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1. 发明授权

US4645855A Preparation of succinic acid diesters 失效
标题翻译：琥珀酸二酯的制备
公开(公告)号：US4645855A
公开(公告)日：1987-02-24
申请号：US644496
申请日：1984-08-24
申请人： Johannes G. Reuvers , Wolfgang Richter , Rudolf Kummer
发明人： Johannes G. Reuvers , Wolfgang Richter , Rudolf Kummer
IPC分类号： C07C67/38 , C07C69/40 , C07C67/03
CPC分类号： C07C67/38
摘要： A process for the preparation of succinic acid diesters by carbonylation of acrylic acid esters in the presence of alcohols, using a cobalt carbonyl complex as the catalyst and a heterocyclic nitrogen base as the promoter, at 80.degree.-200.degree. C. and under a carbon monoxide pressure of 60-300 bar, wherein the reaction is carried out in the presence of not less than 20% by weight, based on the amount of all the liquid constituents of the reaction mixture, of an inert liquid and the concentration of the acrylic acid ester is kept, for the predominant part of the reaction time, at below 15% by weight, again based on the amount of all liquid constituents.
摘要翻译：通过在醇的存在下，使用羰基钴络合物作为催化剂和杂环氮碱作为助催化剂，在丙烯酸酯的羰基化作用下，在80℃-200℃和碳下，制备琥珀酸二酯的方法一氧化碳压力为60-300巴，其中反应在不少于20重量％的存在下进行，基于反应混合物的所有液体组分的量，惰性液体的浓度和丙烯酸的浓度酸性酯在反应时间的主要部分保持在15重量％以下，再次基于所有液体组分的量。

2. 发明授权

US4568653A Working up of hydroformylation or carbonylation reaction mixtures 失效
标题翻译：加工甲酰化或羰基化反应混合物
公开(公告)号：US4568653A
公开(公告)日：1986-02-04
申请号：US222893
申请日：1981-01-06
申请人： Kurt Schwirten , Rudolf Kummer , Wolfgang Richter
发明人： Kurt Schwirten , Rudolf Kummer , Wolfgang Richter
IPC分类号： C07C45/49 , C07C29/16 , C07C29/76 , C07C29/86 , C07C45/00 , C07C45/50 , C07C45/78 , C07C67/00 , C07C67/38 , C07C67/58 , B01J31/40 , C07C51/14
CPC分类号： C07C29/16 , C07C29/76 , C07C29/86 , C07C45/50 , C07C45/78
摘要： Reaction mixtures which are obtained on hydroformylation or carbonylation of olefinically unsaturated compounds and which contain dissolved non-volatile complex compounds of metals of group VIII of the periodic table are worked up by a method wherein the products, after distillative removal of low-boiling constituents alone, or of these constituents plus a part of the high-boiling residue, or a part of the high-boiling residue after distillative removal of the desired products, are or is extracted with carbon dioxide, a C.sub.2 -C.sub.4 -paraffin, a C.sub.2 -C.sub.4 -olefin or a normally gaseous halohydrocarbon at above the critical temperature and above the critical pressure of these (extractant) compounds.
摘要翻译：在烯属不饱和化合物的加氢甲酰化或羰基化获得并且含有周期表第VIII族金属的溶解的非挥发性络合物的反应混合物通过一种方法来处理，其中产物在蒸馏除去低沸点组分之后，或这些成分加上一部分高沸点残余物，或蒸馏除去所需产物后的一部分高沸点残余物，用二氧化碳，C2-C4-链烷烃，C2- 在高于临界温度并高于这些（萃取剂）化合物的临界压力的C4-烯烃或正常气态的卤代烃。

3. 发明授权

US4537987A Preparation of pure monoesters of adipic acid 失效
标题翻译：己二酸纯单酯的制备
公开(公告)号：US4537987A
公开(公告)日：1985-08-27
申请号：US629766
申请日：1984-07-11
申请人： Heinz-Walter Schneider , Wolfgang Richter , Walter Disteldorf , Rudolf Kummer
发明人： Heinz-Walter Schneider , Wolfgang Richter , Walter Disteldorf , Rudolf Kummer
IPC分类号： B01J31/00 , B01J31/20 , B01J31/24 , C07B61/00 , C07C67/313 , C07C67/38 , C07C67/39 , C07C69/44 , C07C69/67
CPC分类号： C07C67/39
摘要： Pure monoesters of adipic acid are prepared by a process in which(a) a pentenoate is reacted with carbon monoxide and hydrogen at from 90.degree. to 140.degree. C. and under from 5 to 300 bar in the presence of a carbonyl complex of cobalt or of rhodium, and a 5-formylvalerate is separated off, and(b) the 5-formylvalerate thus obtained is oxidized with molecular oxygen, or with a gas containing this, at from 20.degree. to 100.degree. C. under from 1 to 10 bar.
摘要翻译：己二酸的纯单酯通过以下方法制备，其中（a）戊烯酸酯与一氧化碳和氢气在90至140℃和5至300巴下在钴或羰基络合物存在下反应的铑，并分离出5-甲酰基戊酸酯，（b）将所得的5-甲酰基戊酸酯用分子氧或含有该气体的气体在20至100℃下在1至10巴。

