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1. 发明授权

US5064906A Thermoplastic resin compositions having excellent impact resistance, weather resistance and moldability, and process for preparing the same 失效
标题翻译：具有优异的耐冲击性，耐候性和可塑性的热塑性树脂组合物及其制备方法
公开(公告)号：US5064906A
公开(公告)日：1991-11-12
申请号：US405428
申请日：1989-08-28
申请人： Kazuo Kishida , Yutaka Toyooka , Haruyoshi Kitahara
发明人： Kazuo Kishida , Yutaka Toyooka , Haruyoshi Kitahara
IPC分类号： C08F285/00 , C08L51/00
CPC分类号： C08L51/00 , Y10S525/902
摘要： Disclosed is a graft copolymer resin prepared by graft polymerizing a vinyl compound onto a composite-structured acrylic rubber whose particles are composed of a core consisting of a diene rubber enlarged by treatment with an acid group-containing copolymer latex, and an outer layer consisting of an acrylate polymer having a crosslinked structure formed by the combined use of a graft-linking agent and a cross-linking agent. This graft copolymer resin may be blended with a rigid thermoplastic resin in a specific proportion. This resin composition imparts a good gloss to the molded articles formed therefrom, while retaining excellent impact resistance and weather resistance.

2. 发明授权

US4912162A Thermoplastic resin compositions having excellent impact resistance, weather resistance and moldability, and process for preparing the same 失效
标题翻译：耐冲击性，耐候性和成型性优异的热塑性树脂组合物及其制备方法
公开(公告)号：US4912162A
公开(公告)日：1990-03-27
申请号：US10426
申请日：1987-02-03
申请人： Kazuo Kishida , Yutaka Toyooka , Haruyoshi Kitahara
发明人： Kazuo Kishida , Yutaka Toyooka , Haruyoshi Kitahara
IPC分类号： C08F285/00 , C08L51/00
CPC分类号： C08L51/00 , Y10S525/902
摘要： Disclosed is a graft copolymer resin prepared by graft polymerizing a vinyl compound onto a composite-structured acrylic rubber whose particles are composed of a core consisting of a diene rubber enlarged by treatment with an acid group-containing copolymer latex, and an outer layer consisting of an acrylate polymer having a crosslinked structure formed by the combined use of a graft-linking agent and a cross-linking agent. This graft copolymer resin may be blended with a rigid thermoplastic resin in a specific proportion. This resin composition imparts a good gloss to the molded articles formed therefrom, while retaining excellent impact resistance and weather resistance.
摘要翻译：公开了通过将乙烯基化合物接枝聚合到复合结构的丙烯酸橡胶上而制备的接枝共聚物树脂，该复合结构的丙烯酸橡胶的颗粒由通过用含酸基的共聚物胶乳处理而扩大的二烯橡胶组成的芯和由具有通过组合使用接枝交联剂和交联剂形成的交联结构的丙烯酸酯聚合物。该接枝共聚物树脂可以与特定比例的刚性热塑性树脂共混。该树脂组合物对由其形成的模塑制品赋予良好的光泽，同时保持优异的耐冲击性和耐候性。

