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1. 发明授权

US08173851B2 Processes for converting gaseous alkanes to liquid hydrocarbons 有权
标题翻译：将气态烷烃转化为液态烃的方法
公开(公告)号：US08173851B2
公开(公告)日：2012-05-08
申请号：US12477319
申请日：2009-06-03
申请人： John J. Waycuilis , William J. Turner , Raphael Thomas
发明人： John J. Waycuilis , William J. Turner , Raphael Thomas
IPC分类号： C07C1/00
CPC分类号： C01B7/093 , C01B7/096 , C01B9/04 , C07C17/10 , C07C17/23 , C07C17/37 , C07C19/075 , C10G50/00 , C10G2300/1011 , C10G2300/1025 , C10G2400/20 , C10G2400/22 , C10L3/10 , C10L3/102 , Y02P30/40
摘要： A process for converting gaseous alkanes to olefins, higher molecular weight hydrocarbons or mixtures thereof wherein a gaseous feed containing alkanes is thermally reacted with a dry bromine vapor to form alkyl bromides and hydrogen bromide. Poly-brominated alkanes present in the alkyl bromides are further reacted with methane over a suitable catalyst to form mono-brominated species. The mixture of alkyl bromides and hydrogen bromide is then reacted over a suitable catalyst at a temperature sufficient to form olefins, higher molecular weight hydrocarbons or mixtures thereof and hydrogen bromide. Various methods are disclosed to remove the hydrogen bromide from the higher molecular weight hydrocarbons, to generate bromine from the hydrogen bromide for use in the process, and to selectively form mono-brominated alkanes in the bromination step.
摘要翻译：将气态烷烃转化为烯烃，较高分子量烃或其混合物的方法，其中含有烷烃的气态进料与干燥溴蒸气反应形成烷基溴化物和溴化氢。存在于烷基溴中的多溴代烷烃进一步与甲烷在合适的催化剂上反应形成单溴化物质。然后在足以形成烯烃，较高分子量烃或其混合物和溴化氢的温度下，通过合适的催化剂使烷基溴和溴化氢的混合物反应。公开了各种方法从高分子量烃中除去溴化氢，从溴化氢中产生溴用于该方法，并在溴化步骤中选择性地形成单溴代烷烃。

2. 发明申请

US20110015458A1 CONVERSION OF HYDROGEN BROMIDE TO ELEMENTAL BROMINE 审中-公开
标题翻译：氢溴化碳转化为元素溴
公开(公告)号：US20110015458A1
公开(公告)日：2011-01-20
申请号：US12792335
申请日：2010-06-02
申请人： John J. Waycuilis , Patrick K. Moore , Greg A. Lisewsky
发明人： John J. Waycuilis , Patrick K. Moore , Greg A. Lisewsky
IPC分类号： C07C2/00 , C01B7/09
CPC分类号： C01B7/096
摘要： A method is provided for converting hydrogen bromide to elemental bromine. A portion of an initial hydrogen bromide-rich gas is thermally oxidized at a thermal oxidation temperature to produce a first fraction of elemental bromine and a remainder of the initial hydrogen bromide-rich gas. At least a portion of the remainder of the initial hydrogen bromide-rich gas is catalytically oxidized at a lower catalytic oxidation temperature to produce a second fraction of elemental bromine.
摘要翻译：提供了一种将溴化氢转化为元素溴的方法。一部分初始的富含溴化氢的气体在热氧化温度下被热氧化，以产生第一级元素溴和剩余的初始富含溴化氢的气体。剩余的初始富含溴化氢的气体的至少一部分在较低的催化氧化温度下被催化氧化以产生第二部分的元素溴。

