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1. 发明申请

US20180044277A1 CONTINUOUS PROCESS OF OXIDATIVE CLEAVAGE OF VEGETABLE OILS 审中-公开
公开(公告)号：US20180044277A1
公开(公告)日：2018-02-15
申请号：US15697515
申请日：2017-09-07
申请人： Novamont S.p.A.
发明人： Arno BIESER , Giampietro Borsotti , Francesca Digioia , Adriano Ferrari , Alessandro Pirocco
IPC分类号： C07C51/285 , C07C51/353 , C07C51/09 , C07C53/126 , C07C51/245 , C07C55/02 , C07C55/18 , C07C51/347 , C07C51/16
CPC分类号： C07C51/285 , C07C51/09 , C07C51/16 , C07C51/245 , C07C51/347 , C07C51/353 , C11C1/04 , C07C55/02 , C07C55/18 , C07C53/126
摘要： A continuous process for the oxidative cleavage of vegetable oils containing triglycerides of unsaturated carboxylic acids, to obtain saturated carboxylic acids, comprising feeding to a first continuous reactor a vegetable oil, an oxidizing compound and catalyst capable of catalyzing the oxidation reaction of the olefinic double bond to obtain an intermediate compound containing vicinal diols: feeding to a second continuous reactor said intermediate compound, a compound containing oxygen and a catalyst capable of catalyzing the oxidation reaction of the vicinal diols to carboxylic groups, to obtain saturated monocarboxylic acids (i) and triglycerides containing saturated carboxylic acids with more than one acid function (ii); separating the saturated monocarboxylic acids (i) from the triglycerides (ii); hydrolyzing in a third reactor the triglycerides (ii) to obtain glycerol and saturated carboxylic acids with more than one acid function; and purifying said saturated carboxylic acids by fractioned crystallization by means of wash column (melt crystallization).

2. 发明授权

US09248381B2 Method of purifying a dicarboxylic acid 有权
标题翻译：纯化二羧酸的方法
公开(公告)号：US09248381B2
公开(公告)日：2016-02-02
申请号：US13358943
申请日：2012-01-26
申请人： Thomas Chad Walker , Stephen W. Turner , Jay William Landwehr , Douglas da Silva Rosa , Mark Elliot Durchholz
发明人： Thomas Chad Walker , Stephen W. Turner , Jay William Landwehr , Douglas da Silva Rosa , Mark Elliot Durchholz
IPC分类号： C07C51/43 , C07C51/44 , C07C51/34 , B01D3/12 , B01D1/22 , B01D3/04
CPC分类号： B01D3/12 , B01D1/22 , B01D3/04 , C07C51/34 , C07C51/43 , C07C51/44 , C07C55/02 , C07C55/10 , C07C55/14 , C07C55/18 , C07C55/20 , C07C55/21
摘要： A process for purifying a dicarboxylic acid that is derived from the mixed oxidation products from an ozonization of a mixture containing an ethylenically unsaturated compound having between 6 to 24 carbons, the process includes distilling the mixed oxidation products to provide a first distillate, and a second distillate, where the second distillate includes the dicarboxylic acid and impurity acids, partitioning the second distillate between water and a organic solvent, separating the organic solvent layer from the water layer, lowering the temperature of the water layer to crystallize at least a portion of the dicarboxylic acid, separating the crystallized dicarboxylic acid solid, melting the crystallized dicarboxylic acid, and distilling the liquid dicarboxylic acid to provide a purified dicarboxylic acid.
摘要翻译：从含有6〜24个碳原子的烯键式不饱和化合物的混合物的臭氧化而得到的来自混合氧化物的二羧酸的方法，该方法包括蒸馏混合氧化产物以提供第一馏出物，第二馏分馏出物，其中第二馏出物包括二羧酸和杂质酸，将第二馏出物在水和有机溶剂之间分配，将有机溶剂层与水层分离，降低水层的温度以使至少一部分二羧酸，分离结晶二羧酸固体，熔融结晶的二羧酸，蒸馏液体二羧酸，得到纯化的二羧酸。

