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    • 1. 发明授权
    • Novel polyimides, and polyamic acid and ester intermediates thereof
    • 新型聚酰亚胺及其聚酰胺酸及其酯中间体
    • US4405770A
    • 1983-09-20
    • US292257
    • 1981-08-12
    • Jules E. SchoenbergStephen P. Anderson
    • Jules E. SchoenbergStephen P. Anderson
    • C08G73/10C08G73/12
    • C08G73/1064C08G73/105Y10T428/31721
    • Novel polyimides, optionally end-capped with polymerizable or inert groups, and the polyamic acid or ester intermediates thereof are prepared by reacting a tetracarboxylic acid compound (e.g. pyromellitic dianhydride or 3,3',4,4'-benzophenone tetracarboxylic acid dianhydride or its methyl diester) with diamines having the general formula ##STR1## wherein Z is oxygen or sulfur, X and/or Y are carbonyl or carbinol groups, the amine groups may be in the 2-, 3-, and/or 4-position, and isomerism is present when X and/or Y is a carbinol group. The polyimides may be end-capped by reaction, during or after their formation, with polymerizable groups such as 3-aminophenyl acetylene or 3,6-endomethylene-1,2,3,6-tetrahydrophthalic anhydride. The diamines are novel classes of amines when Z is sulfur and when Z is oxygen and X, Y, or X and Y are carbinol groups.
    • 可选地用可聚合或惰性基团封端的新型聚酰亚胺,其聚酰胺酸或酯中间体是通过使四羧酸化合物(例如均苯四酸二酐或3,3',4,4'-二苯甲酮四羧酸二酐或其 甲基二酯)与具有通式为“IMAGE”的二胺,其中Z是氧或硫,X和/或Y是羰基或甲醇基,胺基可以是2-,3-和/或4-位, 并且当X和/或Y是甲醇基团时存在异构体。 聚酰亚胺可以通过其形成过程中或之后的反应,可聚合基团如3-氨基苯基乙炔或3,6-内亚甲基-1,2,3,6-四氢邻苯二甲酸酐封端。 当Z是硫时,当Z是氧而X,Y或X和Y是甲醇基时,二胺是新的胺类。
    • 2. 发明授权
    • Aromatic diamines
    • 芳香二胺
    • US4506100A
    • 1985-03-19
    • US405218
    • 1982-08-04
    • Jules E. SchoenbergStephen P. Anderson
    • Jules E. SchoenbergStephen P. Anderson
    • C08G73/10C07C87/50C07C85/11
    • C08G73/105C08G73/1064
    • Novel polyimides, optionally end-capped with polymerizable or inert groups, and the polyamic acid or ester intermediates thereof are prepared by reacting a tetracarboxylic acid compound (e.g. pyromellitic dianhydride or 3,3',4,4'-benzophenone tetracarboxylic acid dianhydride or its methyl diester) with diamines having the general formula ##STR1## wherein Z is oxygen or sulfur, X and/or Y are carbonyl or carbinol groups, the amine groups may be in the 2-, 3-, and/or 4-position, and isomerism is present when X and/or Y is a carbinol group. The polyimides may be end-capped by reaction, during or after their formation, with polymerizable groups such as 3-aminophenyl acetylene or 3,6-endomethylene-1,2,3,6-tetrahydrophthalic anhydride. The diamines are novel classes of amines when Z is sulfur and X and/or Y are carbonyl or carbinol groups and when Z is oxygen and X, Y, or X and Y are carbinol groups.
    • 可选地用可聚合或惰性基团封端的新型聚酰亚胺,其聚酰胺酸或酯中间体是通过使四羧酸化合物(例如均苯四酸二酐或3,3',4,4'-二苯甲酮四羧酸二酐或其 甲基二酯)与具有通式为“IMAGE”的二胺,其中Z是氧或硫,X和/或Y是羰基或甲醇基,胺基可以是2-,3-和/或4-位, 并且当X和/或Y是甲醇基团时存在异构体。 聚酰亚胺可以通过其形成过程中或之后的反应,可聚合基团如3-氨基苯基乙炔或3,6-内亚甲基-1,2,3,6-四氢邻苯二甲酸酐封端。 当Z是硫并且X和/或Y是羰基或甲醇基团时,当Z是氧而X,Y或X和Y是甲醇基时,二胺是新的胺类。