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1. 发明授权

US06350345B1 Curable resin composition 有权
标题翻译：可固化树脂组合物
公开(公告)号：US06350345B1
公开(公告)日：2002-02-26
申请号：US09584075
申请日：2000-06-01
申请人： Jun Kotani , Masato Kusakabe , Hiroshi Iwakiri
发明人： Jun Kotani , Masato Kusakabe , Hiroshi Iwakiri
IPC分类号： C09J18304
CPC分类号： C08L33/06 , C08L43/04 , C08L71/02 , C08L2666/14 , C09J143/04 , Y10S528/901
摘要： This invention has its object to provide a curable resin compositions useful as contact adhesives with a prolonged tack retention period, without affecting the final bond strength. This invention is related to a A curable resin composition which comprises (I) a reactive silicon group-containing polyether oligomer, (II) a copolymer comprising a molecular chain substantially composed of one or more acrylate ester monomer units and/or methacrylate ester monomer units and (III) an accelerator.
摘要翻译：本发明的目的是提供可用作具有延长的粘着保持期的接触粘合剂的可固化树脂组合物，而不影响最终粘合强度。本发明涉及一种可固化树脂组合物，其包含（I）含反应性硅基的聚醚低聚物，（II）包含基本上由一种或多种丙烯酸酯单体单元和/或甲基丙烯酸酯单体单元组成的分子链的共聚物和（III）加速器。

2. 发明授权

US06737482B1 Curable resin composition 失效
标题翻译：可固化树脂组合物
公开(公告)号：US06737482B1
公开(公告)日：2004-05-18
申请号：US09889587
申请日：2001-11-20
申请人： Katsuhiro Ando , Toru Inaya , Masato Kusakabe , Hiroshi Iwakiri
发明人： Katsuhiro Ando , Toru Inaya , Masato Kusakabe , Hiroshi Iwakiri
IPC分类号： C08L8312
CPC分类号： C08L71/02 , C08G65/336 , C08L63/00 , C08L71/00
摘要： The present invention is to provide a curable resin composition comprising (I) a reactive silicon group-containing polyoxyalkylene polymer wherein a introduction rate of a reactive silicon group into molecular chain terminus is not less than 85% as analyzed by 1H-NMR spectrometry and (II) an epoxy resin. The curable resin obtained from this composition reflects improvements in tensile strength and tensile shear bond strength and in adhesion to various substrates.
摘要翻译：本发明提供一种固化性树脂组合物，其包含（I）含有反应性硅基的聚氧化烯聚合物，其中通过1 H-NMR分析，反应性硅基团在分子链末端的引入速率不低于85％光谱测定法和（II）环氧树脂。由该组合物获得的可固化树脂反映了拉伸强度和拉伸剪切粘合强度以及对各种基材的粘附性的改善。

3. 发明授权

US07144953B2 Curable resin composition 有权
标题翻译：可固化树脂组合物
公开(公告)号：US07144953B2
公开(公告)日：2006-12-05
申请号：US10492848
申请日：2002-10-23
申请人： Kazuhiko Ueda , Jun Kotani , Shintaro Komitsu , Hiroshi Iwakiri
发明人： Kazuhiko Ueda , Jun Kotani , Shintaro Komitsu , Hiroshi Iwakiri
IPC分类号： C08L83/06
CPC分类号： C09D133/06 , C08G65/2648 , C08G65/2663 , C08G65/2675 , C08G65/336 , C08L33/06 , C08L43/04 , C08L71/02 , C09D143/04 , C08L2666/04 , C08L71/00
摘要： The present invention provides a composition, which is easy to produce because of high ease of handling the starting materials. The composition exhibits excellent transparency, and a product prepared using the composition exhibits excellent mechanical properties and adhesive properties.The curable resin composition contains (A) an oxyalkylene polymer having silicon-containing functional groups crosslinkable through formation of siloxane bonds; (B) a copolymer having silicon-containing functional groups crosslinkable through formation of siloxane bonds, the molecular chain of the copolymer consisting substantially of (b-1) an alkyl (meth)acrylate monomeric unit having C1–C2 alkyl and (b-2) an alkyl (meth)acrylate monomeric unit having C7–C9 alkyl; and (C) a curing agent.
摘要翻译：本发明提供一种组合物，其易于处理原料易于生产。该组合物表现出优异的透明性，使用该组合物制备的产品表现出优异的机械性能和粘合性能。固化性树脂组合物含有（A）具有通过形成硅氧烷键可交联的含硅官能团的氧化烯聚合物; （B）具有通过形成硅氧烷键可交联的含硅官能团的共聚物，所述共聚物的分子链基本上由（b-1）含有（C 1）烷基的（甲基）丙烯酸烷基酯单体组成，具有C 1〜 -C 2 - 烷基和（b-2）具有C 7 -C 9烷基的（甲基）丙烯酸烷基酯单体单元; 和（C）固化剂。