3. 发明申请

US20150361024A1 PURIFICATION OF POLYCARBOXYLIC ACIDS 有权
标题翻译：纯化聚碳酸
公开(公告)号：US20150361024A1
公开(公告)日：2015-12-17
申请号：US14738600
申请日：2015-06-12
申请人： Verdezyne, Inc.
发明人： Jose LAPLAZA
IPC分类号： C07C51/43 , C07C55/20 , C07C55/02
CPC分类号： C07C51/43 , C07C51/42 , C07C51/47 , C07C55/02 , C07C55/20 , C07C55/18 , C07C55/21 , C07C57/13
摘要： A process for purifying a polycarboxylic acid from a mixture is provided. Optionally, the mixture is an aqueous solution and optionally the process comprises an acidification step and/or the use of one or more organic solvents. Also provided in part are compositions of polycarboxylic acids.
摘要翻译：提供了从混合物中提纯多元羧酸的方法。任选地，混合物是水溶液，任选地该方法包括酸化步骤和/或使用一种或多种有机溶剂。还部分提供多元羧酸的组合物。

4. 发明申请

US20150183704A1 PROCESS FOR THE PREPARATION OF AZELEIC ACID FROM 9-OCTADECENEDIOIC ACID 有权
标题翻译：从9-十一碳烯酸制备三乙酸的方法
公开(公告)号：US20150183704A1
公开(公告)日：2015-07-02
申请号：US14366051
申请日：2012-12-12
申请人： DSM IP ASSETS B.V.
发明人： Paulus Lamburtus Alsters
IPC分类号： C07C51/285 , C08G69/00 , C07C55/18
CPC分类号： C07C51/285 , C07C55/18 , C07C67/333 , C08G69/00 , C07C69/48
摘要： The invention relates to a process for the preparation of azelaic acid or alkyl azelate starting from mono-unsaturated 9-octadecenedioic acid or its corresponding alkylester characterized in that the process comprises at least the following step: reacting the mono-unsaturated 9-octadecene dioic acid or its corresponding alkylester with hydrogen peroxide in the presence of an organic carboxylic acid other than 9-octadecene dioic acid and a suitable catalyst to effect cleavage of the double bond in the mono-unsaturated 9-octadecene dioic acid or its corresponding alkylester. The invention further relates to the azelaic acid or alkyl azelate obtainable by the process according to the invention and to the use of azelaic acid or alkyl azelate or monomers derived there from for the preparation of a polymer, especially a polyamide.
摘要翻译：本发明涉及从单不饱和9-十八烯二酸或其相应的烷基酯开始制备壬二酸或壬二酸烷基酯的方法，其特征在于该方法至少包括以下步骤：使单不饱和9-十八烯二酸或其相应的烷基酯与过氧化氢在除9-十八烯二酸之外的有机羧酸和合适的催化剂存在下进行，以实现单不饱和9-十八烯二酸或其相应的烷基酯中双键的切割。本发明还涉及通过本发明的方法获得的壬二酸或壬基壬磺酸烷基酯，以及由壬二酸或壬二酸烷基酯衍生的单体或其衍生物用于制备聚合物，特别是聚酰胺的用途。

5. 发明申请

US20140200328A1 METHOD FOR PRODUCING ZINC DICARBOXYLATE 审中-公开
标题翻译：生产锌二氰酸酯的方法
公开(公告)号：US20140200328A1
公开(公告)日：2014-07-17
申请号：US14343604
申请日：2012-08-31
申请人： Anna Katharina Brym , Jürgen Zubiller , Gerrit Luinstra , Revaz Korashvili
发明人： Anna Katharina Brym , Jürgen Zubiller , Gerrit Luinstra , Revaz Korashvili
IPC分类号： C08G64/34 , C07F3/06
CPC分类号： C07F3/06 , C07C51/412 , C08G64/34 , C07C55/10 , C07C55/14 , C07C55/16 , C07C55/18 , C07C55/12
摘要： The invention relates to a process for preparing a zinc dicarboxylate from a zinc compound and a C4-C10 dicarboxylic acid in the presence of a cationic emulsifier and a solvent.The invention also relates to zinc dicarboxylates obtainable by the abovementioned process and having a BET surface area of 50 to 750 m2/g.
摘要翻译：本发明涉及一种在阳离子乳化剂和溶剂存在下由锌化合物和C 4 -C 10二羧酸制备二羧酸锌的方法。本发明还涉及通过上述方法获得的BET比表面积为50-750m2 / g的二羧酸锌。