3. 发明申请

US20090247796A1 PROCESSES FOR CONVERTING GASEOUS ALKANES TO LIQUID HYDROCARBONS 有权
标题翻译：将气态碱转化为液体烃的方法
公开(公告)号：US20090247796A1
公开(公告)日：2009-10-01
申请号：US12477319
申请日：2009-06-03
申请人： John J. Waycuilis , William J. Turner , Raphael Thomas
发明人： John J. Waycuilis , William J. Turner , Raphael Thomas
IPC分类号： C07C19/075 , C07C17/013
CPC分类号： C01B7/093 , C01B7/096 , C01B9/04 , C07C17/10 , C07C17/23 , C07C17/37 , C07C19/075 , C10G50/00 , C10G2300/1011 , C10G2300/1025 , C10G2400/20 , C10G2400/22 , C10L3/10 , C10L3/102 , Y02P30/40
摘要： A process for converting gaseous alkanes to olefins, higher molecular weight hydrocarbons or mixtures thereof wherein a gaseous feed containing alkanes is thermally reacted with a dry bromine vapor to form alkyl bromides and hydrogen bromide. Poly-brominated alkanes present in the alkyl bromides are further reacted with methane over a suitable catalyst to form mono-brominated species. The mixture of alkyl bromides and hydrogen bromide is then reacted over a suitable catalyst at a temperature sufficient to form olefins, higher molecular weight hydrocarbons or mixtures thereof and hydrogen bromide. Various methods are disclosed to remove the hydrogen bromide from the higher molecular weight hydrocarbons, to generate bromine from the hydrogen bromide for use in the process, and to selectively form mono-brominated alkanes in the bromination step.
摘要翻译：将气态烷烃转化为烯烃，较高分子量烃或其混合物的方法，其中含有烷烃的气态进料与干燥溴蒸气反应形成烷基溴化物和溴化氢。存在于烷基溴中的多溴代烷烃进一步与甲烷在合适的催化剂上反应形成单溴化物质。然后在足以形成烯烃，较高分子量烃或其混合物和溴化氢的温度下，通过合适的催化剂使烷基溴和溴化氢的混合物反应。公开了各种方法从高分子量烃中除去溴化氢，从溴化氢中产生溴用于该方法，并在溴化步骤中选择性地形成单溴代烷烃。

4. 发明申请

US20090005620A1 PROCESSES FOR CONVERTING GASEOUS ALKANES TO LIQUID HYDROCARBONS 有权
标题翻译：将气态碱转化为液体烃的方法
公开(公告)号：US20090005620A1
公开(公告)日：2009-01-01
申请号：US12138877
申请日：2008-06-13
申请人： John J. Waycuilis , William J. Turner
发明人： John J. Waycuilis , William J. Turner
IPC分类号： C07C17/013
CPC分类号： C07C19/075 , C01B7/093 , C01B7/096 , C01B9/04 , C07C17/10 , C07C17/23 , C07C17/37 , C10G29/205 , C10G50/00 , C10L3/10 , C10L3/102
摘要： A process for converting gaseous alkanes to olefins, higher molecular weight hydrocarbons or mixtures thereof wherein a gaseous feed containing alkanes is reacted with a dry bromine vapor to form alkyl bromides and hydrobromic acid vapor. The mixture of alkyl bromides and hydrobromic acid is then reacted over a suitable catalyst at a temperature sufficient to form olefins, higher molecular weight hydrocarbons or mixtures thereof and hydrobromic acid vapor. Various methods are disclosed to remove the hydrobromic acid vapor from the higher molecular weight hydrocarbons, to generate bromine from the hydrobromic acid for use in the process, and to selectively form monobrominated alkanes in the bromination step.
摘要翻译：将气态烷烃转化为烯烃，较高分子量烃或其混合物的方法，其中含有烷烃的气态原料与干燥的溴蒸气反应形成烷基溴和氢溴酸。然后将烷基溴和氢溴酸的混合物在足以形成烯烃，较高分子量烃或其混合物和氢溴酸蒸气的温度下在合适的催化剂上反应。公开了各种方法以从较高分子量的烃中除去氢溴酸蒸气，以便在该方法中使用氢溴酸产生溴，并在溴化步骤中选择性地形成一溴化烷烃。