3. 发明授权

US4877844A Process for producing a low gloss thermoplastic resin 失效
标题翻译：低光泽热塑性树脂的制造方法
公开(公告)号：US4877844A
公开(公告)日：1989-10-31
申请号：US135470
申请日：1987-12-21
申请人： Kazuo Kishida , Yutaka Toyooka , Yoshiyuki Mikami
发明人： Kazuo Kishida , Yutaka Toyooka , Yoshiyuki Mikami
IPC分类号： C08F236/12 , C08F279/02
CPC分类号： C08F236/12 , C08F279/02
摘要： A process for producing a low gloss thermoplastic resin which comprises polymerizing in two steps from 20 to 70 parts by weight of a butadiene polymer, at least 70% by weight of which is constituted by butadiene, with from 30 to 80 parts by weight of a total of from 15 to 40% by weight of a vinyl cyanide monomer and from 60 to 85% by weight of an aromatic vinyl monomer, characterized in that for the polymerization of the first step, the butadiene polymer, the vinyl cyanide monomer and the aromatic vinyl monomer were charged in amounts corresponding to from 20 to 80% by weight of the entire butadiene polymer, from 20 to 80% by weight of the entire vinyl cyanide monomer and from 20 to 80% by weight of the entire aromatic vinyl monomer, respectively, and after the completion of the polymerization of the first step, the rest of the butadiene polymer, the vinyl cyanide monomer and the aromatic vinyl monomer were charged for the polymerization of the second step.
摘要翻译：一种低光泽性热塑性树脂的制造方法，其特征在于，将20〜70重量份的丁二烯聚合物，其中至少70重量％由丁二烯构成，其中20〜70重量份，总计为15至40重量％的乙烯基氰单体和60至85重量％的芳族乙烯基单体，其特征在于，对于第一步骤的聚合，丁二烯聚合物，乙烯基氰单体和芳族化合物乙烯基单体的量相当于整个丁二烯聚合物的20至80重量％，全部乙烯基氰单体的20至80重量％和芳族乙烯基单体总量的20至80重量％，在第一步聚合完成后，加入其余的丁二烯聚合物，乙烯基氰单体和芳族乙烯基单体进行第二步的聚合反应。

4. 发明授权

US4804706A Process for the preparation of maleimide copolymers and thermoplastic resin composition using the same 失效
标题翻译：用于制备马来酰亚胺共聚物和使用其的热塑性树脂组合物的方法
公开(公告)号：US4804706A
公开(公告)日：1989-02-14
申请号：US25628
申请日：1987-03-02
申请人： Kazuo Kishida , Yutaka Toyooka , Atsushi Kimura
发明人： Kazuo Kishida , Yutaka Toyooka , Atsushi Kimura
IPC分类号： C08F212/04 , C08F222/40 , C08L25/02 , C08L51/04 , C08L77/00 , C08L51/00
CPC分类号： C08F222/40
摘要： The present invention provides a process for the preparation of maleimide copolymers by emulsion polymerization of an aromatic vinyl monomer, a vinyl cyanide monomer and a maleimide monomer in specific proportions wherein the polymerization is carried out by charging not less than a specific proportion of the aromatic vinyl monomer and optionally not more than a specific proportion of the vinyl cyanide monomer into the polymerization system before initiation of the polymerization; adding, continuously or dividedly, a mixture composed of the total amount of the maleimide monomer and the remainder of the other monomers to the polymerization system after initiation of the polymerization; maintaining the pH of the aqueous phase of the polymerization system in the range of 3 to 9 at the initiation of said polymerization; and using a redox catalyst containing an oil-soluble organic peroxide. According to this polymerization process, maleimide copolymers having excellent thermal resistance and resistance to thermal decomposition can be prepared in high yield.The present invention also provides a resin composition having excellent thermal resistance, resistance to thermal decomposition, and impact resistance which is formed by blending, in a specific proportion, a maleimide copolymer prepared by the aforesaid process with a rubber-reinforced resin obtained by grafting a vinyl cyanide monomer or the like onto a specific elastomer; and optionally blending the resulting thermoplastic resin composition with a thermoplastic resin that is hard at room temperature.
摘要翻译：本发明提供了一种通过芳香族乙烯基单体，乙烯基氰单体和马来酰亚胺单体以特定比例的乳液聚合制备马来酰亚胺共聚物的方法，其中聚合通过将不少于特定比例的芳族乙烯基单体，并且任选地不超过特定比例的乙烯基氰单体在聚合开始之前进入聚合体系; 在聚合开始后，向马来酰亚胺单体和剩余的其它单体组成的混合物连续地或分开地加入到聚合体系中; 在所述聚合开始时，将聚合体系的水相的pH保持在3〜9的范围内; 并使用含有油溶性有机过氧化物的氧化还原催化剂。根据该聚合方法，可以高产率制备具有优异的耐热性和耐热分解性的马来酰亚胺共聚物。本发明还提供一种具有优异的耐热性，耐热分解性和耐冲击性的树脂组合物，其通过以特定比例将通过上述方法制备的马来酰亚胺共聚物与通过将上述方法获得的橡胶增强树脂乙烯基氰单体等涂覆在特定的弹性体上; 任选地将得到的热塑性树脂组合物与在室温下硬的热塑性树脂共混。

