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    • 1. 发明授权
    • Dihydroxy enol compounds used in chemical mechanical polishing compositions having metal ion oxidizers
    • 用于具有金属离子氧化剂的化学机械抛光组合物中的二羟基烯醇化合物
    • US08114775B2
    • 2012-02-14
    • US12352700
    • 2009-01-13
    • Junaid Ahmed SiddiquiDaniel Hernandez CastilloSteven Masami AragakiRobin Edward Richards
    • Junaid Ahmed SiddiquiDaniel Hernandez CastilloSteven Masami AragakiRobin Edward Richards
    • H01L21/302
    • C09K3/1463C09G1/02H01L21/02074H01L21/3212H01L21/32125
    • A chemical mechanical polishing composition contains 1) water, 2) optionally an abrasive material, 3) an oxidizer, preferably a per-type oxidizer, 4) a small amount of soluble metal-ion oxidizer/polishing accelerator, a metal-ion polishing accelerator bound to particles such as to abrasive particles, or both; and 5) at least one of the group selected from a) a small amount of a chelator, b) a small amount of a dihydroxy enolic compound, and c) a small amount of an organic accelerator. Ascorbic acid in an amount less than 800 ppm, preferably between about 100 ppm and 500 ppm, is the preferred dihydroxy enolic compound. The polishing compositions and processes are useful for substantially all metals and metallic compounds found in integrated circuits, but is particularly useful for tungsten. The present invention also pertains to surface-modified colloidal abrasive polishing compositions and associated methods of using these compositions, particularly for chemical mechanical planarization, wherein the slurry comprises low levels of chelating free radical quenchers, non-chelating free radical quenchers, or both.
    • 化学机械抛光组合物包含1)水,2)任选的研磨材料,3)氧化剂,优选每种型氧化剂,4)少量可溶性金属离子氧化剂/抛光促进剂,金属离子抛光促进剂 与颗粒结合,例如磨料颗粒或两者; 和5)选自a)少量螯合剂中的至少一种,b)少量的二羟基烯醇化合物,和c)少量的有机促进剂。 少于800ppm,优选在约100ppm和500ppm之间的抗坏血酸是优选的二羟基烯醇化合物。 抛光组合物和方法对于在集成电路中发现的基本上所有的金属和金属化合物都是有用的,但对钨尤其有用。 本发明还涉及表面改性的胶体研磨抛光组合物以及使用这些组合物,特别是用于化学机械平面化的相关方法,其中浆料包含低水平的螯合自由基猝灭剂,非螯合自由基猝灭剂或二者。
    • 2. 发明授权
    • Dihydroxy enol compounds used in chemical mechanical polishing compositions having metal ion oxidizers
    • 用于具有金属离子氧化剂的化学机械抛光组合物中的二羟基烯醇化合物
    • US07476620B2
    • 2009-01-13
    • US11387934
    • 2006-03-24
    • Junaid Ahmed SiddiquiDaniel Hernandez CastilloSteven Masami AragakiRobin Edward Richards
    • Junaid Ahmed SiddiquiDaniel Hernandez CastilloSteven Masami AragakiRobin Edward Richards
    • H01L21/302
    • C09K3/1463C09G1/02H01L21/02074H01L21/3212H01L21/32125
    • A chemical mechanical polishing composition contains 1) water, 2) optionally an abrasive material, 3) an oxidizer, preferably a per-type oxidizer, 4) a small amount of soluble metal-ion oxidizer/polishing accelerator, a metal-ion polishing accelerator bound to particles such as to abrasive particles, or both; and 5) at least one of the group selected from a) a small amount of a chelator, b) a small amount of a dihydroxy enolic compound, and c) a small amount of an organic accelerator. Ascorbic acid in an amount less than 800 ppm, preferably between about 100 ppm and 500 ppm, is the preferred dihydroxy enolic compound. The polishing compositions and processes are useful for substantially all metals and metallic compounds found in integrated circuits, but is particularly useful for tungsten. The present invention also pertains to surface-modified colloidal abrasive polishing compositions and associated methods of using these compositions, particularly for chemical mechanical planarization, wherein the slurry comprises low levels of chelating free radical quenchers, non-chelating free radical quenchers, or both.
