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    • 1. 发明授权
    • Electroconductive elastic member, elastic member and image formation equipment
    • 导电弹性件,弹性件和成像设备
    • US06572791B2
    • 2003-06-03
    • US09730777
    • 2000-12-07
    • Junji SakataHirotaka YamazakiTadashi NakajimaTakahiro Kawagoe
    • Junji SakataHirotaka YamazakiTadashi NakajimaTakahiro Kawagoe
    • H01B100
    • C08J9/0066C08G18/12C08G18/4072C08G18/4837C08G18/632C08G2101/0008C08G2101/0058C08G2101/0066C08J2375/04Y10S206/823Y10S493/96C08G18/302
    • There is disclosed an elastic member constituted of polyurethane foam obtained by agitationally mixing with water, a urethane prepolymer synthesized from a polyol and a polyisocyanate, characterized by simultaneously employing as polyols, a (A) polymer polyol synthesized from a polyether polyol as a basis, comprising at least 70% by weight of oxypropylene moiety; and a (B) hydrophilic polyether polyol comprising at least 50% by weight of oxyethylene moiety, or simultaneously employing as polyols, the component (A), the component (B) and a (C) polyether polyol comprising at least 70% by weight of oxypropylene moiety. The above elastic member is simultaneously imparted with excellent characteristics such as low hardness, fine cells, low residual compressive strain, high strength and the like. The polyurethane foam which constitutes the elastic member can be produced by free foaming. The electroconductive elastic member which is produced by using an aqueous dispersion of carbon instead of water is imparted with low electric resistance in addition to the above excellent characteristics.
    • 公开了一种弹性构件,其由通过与水搅拌混合得到的聚氨酯泡沫构成,由多元醇和多异氰酸酯合成的氨基甲酸酯预聚物,其特征在于同时使用作为多元醇的(A)聚合物多元醇合成的聚合物多元醇作为基础, 包含至少70重量%的氧化丙烯部分; 和(B)亲水性聚醚多元醇,其包含至少50重量%的氧化乙烯部分,或同时使用作为多元醇的组分(A),组分(B)和(C)聚醚多元醇,其包含至少70重量% 的氧亚丙基部分。 上述弹性构件同时具有低硬度,细小电池​​,低残余压缩应变,高强度等优异的特性。 构成弹性部件的聚氨酯泡沫体可以通过自由发泡而制造。 通过使用碳水分散体代替水制造的导电弹性构件除了上述优异的特性外还具有低电阻。
    • 4. 发明授权
    • Elastic member and image formation equipment
    • 弹性件和成像设备
    • US06818674B2
    • 2004-11-16
    • US09985771
    • 2001-11-06
    • Junji SakataHirotaka Yamazaki
    • Junji SakataHirotaka Yamazaki
    • C08G1828
    • C08J9/0061C08J2375/04C08J2483/00G03G15/0808G03G2215/0869
    • There are disclosed an elastic member which comprises (A) polyurethane foam obtained by agitationally mixing a foaming agent, a foam stabiizer and a urethane prepolymer synthesized from a polyol and a polyisocyanate in the presence of a modified silicone, or (B) polyurethane foam obtained by agitationally mixing a polyol, a polyisocyanate, a modified silicone oil bearing a functional group reactive with a polyisocyanate, a foaming agent and a foam stabiizer comprising a polyether modified silicone containing 50 to 100% by weight of a polyoxyethylene unit in the polyether moiety; image formation equipment equipped with the above elastic member; and a toner supply roller which is composed of a foamed elastic member mounted on a developing apparatus and which has a compression spring constant in the range of 0.25 to 5.0 N/mm and a surface friction resistance in the range of 0.4 to 1.2 N. The elastic member has low surface-friction resistance and uniform fine cells, and is well suited as a member for image formation equipment.
