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1. 发明授权

US5728791A Polyvinyl graft-polymers and manufacturing method thereof 失效
标题翻译：聚乙烯基接枝聚合物及其制备方法
公开(公告)号：US5728791A
公开(公告)日：1998-03-17
申请号：US557329
申请日：1995-11-14
申请人： Kazuhiko Tamai , Kazuya Yonezawa
发明人： Kazuhiko Tamai , Kazuya Yonezawa
IPC分类号： C08F291/00 , C08F24/00 , C08F12/08 , C08F16/14 , C08F20/18 , C08F20/42 , C08F269/00
CPC分类号： C08F291/00
摘要： The present invention provides a polyvinyl graft-polymer having one structural unit having a glycidyloxy group represented by the following general formula (I) at side chains of the polyvinyl polymer per 2-1,000 repeating units of vinyl: ##STR1## wherein Ar represents an aromatic hydrocarbon group 6-23 in carbon number having at least one glycidyloxy group, and R represents hydrogen atom or methyl group, and its manufacturing method. The polyvinyl graft-polymer of the present invention is excellent not only in mechanical properties and heat resistance, but also in adhesiveness, paintability dyeability and antistatic property.
摘要翻译：本发明提供一种具有一个结构单元的聚乙烯基接枝聚合物，每个2-1,000个乙烯基重复单元在聚乙烯基聚合物的侧链上具有由以下通式（I）表示的缩水甘油氧基：其中Ar 表示具有至少一个缩水甘油基氧基的碳数为6-23的芳族烃基，R表示氢原子或甲基，及其制造方法。本发明的聚乙烯基接枝聚合物不仅具有机械性能和耐热性，而且在粘合性，可着色性和抗静电性方面也是优异的。

2. 发明授权

US5652276A Foaming resin composition, plastic foam formed from the composition, and method for forming the plastic foam 失效
标题翻译：发泡树脂组合物，由组合物形成的塑料泡沫以及形成塑料泡沫的方法
公开(公告)号：US5652276A
公开(公告)日：1997-07-29
申请号：US669301
申请日：1996-09-05
申请人： Hiroshi Ando , Kensuke Kondo , Naoaki Nakanishi , Hiroshi Ito , Shigeki Hamaguchi , Kazuya Yonezawa
发明人： Hiroshi Ando , Kensuke Kondo , Naoaki Nakanishi , Hiroshi Ito , Shigeki Hamaguchi , Kazuya Yonezawa
IPC分类号： C08J9/00 , C08J9/02 , C08J9/06
CPC分类号： C08J9/02 , C08J9/0061 , C08J2383/04
摘要： A foaming resin composition consisting essentially of (A) an organic compound having a carbon-carbon double bond, (B) a compound having an SiH group, and (C) a compound having an OH group is foamed and cured at room temperature or under heat at relatively low temperatures, to obtain hard, semi-hard or soft plastic foam having good weather resistance and good compatibility with coating compositions and adhesives.
摘要翻译： PCT No.PCT / JP95 / 02335 Sec。 371日期：1996年9月5日 102（e）日期1996年9月5日PCT 1995年11月15日PCT PCT。出版物WO96 / 15194 日期1996年5月23日发泡树脂组合物主要由（A）具有碳 - 碳双键的有机化合物，（B）具有SiH基团的化合物和（C）具有OH基团的化合物组成的发泡树脂组合物发泡固化室温或在相对低的温度下加热，以获得具有良好耐候性和与涂料组合物和粘合剂的良好相容性的硬质，半硬或软塑料泡沫。

3. 发明授权

US5177173A Heat-resting aromatic polyestersulfone and process for preparing the same 失效
标题翻译：热稳定性芳族聚酯和其制备方法
公开(公告)号：US5177173A
公开(公告)日：1993-01-05
申请号：US583820
申请日：1984-02-27
申请人： Hiroshi Iwakiri , Masahiro Asada , Kazuya Yonezawa
发明人： Hiroshi Iwakiri , Masahiro Asada , Kazuya Yonezawa
IPC分类号： C08G63/00 , B32B27/36 , C08G63/18 , C08G63/19 , C08G63/68 , C08G63/688 , C08G63/82
CPC分类号： C08G63/6886
摘要： An aromatic polyestersulfone having improved heat resistance, film-forming property, hydrolysis resistance and mechanical strength which comprises 1 to 100% by mole of recurring units of the general formula: ##STR1## and 99 to 0% by mole of recurring units of the general formula: ##STR2## wherein R and R' are the same or different and each is an alkyl or alkoxyl group having 1 to 4 carbon atoms, Ar is a bivalent aromatic group, and x and y are 0 or an integer of 1 to 4 provided that the sum of x and y is from 1 to 8.
摘要翻译：具有改善的耐热性，成膜性，耐水解性和机械强度的芳族聚酯砜，其包含1至100摩尔％的通式为：IMAGE的重复单元和99至0摩尔％的一般重复单元式：其中R和R'相同或不同，并且各自为具有1至4个碳原子的烷基或烷氧基，Ar为二价芳族基团，x和y为0或1至4的整数条件是x和y的和为1至8。