5. 发明授权

US07064238B2 Conversion of alkanes to oxygenates 失效
标题翻译：烷烃转化为含氧化合物
公开(公告)号：US07064238B2
公开(公告)日：2006-06-20
申请号：US10750984
申请日：2004-01-02
申请人： John J. Waycuilis
发明人： John J. Waycuilis
IPC分类号： C07C41/01 , C07C29/00
CPC分类号： C07C29/124 , C07B41/00 , C07C41/01 , C07C43/043 , C07C31/04 , C07C31/08
摘要： A process is provided for converting an alkane to an oxygenated product by passing an alkane gas over a first fixed bed containing a higher valence bromide salt to produce an alkyl bromide, a hydrobromic acid, and a lower valence bromide salt. The alkyl bromide and hydrobromic acid are conveyed as a gas to a second fixed bed containing a metal oxide and are passed over the second fixed bed to produce the first bromide salt and the oxygenated product. The metal oxide in the second fixed bed is regenerated by passing oxygen over the second fixed bed producing the metal oxide and bromine. The bromine is conveyed as a gas from the second fixed bed to the first fixed bed. The first bromide salt of the first fixed bed is regenerated by passing the bromine over the first fixed bed producing the first bromide salt.
摘要翻译：提供了一种通过使烷烃气体通过含有较高价溴化物盐的第一固定床将烷烃转化为氧化产物以产生烷基溴，氢溴酸和低价溴化物盐的方法。将烷基溴和氢溴酸作为气体输送到含有金属氧化物的第二固定床，并通过第二固定床以产生第一溴化物盐和氧化产物。第二固定床中的金属氧化物通过使氧气通过第二固定床而再生，产生金属氧化物和溴。溴作为气体从第二固定床输送到第一固定床。第一固定床的第一溴化物盐通过将溴通过第一固定床而再生，产生第一溴化物盐。

6. 发明授权

US6130259A Hydrocarbon gas conversion system and process for producing a synthetic hydrocarbon liquid 失效
标题翻译：碳氢化合物气体转化系统和合成烃液体的制造方法
公开(公告)号：US6130259A
公开(公告)日：2000-10-10
申请号：US135821
申请日：1998-08-18
申请人： John J. Waycuilis
发明人： John J. Waycuilis
IPC分类号： C01B3/38 , C07C1/04 , F23C6/04 , F23R3/34 , F23R3/36 , C07C27/06
CPC分类号： C01B3/382 , C10G2/32 , F23C6/047 , F23R3/346 , F23R3/36 , C01B2203/0244 , C01B2203/0415 , C01B2203/062 , C01B2203/0844 , C01B2203/0883 , C01B2203/0894 , C01B2203/1052 , C01B2203/1241 , C01B2203/127 , C01B2203/1276 , C01B2203/141 , C01B2203/142 , C01B2203/148 , C01B2203/1604 , C01B2203/82 , C01B2203/84 , F23C2201/301 , Y02P20/123 , Y02P20/124
摘要： A system and process are provided for converting a light hydrocarbon gas to a synthetic heavier hydrocarbon liquid. The system includes an autothermal reformer, a Fischer-Tropsch reactor and a Brayton cycle that are structurally and functionally integrated. In the practice of the process, a mixture of a hydrocarbon feed gas, a compressed air feed and process steam is fed to the autothermal reformer to produce a synthesis gas. The synthesis gas is fed to the Fischer-Tropsch reactor where it is catalytically reacted to produce heavy hydrocarbons. The outlet from the Fischer-Tropsch reactor is separated into water, a low heating value tail gas, and the desired hydrocarbon liquid product. The water is pressurized and heated to generate process steam. The tail gas is heated and fed with compressed air and steam to the Brayton cycle having a combustor and a series of power turbines and compressors. The tail gas and air feed are burned in the combustor to produce a combustion gas that is used to drive a power turbine linked by a shaft to an air compressor, thereby driving the air compressor. The system further includes a plurality of heat exchangers that enable heat to be recovered from the outlet of the autothermal reformer. The recovered heat is used to make the process steam as well as to preheat the hydrocarbon feed gas before it is fed to the autothermal reformer, preheat the synthesis gas before it is fed to the Fischer-Tropsch reactor and preheat the tail gas before it is fed to the combustor.
摘要翻译：提供了一种用于将轻烃气体转化为合成较重烃液体的系统和方法。该系统包括结构和功能集成的自热重整器，费 - 托反应器和布雷顿循环。在该方法的实践中，将烃进料气体，压缩空气进料和工艺蒸汽的混合物供给到自热重整器以产生合成气。将合成气送入费 - 托反应器，在其中催化反应生成重质烃。费 - 托反应器的出口被分离成水，低热值尾气和所需的烃液体产物。水被加压和加热以产生工艺蒸汽。尾气被加热，并将压缩空气和蒸汽送入具有燃烧器和一系列动力涡轮机和压缩机的布雷顿循环。尾气和空气进料在燃烧器中燃烧以产生用于将由轴连接的动力涡轮机驱动到空气压缩机的燃烧气体，从而驱动空气压缩机。该系统还包括多个热交换器，其使热能够从自热重整器的出口回收。回收的热量用于制造工艺蒸汽，以及在将烃进料气体进料到自热重整器之前对其进行预热，在将合成气送入费 - 托反应器之前对其进行预热，并在尾气预热之前预热尾气进料到燃烧器。

