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1. 发明授权

US5530149A Azolylmethyl-fluorocyclopropyl derivatives 失效
公开(公告)号：US5530149A
公开(公告)日：1996-06-25
申请号：US462730
申请日：1995-06-05
申请人： Jurgen Scherkenbeck , Thomas Himmler , Stefan Bohm , Hermann Hagemann , Klaus Stroech , Stefan Dutzmann , Heinz-Wilhelm Dehne , Gerd Hanssler
发明人： Jurgen Scherkenbeck , Thomas Himmler , Stefan Bohm , Hermann Hagemann , Klaus Stroech , Stefan Dutzmann , Heinz-Wilhelm Dehne , Gerd Hanssler
IPC分类号： A01N43/653 , C07D249/08 , C07D301/02 , C07D303/08 , C07D303/18 , C07D303/20 , C07D521/00
CPC分类号： C07D249/08 , A01N43/653 , C07D231/12 , C07D233/56
摘要： New azolylmethyl-fluorocyclopropyl derivatives of the formula ##STR1## in which R represents ##STR2## and addition products thereof which acids or metal salts are very effective for combating fungi.New oxiranes of the formula ##STR3## in which R has the abovementioned meaning, are valuable intermediates for the preparation of compounds of the formula (I).

2. 发明授权

US5288883A Oxirane intermediates for azolyl-propanol fungicides 失效
标题翻译：环氧乙烷中间体用于唑基丙醇杀真菌剂
公开(公告)号：US5288883A
公开(公告)日：1994-02-22
申请号：US997407
申请日：1992-12-28
申请人： Jurgen Scherkenbeck , Thomas Himmler , Klaus Stroech , Stefan Dutzmann , Gerd Hanssler , Heinz-Wilhelm Dehne
发明人： Jurgen Scherkenbeck , Thomas Himmler , Klaus Stroech , Stefan Dutzmann , Gerd Hanssler , Heinz-Wilhelm Dehne
IPC分类号： A01N43/50 , A01N43/653 , C07D233/60 , C07D249/08 , C07D301/02 , C07D303/08 , C07D303/12 , C07D303/22 , C07D405/06 , C07D407/04 , C07D521/00 , C07C303/08 , C07C303/48 , C07D303/48
CPC分类号： C07D249/08 , A01N43/653 , C07D231/12 , C07D233/56 , C07D303/08
摘要： Fungicidal azolyl-propanols of the formula ##STR1## in which R represents halogenoalkyl, halogenoalkenyl, a 2-phenoxy-isopropyl radical, ##STR2## Y represents nitrogen or a CH group, Z represents halogen, alkyl, halogenoalkyl, alkoxy, halogenoalkoxy, cyano, phenoxy, halophenoxy, or optionally substituted aryl,m represents the number 0, 1, 2, or 3,and addition products thereof with acids and metal salts.
摘要翻译：其中R表示卤代烷基，卤代烯基，2-苯氧基 - 异丙基，Y或Y表示式（I）的杀真菌唑基 - 丙醇代表氮或CH基，Z表示卤素，烷基，卤代烷基，烷氧基，卤代烷氧基，氰基，苯氧基，卤代苯氧基或任选取代的芳基，m表示数0,1,2或3，及其与酸和金属盐的加成产物。

3. 发明授权

US5462955A Azolylmethyl-fluorocyclopropyl derivatives 失效
标题翻译：唑基甲基 - 氟代环丙基衍生物
公开(公告)号：US5462955A
公开(公告)日：1995-10-31
申请号：US197016
申请日：1994-02-15
申请人： Jurgen Scherkenbeck , Thomas Himmler , Stefan Bohm , Hermann Hagemann , Klaus Stroech , Stefan Dutzmann , Heinz-Wilhelm Dehne , Gerd Hanssler
发明人： Jurgen Scherkenbeck , Thomas Himmler , Stefan Bohm , Hermann Hagemann , Klaus Stroech , Stefan Dutzmann , Heinz-Wilhelm Dehne , Gerd Hanssler
IPC分类号： A01N43/653 , C07D249/08 , C07D301/02 , C07D303/08 , C07D303/18 , C07D303/20 , C07D521/00
CPC分类号： C07D249/08 , A01N43/653 , C07D231/12 , C07D233/56
摘要： New azolylmethyl-fluorocyclopropyl derivatives of the formula ##STR1## in which R represents ##STR2## and addition products thereof which acids or metal salts are very effective for combating fungi.New oxiranes of the formula ##STR3## in which R has the abovementioned meaning, are valuable intermediates for the preparation of compounds of the formula (I).
摘要翻译：式（Ⅰ）的新的吡唑基甲基 - 氟代环丙基衍生物，其中R代表