4. 发明授权

US4533757A Continuous hydroformylation of olefinically unsaturated compounds 失效
标题翻译：烯属不饱和化合物的连续加氢甲酰化
公开(公告)号：US4533757A
公开(公告)日：1985-08-06
申请号：US570988
申请日：1984-01-16
申请人： Rudolf Kummer , Wolfgang Richter , Kurt Schwirten , Peter Stops
发明人： Rudolf Kummer , Wolfgang Richter , Kurt Schwirten , Peter Stops
IPC分类号： B01J31/00 , B01J31/22 , B01J31/24 , C07B61/00 , C07C45/00 , C07C45/50 , C07C67/00
CPC分类号： C07C45/50
摘要： Olefinically unsaturated compounds are continuously hydroformylated under from 2 to 30 bar and at from 80.degree. to 130.degree. C. using, as a catalyst, a rhodium complex which contains, as ligands, sparingly volatile compounds of the general formula I ##STR1## where A is phosphorus, arsenic, antimony or bismuth and R.sup.1, R.sup.2 and R.sup.3 are each organic radicals, by a method in which the hydroformylation mixture consisting of liquid and gaseous components is removed from the reactor and is subjected to relatively high temperatures and/or relatively low pressures for a short time in a devolatilization column, the mixture at the same time being separated into a gas phase and a liquid phase, the gas phase is separated into the product and the recycle gas in a separator, and the recycle gas and the liquid phase from the devolatilization column are recycled to the reactor.
摘要翻译：使用作为催化剂的2至30巴和80至130℃下的烯属不饱和化合物连续加氢甲酰化，所述铑配合物含有作为配体的通式Ⅰ的微量挥发性化合物，其中 A是磷，砷，锑或铋，R1，R2和R3各自为有机基团，其中将由液体和气体组分组成的加氢甲酰化混合物从反应器中除去并经受较高温度和/或相对在脱挥发分塔中短时间内的低压，同时将该混合物分离成气相和液相，气相在分离器中分离成产物和再循环气体，再循环气体和来自脱挥发分塔的液相再循环到反应器中。

5. 发明授权

US4400549A Hydroformylation of olefinically unsaturated compounds 失效
标题翻译：烯属不饱和化合物的加氢甲酰化
公开(公告)号：US4400549A
公开(公告)日：1983-08-23
申请号：US324277
申请日：1981-11-23
申请人： Wolfgang Richter , Rudolf Kummer , Kurt Schwirten
发明人： Wolfgang Richter , Rudolf Kummer , Kurt Schwirten
IPC分类号： C07C27/22 , B01J31/00 , B01J31/24 , C07B61/00 , C07C27/00 , C07C29/158 , C07C45/49 , C07C45/50 , C07C67/00
CPC分类号： C07C45/50
摘要： A process for hydroformylating olefinically unsaturated compounds by means of rhodium/triphenylphosphine/carbonyl complexes formed in situ from rhodium acetate, triphenylphosphine and carbon monoxide, wherein the hydroformylation reaction is preceded by a starting phase in which the mixture of the hydroformylation medium, the triphenylphosphine and rhodium acetate is heated at from 90.degree. to 120.degree. C. under a CO/H.sub.2 pressure of from 5 to 20 bar and the acetic acid liberated is discharged from the reactor in gaseous form in a stream of CO and H.sub.2, until virtually no more acetic acid can be detected in this gaseous discharge.
摘要翻译：一种通过铑/三苯基膦/羰基络合物将乙酸铑，三苯基膦和一氧化碳原位形成的铑/三苯基膦/羰基络合物加氢甲酰化的方法，其中加氢甲酰化反应之前是起始阶段，其中加氢甲酰化介质，三苯基膦和乙酸铑在50至20巴的CO / H 2压力下加热至90℃至120℃，释放的乙酸以CO和H 2的气流形式从反应器中排出，直到几乎不再可以在该气体放电中检测乙酸。

