基乙酰胺化合物 2)其中R2,R3,R4和R5与上述定义相同,或其盐; 晶体形式及其制备方法。
    • 7. 发明授权
    • Solid electrolytic capacitor and method of manufacturing the same
    • 固体电解电容器及其制造方法
    • US07619876B2
    • 2009-11-17
    • US12140373
    • 2008-06-17
    • Kunihiko ShimizuTakashi MizukoshiKoji Sakata
    • Kunihiko ShimizuTakashi MizukoshiKoji Sakata
    • H01G4/228H01G9/00
    • H01G9/012H01G9/08H01G9/15Y10T29/417
    • A solid electrolytic capacitor includes a porous sintered body made of a valve-acting metal and embedded with part of an anode lead having a protruding portion, a solid electrolyte layer formed in contact with a dielectric layer formed in the porous sintered body, a mounting anode terminal member, a mounting cathode terminal member, and an insulating casing resin. The capacitor further includes a small piece of a metal frame made of a valve-acting metal. This small piece of the metal frame is formed integrally with the protruding portion of the anode lead by cutting, after the anodic oxidation, the metal frame to which the protruding portion of the anode lead is fixed by resistance welding. The small piece of the metal frame and the mounting anode terminal member are connected together by wire bonding so that the anode lead and the mounting anode terminal member are electrically connected together.
    • 一种固体电解电容器包括由阀作用金属制成的多孔烧结体,并且嵌入一部分具有突出部分的阳极引线,固体电解质层与形成在多孔烧结体中的电介质层接触形成的固体电解质层, 端子构件,安装阴极端子构件和绝缘壳体树脂。 电容器还包括由阀作用金属制成的小块金属框架。 金属框架的该小块通过在阳极氧化之后通过电阻焊接固定阳极引线的突出部分的金属框架进行切割而与阳极引线的突出部分一体地形成。 金属框架的小块和安装阳极端子构件通过引线接合连接在一起,使得阳极引线和安装阳极端子构件电连接在一起。