4. 发明授权

US5162358A Halogenoalkyl-azolyl derivatives 失效
标题翻译：异恶唑烷基衍生物
公开(公告)号：US5162358A
公开(公告)日：1992-11-10
申请号：US737619
申请日：1991-07-30
申请人： Manfred Jautelat , Jurgen Scherkenbeck , Klaus Stroech , Stefan Dutzmann , Heinz-Wilhelm Dehne , Gerd Hanssler , Harl-Heinz Kuck
发明人： Manfred Jautelat , Jurgen Scherkenbeck , Klaus Stroech , Stefan Dutzmann , Heinz-Wilhelm Dehne , Gerd Hanssler , Harl-Heinz Kuck
IPC分类号： A01N43/50 , A01N43/653 , C07D233/60 , C07D249/08 , C07D521/00
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07D233/56 , C07D249/08
摘要： New halogenoalkyl-azolyl derivatives of the formula ##STR1## in which R.sup.1 represents optionally substituted alkyl, optionally substituted alkenyl or optionally substituted cycloalkyl,R.sup.2 represents hydrogen, alkyl, alkenyl, acyl or aralkyl,X.sup.1 represents halogen,X.sup.2 represents halogen,n represents 0 or 1 andY represents nitrogen or a CH group,and acid addition salts and metal salt complexes thereofare very effective for combating undesired microorganisms in plant protection and in the preservation of materials.
摘要翻译：式（I）的新的卤代烷基 - 唑基衍生物，其中R 1表示任选取代的烷基，任选取代的烯基或任选取代的环烷基，R 2表示氢，烷基，烯基，酰基或芳烷基，X 1表示卤素， n表示0或1，Y表示氮或CH基，其酸加成盐和金属盐络合物对于防止植物保护和材料保存中的不希望的微生物非常有效。

5. 发明授权

US5334608A Azolymethyl-cyclopropyl derivatives 失效
标题翻译：芳基甲基 - 环丙基衍生物
公开(公告)号：US5334608A
公开(公告)日：1994-08-02
申请号：US021390
申请日：1993-02-23
申请人： Jurgen Scherkenbeck , Thomas Himmler , Hermann Hagemann , Stefan Dutzmann , Heinz-Wilhelm Dehne , Gerd Hanssler
发明人： Jurgen Scherkenbeck , Thomas Himmler , Hermann Hagemann , Stefan Dutzmann , Heinz-Wilhelm Dehne , Gerd Hanssler
IPC分类号： A01N53/12 , A01N43/653 , A01N53/04 , A61K31/41 , C07D249/08 , C07D301/02 , C07D303/46 , C07D521/00
CPC分类号： C07D249/08 , A01N43/653 , C07D231/12 , C07D233/56 , C07D303/46
摘要： New azolylmethyl-cyclopropyl derivatives of the formula ##STR1## in which R represents cyano or a group of the formula ##STR2## Z represents halogen, alkyl having 1 to 4 carbon atoms, halogenoalkyl having 1 to 4 carbon atoms and 1 to 5 halogen atoms, alkoxy having 1 to 4 carbon atoms, halogenoalkoxy having 1 to 4 carbon atoms and 1 to 5 halogen atoms, or alkoximininoalkyl having 1 to 4 carbon atoms in the alkoxy group and 1 to 4 carbon atoms in the alkyl group andm represents the numbers 0, 1 or 2, and addition products thereof with acids or metal salts are very effective for combating fungi.New oxiranes of the formula ##STR3## in which Z and m have the abovementioned meanings, are valuable intermediates for the preparation of compounds of the formula (I).
摘要翻译：其中R表示氰基的式（I）的新的唑基甲基 - 环丙基衍生物或下式的基团Z表示卤素，具有1至4个碳原子的烷基，具有1至4个碳原子的卤代烷基和1至 5个卤素原子，1〜4个碳原子的烷氧基，1〜4个碳原子的卤代烷氧基和1〜5个卤素原子，烷氧基中1〜4个碳原子的烷基肟基，烷基中1〜4个碳原子代表数字0,1或2，其与酸或金属盐的加成产物对抗真菌非常有效。其中Z和m具有上述含义的式“IMAGE”（II）的新环氧烷是制备式（I）化合物的有价值的中间体。

