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1. 发明授权

US5177173A Heat-resting aromatic polyestersulfone and process for preparing the same 失效
标题翻译：热稳定性芳族聚酯和其制备方法
公开(公告)号：US5177173A
公开(公告)日：1993-01-05
申请号：US583820
申请日：1984-02-27
申请人： Hiroshi Iwakiri , Masahiro Asada , Kazuya Yonezawa
发明人： Hiroshi Iwakiri , Masahiro Asada , Kazuya Yonezawa
IPC分类号： C08G63/00 , B32B27/36 , C08G63/18 , C08G63/19 , C08G63/68 , C08G63/688 , C08G63/82
CPC分类号： C08G63/6886
摘要： An aromatic polyestersulfone having improved heat resistance, film-forming property, hydrolysis resistance and mechanical strength which comprises 1 to 100% by mole of recurring units of the general formula: ##STR1## and 99 to 0% by mole of recurring units of the general formula: ##STR2## wherein R and R' are the same or different and each is an alkyl or alkoxyl group having 1 to 4 carbon atoms, Ar is a bivalent aromatic group, and x and y are 0 or an integer of 1 to 4 provided that the sum of x and y is from 1 to 8.
摘要翻译：具有改善的耐热性，成膜性，耐水解性和机械强度的芳族聚酯砜，其包含1至100摩尔％的通式为：IMAGE的重复单元和99至0摩尔％的一般重复单元式：其中R和R'相同或不同，并且各自为具有1至4个碳原子的烷基或烷氧基，Ar为二价芳族基团，x和y为0或1至4的整数条件是x和y的和为1至8。

2. 发明授权

US4552947A Heat-resisting aromatic polyester and process for preparing the same 失效
标题翻译：耐热芳香族聚酯及其制备方法
公开(公告)号：US4552947A
公开(公告)日：1985-11-12
申请号：US484848
申请日：1983-04-14
申请人： Hiroshi Iwakiri , Masahiro Asada , Kazuya Yonezawa
发明人： Hiroshi Iwakiri , Masahiro Asada , Kazuya Yonezawa
IPC分类号： C08G63/00 , C08G63/19 , C08G63/193 , C08G63/79 , C08G63/82 , C08G63/18
CPC分类号： C08G63/193 , C08G63/79
摘要： An aromatic polyester having improved heat resistance, hydrolysis resistance and alkali resistance which comprises recurring units of the general formula: ##STR1## and recurring units of the general formula: ##STR2## wherein R.sup.1 and R.sup.2 are an alkyl or alkoxyl group having 1 to 4 carbon atoms, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are the same or different and each is an alkyl or alkoxyl group having 1 to 4 carbon atoms, Cl or Br, x and y are an integer of 1 to 4, z, x', y' and z' are 0 or an integer of 1 to 4, and X is an alkylidene or cycloalkylidene group having 1 to 8 carbon atoms, --O--, --S--, --SO.sub.2 -- or --CO--.
摘要翻译：具有改善的耐热性，耐水解性和耐碱性的芳族聚酯，其包含以下通式的重复单元：＆lt; IMAGE＆gt;和以下通式的重复单元：其中R 1和R 2为具有1-4个碳原子的烷基或烷氧基碳原子，R 3，R 4，R 5和R 6相同或不同，各自为具有1至4个碳原子的烷基或烷氧基，Cl或Br，x和y为1至4的整数，z，x'， y'和z'为0或1〜4的整数，X为碳原子数1〜8的亚烷基或亚环烷基，-O-，-S-，-SO 2 - 或-CO-。

