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1. 发明授权

US4289592A Method of separating isotope compounds by selective excitation and reaction in a solid matrix 失效
标题翻译：通过固体基质中选择性激发和反应分离同位素化合物的方法
公开(公告)号：US4289592A
公开(公告)日：1981-09-15
申请号：US895510
申请日：1978-04-11
申请人： Karl Janner , Klaus Gregorius , Reinhold Muller
发明人： Karl Janner , Klaus Gregorius , Reinhold Muller
IPC分类号： B01D59/34 , H01S3/00
CPC分类号： B01D59/34
摘要： Separation of an isotope substance from a vaporous mixture of isotope substances such as UF.sub.6, by selective excitation of low temperature of one isotope compound by electromagnetic radiation to effect chemical reaction of the excited isotope compound with a reaction partner. Separate bodies of the vaporous mixture of isotope compounds and the reaction partner are cooled by adiabatic expansion to a temperature below 100 K. The cooled vapors are mixed in a chamber where the reaction partner is condensed to form solid matter into which isotope compounds are incorporated. The solid matter with or without compacting is subjected to radiation to excite one isotope compound and react it with the reaction product to produce a reaction product which contains predominently the one isotope.
摘要翻译：通过电磁辐射选择性地激发一种同位素化合物的低温，使同位素物质如UF6的汽相混合物分离，以实现激发的同位素化合物与反应配偶体的化学反应。通过绝热膨胀将同位素化合物和反应配对物的蒸汽混合物的分开的物质冷却至低于100K的温度。将冷却的蒸气在反应配对物冷凝的室中混合，形成固体物质，并加入同位素化合物。具有或不具有压实的固体物质经受辐射以激发一种同位素化合物并与反应产物反应以产生主要包含一种同位素的反应产物。

2. 发明授权

US4401627A Device for irradiating isotope mixtures isotope -selectively 失效
标题翻译：选择同位素照射同位素混合物的装置
公开(公告)号：US4401627A
公开(公告)日：1983-08-30
申请号：US186286
申请日：1980-09-11
申请人： Karl Janner , Klaus Gregorius
发明人： Karl Janner , Klaus Gregorius
IPC分类号： B01D59/34 , B01D59/50 , B01J19/08
CPC分类号： B01D59/34 , B01D59/50
摘要： Apparatus for adiabatic expansion and selective irradiation of gaseous isotope mixture employing a device in which there is a concentric arrangement of nozzles and diffusers with irradiation of the gas in the annular gap between the two. The nozzles are in the form of a multiplicity of slit nozzles with mutually parallel axes on an imaginary cylinder surface. Gas enters and flows centrally in the cylinder. Gas from the diffusers is discharged. Radiation enters through a mirror into the annular gap.
摘要翻译：用于绝热膨胀和气态同位素混合物的选择性照射的装置，其采用这样的装置，其中喷嘴和扩散器具有同心排列的气体在两者之间的环形间隙中的照射。喷嘴是多个狭缝喷嘴的形式，在假想的气缸表面上具有相互平行的轴线。气体在气缸中心进入和流动。来自扩散器的气体被排出。辐射通过反射镜进入环形间隙。

3. 发明授权

US4115078A Separation of gaseous mixtures of matter 失效
标题翻译：气体混合物的分离
公开(公告)号：US4115078A
公开(公告)日：1978-09-19
申请号：US579544
申请日：1975-05-21
申请人： Karl Janner , Klaus Gregorius
发明人： Karl Janner , Klaus Gregorius
IPC分类号： B01D59/18 , B01D59/34 , H01S3/00 , H01S3/083 , H01S3/09 , B03C3/38
CPC分类号： B01D59/18 , B01D59/34 , H01S3/0007 , H01S3/083 , H01S3/09
摘要： A gaseous jet of a mixture of matter or isotopes to be separated is penetrated by a polarized electromagnetic wave, e.g., a laser or maser beam. The required frequency is in the vicinity of a resonant frequency of a molecular dipole of the substance to be separated. For deflecting the mixture components and therefore, their separation, the forces on the molecular dipoles produced by the electric and/or the magnetic field are utilized. SUBACKGROUND OF THE INVENTIONThe present invention concerns a method for separating gaseous mixtures of matter or isotopes. The problem of separating mixtures of matter into their individual components occurs frequently in technology. Among this class of problems are, for instance, also the concentration and depletion of individual substances in mixtures of substances, such as, in nuclear technology, the enrichment of fissionable uranium 235, of which only 0.7% is present in the natural isotope mixture of uranium. The methods heretofore applied for this purpose, e.g., gas diffusion installations, are very elaborate and accordingly, also very expensive, particularly because of the very high energy consumption. Other possibilities of reaching this goal are therefore sought. The use of ultracentrifuges is to be viewed in this context also. However, the expense of such apparatus is also very large.SUMMARY OF THE INVENTIONAccording to the present invention, a novel solution of the above problem is achieved, largely avoiding the disadvantages of the methods known heretofore, by directing at least one beam of a polarized electromagnetic wave through a gaseous mixture of matter or isotopes and adjusting the frequencies of the electromagnetic waves so that the individual components of the mixture are selectively influenced differently as far as their dipole behavior is concerned and are segregated by the electric and/or magnetic field of the beam.It is therefore important here that the frequency of the electromagnetic radiation or radiations must be adapted to the kind of substance to be separated. On the other hand, it is then also possible to analyze unknown mixtures of substances qualitatively as well as quantitatively with this method. For this purpose, a radiation source is then required whose frequency can be varied as continuously as possible.
摘要翻译：待分离的物质或同位素混合物的气体射流被极化电磁波（例如激光或激光束）穿透。所要求的频率在被分离物质的分子偶极子的共振频率附近。为了使混合物组分偏转，因此它们的分离，利用由电场和/或磁场产生的分子偶极子上的力。