6. 发明授权

US5216180A Microbicidal hydroxyethyl-cyclopropyl-azolyl derivatives 失效
标题翻译：杀微生物羟乙基 - 环丙基 - 唑基衍生物
公开(公告)号：US5216180A
公开(公告)日：1993-06-01
申请号：US786481
申请日：1991-11-01
申请人： Jurgen Scherkenbeck , Monika Frie , Klaus Stroech , Thomas Himmler , Georg-W. Ludwig , Wilhelm Brandes , Stefan Dutzmann
发明人： Jurgen Scherkenbeck , Monika Frie , Klaus Stroech , Thomas Himmler , Georg-W. Ludwig , Wilhelm Brandes , Stefan Dutzmann
IPC分类号： A01N43/50 , A01N43/653 , C07C33/44 , C07C33/50 , C07C45/74 , C07C49/577 , C07D303/22 , C07D307/46 , C07D333/16 , C07D407/06 , C07D407/14 , C07D409/06 , C07D409/14 , C07D521/00
CPC分类号： C07D303/22 , A01N43/50 , A01N43/653 , C07C33/44 , C07C33/50 , C07C45/74 , C07C49/577 , C07D231/12 , C07D233/56 , C07D249/08 , C07D307/46 , C07D333/16 , C07D407/06 , C07D407/14 , C07D409/06 , C07D409/14
摘要： A herbicidal hydroxyethyl-cyclopropyl-azolyl derivative of the formula ##STR1## in which R.sup.1 represents halogen, phenyl or the grouping --Z-R.sup.3, whereinZ represents oxygen, sulphur, SO or SO.sub.2 andR.sup.3 represents alkyl, phenyl or benzyl,R.sup.2 represents alkenyl, optionally substituted furyl, optionally substituted thienyl or the radical of the formula ##STR2## wherein R.sup.4 represents difluoromethoxy, 1,1,2,2-tetrafluoroethoxy, 1,1,2-trifluoro-2-chloro-ethoxy, cyano, formyl, alkoximinoalkyl, carbalkoxy, dialkoxyalkyl, phenoxyalkyl which is optionally substituted in the phenyl moiety by halogen, or benzyloxy which is optionally substituted in the phenyl moiety by halogen andR.sup.5 represents hydrogen or halogen, orR.sup.4 and R.sup.5 are linked in the ortho-position and together represent --O--CH.sub.2 --O--, orR.sup.2 represents the radical of the formula ##STR3## in which R.sup.6 represents difluoromethoxy, 1,1,2,2-tetrafluoroethoxy or 1,1,2-trifluoro-2-chloro-ethoxy, orR.sup.2 also represents phenyl which is optionally substituted by halogen and/or phenyl if Y represents the grouping ##STR4## X represents nitrogen or a CH group and Y represents the groupings --CH.sub.2 -CH.sub.2 --, --CH.dbd.CH--, --C.tbd.C-- or ##STR5## or an acid or metal salt addition product thereof.
摘要翻译：式（I）的除草羟乙基 - 环丙基 - 唑基衍生物，其中R 1表示卤素，苯基或基团-Z-R 3，其中Z表示氧，硫，SO或SO 2，R 3表示烷基，苯基或苄基，R 2表示烯基，任选取代的呋喃基，任选取代的噻吩基或式的基团其中R 4表示二氟甲氧基，1,1,2,2-四氟乙氧基，1,1,2-三氟-2-氯乙氧基，氰基，甲酰基，肟基烷基，烷氧基，二烷氧基烷基，在苯基部分被卤素任意取代的苯氧基烷基，或在苯基部分被卤素任意取代的苄氧基，R5代表氢或卤素，或R4和R5连接在邻位并且一起表示-O-CH 2 -O-，或R 2表示式“IMAGE”的基团，其中R 6表示二氟甲氧基，1,1,2,2-四氟乙氧基或1,1,2-三氟-2- 氯乙氧基，或R2也表示任选取代的苯基如果Y表示分组，则由卤素和/或苯基发生。X表示氮或CH基，Y表示分组-CH 2 -CH 2 - ， - CH = CH - ， - C 3BOND C或或酸或金属盐加成产物。

