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    • 3. 发明授权
    • Quaternized, bridged benzimidazolylbenzimidazoles, processes for their
preparation and their use
    • 季铵化的桥联苯并咪唑基苯并咪唑,其制备方法及其用途
    • US4309551A
    • 1982-01-05
    • US191709
    • 1980-09-29
    • Norbert SchonbergerErich SchinzelThomas MartiniGunter Rosch
    • Norbert SchonbergerErich SchinzelThomas MartiniGunter Rosch
    • C09B57/00C07D235/02C07D235/20C07D235/24C07D487/14C07D235/30C07D235/04
    • C07D235/02C07D235/20C07D235/24C07D487/14
    • Compounds of the general formula (1) ##STR1## wherein R.sub.1 denotes hydrogen, halogen, alkyl, alkoxy or, conjointly with R.sub.2, a fused benzo ring, R.sub.2 denotes hydrogen, alkyl, alkoxy, halogen, phenyl, cyano, carboalkoxy, carboxyl, carbonamido, monoalkylcarbonamido, dialkylcarbonamido, sulfo, alkylsulfonyl, alkyloxysulfonyl, sulfonamido, monoalkylsulfonamido or dialkylsulfonamido or, conjointly with R.sub.3, a fused benzo ring, R.sub.3 has the same meaning as R.sub.2, R.sub.4 denotes hydrogen, alkyl, alkoxy, halogen or, conjointly with R.sub.3, a fused benzo ring, R.sub.5 denotes alkyl, hydroxyalkyl, alkoxyalkyl, optionally substituted aralkyl, cyanoethyl, cycloalkyl or a group of the formulae --CH.sub.2 CN, --CH.sub.2 CONH.sub.2 or --CH.sub.2 COO--alkyl, A denotes a group of the formulae ##STR2## or--(CH.sub.2).sub.4 --R.sub.6 denotes hydrogen, alkyl, hydroxyalkyl, alkoxyalkyl, aralkyl or optionally substituted phenyl, n denotes 1, 2 or 3 and X.sup.(-) denotes a halide, alkylsulfonate, alkylsulfate, alkylphenylsulfonate or phenylsulfonate ion, and processes for their preparation and their use as optical brighteners.
    • 通式(1)的化合物其中R1表示氢,卤素,烷基,烷氧基或与R2稠合的苯并环,R2表示氢,烷基,烷氧基,卤素,苯基,氰基,烷氧羰基 ,羧基,碳酰氨基,单烷基碳酰氨基,二烷基碳酰氨基,磺基,烷基磺酰基,烷氧基磺酰基,亚磺酰氨基,烷基磺酰氨基或二烷基磺酰氨基,或与R3稠合的苯并环,R3与R2相同,R4表示氢,烷基,烷氧基,卤素或 R 3表示烷基,羟基烷基,烷氧基烷基,任选取代的芳烷基,氰基乙基,环烷基或式-CH 2 CN,-CH 2 CONH 2或-CH 2 COO - 烷基的基团,A表示式 或 - (CH 2)4 -R 6表示氢,烷基,羟基烷基,烷氧基烷基,芳烷基或任选取代的苯基,n表示1,2或3,X( - )表示卤素,烷基磺酸酯,烷基硫酸酯,烷基苯基磺酸酯或苯基磺酸根离子, 过程为 制备及其作为荧光增白剂的用途。
    • 9. 发明授权
    • Liquid oxidative desizing agent and process for oxidative desizing
    • 液体氧化脱浆剂和氧化退浆方法
    • US4478737A
    • 1984-10-23
    • US478245
    • 1983-03-24
    • Klaus AdrianGunter Rosch
    • Klaus AdrianGunter Rosch
    • D06L1/14
    • D06L1/14
    • Oxidative desizing agent consisting substantially of from 5 to 20 weight % of sodium or ammonium persulfate or potassium, sodium, ammonium or calcium peroxodiphosphate, from 20 to 50 weight % of one or more surfactants selected from the group of C.sub.8 -C.sub.20 -sec.-alkanesulfonates, C.sub.4 -C.sub.12 -alkylphenol-oxethylates having 6 to 12 ethylene oxide moieties, or C.sub.10 -C.sub.18 -fatty alcohol-oxethylates having 3 to 8 ethylene oxide moieties, and water in the amount remaining to give 100%. The advantage of this desizing agent resides in the fact that a substantially smaller amount of persulfate is required than for desizing with persulfate alone. Moreover, this desizing agent is liquid and thus easy to be dosed.
    • 氧化脱浆剂,基本上由5-20重量%的过硫酸钠或过硫酸铵或过硫酸钾,过氧二磷酸钠,铵或钙组成,20-50重量%的一种或多种选自C8-C20-仲 - 烷基磺酸酯,具有6-12个环氧乙烷部分的C 4 -C 12烷基苯酚 - 羟乙酯,或具有3-8个环氧乙烷部分的C 10 -C 18脂肪醇 - 氧乙酸酯,剩余的水为100%。 该脱浆剂的优点在于,与仅用过硫酸盐脱浆相比,需要相当少量的过硫酸盐。 此外,这种脱浆剂是液体的,因此容易被给药。