3. 发明授权

US4474936A Polyesteramide and process for preparing the same 失效
标题翻译：聚酯酰胺及其制备方法
公开(公告)号：US4474936A
公开(公告)日：1984-10-02
申请号：US514200
申请日：1983-07-15
申请人： Kazuya Yonezawa , Masahiro Asada , Hiroshi Iwakiri , Miyuki Azuma
发明人： Kazuya Yonezawa , Masahiro Asada , Hiroshi Iwakiri , Miyuki Azuma
IPC分类号： C08G69/00 , C08G69/44
CPC分类号： C08G69/44
摘要： A polyesteramide having structural units of the general formula: ##STR1## wherein Ar is a bivalent aromatic group comprising at least 10% by mole of a group having the following formula: ##STR2## in which R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are the same or different and each is methyl group or ethyl group, and structural units of the general formula: ##STR3## wherein R is a bivalent organic group. At least 10% by mole of a bifunctional phenol compound to be used is a tetraalkylbisphenol-F, and whereby the obtained polyesteramide has improved hydrolysis resistance and electric characteristic with an excellent heat resistance.
摘要翻译：具有以下通式的结构单元的聚酯酰胺：其中Ar是包含至少10摩尔％具有下式的基团的二价芳族基团：其中R 1，R 2，R 3和R 4 相同或不同，各自为甲基或乙基，以及通式为：其中R为二价有机基团的结构单元。至少10摩尔％的双官能酚化合物是四烷基双酚-F，由此得到的聚酯酰胺具有改善的耐水解性和耐热性优异的电特性。

4. 发明授权

US4975511A Glycidyl sulfonamide compound 失效
公开(公告)号：US4975511A
公开(公告)日：1990-12-04
申请号：US432643
申请日：1989-11-07
申请人： Yoshikuni Deguchi , Hiroshi Iwakiri , Kazunari Iwamoto , Kazuya Yonezawa
发明人： Yoshikuni Deguchi , Hiroshi Iwakiri , Kazunari Iwamoto , Kazuya Yonezawa
IPC分类号： C07F7/08 , C08G59/02 , C08G59/30 , C08G77/382
CPC分类号： C08G59/02 , C07F7/0847 , C08G59/302 , C08G59/306 , C08G77/382
摘要： A novel glycidyl sulfonamide compound having a (poly)siloxane main chain of its molecule is used alone or in admixture with an epoxy resin to give a cured material being excellent in flexibility, elongation and impact strength without deteriorating thermal resistance, chemical resistance and water absorption thereof. An epoxy resin composition or a resin composition for an epoxy paint containing a glycidyl sulfonamide compound, the epoxy resin and a curling agent for epoxy resin provides a cured material or a coating film having the above-mentioned excellent properties. A process for preparing a glycidyl sulfonamide compound characterized in that subjecting an amine modified silicone having a (poly)siloxane main chain of its molecule to condensation reaction with a sulfonyl chloride to give a sulfonamide compound, which is subjected to an addition reaction with an epihalohydrin to give the glycidyl sulfonamide compound.

5. 发明授权

US4847395A Glycidyl compounds 失效
标题翻译：缩水甘油基化合物
公开(公告)号：US4847395A
公开(公告)日：1989-07-11
申请号：US105782
申请日：1987-10-08
申请人： Yoshikuni Deguchi , Hiroshi Iwakiri , Kazunari Iwamoto , Kazuya Yonezawa
发明人： Yoshikuni Deguchi , Hiroshi Iwakiri , Kazunari Iwamoto , Kazuya Yonezawa
IPC分类号： C07D303/36 , C08G59/10 , C08G59/14 , C08G59/22 , C08G59/30
CPC分类号： C08G59/226 , C07D303/36 , C08G59/145 , C08G59/302
摘要： Novel glycidyl compounds represented by general formula (I): ##STR1## (wherein all the symbols are as defined in the appended claims), and a process for preparation of the glycidyl compounds are disclosed. The glycidyl compounds are prepared by reacting ethersulfonamide represented by general formula (III): ##STR2## (wherein all the symbols are as defined in the appended claims) and epihalohydrin, and then reacting the resultant adduct with an aqueous caustic alkali solution.

