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1. 发明授权

US4500575A Hot-melt adhesive of a copolyester of a dibasic acid with a polyhydric alcohol 失效
标题翻译：二元酸与多元醇的共聚酯的热熔粘合剂
公开(公告)号：US4500575A
公开(公告)日：1985-02-19
申请号：US543148
申请日：1983-10-18
申请人： Kazuo Taira , Akihiko Morofuji , Hiroshi Ueno , Seishichi Kobayashi
发明人： Kazuo Taira , Akihiko Morofuji , Hiroshi Ueno , Seishichi Kobayashi
IPC分类号： C09J7/00 , C08G63/00 , C08G63/66 , C08G63/672 , C09J167/00 , C08G63/02
CPC分类号： C09J167/00 , C08G63/66 , Y10T428/1355 , Y10T428/1359
摘要： Disclosed is a hot-melt adhesive which comprises a copolyester of a dibasic acid component comprising 70 to 97 mole % of terephthalic acid and other dibasic acid with a polyhydric alcohol component comprising 70 to 97 mole % of 1,4-butane-diol, 3 to 30 mole % of diethylene glycol and up to 20 mole % of other polyhydric alcohol having 2 to 5 carbon atoms, said copolyester having a reduced viscosity of at least 0.6 dl/g as measured at a temperature of 30.degree. C. in a phenol/tetrachloroethane mixed solvent having a phenol/tetrachloroethane weight ratio of 60/40 at a polymer concentration of 0.25 g/100 ml, a glass transition temperature of at least 31.degree. C. and a crystallinity of 15 to 40 %.This hot-melt adhesive is excellent in the operation adaptability, and in the form of a film, the adhesive has an appropriate rigidity and a good dimension stability. Furthermore, when this hot-melt adhesive is formed into an adhesive layer between seams by hot bonding, the adhesive layer provides a high creep resistance and a good dimension stability. This hot-melt adhesive is valuably used for producing a metal vessel having a circumferential side seam by bonding cup-shaped lower and upper members along circumferential open ends of the two members.
摘要翻译：公开了一种热熔粘合剂，其包含二元酸组分的共聚酯，其包含70至97摩尔％的对苯二甲酸和其它二元酸与多元醇组分，所述多元醇组分包含70至97摩尔％的1,4-丁烷二醇，3 至30摩尔％的二甘醇和至多20摩尔％的其他具有2至5个碳原子的多元醇，所述共聚酯在苯酚中在30℃下测得的比浓粘度至少为0.6dl / g /四氯乙烷混合溶剂，聚合物浓度为0.25g / 100ml，玻璃化转变温度为31℃，结晶度为15〜40％，苯酚/四氯乙烷重量比为60/40。该热熔粘合剂的操作适应性优异，并且以薄膜的形式，粘合剂具有适当的刚度和良好的尺寸稳定性。此外，当通过热粘合将该热熔粘合剂形成为接缝之间的粘合剂层时，粘合剂层提供高抗蠕变性和良好的尺寸稳定性。这种热熔粘合剂被有价值地用于制造具有圆周侧接缝的金属容器，所述金属容器通过沿两个构件的周向开口端接合杯状下部和上部构件。