4. 发明授权

US4342727A Method for the separation of gaseous isotope compounds 失效
标题翻译：气相同位素化合物分离方法
公开(公告)号：US4342727A
公开(公告)日：1982-08-03
申请号：US89520
申请日：1979-10-30
申请人： Karl Janner , Klaus Gregorius
发明人： Karl Janner , Klaus Gregorius
IPC分类号： B01D59/34 , B01D59/50 , B01D59/00
CPC分类号： B01D59/50
摘要： Separation of gaseous isotopes such as UF.sub.6 by adiabatically expanding a gas stream containing the isotopes to cool to a temperature at which condensation or dimers are formed. Selectively exciting by electromagnetic radiation one isotope compound to inhibit condensation or to effect dissociation of dimers containing one isotope compound. Deflecting the flow of the gas stream to effect a change of isotope distribution in the gas stream. Separating by peeling the enriched portion of the gas stream from the remainder depleted portion of the gas stream.
摘要翻译：通过将含有同位素的气流绝热膨胀至冷凝或二聚体形成的温度来分离气态同位素如UF6。通过电磁辐射选择性地激发一种同位素化合物，以抑制冷凝或实现含有一种同位素化合物的二聚体的解离。偏转气流的流动以实现气流中同位素分布的变化。通过将气流的富集部分从气流的剩余部分去除部分分离。

5. 发明授权

US4311674A Method of separating isotopes from gaseous mixtures 失效
标题翻译：从气态混合物中分离同位素的方法
公开(公告)号：US4311674A
公开(公告)日：1982-01-19
申请号：US55917
申请日：1979-07-09
申请人： Karl Janner , Klaus Gregorius , Hans-Joachim Niemann , Arno Kersting , Eberhard Schuster
发明人： Karl Janner , Klaus Gregorius , Hans-Joachim Niemann , Arno Kersting , Eberhard Schuster
IPC分类号： B01D59/34 , B01D59/00 , B01D59/02
CPC分类号： B01D59/34
摘要： Separation of isotopes from a gaseous mixture of substances containing the isotopes by incorporating supplemental gas and adiabatically expanding at an expansion ratio and starting temperature to cool the mixture and effect condensation of at least a portion of the supplemental gas. Laser radiation is applied to effect selective excitation of one isotope component with selective retention of the non-excited isotope component in the condensate. The condensation may be accelerated by generating condensation nuclei. A compression joint may be used to effect a temperature rise of the gaseous mixture and peelers employed to separate the gas stream portion rich in excited isotope component from the portion rich in non-excited isotope component.
摘要翻译：通过加入补充气体并以膨胀比和起始温度绝热膨胀来同位素与含有同位素的气体混合物分离以冷却混合物并实现至少一部分补充气体的冷凝。施加激光辐射以选择性地激发一种同位素组分，同时选择性地保留冷凝物中的非激发同位素组分。可以通过产生冷凝核来加速冷凝。可以使用压缩接头来实现用于将富含激发的同位素组分的气流部分与富含非激发同位素组分的部分分离的气态混合物和剥离器的温度升高。

