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    • 5. 发明授权
    • Sol-gel coating for single-layer or multi-layer varnishes
    • 单层或多层清漆的溶胶 - 凝胶涂层
    • US06872765B1
    • 2005-03-29
    • US09914937
    • 2000-03-06
    • Peter BetzHorst Hintze-BrüningWilfried StübbeHeinz-Peter Rink
    • Peter BetzHorst Hintze-BrüningWilfried StübbeHeinz-Peter Rink
    • B05D7/00C08L83/14C09D133/06C09D183/04C09D183/14C08K5/24
    • B05D7/536B05D7/576C08L83/14C09D133/066C09D183/04C09D183/14C08L2666/04C08L2666/28
    • The invention relates to a sol-gel coating material containing (A) an acrylate copolymer solution containing at least one acrylate copolymer (A1); (B) a parent varnish which can be prepared by hydrolysis and condensation of at least one hydrolysable silane (B1) of the general formula (I) SiR4, in which the variable R=hydrolysable groups, hydroxy groups and non-hydrolysable groups, provided that there should be at least one, preferably two, hydrolysable groups; and (C) an additive solution containing c1) at least one ethylenically unsaturated compound containing at least one epoxide group; c2) at least one silane (B1) with at least one non-hydrolysable group R presenting at least one epoxide group; and c3) at least one adduct of at least one silane (B1) with at least one non-hydrolysable group R presenting at least one amino group and at least one cyclic ethylenically unsaturated dicarboxylic acid anhydride. The invention also relates to the use of said sol-gel coating material for producing scratchproof sol-gel coatings.
    • 本发明涉及含有(A)含有至少一种丙烯酸酯共聚物(A1)的丙烯酸酯共聚物溶液的溶胶 - 凝胶涂料; (B)可以通过水解和缩合通式(I)SiR 4的至少一种可水解硅烷(B1)制备的母体清漆,其中可变的R =可水解基团,羟基和不可水解的基团提供 应该有至少一个,优选两个可水解基团; 和(C)含有c1)至少一种含有至少一个环氧基团的烯属不饱和化合物的添加剂溶液; c2)至少一种具有至少一个具有至少一个环氧基团的不可水解基团R的硅烷(B1); 和c3)至少一种至少一种硅烷(B1)与至少一种具有至少一个氨基的至少一种不可水解基团R和至少一种环状烯键式不饱和二羧酸酐的加合物。 本发明还涉及所述溶胶 - 凝胶涂层材料用于制备防刮溶胶 - 凝胶涂层的用途。
    • 6. 发明授权
    • Paints and use of these paints as topcoats for the finishing of
automobile bodies
    • 油漆和使用这些油漆作为汽车车身整理的面漆
    • US5430083A
    • 1995-07-04
    • US945970
    • 1993-01-04
    • Konrad KlierPeter Betz
    • Konrad KlierPeter Betz
    • C09D183/04C09D7/12C09D133/06C09D167/00C09D183/06C09D183/08C09D201/00
    • C09D167/00C09D133/06C09D201/00C09D7/1233
    • The invention relates to paints which contain a compound of the general formula (I) or a mixture of compounds of the general formula (I), the general formula (I) being ##STR1## and n, m, X, R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and Y having the following meaning:- n stands for a number between 2 and 25, preferably for a number between 5 and 15- m stands for a number from 0 to 5- X and Y can be identical or different and stand for a functional group, for example a hydroxyl, amino, carboxyl or NCO group- R.sup.1 and R.sup.4 can be identical or different and stand for an alkylene radical, preferably for an alkylene radical having 1 to 6 carbon atoms, or for an arylene radical, preferably a phenylene radical- R.sup.2 and R.sup.3 can be identical or different and stand for an alkyl radical, preferably for an alkyl radical having 1 to 3 carbon atoms, or for an aryl radical, preferably for a phenyl radical- R.sup.5 stands for ##STR2## Z standing for X, Y or R.sup.2. Compounds of the general formula (I) improve especially the acid, brush and weather resistances and the water-repellent characteristics of the paint films prepared using these paints.