7. 发明申请

US20120141356A1 PROCESSES FOR CONVERTING GASEOUS ALKANES TO LIQUID HYDROCARBONS USING MICROCHANNEL REACTOR 失效
标题翻译：使用微通道反应器将气态碱转化成液体烃的方法
公开(公告)号：US20120141356A1
公开(公告)日：2012-06-07
申请号：US13117785
申请日：2011-05-27
申请人： Raymond T. Brickey , Greg A. Lisewsky , John J. Waycuilis , Stephen D. York
发明人： Raymond T. Brickey , Greg A. Lisewsky , John J. Waycuilis , Stephen D. York
IPC分类号： C07C7/148 , C07C17/013 , B01J19/00 , C01B7/09 , C01B9/04
CPC分类号： C07C1/26 , B01J8/0457 , B01J19/0093 , B01J2208/00256 , B01J2208/025 , B01J2219/00006 , B01J2219/00038 , B01J2219/0004 , B01J2219/00783 , B01J2219/00817 , B01J2219/00822 , B01J2219/00824 , B01J2219/00831 , B01J2219/00835 , B01J2219/00867 , B01J2219/00869 , B01J2219/00873 , C01B7/093 , C07C17/10 , C10G29/205 , C10G2300/1025 , C10G2300/1081 , C10G2400/20 , C10G2400/22 , Y02P30/40 , C07C11/02 , C07C19/075
摘要： A process for converting gaseous alkanes to olefins, higher molecular weight hydrocarbons or mixtures thereof wherein a gaseous feed containing alkanes may be thermally or catalytically reacted with a dry bromine vapor to form alkyl bromides and hydrogen bromide. Poly-brominated alkanes present in the alkyl bromides may be further reacted with methane over a suitable catalyst to form mono-brominated species. The mixture of alkyl bromides and hydrogen bromide may then be reacted over a suitable catalyst at a temperature sufficient to form olefins, higher molecular weight hydrocarbons or mixtures thereof and hydrogen bromide. Various methods and reactions are disclosed to remove the hydrogen bromide from the higher molecular weight hydrocarbons, to generate bromine from the hydrogen bromide for use in the process, to store and subsequently release bromine for use in the process, and to selectively form mono-brominated alkanes in the bromination step. One or more of the reactions of the processes of the present invention may be conducted in a microchannel reactor.
摘要翻译：将气态烷烃转化为烯烃，较高分子量烃或其混合物的方法，其中含有烷烃的气态进料可以与干燥的溴蒸汽热或催化反应形成烷基溴和溴化氢。存在于烷基溴中的多溴代烷烃可以通过合适的催化剂进一步与甲烷反应形成单溴化物质。然后可以在足以形成烯烃，较高分子量烃或其混合物和溴化氢的温度下，在合适的催化剂上使烷基溴和溴化氢的混合物反应。公开了各种方法和反应以从较高分子量的烃中除去溴化氢，从溴化氢中产生溴用于该方法，储存和随后释放用于该方法的溴，并选择性地形成单溴化烷烃在溴化步骤中。本发明方法的一个或多个反应可以在微通道反应器中进行。

8. 发明申请

US20110218374A1 PROCESSES AND SYSTEMS FOR THE STAGED SYNTHESIS OF ALKYL BROMIDES 有权
标题翻译：用于氨基酪氨酸标记合成的方法和系统
公开(公告)号：US20110218374A1
公开(公告)日：2011-09-08
申请号：US13030053
申请日：2011-02-17
申请人： John J. Waycuilis
发明人： John J. Waycuilis
IPC分类号： C07C1/26
CPC分类号： C07C1/30 , B01J8/0453 , B01J8/0457 , B01J2208/00203 , C07C1/26 , C07C2529/08 , C07C2529/40 , C07C2529/70 , C07C9/14 , C07C11/02
摘要： Processes and systems for synthesizing hydrocarbon products, such as high molecular weight hydrocarbons, olefins or mixtures thereof, from alkyl bromides wherein one or more streams of alkyl bromides may be reacted in sequential or concurrent stages at different temperatures. The catalyst used in the synthesis stages may be the same or different and at least in one instance is chosen to form hydrocarbon products having a significant C6+ paraffin content. The stages may be conducted in one or more reactors and the catalyst may be deployed in fixed beds or fluidized beds.
摘要翻译：从烷基溴化物合成烃产物如高分子量烃，烯烃或其混合物的方法和系统，其中一个或多个烷基溴化物流可以在不同温度下以顺序或并行阶段反应。在合成阶段中使用的催化剂可以相同或不同，并且至少在一种情况下选择形成具有显着的C6 +链烷烃含量的烃产物。这些阶段可以在一个或多个反应器中进行，催化剂可以部署在固定床或流化床中。