6. 发明授权

US4426511A Heat-resisting aromatic polyester resin and process for preparing the same 失效
标题翻译：耐热芳香族聚酯树脂及其制备方法
公开(公告)号：US4426511A
公开(公告)日：1984-01-17
申请号：US313670
申请日：1981-10-21
申请人： Masahiro Asada , Miyuki Matsuura , Kazuya Yonezawa
发明人： Masahiro Asada , Miyuki Matsuura , Kazuya Yonezawa
IPC分类号： C08G63/00 , C08G63/19 , C08G63/66 , C08G63/68 , C08G63/688 , C08G63/87 , C08G63/18
CPC分类号： C08G63/19 , C08G63/6886 , C08G63/87
摘要： A heat resisting aromatic polyester resin comprising (a) recurring units of the formula (I): ##STR1## wherein X is a bivalent group selected from the group consisting of an unsubstituted or substituted bivalent hydrocarbon group having 1 to 10 carbon atoms,--O--, --S--, --SO.sub.2 --and--CO--, and (b) recurring units of the formula (II): ##STR2## wherein X is as defined above, R and R' are a group selected from the group consisting of alkyl, aryl, aralkyl, alkoxyl, aryloxyl and phenylalkoxyl groups having 1 to 20 carbon atoms, their substituted groups, a halogen atom and a mixture thereof, p+q=1 to 8, and m and n are 0 or 1, but n is not 0 when m is 1, provided that up to 10% by mole of the total of the units: ##STR3## in the formulas (I) and (II) may be replaced with units: ##STR4## the ratio of (a)/[(a)+(b)]being from 0.05 to 0.95 by mole. The polyester resin is substantially amorphous and soluble in some organic solvents, and has an excellent heat resistance. The polyester resin is prepared by reacting terephthaloyl chloride with alkali metal salts of at least two kinds of particular bivalent phenolic compounds in the presence of a phase transfer catalyst.
摘要翻译：一种耐热性芳族聚酯树脂，其包含（a）式（I）的重复单元：其中X是选自未取代或取代的具有1-10个碳原子的二价烃基的二价基团，-O - ， - S - ， - SO 2 - 和-CO-，和（b）式（II）的重复单元：其中X如上所定义，R和R' 选自具有1至20个碳原子的烷基，芳基，芳烷基，烷氧基，芳氧基和苯基烷氧基，其取代基，卤素原子及其混合物，p + q = 1-8，m和n分别为 0或1，但当m为1时，n不为0，只要式（I）和（II）中的总数高达10摩尔％，则可以用单位代替：

7. 发明授权

US4412057A Process for manufacturing aromatic polyesters 失效
标题翻译：制备芳香族聚酯的方法
公开(公告)号：US4412057A
公开(公告)日：1983-10-25
申请号：US331463
申请日：1981-12-16
申请人： Masahiro Asada , Miyuki Matsuura , Kazuya Yonezawa
发明人： Masahiro Asada , Miyuki Matsuura , Kazuya Yonezawa
IPC分类号： C08G63/19 , C08G63/40 , C08G63/79 , C08G63/18 , C08G63/24
CPC分类号： C08G63/79 , C08G63/19 , C08G63/40
摘要： A process for manufacturing an aromatic polyester by reacting an aromatic dicarboxylic acid dichloride with an alkali metal salt of a bisphenol comprises adding 0.01 to 100 mol %, based on the total monomer quantity, of an acid halide into the reaction system.
摘要翻译：通过使芳族二羧酸二氯化物与双酚的碱金属盐反应来制造芳族聚酯的方法包括向反应体系中加入0.01至100摩尔％的酰基卤的总单体量。

8. 发明授权

US4395537A Polyether resin and method of manufacturing the same 失效
标题翻译：聚醚树脂及其制造方法
公开(公告)号：US4395537A
公开(公告)日：1983-07-26
申请号：US296209
申请日：1981-08-25
申请人： Kazuya Yonezawa , Masahiro Asada , Miyuki Matsuura
发明人： Kazuya Yonezawa , Masahiro Asada , Miyuki Matsuura
IPC分类号： C08G65/00 , C08G65/40
CPC分类号： C08G65/40 , C08G2650/44
摘要： A polyether of the general formula: ##STR1## in which Ar stands for a divalent organic group of the aromatic series, R stands for CH.sub.3, CH.sub.3 CH.sub.2, Cl or Br, and n is an integer of 0 to 4. It contains at least 1 mol % of unit `B`. A method of manufacturing such a polyether is also disclosed.
摘要翻译：一种通式如下的聚醚：其中Ar表示芳香族系的二价有机基团，R表示CH3，CH3CH2，Cl或Br，n表示0〜4的整数。它包含至少1个单位“B”的摩尔％。还公开了制造这种聚醚的方法。