5. 发明授权

US5057574A Process for producing an .alpha.-alkyl-substituted aromatic vinyl copolymer and a thermoplastic resin composition comprising the copolymer 失效
公开(公告)号：US5057574A
公开(公告)日：1991-10-15
申请号：US523269
申请日：1990-05-14
申请人： Makoto Uchida , Yutaka Toyooka , Kazuo Kishida , Akira Nakata , Naoki Yamamoto
发明人： Makoto Uchida , Yutaka Toyooka , Kazuo Kishida , Akira Nakata , Naoki Yamamoto
IPC分类号： C08F212/12 , C08L25/16
CPC分类号： C08F212/12 , C08L25/16
摘要： A process for producing an .alpha.-alkyl-substituted aromatic vinyl copolymer constituted of 60 to 85 parts by weight of the .alpha.-alkyl-substituted aromatic vinyl monomer, 15 to 35 parts by weight of a vinyl cyanide monomer, and 0 to 40 parts by weight of another vinyl monomer copolymerizable with these monomers, which process is characterized in thatall the amount of the aromatic vinyl monomer necessary for the entire polymerization and such partial amounts of the vinyl cyanide monomer and another copolymerizable vinyl monomer as to give a predetermined copolymer composition with respect to the content of the aromatic vinyl monomer, are first charged and emulsified andthe emulsion polymerization is then initiated and carried out by adding dropwise continuously the residual amounts of the vinyl cyanide monomer and another copolymerizable vinyl monomer in such a manner that the range of change in the content of the aromatic vinyl monomer in the copolymer during the polymerization reaction will not vary more than 2% in the range of conversion of 0 to 90%; and a thermoplastic resin composition comprising[A] 50 to 90% by weight of a copolymer constituted of 60 to 85 parts by weight of an .alpha.-alkyl-substituted aromatic vinyl monomer, 15 to 35 parts by weight of a vinyl cyanide monomer, and 0 to 40 parts by weight of another vinyl monomer copolymerizable with these monomers, the copolymer being produced in such a manner that the range of change in the content of the aromatic vinyl monomer in the copolymer during the polymerization reaction will not vary more than 2% in the range of conversion of 0 to 90, and[B] 10 to 50% by weight of a graft copolymer constituted of 30 to 85 parts by weight of a rubber polymer and 15 to 70 parts by weight of a grafted polymer consisting of a monovinyl aromatic monomer, vinyl cyanide monomer, and another monomer copolymerizable with them in respective proportions of 85-40:0-40:0-80,where the total amount of polymers [A] and [B] is 100% by weight.

6. 发明授权

US4757109A Process for the preparation of maleimide copolymers and thermoplastic resin composition using the same 失效
标题翻译：用于制备马来酰亚胺共聚物和使用其的热塑性树脂组合物的方法
公开(公告)号：US4757109A
公开(公告)日：1988-07-12
申请号：US928279
申请日：1986-10-14
申请人： Kazuo Kishida , Yutaka Toyooka , Atsushi Kimura
发明人： Kazuo Kishida , Yutaka Toyooka , Atsushi Kimura
IPC分类号： C08F212/04 , C08F222/40 , C08L25/02 , C08L51/04 , C08L39/04 , C08L51/00
CPC分类号： C08F222/40
摘要： A process for the preparation of maleimide copolymers by emulsion polymerization of 50 to 80% by weight of an aromatic vinyl monomer, 10 to 30% by weight of a vinyl cyanide monomer, and 5 to 40% by weight of a maleimide monomer comprising a three step polymerization process wherein the remaining vinyl cyanide monomer is separately added in the third step of said process.
摘要翻译： PCT No.PCT / JP86 / 00252 Sec。一九八六年十月十四日 102（e）1986年10月14日PCT PCT日期：1986年5月16日PCT公布。出版物WO86 / 06732 日本公报1986年11月20日。一种通过乳液聚合制备马来酰亚胺共聚物的方法，其通过50至80重量％的芳族乙烯基单体，10至30重量％的乙烯基氰单体和5至40重量％的包含三步聚合方法的马来酰亚胺单体，其中在所述方法的第三步中分离加入剩余的乙烯基氰单体。