2. 发明授权

US4683263A Metal vessel having circumferential side seam and adhesive primer for use in production thereof 失效
标题翻译：具有周向侧缝的金属容器和用于生产的粘合剂底漆
公开(公告)号：US4683263A
公开(公告)日：1987-07-28
申请号：US731384
申请日：1985-05-07
申请人： Kazuo Taira , Akihiko Morofuji , Seishichi Kobayashi , Hiroshi Ueno
发明人： Kazuo Taira , Akihiko Morofuji , Seishichi Kobayashi , Hiroshi Ueno
IPC分类号： B21D51/26 , B65D6/24 , B65D8/22 , C08L27/06 , C08L31/08 , C09D163/00 , C09J127/06 , C08L63/00
CPC分类号： B65D7/04 , B21D51/2684 , C09J127/06 , C08L31/08
摘要： Disclosed is a metal vessel comprising an upper member and a lower member, each consisting of a coated cup-shaped formed metal body and a circumferential side seam being formed by lap-bonding the open ends of the upper and lower members to each other through an adhesive, wherein said coated cup-shaped formed metal body is composed of a metal blank having a coating of a vinyl chloride resin having a vinyl chloride unit content of 30 to 97% by weight and a glass transition temperature of at least 40.degree. C. and containing carboxyl groups and/or hydroxyl groups at a concentration of 10 to 500 millimoles/100 g of the resin, said adhesive is an adhesive composed mainly of a copolyester containing in the main chain at least 50 mole %, based on the total acid component, of terephthalic acid, at least 50 mole %, based on the total alcohol component, of 1,4-butane-diol and at least 1 mole % of at least one member selected from other acids and other alcohols, and the upper and lower members are bonded to each other through said vinyl chloride resin coating and said copolyester type adhesive.
摘要翻译：公开了一种金属容器，其包括上部构件和下部构件，每个由上部构件和下部构件组成，所述上部构件和下部构件由涂覆的杯形成形金属体和周向侧接缝形成，所述外部侧接缝通过将上部构件和下部构件的开口端彼此搭接而形成，粘合剂，其中所述涂覆的杯形金属体由具有氯乙烯单元含量为30至97重量％且玻璃化转变温度至少为40℃的氯乙烯树脂涂层的金属坯料组成。并且含有浓度为10-500毫摩尔/ 100g树脂的羧基和/或羟基，所述粘合剂是主要由在主链中含有至少50摩尔％的基于总酸的共聚酯组成的粘合剂组分，对苯二甲酸，至少50摩尔％，基于总醇组分，1,4-丁二醇和至少1摩尔％的至少一种选自其它酸和其它醇的组分，以及上和较低的成员是b 通过所述氯乙烯树脂涂层和所述共聚酯型粘合剂彼此粘合。

3. 发明授权

US4556151A Metal vessel having circumferential side seam and adhesive primer for use in production thereof 失效
公开(公告)号：US4556151A
公开(公告)日：1985-12-03
申请号：US544266
申请日：1983-10-21
申请人： Kazuo Taira , Akihiko Morofuji , Seishichi Kobayashi , Hiroshi Ueno
发明人： Kazuo Taira , Akihiko Morofuji , Seishichi Kobayashi , Hiroshi Ueno
IPC分类号： B21D51/26 , B65D6/24 , B65D8/22 , C08L27/06 , C08L31/08 , C09D163/00 , C09J127/06 , B65D6/00 , B65D8/00
CPC分类号： B65D7/04 , B21D51/2684 , C09J127/06 , C08L31/08
摘要： Disclosed is a metal vessel comprising an upper member and a lower member, each consisting of a coated cup-shaped formed metal body and a circumferential side seam being formed by lap-bonding the open ends of the upper and lower members to each other through an adhesive, wherein said coated cup-shaped formed metal body is composed of a metal blank having a coating of a vinyl chloride resin having a vinyl chloride unit content of 30 to 97% by weight and a glass transition temperature of at least 40.degree. C. and containing carboxyl groups and/or hydroxyl groups at a concentration of 10 to 500 millimoles/100 g of the resin, said adhesive is an adhesive composed mainly of a copolyester containing in the main chain at least 50 mole %, based on the total acid component, of terephthalic acid, at least 50 mole %, based on the total alcohol component, of 1,4-butane-diol and at least 1 mole % of at least one member selected from other acids and other alcohols, and the upper and lower members are bonded to each other through said vinyl chloride resin coating and said copolyester type adhesive.

4. 发明授权

US4395538A Adhesive for production of metal bottles 失效
标题翻译：粘合剂用于生产金属瓶
公开(公告)号：US4395538A
公开(公告)日：1983-07-26
申请号：US416479
申请日：1982-09-10
申请人： Kazuo Taira , Akihiko Morofuji , Hiroshi Ueno
发明人： Kazuo Taira , Akihiko Morofuji , Hiroshi Ueno
IPC分类号： C09J167/00 , C08G63/02
CPC分类号： C09J167/00
摘要： Disclosed is a metal bottle adhesive for lap-bonding upper and lower members, each consisting of a cup-like formed article of a metal, on the peripheral ends thereof, said adhesive comprising at least one high-molecular-weight thermoplastic resin having a post crystallinity .DELTA.Wc, defined by the following formula, of less than 20%:.DELTA.Wc=Wc.sub.II -Wc.sub.Iwherein Wc.sub.I stands for the crystallinity (%) of the adhesive which has been molten at a temperature higher by 30.degree. than the softening point thereof and then naturally cooled at room temperature, determined according to the density method, and Wc.sub.II stands for the crystallinity of the adhesive which has then been immersed in water maintained at 70.degree. C. for 10 hours and then naturally cooled and dried at room temperature, determined according to the density method,a shear creep compliance J(t).sub.t=2 hrs of less than 10.sup.-4 cm.sup.2 /hyne at 90.degree. C. and a time constant of 2 hours and a concentration of ##STR1## groups, contained in the main or side chain, of 10 to 1400 meq/100 g of the resin.
摘要翻译：公开了一种用于搭接上部和下部构件的金属瓶粘合剂，每个由其上的一个金属的杯状成形件组成，所述粘合剂包括至少一种具有柱的高分子量热塑性树脂结晶度DELTA Wc由下式定义为小于20％：DELTA Wc = WcII-WcI其中WcI表示在比其软化点高30℃的温度下熔融的粘合剂的结晶度（％）然后在室温下自然冷却，根据密度法测定，WcII表示粘合剂的结晶度，然后将其浸入保持在70℃的水中10小时，然后自然冷却并在室温下干燥，根据密度法确定，90℃下剪切蠕变柔量J（t）t = 2小时小于10 -4 cm 2 / hyne，时间常数为2小时，浓度为组，含在主要或si de链，为10〜1400meq / 100g树脂。