6. 发明授权

US4286153A Method and apparatus for the separation of isotope mixtures 失效
标题翻译：用于分离同位素混合物的方法和装置
公开(公告)号：US4286153A
公开(公告)日：1981-08-25
申请号：US703784
申请日：1976-07-09
申请人： Karl Janner , Klaus Gregorius , Eberhard Schuster
发明人： Karl Janner , Klaus Gregorius , Eberhard Schuster
IPC分类号： B01D59/34 , B01J19/12 , B01D59/00
CPC分类号： B01J19/121 , B01D59/34
摘要： Method and apparatus for separation of an isotope substance from a mixture of isotope substances such as UF.sub.6 by adiabatically decompressing the mixture in vaporous or gaseous form to cool the mixture to a temperature below 100.degree. K. and irradiating by an electromagnetic wave selectively absorbed by an isotope substance, passing the mixture after cooling and irradiating in a diffuser at a velocity greater than the speed of sound and decelerating to convert the velocity into pressure with reduced velocity of the mixture. The higher pressure results in substantial reduction in operating costs and capital investment.
摘要翻译：将同位素物质与UF6同位素物质的混合物分离的方法和装置，通过将气态或气态混合物绝热减压，将混合物冷却至低于100°K的温度，并通过选择性吸收的电磁波照射同位素物质，冷却后通过混合物并以大于声速和速度的速度在扩散器中照射，以将混合物的速度降低到速度。压力越大，运营成本和资本投入大幅度下降。

7. 发明授权

US4431136A Slit nozzle and fast-acting shutoff valve 失效
标题翻译：狭缝喷嘴和快速截止阀
公开(公告)号：US4431136A
公开(公告)日：1984-02-14
申请号：US242920
申请日：1981-03-12
申请人： Karl Janner , Klaus Gregorius
发明人： Karl Janner , Klaus Gregorius
IPC分类号： B01D59/34 , B05C5/02 , B01D59/00
CPC分类号： B01D59/34 , B05C5/0262
摘要： Slit nozzle and fast-acting shutoff valve for producing very brief gas flows accurately reproducible with respect to pulse width and spacing such as are required with pulse laser excitation for separation processes and photochemical processes including a first and a second nozzle part defining a nozzle slit therebetween, the first and the second nozzle parts forming the slit nozzle and, simultaneously, the fast-acting shutoff valve, at least one of the nozzle parts being rapidly movable for varying the width of the nozzle slit practically between zero and a nominal size.
摘要翻译：狭缝喷嘴和快速截止阀，用于产生非常简单的气体流动，相对于脉冲宽度和间隔精确地可再现，例如用于分离过程和光化学过程的脉冲激光激发所需的，包括限定其间的喷嘴狭缝的第一和第二喷嘴部分，形成狭缝喷嘴的第一和第二喷嘴部分，同时快速切断阀，至少一个喷嘴部分可以快速移动，以实际上在零和标称尺寸之间改变喷嘴狭缝的宽度。

8. 发明授权

US4138297A Method for isotope separation by means of coherent electromagnetic radiation 失效
标题翻译：通过相干电磁辐射同位素分离的方法
公开(公告)号：US4138297A
公开(公告)日：1979-02-06
申请号：US773505
申请日：1977-03-02
申请人： Karl Janner , Klaus Gregorius , Heinz Stehle
发明人： Karl Janner , Klaus Gregorius , Heinz Stehle
IPC分类号： B01D59/34 , G02B27/00 , B01J1/10
CPC分类号： B01D59/34
摘要： Method for isotope separation or enrichment in a vaporous mixture of compounds containing the isotopes to selectively excite the group of molecules containing one isotope by means of coherent, polarized electromagnetic radiation (lasers) in which a frequency shift is prevented or greatly reduced and the excitation state can be driven very high to beyond the dissociation limit. This is accomplished by adjusting the frequency and field strength of the radiation so that the dipole moment of the group of molecules to be excited, oscillates, at least at the final amplitude, mainly in phase opposition to the exciting field, and the other group of molecules mainly in phase with the exciting field. In another procedure the radiation has a frequency closer to the resonance frequency of the group of molecules to be separated and is of the order of magnitude of the isotope-determined frequency difference, and both groups of molecules operate in phase opposition.
摘要翻译：含有同位素的化合物的汽相混合物中同位素分离或富集的方法，用于通过相干偏振电磁辐射（激光）选择性地激发含有一个同位素的分子组，其中抑制了频移或大大降低了激发态可以驱动非常高，超过解离极限。这是通过调节辐射的频率和场强来实现的，使得待激发的分子组的偶极矩至少在最后的幅度振荡，主要与激励场相反，而另一组分子主要与激发场相同步。在另一个过程中，辐射具有更接近待分离的分子组的共振频率的频率，并且是同位素确定的频率差的数量级，并且两组分子以相反方向操作。