9. 发明申请

US20110218372A1 PROCESSES AND SYSTEMS FOR THE STAGED SYNTHESIS OF ALKYL BROMIDES 失效
标题翻译：用于氨基酪氨酸标记合成的方法和系统
公开(公告)号：US20110218372A1
公开(公告)日：2011-09-08
申请号：US12715526
申请日：2010-03-02
申请人： John J. Waycuilis , William J. Turner
发明人： John J. Waycuilis , William J. Turner
IPC分类号： C07C1/26 , B01J8/04
CPC分类号： B01J8/04 , C07C1/26
摘要： Processes and systems for synthesizing alkyl bromides to hydrocarbon products, such as high molecular weight hydrocarbons, olefins or mixtures thereof, wherein one or more streams of alkyl bromides may be synthesized in sequential or concurrent stages at different temperatures. The catalyst used in the synthesis stages may be the same or different and at least in one instance is chosen to form hydrocarbon products having a significant C6+ paraffin content. The stages may be conducted in one or more reactors and the catalyst may be deployed in fixed beds or fluidized beds.
摘要翻译：将烷基溴化物合成烃产物如高分子量烃，烯烃或其混合物的方法和系统，其中一个或多个烷基溴流可以在不同温度下以顺序或并行阶段合成。在合成阶段中使用的催化剂可以相同或不同，并且至少在一种情况下选择形成具有显着的C6 +链烷烃含量的烃产物。这些阶段可以在一个或多个反应器中进行，催化剂可以部署在固定床或流化床中。

10. 发明申请

US20110071326A1 PROCESS FOR CONVERTING GASEOUS ALKANES TO LIQUID HYDROCARBONS 审中-公开
标题翻译：将气态碱转化为液体烃的方法
公开(公告)号：US20110071326A1
公开(公告)日：2011-03-24
申请号：US12957036
申请日：2010-11-30
申请人： John J. Waycuilis
发明人： John J. Waycuilis
IPC分类号： C07C17/10 , C07C1/26
CPC分类号： C07C1/30 , C01B7/093 , C01B7/096 , C01B9/04 , C07C1/26 , C07C1/321 , C07C17/07 , C07C17/10 , C07C17/35 , C07C2529/40 , C10G29/205 , C10G29/26 , C10G50/00 , C10G50/02 , C10G2400/02 , C10G2400/20 , C07C9/00 , C07C19/075
摘要： Embodiments disclose a process for converting gaseous alkanes to higher molecular weight hydrocarbons, olefins or mixtures thereofs wherein a gaseous feed containing alkanes may be reacted with a dry bromine vapor to form alkyl bromides and hydrobromic acid vapor. The mixture of alkyl bromides and hydrobromic acid then may be reacted over a synthetic crystalline alumino-silicate catalyst, such as a ZSM-5 or an X or Y type zeolite, at a temperature of from about 250° C. to about 500° C. so as to form hydrobromic acid vapor and higher molecular weight hydrocarbons, olefins or mixtures thereof. Various methods are disclosed to remove the hydrobromic acid vapor from the higher molecular weight hydrocarbons, olefins or mixtures thereof and to generate bromine from the hydrobromic acid for use in the process.
摘要翻译：实施方案公开了将气态烷烃转化为较高分子量烃，烯烃或其混合物的方法，其中含有烷烃的气态进料可与干燥溴蒸汽反应形成烷基溴和氢溴酸蒸气。烷基溴和氢溴酸的混合物然后可以在约250℃至约500℃的温度下在合成的结晶铝硅酸盐催化剂如ZSM-5或X或Y型沸石上反应以形成氢溴酸蒸气和较高分子量的烃，烯烃或其混合物。公开了各种方法从较高分子量的烃，烯烃或其混合物中除去氢溴酸蒸气，并从氢溴酸中产生溴，以用于该方法。

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