5. 发明授权

US4472219A Process for preparation of metallic bottles 失效
标题翻译：金属瓶的制备工艺
公开(公告)号：US4472219A
公开(公告)日：1984-09-18
申请号：US418400
申请日：1982-09-15
申请人： Kazuo Taira , Akihiko Morofuji , Hiroshi Ueno
发明人： Kazuo Taira , Akihiko Morofuji , Hiroshi Ueno
IPC分类号： B21D51/24 , B65D8/22 , C09J5/10 , C09J195/00 , C09J201/00 , B29C27/00 , B65B7/28
CPC分类号： C09J5/10 , B65D7/04 , Y10S220/906 , Y10T428/1355 , Y10T428/31681
摘要： Disclosed is a process for the preparation of metallic bottles which comprises lap-bonding circumferential open end portions of upper and lower members, each consisting of a formed cup of a metal, said process being characterized by using at least one thermoplastic resin adhesive having a water absorption of less than 2%, as measured at a temperature of 23.degree. C. and a relative humidity of 80%, and an elasticity contribution ratio [R(t).sub.t=1 ] of from 1.times.10.sup.-4 to 5.times.10.sup.-1, defined by the following formula:R(t).sub.t=1 =J(t).sub.rec,t=1 /J(t).sub.t=1wherein J(t).sub.t=1 represents a creep compliance at a time constant of 1 second when the adhesive is caused to creep at a temperature higher by 30.degree. C. than the melting point of the adhesive under a shear stress of 50 to 5,000 dyne/cm.sup.2, and J(t).sub.rec,t=1 represents an equilibrium recovery creep compliance when the adhesive is caused to creep under the same conditions as described above and the adhesive is then let to recover, and containing in the main or side chain groups ##STR1## at a concentration of 10 to 1400 milliequivalents per 100 g of the adhesive.
摘要翻译：公开了一种用于制备金属瓶的方法，该方法包括搭接上部和下部构件的周向开口端部，每个由形成的金属杯组成，所述方法的特征在于使用至少一种具有水的热塑性树脂粘合剂在23℃和相对湿度为80％，弹性贡献率[R（t）t = 1]下测定的吸收小于2％，定义为1×10-4至5×10-1，通过以下公式：R（t）t = 1 = J（t）rec，t = 1 / J（t）t = 1其中J（t）t = 1表示在1秒的时间常数下的蠕变柔量在50至5000达因/厘米2的剪切应力下，粘合剂在比粘合剂的熔点高30℃的温度下蠕变，J（t）rec，t = 1表示平衡恢复蠕变依从性当在与上述相同的条件下使粘合剂蠕变时，然后让粘合剂回收，并且包含在主链或侧链中组合，每100g粘合剂的浓度为10至1400毫当量。