9. 发明授权

US4025787A Separation of mixtures of gaseous isotopes 失效
标题翻译：气相同位素混合物的分离
公开(公告)号：US4025787A
公开(公告)日：1977-05-24
申请号：US588183
申请日：1975-06-19
申请人： Karl Janner , Klaus Gregorius
发明人： Karl Janner , Klaus Gregorius
IPC分类号： B01D59/50 , G21K1/08 , H01J49/34 , H01J39/34
CPC分类号： H01J49/34 , B01D59/50 , G21K1/08
摘要： A standing electromagnetic wave haing nodes, penetrates through a gaseous jet of the mixture of the isotopes to be separated, while relative motion takes place between the wave and mixture in such a manner that the isotopes are prevented from dwelling in the vicinity of the wave nodes while the isotopes are traversed by the electromagnetic wave. By adjusting the frequency of the electromagnetic wave so that the individual isotopes of the mixture are selectively influenced differently as far as their dipole behavior is concerned, they can be segregated by the electric and/or magnetic field of the wave. Undesirable effects of such dwelling can also be reduced by the angularity at which the wave penetrates the gaseous jet.
摘要翻译：站立的电磁波发出节点，穿过要分离的同位素混合物的气体射流，同时在波和混合物之间发生相对运动，使得同位素被阻止在波节附近居住而同位素则被电磁波穿过。通过调节电磁波的频率，使得混合物的各个同位素就其偶极子行为而有选择性的影响，可以通过波的电场和/或磁场分离。这种住宅的不良影响也可以通过波浪穿透气体射流的角度来降低。

10. 发明授权

US09149737B2 Purification of multi-specific receptors 有权
标题翻译：多特异性受体的纯化
公开(公告)号：US09149737B2
公开(公告)日：2015-10-06
申请号：US13496006
申请日：2010-09-16
申请人： Nicolas Otto Krogh , Klaus Gregorius
发明人： Nicolas Otto Krogh , Klaus Gregorius
IPC分类号： A61K31/74 , B01D15/38 , B01J20/26 , B01D15/18
CPC分类号： A61K31/74 , B01D15/1807 , B01D15/3804 , B01J20/26 , B01J20/268
摘要： Disclosed is a method for preparing a composition enriched for receptors (typically molecular impringet polymers, MIPs) that bind an agent, where said receptors each specifically bind at least two discrete sites on said agent, by subjecting a sample of receptors to a first step of affinity purification with the agent where one binding site on the agent is non-accessible for binding to the receptors and subsequently subjecting the purified receptors to at least one further step of affinity purification with the agent where a second binding site on the agent is non-accessible. Also disclosed is a method for treatment, amelioration or prophylaxis of a disease selected from the group consisting of phenylketonuria (PKU, Følling's disease), hyperphenylalaninemia (HPA), alcaptonuria (black urine disease), tyrosinemia, hypertyrosinemia, myasthenia gravis, histidinemia, urocanic aciduria, maple syrup urine disease (MSUD), isovaleric acidemia (isovaleryl-CoA dehydrogenase deficiency), homocystinuria, propionic acidemia, methylmalonic acidemia, and glutaric aciduria Type 1 (GA-I), galactosemia, comprising administering to the gastrointestinal tract of a patient in need thereof an effective amount of a composition of molecular imprinted polymers (MIPs), said composition being capable of binding a symptom provoking agent of said disease.
摘要翻译：公开了一种制备富含结合试剂的受体（通常是分子侵入聚合物，MIP）的组合物的方法，其中所述受体各自特异性结合所述试剂上的至少两个离散位点，通过使受体样品经受第一步与试剂亲和纯化，其中试剂上的一个结合位点不能与受体结合，然后使纯化的受体与试剂上的第二结合位点不相容的至少一个进一步的亲和纯化步骤进行，无障碍。还公开了治疗，改善或预防选自苯丙酮尿症（PKU，Følling氏病），高苯丙氨酸血症（HPA），尿酸血症（黑尿病），酪氨酸血症，高铁血症，重症肌无力，组氨酸血症，尿路感染酸尿，枫糖尿病（MSUD），异戊酸 - 异丙酰脱氢酶缺乏症，同型胱尿蛋白尿，丙酸血症，甲基丙二酸血症和戊二酸1型糖尿病（GA-I），半乳糖血症，包括给予患者胃肠道在有需要的情况下，有效量的分子印迹聚合物（MIP）的组合物，所述组合物能够结合所述疾病的症状发作剂。

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