4. 发明授权

US4334036A Process for producing curable vinyl polymer having silyl group 失效
标题翻译：制备具有甲硅烷基的可固化乙烯基聚合物的方法
公开(公告)号：US4334036A
公开(公告)日：1982-06-08
申请号：US167657
申请日：1980-07-11
申请人： Kazuya Yonezawa , Hisao Furukawa , Masaaki Azuma
发明人： Kazuya Yonezawa , Hisao Furukawa , Masaaki Azuma
IPC分类号： C08F8/42 , C08F8/34 , C08F236/02
CPC分类号： C08F8/42
摘要： A curable vinyl polymer having at least one silyl group of the formula: ##STR1## wherein R.sub.1 and R.sub.2 are each a hydrogen or a monovalent hydrocarbon radical having 1 to 10 carbon atoms, X is a group selected from halogen, alkoxy, acryloxy, aminoxy, phenoxy, thioalkoxy and amino groups; and "a" is a whole number equal to 0, 1 or 2, and having molecular weight of between 200 and 30,000, preferably between 1,500 and 25,000; and method for producing same, and products comprised of same; and wherein said method comprises reacting hydrosilane represented by the formula: ##STR2## wherein the same designations as above apply, with a polymer having carbon-carbon double bonds in the terminal or side chains of the polymer in which the main chain is a vinyl polymer having a molecular weight of between 200 and 30,000, and at a temperature of between 50.degree. and 150.degree. C.
摘要翻译：一种具有至少一个具有下式的甲硅烷基的可固化乙烯基聚合物：其中R 1和R 2各自为氢或具有1-10个碳原子的一价烃基，X为选自卤素，烷氧基，丙烯酰氧基，氨基，苯氧基，硫代烷氧基和氨基; 和“a”是等于0,1或2的整数，分子量在200至30,000之间，优选在1,500至25,000之间; 及其制造方法及其制造方法。并且其中所述方法包括使由下式表示的氢硅烷：其中与上述相同的名称适用于具有碳 - 碳双键的聚合物的聚合物的末端或侧链中的聚合物，其中主链是乙烯基聚合物分子量为200至30,000，温度为50至150℃。

5. 发明授权

US4191714A Curable polyester oligomer and a process for producing same 失效
标题翻译：可固化聚酯低聚物及其制备方法
公开(公告)号：US4191714A
公开(公告)日：1980-03-04
申请号：US973889
申请日：1978-12-28
申请人： Kazuya Yonezawa , Yasushi Kato , Hisao Furukawa , Masaaki Azuma
发明人： Kazuya Yonezawa , Yasushi Kato , Hisao Furukawa , Masaaki Azuma
IPC分类号： C08G63/695 , C08L83/12 , C08L43/04
CPC分类号： C08G63/695
摘要： A curable polyester oligomer having a molecular weight of between 300 and 10,000 and at least one silyl radical at the side chain or at the end of the molecule, with the silyl radical being represented by the formula: ##STR1## wherein R, R.sub.1 and R.sub.2 represent hydrogen or any monovalent hydrocarbon radical with 1 to 10 carbon atoms, selected from the group consisting of alkyl radical, aryl radical and aralkyl radical; R.sub.3 represents divalent hydrocarbon radical with 0 to 10 carbon atoms, "X" represents any radical selected from the group consisting of halogen, alkoxy, acyloxy, aminoxy, phenoxy, thioalkoxy, and amino radicals; "a" is an integer 0, 1 or 2; and "b" is an integer 0 or 1.
摘要翻译：分子量为300至10,000的可固化的聚酯低聚物和分子侧链或末端的至少一个甲硅烷基，其中甲硅烷基由下式表示：其中R，R 1和R 2 表示氢或具有1至10个碳原子的任何一价烃基，其选自烷基，芳基和芳烷基; R3表示具有0至10个碳原子的二价烃基，“X”表示选自卤素，烷氧基，酰氧基，氨氧基，苯氧基，硫代烷氧基和氨基的任何基团; “a”是整数0,1或2; “b”为整数0或1。