6. 发明授权

US4324822A Metal can paint providing coating retaining high adhesion even with lapse of time 失效
标题翻译：金属罐可以提供涂层，即使随着时间的流逝也能保持高附着力
公开(公告)号：US4324822A
公开(公告)日：1982-04-13
申请号：US165658
申请日：1980-07-03
申请人： Seishichi Kobayashi , Tatsuo Mori , Akihiko Morofuji
发明人： Seishichi Kobayashi , Tatsuo Mori , Akihiko Morofuji
IPC分类号： C08G59/00 , C08G8/24 , C08G12/12 , C08G59/04 , C08G59/06 , C08G59/14 , C08L63/00 , C09D163/00 , C09D163/02 , C08G59/20 , C08G59/24
CPC分类号： C09D163/00 , C08G12/12 , C08G59/1427 , C08G59/4021 , C08G59/42 , C08G8/24 , Y10T428/1355 , Y10T428/31529
摘要： Disclosed is a paint for a can which comprises an epoxy resin component formed by condensation of a dihydroxyl compound with an epihalohydrin and a curing agent component, said epoxy resin component containing terminal .alpha.-glycol groups at a concentration of 0.05 to 0.60 equivalent per Kg of the resin.This paint provides a coating capable of retaining a high adhesion even with the lapse of time and resisting a severe treatment such as retort sterilization.When this paint is applied to a bonded can, leakage of the content from the side seam with the lapse of time can be effectively prevented. When this paint is applied to a can provided with an easy-open can lid, occurrence of the enamel feather can be prevented at the time of opening the lid.
摘要翻译：公开了一种罐用涂料，其包含通过二羟基化合物与表卤代醇缩合形成的环氧树脂组分和固化剂组分，所述环氧树脂组分含有末端α-二醇基团，浓度为0.05至0.60当量/ Kg 树脂。这种涂料提供了即使经过时间也能够保持高附着力并且能够抗腐蚀灭菌等严格处理的涂料。当将这种涂料应用于粘合罐时，可以有效地防止内容物从侧缝随时间的泄漏。当将这种涂料施加到具有容易打开的罐盖的罐上时，在打开盖子时可以防止发生搪瓷羽毛。

7. 发明授权

US5432536A Process for printing on a surface of an object utilizing a specific toner particle size and minimum print element dimension 失效
标题翻译：使用特定调色剂颗粒尺寸和最小印刷元件尺寸在物体表面上印刷的方法
公开(公告)号：US5432536A
公开(公告)日：1995-07-11
申请号：US966090
申请日：1992-10-23
申请人： Junichi Takada , Tsuneo Imatani , Masaki Morotomi , Akihiko Morofuji , Kosaku Tsukimi
发明人： Junichi Takada , Tsuneo Imatani , Masaki Morotomi , Akihiko Morofuji , Kosaku Tsukimi
IPC分类号： B41F17/20 , B41J2/44 , G03G9/12 , G03G15/01 , G03G15/04 , G03G15/10 , G03G15/22 , H04N1/06 , H04N1/29 , H04N1/405
CPC分类号： H04N1/4056 , G03G15/10 , H04N1/06 , H04N1/29
摘要： Dots for producing a multiple tone electrostatic latent image are formed by selectively discharging a charged surface with a scanned laser beam. The multiple tones are produced by pulse width modulation of the laser beam according to the tones required in the dots. High resolution is maintained by limiting the diameter of toner particles to 1/5 to 5 times a minimum exposed dot dimension of less than 1 micron. A laser beam exposure device includes a galvanometer mirror from which the scanning laser beam is reflected. The galvanometer mirror is tilted in synchronism with the conveying direction of the surface being scanned in order to maintain focus of the laser beam on the surface.
摘要翻译：通过用扫描的激光束选择性地放电带电表面来形成用于产生多色调静电潜像的点。根据点中所需的音调，通过激光束的脉冲宽度调制产生多个音调。通过将调色剂颗粒的直径限制在小于1微米的最小曝光点尺寸的1/5至5倍来保持高分辨率。激光束曝光装置包括电子计镜，扫描激光束从该反射镜反射。电流计反射镜与被扫描表面的输送方向同步地倾斜，以保持激光束在表面上的聚焦。

8. 发明授权

US5018640A Multiple color printing method for metallic container and thin plate metal and printed matter 失效
标题翻译：金属容器和薄板金属和印刷品的多色印刷方法
公开(公告)号：US5018640A
公开(公告)日：1991-05-28
申请号：US295946
申请日：1988-11-29
申请人： Akihiko Morofuji , Masaki Morotomi
发明人： Akihiko Morofuji , Masaki Morotomi
IPC分类号： B41M1/28 , G03G7/00 , G03G13/01 , G03G13/16 , G03G13/20 , G03G15/01 , G03G15/16 , G03G15/20
CPC分类号： G03G15/1625 , G03G13/01 , G03G15/0194 , G03G2215/0119
摘要： Toners are sticked on a thin plate metal or a metallic container by electrophotographic-printing units (3), (4), and (5), and during the sticking processes, the toners are preliminarily fixed with a lower temperature and finally fixed with a higher temperature, thus being printed. A photoconductive material layer can be directly laminated on the surface of the thin plate metal or the metallic container or is disposed on a drum. A firm printed surface can be obtained by coating a finishing vanish on the toners.

