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    • 2. 发明授权
    • Methyl .alpha.-(2-substituted)pyrid-3-yl-.beta.-methoxyacrylates,
compositions containing them and their use as fungicides
    • 甲基α-(2-取代)吡啶-3-基-β-甲氧基丙烯酸酯,含有它们的组合物及其作为杀真菌剂的用途
    • US5198444A
    • 1993-03-30
    • US597398
    • 1990-10-15
    • John M. CloughChristopher R. A. GodfreyStephen P. HeaneyKenneth Anderton
    • John M. CloughChristopher R. A. GodfreyStephen P. HeaneyKenneth Anderton
    • A01N43/40A01N43/54A01N43/78C07D213/64C07D213/643C07D213/65C07D213/68C07D213/70C07D213/71C07D213/74C07D213/79C07D213/80C07D213/81C07D213/84C07D213/85C07D213/89C07D401/12C07D405/12C07D409/12C07D413/12C07D417/12C07D473/30C07D473/34C07D473/38
    • C07D213/643A01N43/40A01N43/54A01N43/78C07D213/65C07D213/68C07D213/70C07D213/71C07D213/74C07D213/79C07D213/80C07D213/81C07D213/84C07D213/85C07D213/89C07D401/12C07D405/12C07D409/12C07D413/12C07D417/12C07D473/30C07D473/34C07D473/38
    • Fungicidal compounds of the formula (I): ##STR1## and stereoisomers thereof, wherein K is oxygen or sulphur; Z is optionally substituted aryl or optionally substituted heteroaryl; X is O, S(O).sub.n, NR.sup.4, CR.sup.1 R.sup.2, CHR.sup.5, CO, CR.sup.1 (OR.sup.2), C.dbd.CR.sup.1 R.sup.2, CHR.sup.1 CHR.sup.2, CR.sup.1 .dbd.CR.sup.2, CHR.sup.1 CR.sup.2 .dbd.CH, C.dbd.C, OCHR.sup.1, CHR.sup.1 O, OCHR.sup.1 O, S(O).sub.n CHR.sup.1, S(O).sub.n CHR.sup.1 O, CHR.sup.1 S(O).sub.n, CHR.sup.1 OSO.sub.2, NR.sup.4 CHR.sup.1, CHR.sup.1 NR.sup.4, CO.sub.2, O.sub.2 C, SO.sub.2 O, OSO.sub.2, CO.CO, COCHR.sup.1, COCHR.sup.1 O, CHR.sup.1 CO, CHOH.CHR.sup.1, CHR.sup.1.CHOH, ##STR2## CONR.sup.4, OCONR.sup.4, NR.sup.4 CO, CSNR.sup.4, OCS.NR.sup.4, SCO.NR.sup.4, NR.sup.4 CO.sub.2, NR.sup.4 CS, NR.sup.4 CSO, NR.sup.4 COS, NR.sup.4 CONR.sup.4, S(O).sub.n NR.sup.4, NR.sup.4 S(O).sub.n, CS.sub.2, S.sub.2 C, CO.S, SCO, N.dbd.N, N.dbd.CR.sup.1, CR.sup.1 .dbd.N, CHR.sup.1 CHR.sup.2 CH(OH), CHR.sup.1 OCO, CHR.sup.1 SCO, CHR.sup.1 NR.sup.4 CO, CHR.sup.1 NR.sup.4 COR.sup.4, CHR.sup.1 CHR.sup.2 CO, O.N.dbd.CR.sup.1, CHR.sup.1 O.N.dbd.CR.sup.2, CO.OCR.sup.1 R.sup.2, CHR.sup.1 CHR.sup.2 CHR.sup.3, OCHR.sup.1 CHR.sup.2, (CH.sub.2).sub.m O, CHR.sup.1 OCHR.sup.2, CHR.sup.1 CHR.sup.2 O, OCHR.sup.1 CHR.sup.2 O, S(O).sub.n CHR.sup.1 CHR.sup.2, CHR.sup.1 S(O).sub.n CHR.sup.2, CHR.sup.1 CHR.sup.2 S(O).sub.n, CR.sup.1 .dbd.NNR.sup.4, NR.sup.4 N.dbd.CR.sup.1, CHR.sup.1 CONR.sup.2, CHR.sup.1 OCO.NR.sup.2, CH.dbd.CHCH.sub.2 O, COCHR.sup.1 CHR.sup.2 O or (R.sup.5).sub.2 P.sup. + CHR.sup.2 Q.sup.- ; A, B and E, which may be the same or different, are H, hydroxy, halo, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, C.sub.1-4 haloalkyl, C.sub.1-4 haloalkoxy, C.sub.1-4 alkylcarbonyl, C.sub.1-4 alkoxycarbonyl, phenoxy, nitro or cyano; R.sup.1, R.sup.2 and R.sup.3, which may be the same or different, are H, C.sub.1-4 alkyl or phenyl; R.sup.4 is H, C.sub.1-4 alkyl or COR.sup.1 ; R.sup.5 is optionally substituted phenyl; Q.sup.- is a halide anion; n is 0, 1, or 2 and m is a 3, 4 or 5.
    • 式(I)的杀真菌化合物:其中K为氧或硫; Z是任选取代的芳基或任选取代的杂芳基; X是O,S(O)n,NR4,CR1R2,CHR5,CO,CR1(OR2),C = CR1R2,CHR1CHR2,CR1 = CR2,CHR1CR2 = CH,C = C,OCHR1,CHR1O,OCHR1O, )nCHR1,S(O)nCHR1O,CHR1S(O)n,CHR1OSO2,NR4CHR1,CHR1NR4,CO2,O2C,SO2O,OSO2,CO.CO,COCHR1,COCHR1O,CHR1CO,CHOH.CHR1,CHR1.CHOH, CONR4,OCONR4,NR4CO,CSNR4,OCS.NR4,SCO.NR4,NR4CO2,NR4CS,NR4CSO,NR4COS,NR4CONR4,S(O)nNR4,NR4S(O)n,CS2,S2C,CO.S,SCO,N = N = CR1,CR1 = N,CHR1CHR2CH(OH),CHR1OCO,CHR1SCO,CHR1NR4CO,CHR1NR4COR4,CHR1CHR2CO,ON = CR1,CHR1O.N = CR2,CO.OCR1R2,CHR1CHR2CHR3,OCHR1CHR2,(CH2)mO,CHR1OCHR2, CHR1CHR2O,OCHR1CHR2O,S(O)nCHR1CHR2,CHR1S(O)nCHR2,CHR1CHR2S(O)n,CR1 = NNR4,NR4N = CR1,CHR1CONR2,CHR1OCO.NR2,CH = CHCH2O,COCHR1CHR2O或(R5)2P + CHR2Q-; A,B和E可以相同或不同,是H,羟基,卤素,C 1-4烷基,C 1-4烷氧基,C 1-4卤代烷基,C 1-4卤代烷氧基,C 1-4烷基羰基,C 1-4烷氧基羰基 ,苯氧基,硝基或氰基; R 1,R 2和R 3可以相同或不同,为H,C 1-4烷基或苯基; R4是H,C1-4烷基或COR1; R5是任选取代的苯基; Q-是卤素阴离子; n为0,1或2,m为3,4或5。