7. 发明授权

US5096912A Microbicidal hydroxyethyl-cyclopropyl-azolyl derivatives 失效
标题翻译：微生物羟丙基 - 环丙基 - 氨基醇衍生物
公开(公告)号：US5096912A
公开(公告)日：1992-03-17
申请号：US535266
申请日：1990-06-08
申请人： Jurgen Scherkenbeck , Monika Frie , Klaus Stroech , Thomas Himmler , Georg-W. Ludwig , Wilhelm Brandes , Stefan Dutzmann
发明人： Jurgen Scherkenbeck , Monika Frie , Klaus Stroech , Thomas Himmler , Georg-W. Ludwig , Wilhelm Brandes , Stefan Dutzmann
IPC分类号： A01N43/50 , A01N43/653 , C07C33/44 , C07C33/50 , C07C45/74 , C07C49/577 , C07D233/60 , C07D249/08 , C07D303/22 , C07D307/46 , C07D333/16 , C07D405/06 , C07D407/06 , C07D407/14 , C07D409/06 , C07D409/14 , C07D521/00
CPC分类号： C07D303/22 , A01N43/50 , A01N43/653 , C07C33/44 , C07C33/50 , C07C45/74 , C07C49/577 , C07D231/12 , C07D233/56 , C07D249/08 , C07D307/46 , C07D333/16 , C07D407/06 , C07D407/14 , C07D409/06 , C07D409/14
摘要： A microbicidal hydroxyethyl-cyclopropyl-azolyl derivative of the formula ##STR1## in which R.sup.1 represents halogen, phenyl or the grouping --Z--R.sup.3, whereinZ represents oxygen, sulphur, SO or SO.sub.2 andR.sup.3 represents alkyl, phenyl or benzyl,R.sup.2 represents alkenyl, optionally substituted furyl, optionally substituted thienyl or the radical of the formula ##STR2## wherein R.sup.4 represents difluoromethoxy, 1,1,2,2-tetrafluoroethoxy, 1,1,2-trifluoro-2-chloro-ethoxy, cyano, formyl, alkoximinoalkyl, carbalkoxy, dialkoxyalkyl, phenoxyalkyl which is optionally substituted in the phenyl moiety by halogen, or benzyloxy which is optionally substituted in the phenyl moiety by halogen andR.sup.5 represents hydrogen or halogen, orR.sup.4 and R.sup.5 are linked in the ortho-position and together represent --O--CH.sub.2 --O--, orR.sup.2 represents the radical of the formula ##STR3## in which R.sup.6 represents difluoromethoxy, 1,1,2,2-tetrafluoroethoxy or 1,1,2-trifluoro-2-chloro-ethoxy, orR.sup.2 also represents phenyl which is optionally substituted by halogen and/or phenyl if Y represents the grouping ##STR4## X represents nitrogen or a CH group and Y represents the groupings --CH.sub.2 --CH.sub.2 --, --CH.dbd.CH--, --C.tbd.C--or ##STR5## or an acid or metal salt addition product thereof.
摘要翻译：式（I）的杀微生物羟乙基 - 环丙基 - 唑基衍生物，其中R 1表示卤素，苯基或基团-Z-R 3，其中Z表示氧，硫，SO或SO 2，R 3表示烷基，苯基或苄基，R 2表示烯基，任选取代的呋喃基，任选取代的噻吩基或式的基团其中R 4表示二氟甲氧基，1,1,2,2-四氟乙氧基，1,1,2-三氟-2-氯乙氧基，氰基，甲酰基，肟基烷基，烷氧基，二烷氧基烷基，在苯基部分被卤素任意取代的苯氧基烷基，或在苯基部分被卤素任意取代的苄氧基，R5代表氢或卤素，或R4和R5连接在邻位并且一起表示-O-CH 2 -O-，或R 2表示式“IMAGE”的基团，其中R 6表示二氟甲氧基，1,1,2,2-四氟乙氧基或1,1,2-三氟-2- 氯乙氧基或R2也表示任选被取代的苯基如果Y表示分组，则由卤素和/或苯基引发。X表示氮或CH基，Y表示分组-CH 2 -CH 2 - ， - CH = CH - ， - C 3BOND C - 或或酸或金属盐加成产物。