9. 发明授权

US08784957B2 Flat container comprising thermoplastic resin and method for molding the same 有权
标题翻译：包含热塑性树脂的扁平容器及其模塑方法
公开(公告)号：US08784957B2
公开(公告)日：2014-07-22
申请号：US11575435
申请日：2005-09-15
申请人： Atsushi Komiya , Hiroyuki Honda , Takuya Fujikawa , Akihiko Morofuji
发明人： Atsushi Komiya , Hiroyuki Honda , Takuya Fujikawa , Akihiko Morofuji
IPC分类号： B32B1/02 , B32B1/08
CPC分类号： B29C49/18 , B29B2911/14053 , B29B2911/14066 , B29B2911/1408 , B29B2911/14093 , B29B2911/14113 , B29B2911/1412 , B29B2911/1414 , B29B2911/14146 , B29B2911/14166 , B29B2911/14173 , B29B2911/1444 , B29B2911/14466 , B29B2911/14593 , B29B2911/14653 , B29B2911/14713 , B29B2911/14926 , B29C37/0067 , B29C49/0073 , B29C49/04 , B29C49/06 , B29C49/22 , B29C49/4242 , B29K2067/00 , B29K2067/003 , B29K2995/0041 , B29K2995/0043 , B29K2995/0077 , B29K2995/0097 , B29L2031/7158 , B65D1/0215 , B65D1/0223 , B65D2501/0018 , B65D2501/0036 , B65D2501/0081 , Y10T428/13 , Y10T428/1303 , Y10T428/1352 , Y10T428/1359 , Y10T428/139
摘要： The invention realizes easy manufacturing of a flat container molded by blow molding, in which the wall thickness of a container wall is made uniform, and which provides improved mechanical strength, heat resistance, etc. and has a good appearance.The flat container obtained by the blow molding of a polyester resin is characterized in that the container has a flatness ratio of not less than 1.3, and in that its body has a wall thickness ratio of a maximum wall thickness to a minimum wall thickness of not more than 1.6, a difference in elongation between a maximally stretched portion and a minimally stretched portion of not more than 150% in a tensile test at 95° C., a crystallinity of not less than 30%, and a difference in TMA non-load change between a maximally stretched portion and a minimally stretched portion of not more than 500 μm at 75° C. and 100° C.
摘要翻译：本发明实现了容易地制造通过吹塑成型的扁平容器，其中容器壁的壁厚均匀，并且提供了改善的机械强度，耐热性等并且具有良好的外观。通过聚酯树脂的吹塑成型获得的扁平容器的特征在于，容器的平坦度比不小于1.3，并且其主体具有最大壁厚与最小壁厚的壁厚比不是超过1.6，在95℃的拉伸试验中，最大拉伸部分和最小拉伸部分之间的伸长率差不超过150％，结晶度不小于30％，TMA非拉伸部分的差异不大，在75℃和100℃下最大拉伸部分和最小拉伸部分之间的载荷变化不大于500μm。

10. 发明授权

US5093671A Printed metallic container and method for multicolor printing thereof 失效
标题翻译：印刷金属容器及其多色印刷方法
公开(公告)号：US5093671A
公开(公告)日：1992-03-03
申请号：US602236
申请日：1990-10-26
申请人： Masaki Morotomi , Tsuneo Imatani , Akihiko Morofuji
发明人： Masaki Morotomi , Tsuneo Imatani , Akihiko Morofuji
IPC分类号： G03G7/00 , G03G13/01 , G03G15/01
CPC分类号： G03G7/0013 , G03G13/01 , G03G15/0142 , G03G15/0163 , G03G7/0093
摘要： A printed metallic container comprising a metallic substrate provided with a titanium oxide-containing organic resin coat film layer as a substrate coat film for printing having a photosensitive characteristic of I.times.t.sub.1/2
摘要翻译：一种印刷金属容器，包括具有含氧化钛的有机树脂涂膜层的金属基材，作为具有Ixt1 / 2 <100mWxsec / cm 2的感光特性的印刷用基材涂膜（I：光强度，t1 / 2：光衰减表面电位的半衰期）。一种多色打印方法，包括连续地旋转和传送金属容器，通过与容器的旋转传送同步地移动来自光源的光来使充电相位均匀地充电，从而使容器移位和暴露。

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