7. 发明授权

US5055529A Processing aid for thermoplastic resin, and thermoplastic resin composition comprising same 失效
标题翻译：用于热塑性树脂的加工助剂和包含其的热塑性树脂组合物
公开(公告)号：US5055529A
公开(公告)日：1991-10-08
申请号：US329872
申请日：1989-03-28
申请人： Kazuo Kishida , Kiyokazu Kitai , Masahiro Kaneda , Kenji Okano
发明人： Kazuo Kishida , Kiyokazu Kitai , Masahiro Kaneda , Kenji Okano
IPC分类号： C08F2/24 , C08F2/44 , C08F220/00 , C08F220/14 , C08F220/18 , C08F265/06 , C08L27/06 , C08L33/10 , C08L51/00 , C08L101/00
CPC分类号： C08L27/06 , C08F265/06 , C08L101/00 , C08L51/003
摘要： A processing aid for a thermoplastic resin is disclosed, which is a two-stage polymer obtained by polymerizing (B) 5 to 50 parts by weight of a monomer or monomer mixture composed mainly of methyl methacrylate in the presence of (A) 50 to 95 parts by weight of a polymer comprising 100 to 50% by weight of units of a methacrylic acid ester other than methyl methacrylate and 0 to 50% by weight of units of other monomer copolymerizable with the methacrylic acid ester and having a reduced viscosity .eta.sp/C not larger than 2.0 dl/g, so that the total amount of the components (A) and (B) is 100 parts by weight and the reduced viscosity .eta.sp of the final polymer is not larger than 2.0 dl/g. A thermoplastic resin having the processing aid incorporated therein has an improved shaping processability, and a shaped article mode therefrom has good surface characteristics.

8. 发明授权

US5008313A Impact modifier for thermoplastic resin having good heat discoloration resistance and heat deterioration resistance, and thermoplastic resin composition comprising this impact modifier 失效
标题翻译：具有良好耐热变色性和耐热劣化性的热塑性树脂的抗冲改性剂和包含该抗冲改性剂的热塑性树脂组合物
公开(公告)号：US5008313A
公开(公告)日：1991-04-16
申请号：US329256
申请日：1989-03-27
申请人： Kazuo Kishida , Kiyokazu Kitai , Masaaki Mohri
发明人： Kazuo Kishida , Kiyokazu Kitai , Masaaki Mohri
IPC分类号： C08L51/04 , C08J3/22 , C08K5/00
CPC分类号： C08J3/226 , C08K5/005 , C08J2451/00
摘要： An impact modifier for a thermoplastic resin is disclosed, which comprises (I) 100 parts by weight of a graft copolymer formed by graft-polymerizing (B) a monomer having a vinyl group in the molecule onto (A) a butadiene polymer and, incorporated therein, (II) 0.01 to 5 parts by weight of a thioether type heat stabilizer, (III) 0.01 to 5 parts by weight of a phosphite type heat stabilizer and (IV) 0.01 to 5 parts by weight of a phenol type heat stabilizer having a molecular eight of at least 500. A thermoplastic resin composition having this impact modifier incorporated therein exhibits a good heat discoloration resistance and heat deterioration resistance under high-temperature conditions, as well as an improved impact resistance.

