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    • 3. 发明申请
    • OXIME ESTER
    • US20130188270A1
    • 2013-07-25
    • US13824678
    • 2011-10-04
    • Yuichi NishimaeHisatoshi KuraKazuhiko KunimotoRyuhei YamagamiKeita Tanaka
    • Yuichi NishimaeHisatoshi KuraKazuhiko KunimotoRyuhei YamagamiKeita Tanaka
    • C08F2/50C07D409/10G02B5/22C07D409/12C07D403/10C07D209/80C07D405/12
    • C08F2/50B33Y70/00C07D209/80C07D209/86C07D403/10C07D405/12C07D409/10C07D409/12G02B5/223G03F7/0007G03F7/029G03F7/031G03F7/105
    • Compounds of the formula (I), wherein R1, R2, R3, R4, R5, R6, R7 and R8 for example independently of each other are hydro-gen, C1-C20alkyl, (II), COR16 or NO2, provided that at least one pair of R1 and R2, R2 and R3, R3 and R4, R5 and R6, R6 and R7, or R7 and R8 is (III); R9, R10, R11 and R12 for example independently of each other are hydrogen, C1-C20alkyl which optionally substituted; or R9, R10, R11, and R12 independently of each other are unsubstituted or substituted phenyl; X is CO or a direct bond; R13 is for example C1-C20alkyl which optionally is substituted, C2-C12alkenyl, C4-C8cycloalkenyl, C2-C12alkinyl, C3-C10-cycloalkyl, phenyl or naphthyl both of which are optionally substituted; R14 is for example hydrogen, C3-C8cycloalkyl, C2-C5alkenyl, C1-C20alkoxy, C1-C20alkyl, phenyl or naphthyl; R15 is for example C6-C20aryl or C5-C20heteroaryl; R16 is for example C6-C20aryl which is unsubstituted or substituted by one or more C1-C20alkoxy or C1-C20alkyl; are in particular suitable as photoinitiators for color filter applications.
    • 式(I)的化合物,其中R 1,R 2,R 3,R 4,R 5,R 6,R 7和R 8例如彼此独立地是氢,C 1 -C 20烷基,(II),COR 16或NO 2, 至少一对R1和R2,R2和R3,R3和R4,R5和R6,R6和R7,或R7和R8是(III); R9,R10,R11和R12彼此独立地是氢,任选取代的C 1 -C 20烷基; 或R 9,R 10,R 11和R 12彼此独立地是未取代或取代的苯基; X是CO或直接键; R13是例如任选被取代的C 1 -C 20烷基,C 2 -C 12烯基,C 4 -C 8环烯基,C 2 -C 12炔基,C 3 -C 10 - 环烷基,苯基或萘基,它们都是任选取代的; R 14是例如氢,C 3 -C 8环烷基,C 2 -C 5烯基,C 1 -C 20烷氧基,C 1 -C 20烷基,苯基或萘基; R 15例如是C 6 -C 20芳基或C 5 -C 20杂芳基; R 16是例如未被取代或被一个或多个C 1 -C 20烷氧基或C 1 -C 20烷基取代的C 6 -C 20芳基; 特别适用于用于滤色器应用的光引发剂。
    • 7. 发明授权
    • Oxime ester photoinitiators
    • 肟酯光引发剂
    • US07759043B2
    • 2010-07-20
    • US11660346
    • 2005-08-08
    • Junichi TanabeKazuhiko KunimotoHisatoshi KuraHidetaka OkaMasaki Ohwa
    • Junichi TanabeKazuhiko KunimotoHisatoshi KuraHidetaka OkaMasaki Ohwa
    • G03C1/00C07D213/00C07D207/00C07D209/56C09B5/00G03F7/26C08F2/50
    • G03F7/031B33Y70/00C07D209/86C07D413/10
    • Compounds of the formula (I), wherein R1, R2 and R10 independently of one another are C1-C20alkyl, phenyl, C1-C12alkylphenyl or phenyl-C1-C6alkyl; R3 and R4 independently of one another are hydrogen, C1-C20alkyl, NR6R7 or SR8, provided that at least one of R3 or R4 is NR6R7 or SR8; R5 is hydrogen or C1-C20alkyl; R6 and R7 independently of one another are C1-C20alkyl, or R6 and R7 together with the N-atom to which they are attached form a 5 or 6 membered ring, which optionally is interrupted by O, S or NR9 and which optionally additionally is substituted by one or more C1-C4alkyl; R8 is phenyl, biphenylyl, naphthyl, anthryl or phenanthryl, all of which optionally are substituted by one or more C1-C4alkyl; and R9 is hydrogen, C1-C20alkyl, C2-C4hydroxyalkyl or phenyl; exhibit an unexpectedly good performance in photopolymerization reactions.
    • 式(I)化合物,其中R 1,R 2和R 10彼此独立地是C 1 -C 20烷基,苯基,C 1 -C 12烷基苯基或苯基-C 1 -C 6烷基; R 3和R 4彼此独立地是氢,C 1 -C 20烷基,NR 6 R 7或SR 8,条件是R 3或R 4中的至少一个是NR 6 R 7或SR 8; R5是氢或C1-C20烷基; R 6和R 7彼此独立地是C 1 -C 20烷基,或者R 6和R 7与它们所连接的N原子一起形成5或6元环,其任选地被O,S或NR 9中断,并且任选地另外是 被一个或多个C 1 -C 4烷基取代; R8是苯基,联苯基,萘基,蒽基或菲基,它们全部被一个或多个C 1 -C 4烷基取代; 且R 9为氢,C 1 -C 20烷基,C 2 -C 4羟烷基或苯基; 在光聚合反应中表现出出人意料的良好性能。