6. 发明授权

US4161572A Curable diallyl phthalate compounds and process for producing same 失效
标题翻译：可固化邻苯二甲酸二烯丙酯化合物及其制备方法
公开(公告)号：US4161572A
公开(公告)日：1979-07-17
申请号：US936378
申请日：1978-08-24
申请人： Kazuya Yonezawa , Hisao Furukawa , Masaaki Azuma
发明人： Kazuya Yonezawa , Hisao Furukawa , Masaaki Azuma
IPC分类号： C08F8/00 , C08F8/42 , C08F30/00 , C08F30/08 , C09D4/00 , C09J131/00 , C09J137/00 , C08F8/18 , C08F8/32 , C08F8/34
CPC分类号： C08F8/42
摘要： Diallyl Phthalate compounds having a molecular weight of 250 to 20,000 and having at least one silyl group represented by the formula: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are each a hydrogen or a monovalent hydrocarbon radicals having 1 to 10 carbon atoms, such as alkyl, aryl or aralkyl radicals; X is a group selected from halogen, alkoxy, acryloxy, aminoxy, phenoxy, thioalkoxy and amino groups, and "a" is an integer 0, 1 or 2, in the molecule; and process for producing same wherein a diallyl phthalate monomer or prepolymer having molecular weight of 20,000 or less is reacted with a hydrosilane compound having the formula: ##STR2## WHEREIN THE DESIGNATIONS ARE THE SAME AS ABOVE, AND AT A TEMPERATURE WITHIN THE RANGE OF 50.degree. TO 150.degree. C.
摘要翻译：具有250至20,000分子量的具有至少一个由下式表示的甲硅烷基的邻苯二甲酸二烯丙酯化合物：其中R 1，R 2和R 3各自为氢或具有1至10个碳原子的一价烃基，例如烷基，芳基或芳烷基; X是选自卤素，烷氧基，丙烯酰氧基，氨氧基，苯氧基，硫代烷氧基和氨基的基团，“a”是分子中0,1或2的整数; 和其制备方法，其中分子量为20,000以下的邻苯二甲酸二烯丙酯单体或预聚物与具有下列结构式的氢化硅烷化合物反应：其中指定为上述，在50℃范围内的温度下 ℃至150℃

7. 发明授权

US5567833A Curing agent, preparation thereof and curable composition comprising the same 失效
公开(公告)号：US5567833A
公开(公告)日：1996-10-22
申请号：US313923
申请日：1994-09-26
申请人： Takahisa Iwahara , Makoto Chiba , Tomoko Takahara , Kazuya Yonezawa
发明人： Takahisa Iwahara , Makoto Chiba , Tomoko Takahara , Kazuya Yonezawa
IPC分类号： C07F7/08 , C07F7/21 , C08G65/336 , C08G77/48 , C08G77/50 , C08K5/54 , C08L43/04 , C08L71/00 , C08L101/10
CPC分类号： C08L71/00 , C07F7/0896 , C07F7/21 , C08G65/336 , C08G77/48 , C08G77/50 , C08K5/54 , C08L101/10 , C08L43/04
摘要： A curable composition which comprises(C) a non-polymeric organic curing agent having at least two hydrosilyl groups in a molecule,(D) an organic polymer having at least one alkenyl group in a molecule, and(E) a hydrosilylation catalysthas rapid curability and good depth curability, and gives a homogeneous cured material having good mechanical properties.

8. 发明授权

US4709062A Glycidyl compound 失效
标题翻译：缩水甘油基化合物
公开(公告)号：US4709062A
公开(公告)日：1987-11-24
申请号：US823410
申请日：1986-01-28
申请人： Haruo Tomita , Yasuo Okamoto , Kazuya Yonezawa
发明人： Haruo Tomita , Yasuo Okamoto , Kazuya Yonezawa
IPC分类号： C07D303/20 , C07D301/27 , C07D303/22 , C07D303/24 , C07D303/27 , C08G59/00 , C08G59/28 , C08G59/40 , C08G65/26 , C07D303/46
CPC分类号： C07D303/22 , C07D303/24 , C08G65/26
摘要： A glycidyl compound having the formula (I): ##STR1## wherein R is hydrogen atom or methyl group, p is an integer of 1 to 4 and Ar is aromatic hydrocarbon group selected from the group consisting of groups having the formula (II), (III) and (IV): ##STR2## wherein R.sup.1 R.sup.2 are the same or different and each is an alkyl group having 1 to 4 carbon atoms.The glycidyl compound can be cured by either heat, radical initiators or irradiation of ultraviolet rays and curing compounds prepared by using the glycidyl compound have high heat resistance and high surface hardness.
摘要翻译：具有式（I）的缩水甘油基化合物：其中R是氢原子或甲基，p是1〜4的整数，Ar是选自具有下式的基团的芳香族烃基（I II），（III）和（IV）：其中R 1 R2相同或不同，并且各自为具有1至4个碳原子的烷基。缩水甘油基化合物可以通过加热，自由基引发剂或紫外线照射固化，并且通过使用缩水甘油基化合物制备的固化化合物具有高耐热性和高表面硬度。