    • 化学机械抛光组合物包含1)水,2)任选的研磨材料,3)氧化剂,优选每种型氧化剂,4)少量可溶性金属离子氧化剂/抛光促进剂,金属离子抛光促进剂 与颗粒结合,例如磨料颗粒或两者; 和5)选自a)少量螯合剂中的至少一种,b)少量的二羟基烯醇化合物,和c)少量的有机促进剂。 少于800ppm,优选在约100ppm和500ppm之间的抗坏血酸是优选的二羟基烯醇化合物。 抛光组合物和方法对于在集成电路中发现的基本上所有的金属和金属化合物都是有用的,但对钨尤其有用。 本发明还涉及表面改性的胶体研磨抛光组合物以及使用这些组合物,特别是用于化学机械平面化的相关方法,其中浆料包含低水平的螯合自由基猝灭剂,非螯合自由基猝灭剂或二者。
    • 5. 发明申请
    • DIHYDROXY ENOL COMPOUNDS USED IN CHEMICAL MECHANICAL POLISHING COMPOSITIONS HAVING METAL ION OXIDIZERS
    • 具有金属氧化物的化学机械抛光组合物中使用的二氢氧化合物
    • US20090308836A1
    • 2009-12-17
    • US12352700
    • 2009-01-13
    • Junaid Ahmed SiddiquiDaniel Hernandez CastilloSteven Masaml AragakiRobin Edward Richards
    • Junaid Ahmed SiddiquiDaniel Hernandez CastilloSteven Masaml AragakiRobin Edward Richards
    • B44C1/22C09K13/00
    • C09K3/1463C09G1/02H01L21/02074H01L21/3212H01L21/32125
    • A chemical mechanical polishing composition contains 1) water, 2) optionally an abrasive material, 3) an oxidizer, preferably a per-type oxidizer, 4) a small amount of soluble metal-ion oxidizer/polishing accelerator, a metal-ion polishing accelerator bound to particles such as to abrasive particles, or both; and 5) at least one of the group selected from a) a small amount of a chelator, b) a small amount of a dihydroxy enolic compound, and c) a small amount of an organic accelerator. Ascorbic acid in an amount less than 800 ppm, preferably between about 100 ppm and 500 ppm, is the preferred dihydroxy enolic compound. The polishing compositions and processes are useful for substantially all metals and metallic compounds found in integrated circuits, but is particularly useful for tungsten. The present invention also pertains to surface-modified colloidal abrasive polishing compositions and associated methods of using these compositions, particularly for chemical mechanical planarization, wherein the slurry comprises low levels of chelating free radical quenchers, non-chelating free radical quenchers, or both.
    • 化学机械抛光组合物包含1)水,2)任选的研磨材料,3)氧化剂,优选每种型氧化剂,4)少量可溶性金属离子氧化剂/抛光促进剂,金属离子抛光促进剂 与颗粒结合,例如磨料颗粒或两者; 和5)选自a)少量螯合剂中的至少一种,b)少量的二羟基烯醇化合物,和c)少量的有机促进剂。 少于800ppm,优选在约100ppm和500ppm之间的抗坏血酸是优选的二羟基烯醇化合物。 抛光组合物和方法对于在集成电路中发现的基本上所有的金属和金属化合物都是有用的,但对钨尤其有用。 本发明还涉及表面改性的胶体研磨抛光组合物以及使用这些组合物,特别是用于化学机械平面化的相关方法,其中浆料包含低水平的螯合自由基猝灭剂,非螯合自由基猝灭剂或二者。
    • 6. 发明授权
    • Free radical-forming activator attached to solid and used to enhance CMP formulations
    • 自由基形成活化剂连接到固体上并用于增强CMP配方
    • US07513920B2
    • 2009-04-07
    • US11264027
    • 2005-11-02
    • Junaid Ahmed SiddiquiRobert J. SmallDaniel Hernandez Castillo
    • Junaid Ahmed SiddiquiRobert J. SmallDaniel Hernandez Castillo
    • C09G1/02C09G1/04
    • C09G1/02C03C19/00C09K3/1463C23F3/04G11B5/3163G11B5/3169H01L21/3212
    • A CMP composition having: a fluid comprising water and at least one oxidizing compound that produces free radicals when contacted with an activator; and a plurality of particles having a surface and comprising at least one activator selected from ions or compounds of Cu, Fe, Mn, Ti, or mixtures thereof disposed on said surface, wherein at least a portion of said surface comprises a stabilizer. Preferred activators are selected from inorganic oxygen-containing compounds of B, W, Al, and P, for example borate, tungstate, aluminate, and phosphate. The activators are preferably ions of Cu or Fe. Surprisingly, as little as 0.2 ppm and 12 ppm of activator is useful, if the activator-containing particles are suspended in the fluid as a slurry. Advantageously, certain organic acids, and especially dihydroxy enolic acids, are included in an amount less than about 4000 ppm. Advantageously, activator is coated onto abrasive particles after the particles have been coated with stabilizer.
    • 一种CMP组合物,其具有:包含水和至少一种在与活化剂接触时产生自由基的氧化化合物的流体; 以及多个具有表面并且包含至少一种选自Cu,Fe,Mn,Ti或其混合物的离子或化合物的活化剂的颗粒,其中所述表面的至少一部分包含稳定剂。 优选的活化剂选自B,W,Al和P的无机含氧化合物,例如硼酸盐,钨酸盐,铝酸盐和磷酸盐。 活化剂优选为Cu或Fe的离子。 令人惊奇的是,只要0.2ppm和12ppm的活化剂是有用的,如果含活化剂的颗粒作为浆料悬浮在流体中。 有利地,某些有机酸,特别是二羟基烯醇酸的含量小于约4000ppm。 有利地,在颗粒已经用稳定剂涂覆之后,将活化剂涂覆到磨料颗粒上。