    • PCT No.PCT / EP91 / 00852 Sec。 371日期:1993年1月4日 102(e)日期1993年1月4日PCT提交1991年5月6日PCT公布。 第WO91 / 18954号公报 1991年12月12日,本发明涉及含有通式(I)的化合物或通式(I)的化合物,通式(I)为(IMA)(I)的化合物和 n,m,X,R 1,R 2,R 3,R 4,R 5和Y具有以下含义:-n表示2至25之间的数,优选为5至15的数,m表示0至 5-X和Y可以相同或不同,代表官能团,例如羟基,氨基,羧基或NCO基团-R 1和R 4可以相同或不同,代表亚烷基,优选为具有 1至6个碳原子,或对于亚芳基,优选亚苯基-R 2和R 3可以相同或不同,代表烷基,优选为具有1至3个碳原子的烷基或芳基, 优选用于苯基 - R5代表X,Y或R2表示的。 通式(I)的化合物特别提高了使用这些涂料制备的漆膜的酸,刷和耐候性以及防水性能。
    • 8. 发明授权
    • Sol-gel coating
    • 溶胶 - 凝胶涂层
    • US06828381B1
    • 2004-12-07
    • US10049532
    • 2002-02-12
    • Manuela ArmbrustWolfgang BremserHorst Hintze-BrüningWilfried StübbePeter BetzChristel Ehlig
    • Manuela ArmbrustWolfgang BremserHorst Hintze-BrüningWilfried StübbePeter BetzChristel Ehlig
    • C08L8306
    • C09D133/066C08L83/04C08L85/00C09D183/04C09D183/14Y10T428/31663C08L2666/14C08L2666/02
    • A sol-gel coating material, containing (A) an acrylate copolymer solution, consisting of at least one acrylate copolymer; (B) a parent lacquer which can be produced by the hydrolysis and condensation of at least one hydrolysable silane of the formula (I): SiR4; wherein: R=hydrolysable groups, hydroxy groups and non-hydrolysable groups, with the proviso that there should be at least one hydrolysable group; and (C) a sol which can be produced by the hydrolysis, condensation and complexing of (C1) at least one hydrolysable metal compound of the (II): MRn; wherein: M=aluminium, titanium or zirconium, R=the aforementioned given groups and n=3 or 4; of (C2) at least one organic thio compound of the formula (III): S(R1X)2, wherein R1 represents a two-bond organic radical and X represents hydroxyl, thiol and/or primary and/or secondary amino groups; and of (C3) a hydrolysable silane of the general formula (I).
    • 一种溶胶凝胶涂层材料,其包含(A)丙烯酸酯共聚物溶液,由至少一种丙烯酸酯共聚物组成; (B)可以通过至少一种式(I)的可水解硅烷:SiR 4的水解和缩合产生的母漆; 其中:R =可水解基团,羟基和不可水解基团,条件是应存在至少一个可水解基团; 和(C)可以通过(C1)至少一种(II)的可水解金属化合物:MRn的水解,缩合和络合来制备的溶胶; 其中:M =铝,钛或锆,R =上述给定的基团,n = 3或4; 的(C2)至少一种式(III)的有机硫代化合物:S(R 1 X)2,其中R 1表示双键有机基团,X表示羟基,硫醇和/或伯和 /或仲氨基; 和(C3)通式(I)的可水解硅烷。
    • 9. 发明授权
    • Method for producing scratch resistant coatings, especially for producing multi-layer enamels
    • 制备耐刮涂层的方法,特别是用于生产多层瓷漆
    • US06410646B1
    • 2002-06-25
    • US09380524
    • 1999-11-08
    • Ulrike RöckrathPeter BetzFritz BartolGeorg WiggerHubert Baumgart
    • Ulrike RöckrathPeter BetzFritz BartolGeorg WiggerHubert Baumgart
    • C08F890
    • C09D175/04
    • A process for producing scratch-resistant coatings, especially scratch-resistant multicoat finishes, involving use of coating compositions which, after curing, have a storage modulus E′ in the rubber-elastic range of at least 107.5 Pa and a loss factor tan&dgr; at 20° C. of at least 0.05, the storage modulus E′ and the loss factor having been measured by dynamic mechanical thermoanalysis on free films having a film thickness of 40±10 &mgr;m, and comprise as binders one or more polyacrylate resins having a hydroxyl number of from 100 to 240, an acid number of from 0 to 35, and a number-average molecular weight of from 1500 to 10,000, and as crosslinkers one or more free or blocked isocyanates and/or triazine-based components which crosslink with the hydroxyl groups of the binder to form ether and/or ester structures.