9. 发明授权

US5652276A Foaming resin composition, plastic foam formed from the composition, and method for forming the plastic foam 失效
标题翻译：发泡树脂组合物，由组合物形成的塑料泡沫以及形成塑料泡沫的方法
公开(公告)号：US5652276A
公开(公告)日：1997-07-29
申请号：US669301
申请日：1996-09-05
申请人： Hiroshi Ando , Kensuke Kondo , Naoaki Nakanishi , Hiroshi Ito , Shigeki Hamaguchi , Kazuya Yonezawa
发明人： Hiroshi Ando , Kensuke Kondo , Naoaki Nakanishi , Hiroshi Ito , Shigeki Hamaguchi , Kazuya Yonezawa
IPC分类号： C08J9/00 , C08J9/02 , C08J9/06
CPC分类号： C08J9/02 , C08J9/0061 , C08J2383/04
摘要： A foaming resin composition consisting essentially of (A) an organic compound having a carbon-carbon double bond, (B) a compound having an SiH group, and (C) a compound having an OH group is foamed and cured at room temperature or under heat at relatively low temperatures, to obtain hard, semi-hard or soft plastic foam having good weather resistance and good compatibility with coating compositions and adhesives.
摘要翻译： PCT No.PCT / JP95 / 02335 Sec。 371日期：1996年9月5日 102（e）日期1996年9月5日PCT 1995年11月15日PCT PCT。出版物WO96 / 15194 日期1996年5月23日发泡树脂组合物主要由（A）具有碳 - 碳双键的有机化合物，（B）具有SiH基团的化合物和（C）具有OH基团的化合物组成的发泡树脂组合物发泡固化室温或在相对低的温度下加热，以获得具有良好耐候性和与涂料组合物和粘合剂的良好相容性的硬质，半硬或软塑料泡沫。

10. 发明授权

US4334036A Process for producing curable vinyl polymer having silyl group 失效
标题翻译：制备具有甲硅烷基的可固化乙烯基聚合物的方法
公开(公告)号：US4334036A
公开(公告)日：1982-06-08
申请号：US167657
申请日：1980-07-11
申请人： Kazuya Yonezawa , Hisao Furukawa , Masaaki Azuma
发明人： Kazuya Yonezawa , Hisao Furukawa , Masaaki Azuma
IPC分类号： C08F8/42 , C08F8/34 , C08F236/02
CPC分类号： C08F8/42
摘要： A curable vinyl polymer having at least one silyl group of the formula: ##STR1## wherein R.sub.1 and R.sub.2 are each a hydrogen or a monovalent hydrocarbon radical having 1 to 10 carbon atoms, X is a group selected from halogen, alkoxy, acryloxy, aminoxy, phenoxy, thioalkoxy and amino groups; and "a" is a whole number equal to 0, 1 or 2, and having molecular weight of between 200 and 30,000, preferably between 1,500 and 25,000; and method for producing same, and products comprised of same; and wherein said method comprises reacting hydrosilane represented by the formula: ##STR2## wherein the same designations as above apply, with a polymer having carbon-carbon double bonds in the terminal or side chains of the polymer in which the main chain is a vinyl polymer having a molecular weight of between 200 and 30,000, and at a temperature of between 50.degree. and 150.degree. C.
摘要翻译：一种具有至少一个具有下式的甲硅烷基的可固化乙烯基聚合物：其中R 1和R 2各自为氢或具有1-10个碳原子的一价烃基，X为选自卤素，烷氧基，丙烯酰氧基，氨基，苯氧基，硫代烷氧基和氨基; 和“a”是等于0,1或2的整数，分子量在200至30,000之间，优选在1,500至25,000之间; 及其制造方法及其制造方法。并且其中所述方法包括使由下式表示的氢硅烷：其中与上述相同的名称适用于具有碳 - 碳双键的聚合物的聚合物的末端或侧链中的聚合物，其中主链是乙烯基聚合物分子量为200至30,000，温度为50至150℃。

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