6. 发明申请

US20130131379A1 METHOD FOR PREPARING CARBOXYLIC ACIDS BY OXIDATIVE CLEAVAGE OF A VICINAL DIOL 审中-公开
标题翻译：通过维生素D氧化氧化制备羧酸的方法
公开(公告)号：US20130131379A1
公开(公告)日：2013-05-23
申请号：US13582345
申请日：2011-03-04
申请人： Marc Lemaire , Alain Favre-Reguillon , Bénédicte Paquit , Sylvain Claude , Yann Raoul
发明人： Marc Lemaire , Alain Favre-Reguillon , Bénédicte Paquit , Sylvain Claude , Yann Raoul
IPC分类号： C07C51/377 , C07C51/31
CPC分类号： C07C51/377 , C07C51/29 , C07C51/31 , C07C67/31 , C07C67/333 , C07C55/18 , C07C53/126 , C07C55/14 , C07C69/675 , C07C69/48
摘要： The present invention relates to a method for preparing carboxylic acids, in particular mono- and dicarboxylic acids, by oxidative cleavage of a vicinal diol.According to the invention, said method consists of reacting a vicinal diol of formula I: where: p is an integer comprised between 1 and 6; R1 and R2 are, separately: an alkyl or hydroxyl group having 1 to 12 carbon atoms; a —(CH2)n—C02M group where n, which can be identical or different in R1 and R2, is an integer comprised between 1 and 11 and M is a hydrogen atom or an alkyl group having 1 to 4 carbon atoms or an alkaline cation; or R1 and R2 jointly form an alkylene —(CH2)m- group where m is an integer comprised between 2 and 10, preferably between 2 and 6; with industrial-grade sodium hypochlorite (or bleach), in the absence of an organic solvent and without adding a catalyst, preferably at room temperature. The invention can be used for recycling natural vegetable oils.
摘要翻译：本发明涉及通过邻位二醇的氧化裂解制备羧酸，特别是单羧酸和二羧酸的方法。根据本发明，所述方法包括使式I的邻二醇反应：其中：p是1至6之间的整数; R1和R2分别是具有1至12个碳原子的烷基或羟基; - （CH 2）n -CO 2 M基团，其中在R1和R2中可以相同或不同的n是1和11之间的整数，M是氢原子或具有1至4个碳原子的烷基或碱阳离子; 或R 1和R 2共同形成亚烷基 - （CH 2）m - 基团，其中m为2至10，优选2至6的整数; 在工业级次氯酸钠（或漂白剂）中，在不存在有机溶剂的情况下，优选在室温下不加入催化剂。本发明可用于回收天然植物油。

7. 发明授权

US07186858B2 Method for producing carboxylic acid 失效
标题翻译：羧酸生产方法
公开(公告)号：US07186858B2
公开(公告)日：2007-03-06
申请号：US10522367
申请日：2003-07-24
申请人： Kazuhiko Sato , Youko Usui
发明人： Kazuhiko Sato , Youko Usui
IPC分类号： C07C51/00
CPC分类号： C07C51/31 , B01J23/24 , C07C55/02 , C07C55/16 , C07C55/12 , C07C55/18 , C07C55/14
摘要： The present invention provides a safe, convenient and efficient method for producing carboxylic acid by a reaction of alicyclic alcohol with an aqueous hydrogen peroxide to thereby obtain carboxylic acid in high yield from alicyclic alcohol or alicyclic ketone under mild reaction conditions, wherein the reaction operation is simple and easy, a step for removing solvent after completion of the reaction is not necessary and influence and toxicity upon the environment and human body are markedly small. In order to provide it, an oily alicyclic alcohol is allowed to react with an aqueous hydrogen peroxide in the presence of a catalyst containing a metal compound belonging to Group 6 of the Periodic Table in a heterogeneous solution system.
摘要翻译：本发明提供一种通过脂环醇与过氧化氢水溶液的反应制备羧酸的安全，方便和有效的方法，从而在温和的反应条件下从脂环族醇或脂环族酮得到高产率的羧酸，其中反应操作是简单易行，不需要在反应完成后除去溶剂的步骤，对环境和人体的影响和毒性明显较小。为了提供它，使油性脂环醇在含有属于元素周期表第6族的金属化合物的催化剂的存在下在过氧化氢水溶液的异构溶液体系中反应。