8. 发明授权

US5304568A Ethyl-triazolyl derivatives 失效
标题翻译：乙基 - 三唑基衍生物
公开(公告)号：US5304568A
公开(公告)日：1994-04-19
申请号：US103872
申请日：1993-08-06
申请人： Jurgen Scherkenbeck , Michael Lindemann , Stefan Dutzmann , Heinz-Wilhelm Dehne
发明人： Jurgen Scherkenbeck , Michael Lindemann , Stefan Dutzmann , Heinz-Wilhelm Dehne
IPC分类号： A01N43/653 , C07D249/08 , C07D521/00
CPC分类号： C07D231/12 , A01N43/653 , C07D233/56 , C07D249/08
摘要： New ethyl-triazolyl derivatives of the formula ##STR1## in which R represents halogen,X.sup.1 represents fluorine, chlorine or bromine,X.sup.2 represents fluorine, chlorine or bromine,Z represents halogen, alkyl having 1 to 4 carbon atoms, alkoxy having 1 to 4 carbon atoms, ethyl having 1 or 2 carbon atoms and 1 to 5 halogen atoms, halogenoalkoxy having 1 or 2 carbon atoms and 1 to 5 halogen atoms, phenyl, phenoxy, nitro or alkoximinoalkyl having 1 to 4 carbon atoms in the alkoxy moiety and 1 to 4 carbon atoms in the alkyl moiety andm represents the numbers 0, 1, 2 or 3,and addition products thereof with acids or metal salts are very effective for combating fungi.Novel ethyl-triazolyl derivatives of the formula ##STR2## in which R, Z and m have the abovementioned meanings,and addition products thereof with acids or metal salts are very effective for combating fungi.The ethyl-triazolyl derivatives of the formula (II) are also valuable intermediates for the synthesis of ethyl-triazolyl derivatives of the formula (I).
摘要翻译：新的式（I）的乙基 - 三唑基衍生物，其中R表示卤素，X 1表示氟，氯或溴，X 2表示氟，氯或溴，Z表示卤素，具有1至4个碳原子的烷基，具有 1至4个碳原子，具有1或2个碳原子和1至5个卤素原子的乙基，具有1或2个碳原子和1至5个卤素原子的卤代烷氧基，在烷氧基中具有1至4个碳原子的苯基，苯氧基，硝基或烷肟基烷基烷基部分和1至4个碳原子，m表示数字0,1,2或3，其与酸或金属盐的加成产物对抗真菌非常有效。新颖的式（II）的乙基 - 三唑基衍生物，其中R，Z和m具有上述含义，其与酸或金属盐的加成产物对抗真菌是非常有效的。式（II）的乙基 - 三唑基衍生物也是用于合成式（I）的乙基 - 三唑基衍生物的有价值的中间体。

9. 发明授权

US5266584A Ethyl-triazolyl derivatives 失效
标题翻译：乙基 - 三唑基衍生物
公开(公告)号：US5266584A
公开(公告)日：1993-11-30
申请号：US42339
申请日：1993-04-02
申请人： Jurgen Scherkenbeck , Michael Lindemann , Stefan Dutzmann , Heinz-Wilhelm Dehne
发明人： Jurgen Scherkenbeck , Michael Lindemann , Stefan Dutzmann , Heinz-Wilhelm Dehne
IPC分类号： A01N43/653 , C07D249/08 , C07D521/00
CPC分类号： C07D231/12 , A01N43/653 , C07D233/56 , C07D249/08
摘要： New Ethyl-triazolyl derivatives of the formula ##STR1## in which R represents halogen,X.sup.1 represents fluorine, chlorine or bromine,X.sup.2 represents fluorine, chlorine or bromine,Z represents halogen, alkyl having 1 to 4 carbon atoms, alkoxy having 1 to 4 carbon atoms, ethyl having 1 or 2 carbon atoms and 1 to 5 halogen atoms, halogenoalkoxy having 1 or 2 carbon atoms and 1 to 5 halogen atoms, phenyl, phenoxy, nitro or alkoximinoalkyl having 1 to 4 carbon atoms in the alkoxy moiety and 1 to 4 carbon atoms in the alkyl moiety andm represents the numbers 0, 1, 2 or 3,and addition products thereof with acids or metal salts are very effective for combating fungi.
摘要翻译：新的式（I）的乙基 - 三唑基衍生物，其中R表示卤素，X 1表示氟，氯或溴，X 2表示氟，氯或溴，Z表示卤素，具有1至4个碳原子的烷基， 1至4个碳原子，具有1或2个碳原子和1至5个卤素原子的乙基，具有1或2个碳原子和1至5个卤素原子的卤代烷氧基，在烷氧基中具有1至4个碳原子的苯基，苯氧基，硝基或烷肟基烷基烷基部分和1至4个碳原子，m表示数字0,1,2或3，其与酸或金属盐的加成产物对抗真菌非常有效。

