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    • 4. 发明授权
    • Silver halide photographic materials
    • US4977062A
    • 1990-12-11
    • US178391
    • 1988-04-06
    • Morio YagiharaHisashi OkadaKazunobu KatohNobuaki Inoue
    • Morio YagiharaHisashi OkadaKazunobu KatohNobuaki Inoue
    • G03C1/06
    • G03C1/061
    • An ultra-high contrast negative type silver halide photographic material comprising:(1) at least one silver halide emulsion layer on a support;(2) at least one compound selected from among hydrazine derivatives which can be represented by formula (I) below, which is included in said emulsion layer or in another hydrophilic colloid layer, ##STR1## wherein A.sub.1 and A.sub.2 both represent hydrogen atoms or one represents a hydrogen atom and the other represents a sulfinic acid residual group or an acyl group, R.sub.1 represents an aliphatic group, an aromatic group or a heterocyclic group, R.sub.2 represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, or an amino group, G.sub.1 represents a carbonyl group, a sulfonyl group, a sulfoxy group, a phosphoryl group or an N-substituted or unsubstituted iminomethylene group, and at least one of R.sub.1 and R.sub.2 has a group which promotes adsorption on silver halide; and(3) at least one compound selected from among the hydrazine derivatives which can be represented by the formula (II) below, which is included in the said emulsion layer or in another hydrophilic colloid layer, ##STR2## wherein A.sub.3 and A.sub.4 both represent hydrogen atoms or one represents a hydrogen atom and the other represents a sulfinic acid residual group or an acyl group, R.sub.3 represents an aliphatic group, an aromatic group or a heterocyclic group, R.sub.4 represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group or an amino group, G.sub.2 represents a carbonyl group, a sulfonyl group, a sulfoxy group, a phosphoryl group, or an iminomethylene group, and the total number of carbon atoms in R.sub.3 and R.sub.4 is at least 13.
    • 8. 发明授权
    • Silver halide photographic material
    • 卤化银照相材料
    • US5190846A
    • 1993-03-02
    • US614181
    • 1990-11-13
    • Morio YagiharaHisashi OkamuraKazunobu Katoh
    • Morio YagiharaHisashi OkamuraKazunobu Katoh
    • G03C7/26G03C1/06G03C1/295G03C1/34G03C1/40G03C1/43G03C5/29G03C7/305G03C7/392
    • G03C1/34G03C1/06G03C1/295G03C1/40G03C1/43G03C7/305G03C1/061G03C1/07G03C2200/22G03C7/30541Y10S430/156Y10S430/158Y10S430/16
    • A silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer, wherein the silver halide photographic material contains at least one photographic agent represented by the following formula (I): ##STR1## wherein X represents a hydrogen atom or a group capable of forming a hydrogen atom upon hydrolysis; Time represents a divalent linking group; PUG represents a photographically useful group; V represents ##STR2## wherein R.sub.0 represents n alkoxy group or an aryloxy group, ##STR3## an iminomethylene group or ##STR4## R.sub.1 represents a hydrogen atom, an aliphatic group, an aromatic group, a heterocyclic group, an alkoxy group, an aryloxy group, an amino group or --CHR.sub.2 --(Time).sub.m PUG; R.sub.2 represents a hydrogen atom, an aliphatic group, an aromatic group or a heterocyclic group; m represents 0 or 1; and n represents 0 or 1. The redox compound represented by formula (I) has excellent preservability and rapidly releases a photographically useful agent.
    • 一种卤化银照相材料,其包含其上具有至少一种感光卤化银乳剂层的载体,其中所述卤化银照相材料含有至少一种下式(I)表示的照相剂:其中X 表示氢原子或在水解时能够形成氢原子的基团; 时间表示二价连接基团; PUG代表一个摄影有用的组; V表示其中R 0表示n个烷氧基或芳氧基,其中R 1表示亚氨基亚甲基或R 1表示氢原子,脂族基团,芳基,杂环基,烷氧基,芳氧基 基团,氨基或-CHR2-(时间)mPUG; R2表示氢原子,脂肪族基团,芳香族基团或杂环基团; m表示0或1; 并且n表示0或1.由式(I)表示的氧化还原化合物具有优异的保存性并快速释放照相用的试剂。
    • 10. 发明授权
    • Silver halide photographic material
    • 卤化银照相材料
    • US5006445A
    • 1991-04-09
    • US343441
    • 1989-04-26
    • Morio YagiharaHisashi OkadaKazunobu Katoh
    • Morio YagiharaHisashi OkadaKazunobu Katoh
    • G03C1/06G03C1/485
    • G03C1/061
    • A silver halide photographic material comprising a support having thereon at least one hydrophilic colloid layer, at least one of which is a silver halide photographic emulsion layer, is disclosed. At least one of the silver halide emulsion layers or other hydrophilic colloid layers of the photographic material contains a compound represented by formula (I): ##STR1## wherein, A.sub.1 and A.sub.2 both represent hydrogen atoms or one represents a hydrogen atom and the other a sulfonyl group or an acyl group, R.sub.1 represents an aliphatic group, an aromatic group or a heterocyclic group, G.sub.1 represents a carbonyl group, a sulfonyl group, a sulfoxy group, a ##STR2## group wherein R.sub.2 represents an alkoxy group or an aryloxy group, a ##STR3## group or an iminomethylene group, X.sub.1 is a moiety which instigates a ring-forming reaction by cleaving the --G.sub.1 --X.sub.1 moiety from the residual molecule and forms a cyclic structure containing the atoms of the --G.sub.1 --X.sub.1 moiety, and at least one of R.sub.1 and X.sub.1 has a silver halide adsorption accelerating group.
    • 公开了一种卤化银照相材料,其包含其上具有至少一个亲水胶体层的载体,其中至少一个是卤化银照相乳剂层。 照相材料的卤化银乳剂层或其他亲水胶体层中的至少一种含有由式(I)表示的化合物:其中,A1和A2均代表氢原子或一个表示氢原子, 另一个是磺酰基或酰基,R 1表示脂族基团,芳族基团或杂环基团,G 1表示羰基,磺酰基,磺基氧基,其中R 2表示烷氧基或 一个芳氧基,一个“IMAGE”基团或一亚氨基亚甲基,X 1是通过从残留分子中切割-G1-X1部分并形成含有-G1-的原子的环状结构来引发成环反应的部分, X1部分,并且R1和X1中的至少一个具有卤化银吸附促进基团。