9. 发明授权

US4720516A Composite material with improved properties 失效
标题翻译：具有改善性能的复合材料
公开(公告)号：US4720516A
公开(公告)日：1988-01-19
申请号：US450378
申请日：1982-12-16
申请人： Kazuo Kishida , Isao Sasaki , Hiroshi Mori , Yasuaki Ii
发明人： Kazuo Kishida , Isao Sasaki , Hiroshi Mori , Yasuaki Ii
IPC分类号： C08L23/26 , C08G18/62 , C08K3/00 , C08K5/17 , C08K5/29 , C08K7/00 , C08K7/02 , C08L7/00 , C08L21/00 , C08L23/00 , C08L51/00 , C08L51/02 , C08L51/06 , C08L77/00 , C08L77/10 , C08L101/00 , C08K7/06 , C08K7/22
CPC分类号： C08G18/6204 , C08L51/06
摘要： A polyolefin resin composition comprising a polyolefin modified with an unsaturated carboxylic acid, at least one member selected from the group consisting of polyepoxides, polyisocyanates, and polyamines, and a reinforcement.
摘要翻译：一种聚烯烃树脂组合物，其包含用不饱和羧酸改性的聚烯烃，选自聚环氧化物，多异氰酸酯和多胺中的至少一种，以及增强剂。

10. 发明授权

US4665125A Thermoplastic resin composition of a polycarbonate and vinyl aromatic-vinyl cyanide comonomers/diene rubber graft copolymer 失效
标题翻译：聚碳酸酯和乙烯基芳族乙烯基氰化物共聚单体/二烯橡胶接枝共聚物的热塑性树脂组合物
公开(公告)号：US4665125A
公开(公告)日：1987-05-12
申请号：US798431
申请日：1985-11-15
申请人： Kazuo Kishida , Hiroshi Kawasaki , Hideyuki Shigemitsu
发明人： Kazuo Kishida , Hiroshi Kawasaki , Hideyuki Shigemitsu
IPC分类号： C08L25/12 , C08L51/00 , C08L69/00
CPC分类号： C08L51/00 , C08L25/12 , C08L69/00
摘要： A thermoplastic resin composition having excellent heat resistance, impact resistance, moldability and platability, which comprises:(i) from 10 to 90% by weight of a thermoplastic polycarbonate;(ii) from 10 to 90% by weight of a graft copolymer obtained by firstly polymerizing a monomer mixture comprising more than 30 and not more than 50% by weight of acrylonitrile and at least 50 and less than 70% by weight of styrene, as monomers for the first stage of graft polymerization, in the presence of a rubber-like polymer, and then polymerizing a monomer mixture comprising from 15 to 40% by weight of acrylonitrile and from 60 to 85% by weight of .alpha.-methylstyrene, as monomers for the second stage of graft polymerization, in the presence of the polymer obtained in the first stage; and(iii) from 0 to 60% by weight of a copolymer obtained by co-polymerizing from 50 to 80% by weight of an aromatic vinyl monomer and from 20 to 50% by weight of a vinyl cyanide monomer;the total amount of components (i), (ii) and (iii) being 100% by weight. The composition is useful for making molded products having excellent heat resistance, impact resistance and platability.
摘要翻译：具有优异的耐热性，耐冲击性，成型性和可镀性的热塑性树脂组合物，其包含：（i）10〜90重量％的热塑性聚碳酸酯; （ii）10至90重量％的接枝共聚物，其通过首先将包含大于30重量％至50重量％的丙烯腈和至少50重量％且小于70重量％的苯乙烯的单体混合物聚合而获得，其为在第一阶段接枝聚合的单体中，在橡胶状聚合物的存在下，然后将包含15-40％（重量）丙烯腈和60-85％（重量）α-甲基苯乙烯的单体混合物聚合成单体在第一阶段获得的聚合物存在下进行接枝聚合的第二阶段; 和（iii）0至60重量％的通过共聚合50-80重量％的芳族乙烯基单体和20至50重量％的乙烯基氰单体得到的共聚物; 组分（i），（ii）和（iii）的总量为100重量％。该组合物可用于制备具有优异的耐热性，耐冲击性和可镀性的成型产品。

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