8. 发明授权

US4713201A Process for the preparation of salts of a dicarboxylic acid and a diamine 失效
标题翻译：二羧酸和二胺的盐的制备方法
公开(公告)号：US4713201A
公开(公告)日：1987-12-15
申请号：US875547
申请日：1986-06-18
申请人： Georg Pilz , Gert Buerger , Manfred Barl , Gerhard Thiel
发明人： Georg Pilz , Gert Buerger , Manfred Barl , Gerhard Thiel
IPC分类号： C07C51/41 , C07C51/00 , C07C55/02 , C07C55/14 , C07C55/18 , C07C55/20 , C07C55/21 , C07C67/00 , C07C213/00 , C07C217/08 , C07C83/00
CPC分类号： C07C55/14 , C07C55/18 , C07C55/20 , C07C55/21
摘要： A process for the preparation of salts of dicarboxylic acids and diamines of the formulaH.sub.2 N-(R.sup.1 -O).sub.n -R.sup.2 -NH.sub.2 Iwhere R.sup.1 and R.sup.2 may be identical or different and are each alkylene of 2 to 4 carbon atoms and n is an integer from 1 to 3, which contain hydrazine in the form of hydrazine hydrate.
摘要翻译：制备式H2N-（R1-O）n-R2-NH2I的二羧酸和二胺的盐的方法，其中R 1和R 2可以相同或不同，并且各自是2至4个碳原子的亚烷基，n是 1〜3的整数，含有水合肼形式的肼。

9. 发明授权

US3895040A Method for manufacture of fatty acids and dibasic acids 失效
标题翻译：脂肪酸和二元酸的制造方法
公开(公告)号：US3895040A
公开(公告)日：1975-07-15
申请号：US29772772
申请日：1972-10-16
申请人： AGENCY IND SCIENCE TECHN
发明人： MIYAZAKI SHOJI , SUHARA YASUO
IPC分类号： C07C51/235 , C07C51/245 , C08H17/36
CPC分类号： C07C51/245 , C07C51/235 , C07C55/10 , C07C53/126 , C07C55/21 , C07C53/124 , C07C53/122 , C07C55/02 , C07C55/18 , C07C55/20
摘要： An Alpha , omega -glycol, a primary alcohol or an aliphatic compound having one or two secondary alcohol groups is dissolved in a solvent. The resulting solution is heated to 10* - 70*C and brought into contact with an ozone-containing gas. Then, the solution is elevated to 70* - 110*C and brought into contact with an oxygen-containing gas. By thus oxidizing the starting material, there is formed in the solution a dibasic acid or a fatty acid; the former acid occurs where the starting material being used is an Alpha , omega -glycol and the latter acid occurs where it is either a primary alcohol or an aliphatic compound having one or two secondary alcohol groups. The dibasic acid or fatty acid thus formed within the solution can be isolated by removing the solvent from the solution.
摘要翻译：将α，ω-二醇，伯醇或具有一个或两个仲醇基团的脂肪族化合物溶解在溶剂中。将所得溶液加热至10〜70℃，与含臭氧气体接触。然后，将溶液升温至70〜110℃，与含氧气体接触。通过这样氧化原料，在溶液中形成二元酸或脂肪酸; 在使用起始原料为α，ω-二醇的情况下，发生前者酸，后者在其中是伯醇或具有一个或两个仲醇基团的脂族化合物的情况下发生。通过从溶液中除去溶剂，可以分离溶液中形成的二元酸或脂肪酸。

10. 发明授权

US3845119A Organics from trona brine by co2 treatment 失效
标题翻译：二氧化碳处理来自TRONA BRINE的有机物
公开(公告)号：US3845119A
公开(公告)日：1974-10-29
申请号：US30647772
申请日：1972-11-10
申请人： MARATHON OIL CO
发明人： DUKE R , SEPPI N
IPC分类号： C07C51/42 , C07C51/48 , C07C51/487 , C07C55/02 , C07C55/10 , C07C55/12 , C07C55/14 , C07C55/16 , C07C55/18 , C07C55/20 , C07C55/21
CPC分类号： C07C51/42 , C07C51/48 , C07C51/487 , C07C55/02 , C07C55/10 , C07C55/12 , C07C55/14 , C07C55/16 , C07C55/18 , C07C55/20 , C07C55/21
摘要： 1. A PROCESS FOR THE RECOVERY OF CARBOXYLIC ACIDS FROM BLACK TRONA BRINE, COMPRISING THE STEPS OF: (A) REACTION OF THE BRINE WITH CARBON DIOXIDE TO EFFECT PRECIPITATION OF THE BULK OF THE ORGANIC MATTER, (B) FILTRATION OR CENTRIFUGATION OF THE REACTION MIXTURE TO SEPARATE A MIXTURE OF INSOLUBLE POLYMERIC CARBOXYLIC ACIDS FROM A FILTRATE CONTAINING A MIXTURE OF C4-C14 DICARBOXYLIC ACIDS OR SODIUM SALTS THEREOF (C) RECOVERING A MIXTURE OF C4-C14 DICARBOXYLIC ACIDS FROM THE FILTRATE.

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