4. 发明申请

US20050004327A1 Curable resin composition 有权
标题翻译：可固化树脂组合物
公开(公告)号：US20050004327A1
公开(公告)日：2005-01-06
申请号：US10492848
申请日：2002-10-23
申请人： Kazuhiko Ueda , Jun Kotani , Shintaro Komitsu , Hiroshi Iwakiri
发明人： Kazuhiko Ueda , Jun Kotani , Shintaro Komitsu , Hiroshi Iwakiri
IPC分类号： C08G65/26 , C08G65/336 , C08L33/06 , C08L43/04 , C08L71/02 , C09D133/06 , C09D143/04 , C08G77/00
CPC分类号： C09D133/06 , C08G65/2648 , C08G65/2663 , C08G65/2675 , C08G65/336 , C08L33/06 , C08L43/04 , C08L71/02 , C09D143/04 , C08L2666/04 , C08L71/00
摘要： The present invention provides a composition, which is easy to produce because of high ease of handling the starting materials. The composition exhibits excellent transparency, and a product prepared using the composition exhibits excellent mechanical properties and adhesive properties. The curable resin composition contains (A) an oxyalkylene polymer having silicon-containing functional groups crosslinkable through formation of siloxane bonds; (B) a copolymer having silicon-containing functional groups crosslinkable through formation of siloxane bonds, the molecular chain of the copolymer consisting substantially of (b-1) an alkyl (meth)acrylate monomeric unit having C1-C2 alkyl and (b-2) an alkyl (meth)acrylate monomeric unit having C7-C9 alkyl; and (C) a curing agent.
摘要翻译：本发明提供一种组合物，其易于处理原料易于生产。该组合物显示出优异的透明性，并且使用该组合物制备的产品表现出优异的机械性能和粘合性能。固化性树脂组合物含有（A）具有通过形成硅氧烷键可交联的含硅官能团的氧化烯聚合物; （B）具有通过形成硅氧烷键可交联的含硅官能团的共聚物，所述共聚物的分子链基本上由（b-1）具有C 1 -C 2烷基的（甲基）丙烯酸烷基酯单体单元和（b-2））具有C7-C9烷基的（甲基）丙烯酸烷基酯单体单元; 和（C）固化剂。

5. 发明授权

US07652119B2 Curable composition 有权
标题翻译：可固化组合物
公开(公告)号：US07652119B2
公开(公告)日：2010-01-26
申请号：US11667459
申请日：2005-11-09
申请人： Katsuyu Wakabayashi , Hiroshi Iwakiri , Masahiro Murakami
发明人： Katsuyu Wakabayashi , Hiroshi Iwakiri , Masahiro Murakami
IPC分类号： C08G77/00 , C08G77/24
CPC分类号： C08K5/16 , C08K5/541 , C08L101/10 , C09K3/1018 , C08L71/02
摘要： A problem of the present invention is to provide a curable composition which gives good curability by use of a catalyst other than organic tin catalysts. The above problem is solved by a curable composition, comprising: (A) one or more polymers having a silicon-containing group which is crosslinkable by forming siloxane bonds, (B) an amine compound, and (C) a silicon compound having, as substituents on its silicon, at least one electron withdrawing group, and at least one group selected from the group consisting of alkoxy groups, alkenyloxy groups, acyloxy groups, and a hydroxyl group.
摘要翻译：本发明的问题是提供一种通过使用除了有机锡催化剂之外的催化剂提供良好固化性的可固化组合物。上述问题是通过一种可固化组合物来解决的，其包括：（A）一种或多种具有通过形成硅氧烷键可交联的含硅基团的聚合物，（B）胺化合物，和（C）具有如下其硅上的取代基，至少一个吸电子基团和至少一个选自烷氧基，烯氧基，酰氧基和羟基的基团。