6. 发明授权

US4262141A Preparation of aldehydes 失效
标题翻译：醛的制备
公开(公告)号：US4262141A
公开(公告)日：1981-04-14
申请号：US69919
申请日：1979-08-27
申请人： Wolfgang Richter , Rudolf Kummer , Kurt Schwirten
发明人： Wolfgang Richter , Rudolf Kummer , Kurt Schwirten
IPC分类号： B01J31/00 , B01J31/28 , C07B61/00 , C07C45/00 , C07C45/50 , C07C67/00
CPC分类号： C07C45/50
摘要： Aldehydes are prepared by hydroformylating the corresponding olefinically unsaturated compounds with the aid of rhodium-carbonyl complexes which contain tertiary phosphines as ligands, by carrying out the reaction in the presence of compounds of copper, silver or zinc which are soluble in the reaction mixture and do not contain any component which deactivates the rhodium-carbonyl complexes.
摘要翻译：通过在可溶于反应混合物的铜，银或锌化合物的存在下进行反应，借助于含有叔膦作为配体的铑 - 羰基络合物，通过对相应的烯属不饱和化合物进行加氢甲酰化来制备醛不含任何使铑 - 羰基络合物失活的组分。

7. 发明授权

US4454358A Continuous production of ethanol and plural stage distillation of the same 失效
标题翻译：连续生产乙醇和多级蒸馏相同
公开(公告)号：US4454358A
公开(公告)日：1984-06-12
申请号：US337683
申请日：1982-01-07
申请人： Rudolf Kummer , Volker Taglieber , Heinz-Walter Schneider
发明人： Rudolf Kummer , Volker Taglieber , Heinz-Walter Schneider
IPC分类号： C07C29/132 , B01J31/00 , B01J31/20 , C07B61/00 , C07C27/00 , C07C27/04 , C07C29/149 , C07C29/80 , C07C29/92 , C07C31/08 , C07C67/00 , B01D3/00
CPC分类号： C07C29/80 , C07C29/149 , C07C67/08 , C07C67/36 , C07C67/54 , Y02P20/52 , Y10S203/06 , Y10S203/20
摘要： Ethanol is produced continuously via the carbonylation of methanol, by(a) carbonylating methanol, in a reactor R, in the presence of a carbonyl complex of a metal of group VIII of the periodic table and of a halogen compound,(b) separating, in a distillation column D1, the reactor discharge, into a top fraction comprising methyl acetate, methanol, dimethyl ether and an organohalogen compound, and into a bottom fraction comprising water, small quantities of acetic acid and the catalyst, if the latter is not in a fixed bed, the residence time being so adjusted that the greater part of the acetic acid reacts with the methanol present to give methyl acetate,(c) separating the top fraction from D1, in a distillation column D2, into a top fraction comprising small quantities of methyl acetate, methanol, dimethyl ether and the organo-halogen compound, and a bottom fraction comprising methyl acetate and methanol, and recycling the top fraction to reactor R,(d) distilling off, via the top of distillation column D3, the greater part of the water from the bottom fraction from D1and removing this water from circulation, and recycling to reactor R the bottom fraction consisting of small quantities of water, acetic acid and the catalyst,(e) using hydrogen to hydrogenate, in the hydrogenation reactor H, the bottom fraction from D2, in a conventional manner, to give a mixture of methanol and ethanol, and(f) separating the mixture into ethanol and methanol in a distillation column D4, and recycling the methanol to reactor R.
摘要翻译：通过（a）在反应器R中羰基化甲醇，在周期表第VIII族金属的羰基络合物和卤素化合物的存在下，连续生产乙醇，（b）分离，在蒸馏塔D1中，反应器排出成为包含乙酸甲酯，甲醇，二甲醚和有机卤素化合物的顶级馏分，并进入包含水，少量乙酸和催化剂的底部馏分，如果后者不在固定床，停留时间如此调节，使得大部分乙酸与存在的甲醇反应得到乙酸甲酯，（c）将蒸馏塔D2中的顶馏分与D1分离成包含小分子的顶馏分数量的乙酸甲酯，甲醇，二甲醚和有机卤素化合物，以及包含乙酸甲酯和甲醇的底部馏分，并将顶部馏分再循环到反应器R中，（d）通过顶部o蒸馏 f蒸馏塔D3，来自D1的底部馏分的大部分水从循环中除去，并且将反应器R再循环到由少量水，乙酸和催化剂组成的底部馏分，（e）使用氢气以常规方式在氢化反应器H中将来自D2的塔底馏分氢化，得到甲醇和乙醇的混合物，和（f）将混合物在蒸馏塔D4中分离成乙醇和甲醇，并将甲醇再循环至反应器