10. 发明授权

US5140035A Fungicidal triazolymethyl-cyclopropyl derivatives 失效
标题翻译：杀真菌三唑甲基环丙基衍生物
公开(公告)号：US5140035A
公开(公告)日：1992-08-18
申请号：US629284
申请日：1990-12-17
申请人： Jurgen Scherkenbeck , Klaus Stroech , Burghard Fugmann , Stefan Dutzmann
发明人： Jurgen Scherkenbeck , Klaus Stroech , Burghard Fugmann , Stefan Dutzmann
IPC分类号： A01N43/653 , C07C45/00 , C07C45/45 , C07C49/577 , C07C49/84 , C07C51/06 , C07C62/08 , C07C259/08 , C07D249/08 , C07D301/02 , C07D303/22 , C07D521/00
CPC分类号： C07D303/22 , A01N43/653 , C07C259/08 , C07C45/004 , C07C45/455 , C07C49/577 , C07C49/84 , C07C62/08 , C07D231/12 , C07D233/56 , C07D249/08 , C07C2101/02
摘要： Fungicidal triazolylmethyl-cyclopropyl derivatives of the formula ##STR1## in which R represents a radical of the formula ##STR2## in which Z represents halogen, alkyl having 1 to 4 carbon atoms, alkoxy having 1 to 4 carbon atoms, alkylthio having 1 to 4 carbon atoms, halogenoalkyl having 1 or 2 carbon atoms and 1 to 5 halogen atoms, halogenoalkoxy having 1 or 2 carbon atoms and 1 to 5 halogen atoms, halogenoalkylthio having 1 or 2 carbon atoms and 1 to 5 halogen atoms, phenyl which is optionally substituted by at least one of alkyl having 1 or 2 carbon atoms and halogen, or represents phenoxy which is optionally substituted by at least one of alkyl having 1 or 2 carbon atoms and halogen, andm represents the numbers 0, 1, 2 or 3,R.sup.1 represents halogen, alkyl having 1 to 4 carbon atoms or alkoxy having 1 to 4 carbon atoms,n represents the numbers 0, 1 or 2,R.sup.2 represents halogen, alkyl having 1 to 4 carbon atoms or alkoxy having 1 to 4 carbon atoms andp represents the numbers 0, 1 or 2, andX represents CH.sub.2 or a direct bond,and addition products thereof with acids and metal salts.
摘要翻译：式（I）的杀真菌三唑基甲基 - 环丙基衍生物，其中R表示式为“IMAGE”的基团，其中Z表示卤素，具有1至4个碳原子的烷基，具有1至4个碳原子的烷氧基， 1至4个碳原子，具有1或2个碳原子和1至5个卤素原子的卤代烷基，1或2个碳原子和1至5个卤素原子的卤代烷氧基，1或2个碳原子的卤代烷硫基和1至5个卤素原子，任选被至少一个具有1或2个碳原子的烷基和卤素取代，或表示任选被至少一个具有1或2个碳原子的烷基和卤素取代的苯氧基，m表示数字0,1,2 或3，R 1表示卤素，具有1至4个碳原子的烷基或具有1至4个碳原子的烷氧基，n表示0,1或2，R2表示卤素，具有1至4个碳原子的烷基或具有1至4个碳原子的烷氧基碳原子，p表示数字0,1 或2，X表示CH 2或直接键，并且其与酸和金属盐的加成产物。

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