6. 发明授权

US06486289B1 Curable composition 失效
标题翻译：可固化组合物
公开(公告)号：US06486289B1
公开(公告)日：2002-11-26
申请号：US09529168
申请日：2000-06-14
申请人： Izumi Yamaguchi , Masayuki Fujita , Hiroshi Iwakiri
发明人： Izumi Yamaguchi , Masayuki Fujita , Hiroshi Iwakiri
IPC分类号： C08G7708
CPC分类号： C08K5/17 , C08G65/336 , C08K5/09 , C08K5/57 , C08L71/02
摘要： The present invention has its object to provide a curable composition insuring a reduced stress without sacrificing restoring force and other physical properties and having a sufficient degree of adhesiveness. The present invention is related to a curable composition comprising comprising an oxyalkylene polymer having at least one reactive silicon group per molecule (A-1), an acid (B), an amine (C), and a tin-series curing catalyst (D). This composition optionally contains a vinyl polymer having at least one reactive silicon group.
摘要翻译：本发明的目的是提供一种固化组合物，其确保减少的应力而不会牺牲恢复力和其它物理性能并具有足够的粘附性。本发明涉及一种可固化组合物，其包含含有至少一种反应性的氧化烯聚合物（A-1），酸（B），胺（C）和锡系固化催化剂（D）。该组合物任选地含有具有至少一个反应性硅基团的乙烯基聚合物。

7. 发明授权

US06248915B1 Method of producing reactive silicon group-containing polyether oligomers 有权
标题翻译：制备含反应性基团的聚醚低聚物的方法
公开(公告)号：US06248915B1
公开(公告)日：2001-06-19
申请号：US09472962
申请日：1999-12-28
申请人： Hiroshi Ito , Hidetoshi Odaka , Hideharu Jyono , Hiroshi Iwakiri , Fumio Kawakubo
发明人： Hiroshi Ito , Hidetoshi Odaka , Hideharu Jyono , Hiroshi Iwakiri , Fumio Kawakubo
IPC分类号： C07F708
CPC分类号： C08G65/336
摘要： The invention provides a method of producing a reactive silicon group-containing polyether oligomer which comprises reacting (a) a polyether oligomer having main chain of a polyether and, in each molecule, at least one unsaturated group represented by the general formula (1): H2C═C(R1)—R2—O— (1) (in the formula, R1 is a hydrocarbon group containing not more than 10 carbon atoms and R2 is a divalent organic group containing 1 to 20 carbon atoms and one or more species selected from the group consisting of hydrogen, oxygen and nitrogen atoms as a constituent atom) or the general formula (2): HC(R1)═CH—R2—O— (2) on a side chain or at a terminus with (b) a reactive silicon group-containing compound in the presence of (c) a group VIII transition metal catalyst to introduce the reactive silicon group into said polyether oligomer (a), wherein the reaction is carried out in the presence of (d) a sulfur compound.
摘要翻译：本发明提供一种制备含反应性含硅基团的聚醚低聚物的方法，该方法包括使（a）具有聚醚主链的聚醚低聚物和每个分子中至少一个由通式（1）表示的不饱和基团：（式中，R 1为含有10个以下碳原子的烃基，R 2为含有1〜20个碳原子的二价有机基团和选自氢，氧和氮原子作为成分的一种以上的物质原子）或通式（2）：在侧链或末端具有（b）含有反应性硅基团的化合物，在（c）第Ⅷ族过渡金属催化剂的存在下将反应性硅基团引入所述聚醚低聚物（a），其中反应在（d）硫化合物的存在下进行。

8. 发明授权

US5880245A Process for the preparation of novel reactive silicon group-containing polymer 失效
标题翻译：制备新型反应性含硅基聚合物的方法
公开(公告)号：US5880245A
公开(公告)日：1999-03-09
申请号：US980976
申请日：1997-11-13
申请人： Masayuki Fujita , Hiroshi Iwakiri , Fumio Kawakubo
发明人： Masayuki Fujita , Hiroshi Iwakiri , Fumio Kawakubo
IPC分类号： C08G65/336 , C08G77/46 , C08G77/04
CPC分类号： C08G77/46 , C08G65/336
摘要： The present invention provides a process for the preparation of a reactive silicon group-containing polymer. A novel process for the preparation of the polymer includes allowing an alkylene oxide to undergo ring opening polymerization with an organopolysiloxane compound having an active hydrogen-containing functional group with which the alkylene oxide is reactive as an initiator in the presence of a catalyst to synthesize a polymer of organopolysiloxane and polyoxyalkylene, and then introducing a reactive silicon group into the polymer. Another process for the preparation of the polymer as defined above is provided, which includes allowing an alkylene oxide to undergo ring opening polymerization with an organopolysiloxane compound having an epoxy group in the presence of a catalyst with an active hydrogen-containing compound as an initiator to synthesize a polymer the main chain of which is essentially a copolymer of organopolysiloxane and polyoxyalkylene, and then introducing a reactive silicon group into the polymer.
摘要翻译：本发明提供了制备含反应性含硅基团的聚合物的方法。用于制备聚合物的新方法包括使烯化氧与催化剂存在下的具有活性含氢官能团的有机聚硅氧烷化合物进行开环聚合，其中环氧烷作为引发剂反应，合成一种有机聚硅氧烷和聚氧化烯的聚合物，然后将反应性硅基团引入聚合物中。提供另一种制备如上所述聚合物的方法，其中包括使烯化氧在具有活性氢化合物作为引发剂的催化剂存在下，与具有环氧基的有机聚硅氧烷化合物进行开环聚合，合成聚合物，其主链基本上是有机聚硅氧烷和聚氧化烯的共聚物，然后将反应性硅基团引入聚合物中。