8. 发明授权

US4350572A Purification of carboxylic acid esters containing aldehydes and/or acetals 失效
标题翻译：含醛和/或缩醛的羧酸酯的纯化
公开(公告)号：US4350572A
公开(公告)日：1982-09-21
申请号：US204637
申请日：1980-11-06
申请人： Rudolf Kummer , Volker Taglieber , Franz-Josef Weis , Heinz-Walter Schneider
发明人： Rudolf Kummer , Volker Taglieber , Franz-Josef Weis , Heinz-Walter Schneider
IPC分类号： C07C67/48 , C07C67/38 , C07C67/56 , C07C67/60 , C07C69/44 , B01D3/34
CPC分类号： C07C67/60
摘要： A process for purifying carboxylic acid esters which have been obtained by reacting olefinically unsaturated compounds with carbon monoxide and alkanols and which contain aldehydes or acetals, wherein the said esters are treated with a strongly acidic agent, with or without addition of water.
摘要翻译：通过使烯属不饱和化合物与一氧化碳和链烷醇反应并且含有醛或缩醛而获得的羧酸酯的方法，其中所述酯用强酸性剂处理，或不加入水。

9. 发明授权

US4305888A Manufacture of salts of dicarboxylic acids and diamines 失效
标题翻译：二羧酸和二胺的盐的制造
公开(公告)号：US4305888A
公开(公告)日：1981-12-15
申请号：US813971
申请日：1977-07-08
申请人： Rudolf Kummer , Rolf Platz , Heinz-Walter Schneider
发明人： Rudolf Kummer , Rolf Platz , Heinz-Walter Schneider
IPC分类号： C07C55/02 , C07C51/00 , C07C55/10 , C07C55/12 , C07C55/14 , C07C55/16 , C07C55/18 , C07C55/20 , C07C55/21 , C07C67/00 , C07C209/00 , C07C211/09 , C07C87/14
CPC分类号： C07C55/20 , C07C55/10 , C07C55/12 , C07C55/14 , C07C55/16 , C07C55/18 , C07C55/21
摘要： A process for the manufacture of salts of alkanedicarboxylic acids of 4 to 12 carbon atoms and alkanediamines of 3 to 14 carbon atoms, comprising reacting esters of alkanols of 1 to 4 carbon atoms and alkanedicarboxylic acids of 4 to 12 carbon atoms with alkanediamines of 3 to 14 carbon atoms in stoichiometric amounts in the presence of water at an elevated temperature, with continuous removal of the alkanols formed, in which process the reaction is carried out, from the start, in the presence of the particular salt of alkanedicarboxylic acid and alkanediamine which is to be manufactured.
摘要翻译：一种制备4至12个碳原子的链烷二羧酸盐和3至14个碳原子的烷二胺的方法，包括使1至4个碳原子的链烷醇与4至12个碳原子的烷基二羧酸酯与3个烷二胺反应在高温存在下，在水存在下，化学计算量为14个碳原子，连续除去所形成的链烷醇，在该过程中进行反应，从一开始就在特定的烷基二羧酸和烷二胺盐存在下将被制造。

10. 发明授权

US4259520A Preparation of butanedicarboxylic acid esters 失效
标题翻译：丁烷二羧酸酯的制备
公开(公告)号：US4259520A
公开(公告)日：1981-03-31
申请号：US2329
申请日：1979-01-10
申请人： Rudolf Kummer , Heinz-Walter Schneider , Franz-Josef Weiss
发明人： Rudolf Kummer , Heinz-Walter Schneider , Franz-Josef Weiss
IPC分类号： C07C67/38
CPC分类号： C07C67/38
摘要： In a process for the preparation of butanedicarboxylic acid esters by(a) reacting butadiene or hydrocarbon mixtures containing butadiene with carbon monoxide and a C.sub.1 -C.sub.4 -alkanol in the presence of a tertiary nitrogen base and a cobalt carbonyl catalyst at from 80.degree. to 150.degree. C. under superatmospheric pressure,(b) removing the greater part of the tertiary nitrogen base together with any excess hydrocarbon and(c) reacting the resulting pentenoic acid ester, in the presence of the catalyst remaining in the reaction mixture, and in the presence of the remaining amount of tertiary nitrogen base, with carbon monoxide and a C.sub.1 - to C.sub.4 -alkanol at from 140.degree. to 200.degree. C. under superatmospheric pressure, to give the butanedicarboxylic acid ester, the improvement wherein the reaction mixture in stage c) is substantially free from dissolved butadiene or butadiene bonded to the catalyst.Butanedicarboxylic acid esters may be used for the preparation of polymers.
摘要翻译：在（a）将叔丁基或含有丁二烯的烃混合物与一氧化碳和C 1 -C 4烷醇在叔氮碱和羰基钴催化剂存在下反应制备丁烷二羧酸酯的方法中，（b）将大部分叔氮碱与任何过量的烃一起除去，和（c）使所得戊烯酸酯在残留在反应混合物中的催化剂存在下反应，并在在超大气压下，在140℃至200℃下存在剩余量的叔氮碱，一氧化碳和一种C 1 -C 4烷醇，得到丁烷二羧酸酯，其中阶段c中的反应混合物）基本上不含结合到催化剂上的溶解的丁二烯或丁二烯。丁二羧酸酯可用于制备聚合物。

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