    • 一种用于生产耐刮擦涂层的方法,特别是耐刮擦多层涂饰,涉及使用涂料组合物,其在固化之后的橡胶弹性范围内的储能模量E'至少为107.5Pa,损耗因子tandelta为20 ℃至少为0.05,储存模量E'和损失因子已经通过动态机械热分析测量了膜厚度为40±10um的游离膜,并且包含作为粘合剂的一种或多种具有羟值的聚丙烯酸酯树脂 为100至240,酸值为0至35,数均分子量为1500至10,000,并且作为交联剂,与羟基交联的一种或多种游离或封端的异氰酸酯和/或三嗪基组分 组合的粘合剂以形成醚和/或酯结构。
    • 10. 发明授权
    • Cable connection into tube
    • 电缆连接管
    • US06906267B2
    • 2005-06-14
    • US10407730
    • 2003-04-07
    • Hans F. LevyPeter Betz
    • Hans F. LevyPeter Betz
    • E04F15/024H02G3/04H01B17/26
    • E04F15/024F24F2221/40H02G3/0481
    • Disclosed is a cable installation in an office layout having a raised floor forming a plenum having air conditioned air charged therein. The conditioned air is lead through the floor by way of flexible tubes that are guided to the various office stations located above the floor. Wherever needed, the flexible tubes are connected above the floor and below the floor to rigid tubes that are located in the replaceable tiles in the raised floor. This installation requires that various cables also must be installed. It has been found that the most convenient way to accomplish this is to lead the cables through the flexible tubes to wherever they are needed. The cables are conveniently located under the floor. The rigid tube installed in the tile of the floor has a lower rigid extension. An opening is placed laterally into the rigid tube, a special plate is placed to cover the opening including a sealing element. The special plate has an opening therein so that a cable can be passed into the interior of the rigid tube and from there to the office station above the floor. Special precautions are taken to protect the cable from any damage and to prevent excessive air leakage. The cable installation can be used with either rigid or flexible tubes wherever feasible and practical.
    • 公开了一种办公室布局中的电缆装置,其具有形成具有空气调节空气的充气室的高架地板。 调节空气通过柔性管引导通过地板,导管被引导到位于地板上方的各个办公室。 无论何时需要,柔性管连接在地板之上和地板下面,并且位于高架地板中的可替换砖中的刚性管。 此安装要求也必须安装各种电缆。 已经发现,实现这一点的最方便的方法是将电缆穿过柔性管导向需要的位置。 电缆位于地板的下方。 安装在地板瓷砖中的刚性管具有较低的刚性延伸。 将开口侧向放置在刚性管中,放置特殊板以覆盖包括密封元件的开口。 特殊板在其中具有开口,使得电缆可以进入刚性管的内部并且从那里到位于地板上方的办公室。 采取特殊的预防措施来保护电缆免受任何损坏,并防止漏气过多。 电缆安装可以在可行和实用的情况下与刚性或柔性管一起使用。