9. 发明授权

US5650467A Curable composition 失效
标题翻译：可固化组合物
公开(公告)号：US5650467A
公开(公告)日：1997-07-22
申请号：US583954
申请日：1996-01-11
申请人： Mikiko Suzuki , Jo Kawamura , Hiroshi Iwakiri , Fumio Kawakubo
发明人： Mikiko Suzuki , Jo Kawamura , Hiroshi Iwakiri , Fumio Kawakubo
IPC分类号： C08L33/06 , C08G65/336 , C08L33/04 , C08L71/02 , C09J183/12 , C08L83/14
CPC分类号： C09J183/12 , C08G65/336 , C08L71/02
摘要： A curable resin composition is disclosed which is composed of (a) an oxyalkylene polymer containing at least one reactive silicon group per molecule and having a number average molecular weight of not less than 3000 and an Mw/Mn ratio of not higher than 1.6, (b) a copolymer having a molecular chain which comprises (A) an alkyl acrylate monomer unit and/or an alkyl methacrylate monomer unit each having 1 to 8 carbon atoms in the alkyl moiety thereof and (B) an alkyl acrylate monomer unit and/or an alkyl methacrylate monomer unit each having 10 or more carbon atoms wherein the total number of monomer units (A) and monomer units (B) constitutes more than 50% of the monomer units in the copolymer (b), and (c) a curing catalyst.
摘要翻译：公开了一种固化树脂组合物，其由（a）每分子含有至少一个反应性硅基的氧化烯聚合物组成，数均分子量不小于3000，Mw / Mn比不高于1.6（（ b）具有分子链的共聚物，其包含（A）丙烯酸烷基酯单体单元和/或其烷基部分中具有1至8个碳原子的甲基丙烯酸烷基酯单体单元和（B）丙烯酸烷基酯单体单元和/或每个具有10个或更多个碳原子的甲基丙烯酸烷基酯单体单元，其中单体单元（A）和单体单元（B）的总数构成共聚物（b）中单体单元的50％以上，和（c）固化催化剂。

10. 发明授权

US5177173A Heat-resting aromatic polyestersulfone and process for preparing the same 失效
标题翻译：热稳定性芳族聚酯和其制备方法
公开(公告)号：US5177173A
公开(公告)日：1993-01-05
申请号：US583820
申请日：1984-02-27
申请人： Hiroshi Iwakiri , Masahiro Asada , Kazuya Yonezawa
发明人： Hiroshi Iwakiri , Masahiro Asada , Kazuya Yonezawa
IPC分类号： C08G63/00 , B32B27/36 , C08G63/18 , C08G63/19 , C08G63/68 , C08G63/688 , C08G63/82
CPC分类号： C08G63/6886
摘要： An aromatic polyestersulfone having improved heat resistance, film-forming property, hydrolysis resistance and mechanical strength which comprises 1 to 100% by mole of recurring units of the general formula: ##STR1## and 99 to 0% by mole of recurring units of the general formula: ##STR2## wherein R and R' are the same or different and each is an alkyl or alkoxyl group having 1 to 4 carbon atoms, Ar is a bivalent aromatic group, and x and y are 0 or an integer of 1 to 4 provided that the sum of x and y is from 1 to 8.
摘要翻译：具有改善的耐热性，成膜性，耐水解性和机械强度的芳族聚酯砜，其包含1至100摩尔％的通式为：IMAGE的重复单元和99至0摩尔％的一般重复单元式：其中R和R'相同或不同，并且各自为具有1至4个碳原子的烷基或烷氧基，Ar为二价芳族基团，x和y为0或1至4的整数条件是x和y的和为1至8。

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