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1. 发明授权

US08642822B2 Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor 失效
标题翻译：使用微通道反应器将气态烷烃转化为液态烃的方法
公开(公告)号：US08642822B2
公开(公告)日：2014-02-04
申请号：US13117785
申请日：2011-05-27
申请人： Raymond T. Brickey , Greg A. Lisewsky , John J. Waycuilis , Stephen D. York
发明人： Raymond T. Brickey , Greg A. Lisewsky , John J. Waycuilis , Stephen D. York
IPC分类号： C07C1/00
CPC分类号： C07C1/26 , B01J8/0457 , B01J19/0093 , B01J2208/00256 , B01J2208/025 , B01J2219/00006 , B01J2219/00038 , B01J2219/0004 , B01J2219/00783 , B01J2219/00817 , B01J2219/00822 , B01J2219/00824 , B01J2219/00831 , B01J2219/00835 , B01J2219/00867 , B01J2219/00869 , B01J2219/00873 , C01B7/093 , C07C17/10 , C10G29/205 , C10G2300/1025 , C10G2300/1081 , C10G2400/20 , C10G2400/22 , Y02P30/40 , C07C11/02 , C07C19/075
摘要： A process for converting gaseous alkanes to olefins, higher molecular weight hydrocarbons or mixtures thereof wherein a gaseous feed containing alkanes may be thermally or catalytically reacted with a dry bromine vapor to form alkyl bromides and hydrogen bromide. Poly-brominated alkanes present in the alkyl bromides may be further reacted with methane over a suitable catalyst to form mono-brominated species. The mixture of alkyl bromides and hydrogen bromide may then be reacted over a suitable catalyst at a temperature sufficient to form olefins, higher molecular weight hydrocarbons or mixtures thereof and hydrogen bromide. Various methods and reactions are disclosed to remove the hydrogen bromide from the higher molecular weight hydrocarbons, to generate bromine from the hydrogen bromide for use in the process, to store and subsequently release bromine for use in the process, and to selectively form mono-brominated alkanes in the bromination step. One or more of the reactions of the processes of the present invention may be conducted in a microchannel reactor.
摘要翻译：将气态烷烃转化为烯烃，较高分子量烃或其混合物的方法，其中含有烷烃的气态进料可以与干燥的溴蒸汽热或催化反应形成烷基溴和溴化氢。存在于烷基溴中的多溴代烷烃可以通过合适的催化剂进一步与甲烷反应形成单溴化物质。然后可以在足以形成烯烃，较高分子量烃或其混合物和溴化氢的温度下，在合适的催化剂上使烷基溴和溴化氢的混合物反应。公开了各种方法和反应以从较高分子量的烃中除去溴化氢，从溴化氢中产生溴用于该方法，储存和随后释放用于该方法的溴，并选择性地形成单溴化烷烃在溴化步骤中。本发明方法的一个或多个反应可以在微通道反应器中进行。

2. 发明授权

US5058012A Method of extrapolating reservoir performance 失效
标题翻译：外推油藏性能的方法
公开(公告)号：US5058012A
公开(公告)日：1991-10-15
申请号：US609039
申请日：1990-11-05
申请人： Steven B. Hinchman , Raymond T. Brickey , Michael J. Heymans
发明人： Steven B. Hinchman , Raymond T. Brickey , Michael J. Heymans
IPC分类号： E21B49/00
CPC分类号： E21B49/00
摘要： A method of determining a numerical index from a cored well that corresponds to the performance data of a portion of a reservoir and a method of extrapolating the performance of such portion of a reservoir to the entire reservoir through use of the numerical index. Selected variables which affect fluid flow in the reservoir are compared by a statistical analysis computer program to performance data of the computer simulated portion of the reservoir after both the data and variables have been normalized to dimensionless values. The resulting numerical index is computed for the cored wells both inside and outside the small reservoir area, and a contour or iso-index map is drawn. Well performance outside the simulated area can be compared to expected performance through the numerical index values.
摘要翻译：一种从核心井确定与储层的一部分的性能数据相对应的数值指标的方法，以及通过使用数字指数将储层的这种部分的性能外推到整个储层的方法。通过统计分析计算机程序将数据和变量的数据和变量归一化为无量纲值，将影响储层中流体流量的选定变量与储层计算机模拟部分的性能数据进行比较。对小库区内外的核心井计算得到的数值指标，绘制轮廓或等指标图。模拟区域外的良好性能可以通过数值指标值与预期的性能进行比较。

3. 发明申请

US20120141356A1 PROCESSES FOR CONVERTING GASEOUS ALKANES TO LIQUID HYDROCARBONS USING MICROCHANNEL REACTOR 失效
标题翻译：使用微通道反应器将气态碱转化成液体烃的方法
公开(公告)号：US20120141356A1
公开(公告)日：2012-06-07
申请号：US13117785
申请日：2011-05-27
申请人： Raymond T. Brickey , Greg A. Lisewsky , John J. Waycuilis , Stephen D. York
发明人： Raymond T. Brickey , Greg A. Lisewsky , John J. Waycuilis , Stephen D. York
IPC分类号： C07C7/148 , C07C17/013 , B01J19/00 , C01B7/09 , C01B9/04
CPC分类号： C07C1/26 , B01J8/0457 , B01J19/0093 , B01J2208/00256 , B01J2208/025 , B01J2219/00006 , B01J2219/00038 , B01J2219/0004 , B01J2219/00783 , B01J2219/00817 , B01J2219/00822 , B01J2219/00824 , B01J2219/00831 , B01J2219/00835 , B01J2219/00867 , B01J2219/00869 , B01J2219/00873 , C01B7/093 , C07C17/10 , C10G29/205 , C10G2300/1025 , C10G2300/1081 , C10G2400/20 , C10G2400/22 , Y02P30/40 , C07C11/02 , C07C19/075
摘要： A process for converting gaseous alkanes to olefins, higher molecular weight hydrocarbons or mixtures thereof wherein a gaseous feed containing alkanes may be thermally or catalytically reacted with a dry bromine vapor to form alkyl bromides and hydrogen bromide. Poly-brominated alkanes present in the alkyl bromides may be further reacted with methane over a suitable catalyst to form mono-brominated species. The mixture of alkyl bromides and hydrogen bromide may then be reacted over a suitable catalyst at a temperature sufficient to form olefins, higher molecular weight hydrocarbons or mixtures thereof and hydrogen bromide. Various methods and reactions are disclosed to remove the hydrogen bromide from the higher molecular weight hydrocarbons, to generate bromine from the hydrogen bromide for use in the process, to store and subsequently release bromine for use in the process, and to selectively form mono-brominated alkanes in the bromination step. One or more of the reactions of the processes of the present invention may be conducted in a microchannel reactor.
摘要翻译：将气态烷烃转化为烯烃，较高分子量烃或其混合物的方法，其中含有烷烃的气态进料可以与干燥的溴蒸汽热或催化反应形成烷基溴和溴化氢。存在于烷基溴中的多溴代烷烃可以通过合适的催化剂进一步与甲烷反应形成单溴化物质。然后可以在足以形成烯烃，较高分子量烃或其混合物和溴化氢的温度下，在合适的催化剂上使烷基溴和溴化氢的混合物反应。公开了各种方法和反应以从较高分子量的烃中除去溴化氢，从溴化氢中产生溴用于该方法，储存和随后释放用于该方法的溴，并选择性地形成单溴化烷烃在溴化步骤中。本发明方法的一个或多个反应可以在微通道反应器中进行。

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