    • 公开了一种弹性构件,其包含(A)通过搅拌混合发泡剂,泡沫稳定剂和由多元醇和多异氰酸酯合成的氨基甲酸酯预聚物在改性聚硅氧烷的存在下获得的聚氨酯泡沫,或(B)聚氨酯泡沫,获得的聚氨酯泡沫 通过搅拌混合多元醇,多异氰酸酯,具有与多异氰酸酯反应的官能团的改性硅油,发泡剂和泡沫稳定剂,其包含聚醚部分中含有50至100重量%的聚氧乙烯单元的聚醚改性硅氧烷; 配备上述弹性构件的成像设备; 以及调色剂供应辊,其由安装在显影装置上的发泡弹性构件组成,并且压缩弹簧的常数范围为0.25至5.0N / mm,表面摩擦阻力在0.4至1.2N的范围内。 弹性构件具有低的表面摩擦阻力和均匀的细小单元,并且非常适合作为图像形成设备的构件。
    • 7. 发明授权
    • Foamed elastic member for use in image forming apparatus
    • 用于图像形成装置的发泡弹性构件
    • US06810227B2
    • 2004-10-26
    • US10303999
    • 2002-11-26
    • Junji SakataHirotaka Yamazaki
    • Junji SakataHirotaka Yamazaki
    • G03G1508
    • G03G15/0808G03G2215/0869
    • A foamed elastic member according to the invention comprises an elastic member made of polyurethane foam molded by an in-mold foaming process, and has properly determined physical properties of its surface and/or properly determined shape and arrangement of foam cells opened on the surface. The foamed elastic member is suitably used for a toner feed roller in a developing device for electrically charging toner from a toner storage portion, feeding the toner onto the surface of a photosensitive member and forming a toner image corresponding to an electrostatic latent image on the surface of the photosensitive member. In this case, it exhibits an excellent toner scraping and toner feeding performance, to form an image free from such defect as irregularity in pitch and density, or free from reduction in density.
    • 根据本发明的泡沫弹性构件包括由通过模内发泡方法模制的聚氨酯泡沫制成的弹性构件,并且具有适当确定的表面的物理性质和/或在表面上开口的泡沫单元的适当确定的形状和布置。 泡沫弹性构件适合用于显影装置中的调色剂供给辊,用于从调色剂存储部分对调色剂进行充电,将调色剂供给到感光构件的表面上,并在表面上形成对应于静电潜像的调色剂图像 的光敏元件。 在这种情况下,它表现出优异的调色剂刮擦和调色剂进料性能,以形成没有间距和密度不规则的缺陷或没有密度降低的图像。
    • 9. 发明申请
    • CONDUCTIVE ELASTIC ROLLER AND IMAGE FORMING APPARATUS COMPRISING THE SAME
    • 导电弹性辊和图像形成装置包括它们
    • US20100014891A1
    • 2010-01-21
    • US12444259
    • 2007-09-28
    • Junji Sakata
    • Junji Sakata
    • G03G15/02
    • G03G15/0233G03G15/0818G03G15/1685G03G15/2057
    • This invention is a conductive elastic roller (1) comprising a shaft member (2) and one or more elastic layers (3) disposed on an outside of the shaft member (2) in a radial direction, wherein at least one of the elastic layers (3) is composed of an ultraviolet-curing type resin formed by curing a raw material for the elastic layer comprising a urethane acrylate oligomer (A), a photo-polymerization initiator (B) and a conductive agent (C) through ultraviolet irradiation, and the urethane acrylate oligomer (A) is a urethane acrylate oligomer synthesized by using as a polyol a polyether polyol (a1) having a proportion of primary hydroxyl groups in hydroxyl groups located at molecular ends of not less than 40% obtained by an addition polymerization of propylene oxide to a polyhydric alcohol alone, or the polyether polyol (a1) and another polyol (a2), and provides a conductive elastic roller (1) provided with an elastic layer having a low hardness, a small compression residual strain and an improved stain resistance to an adjoining member such as Organic Photoconductors or the like.
    • 本发明是一种导电性弹性辊(1),其包括轴部件(2)和一个或多个在径向方向上设置在轴部件(2)的外侧上的弹性层(3),其中至少一个弹性层 (3)由通过紫外线照射使包含氨基甲酸酯丙烯酸酯低聚物(A),光聚合引发剂(B)和导电剂(C)的弹性层的原料固化而形成的紫外线固化型树脂, 氨基甲酸酯丙烯酸酯低聚物(A)是通过使用作为多元醇而合成的氨基甲酸酯丙烯酸酯低聚物的方法,所述聚醚多元醇(a1)具有通过加成聚合得到的位于分子末端的羟基中的羟基的比例为40质量% 的环氧丙烷与单独的多元醇,或聚醚多元醇(a1)和另一种多元醇(a2)反应,并提供具有低硬度,小压缩残余应变的弹性层的导电性弹性辊(1)和 n改善对诸如有机感光体等的邻接构件的耐污染性。