9. 发明授权

US4540802A Epoxy resin and process for preparing the same 失效
标题翻译：环氧树脂及其制备方法
公开(公告)号：US4540802A
公开(公告)日：1985-09-10
申请号：US491226
申请日：1983-05-03
申请人： Haruo Tomita , Kazuya Yonezawa
发明人： Haruo Tomita , Kazuya Yonezawa
IPC分类号： C07D303/26 , C07B61/00 , C07D303/24 , C07D303/27 , C08G59/00 , C08G59/20 , C08G59/24 , C08G59/32 , C07D301/30 , C07D303/16
CPC分类号： C07D303/24 , C08G59/245 , C08G59/3218
摘要： An epoxy resin of the general formula: ##STR1## wherein X.sub.1 and X.sub.2 are --OH or ##STR2## and X.sub.3 is --OH, ##STR3## or a group of the general formula: ##STR4## in which X.sub.4, X.sub.5 and X.sub.6 are --OH or ##STR5## provided that at least one of X.sub.1 to X.sub.6 is ##STR6## The epoxy resin is prepared by reacting gallic acid or tannic acid with an epihalohydrin in the presence of a phase transfer catalyst and reacting the obtained reaction mixture with an aqueous alkali solution.
摘要翻译：一种下列通式的环氧树脂：其中X 1和X 2是-OH或者X 3和X 3是-OH，或者一个通式如下的组合：其中X 4，X 5和X 6是 -OH或，条件是X1至X6中的至少一个为环氧树脂。在相转移催化剂存在下，将没食子酸或单宁酸与表卤代醇反应制备环氧树脂，并将所得反应混合物与碱性水溶液。

10. 发明授权

US4426511A Heat-resisting aromatic polyester resin and process for preparing the same 失效
标题翻译：耐热芳香族聚酯树脂及其制备方法
公开(公告)号：US4426511A
公开(公告)日：1984-01-17
申请号：US313670
申请日：1981-10-21
申请人： Masahiro Asada , Miyuki Matsuura , Kazuya Yonezawa
发明人： Masahiro Asada , Miyuki Matsuura , Kazuya Yonezawa
IPC分类号： C08G63/00 , C08G63/19 , C08G63/66 , C08G63/68 , C08G63/688 , C08G63/87 , C08G63/18
CPC分类号： C08G63/19 , C08G63/6886 , C08G63/87
摘要： A heat resisting aromatic polyester resin comprising (a) recurring units of the formula (I): ##STR1## wherein X is a bivalent group selected from the group consisting of an unsubstituted or substituted bivalent hydrocarbon group having 1 to 10 carbon atoms,--O--, --S--, --SO.sub.2 --and--CO--, and (b) recurring units of the formula (II): ##STR2## wherein X is as defined above, R and R' are a group selected from the group consisting of alkyl, aryl, aralkyl, alkoxyl, aryloxyl and phenylalkoxyl groups having 1 to 20 carbon atoms, their substituted groups, a halogen atom and a mixture thereof, p+q=1 to 8, and m and n are 0 or 1, but n is not 0 when m is 1, provided that up to 10% by mole of the total of the units: ##STR3## in the formulas (I) and (II) may be replaced with units: ##STR4## the ratio of (a)/[(a)+(b)]being from 0.05 to 0.95 by mole. The polyester resin is substantially amorphous and soluble in some organic solvents, and has an excellent heat resistance. The polyester resin is prepared by reacting terephthaloyl chloride with alkali metal salts of at least two kinds of particular bivalent phenolic compounds in the presence of a phase transfer catalyst.
摘要翻译：一种耐热性芳族聚酯树脂，其包含（a）式（I）的重复单元：其中X是选自未取代或取代的具有1-10个碳原子的二价烃基的二价基团，-O - ， - S - ， - SO 2 - 和-CO-，和（b）式（II）的重复单元：其中X如上所定义，R和R' 选自具有1至20个碳原子的烷基，芳基，芳烷基，烷氧基，芳氧基和苯基烷氧基，其取代基，卤素原子及其混合物，p + q = 1-8，m和n分别为 0或1，但当m为1时，n不为0，只要式（I）和（II）中的总数高达10摩尔％，则可以用单位代替：

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