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1. 发明授权

US4186257A Process for the preparation of new segmented polyurethane resins derived from block copolymers being linked together through ester and/or urethane and/or urea groups 失效
标题翻译：制备由嵌段共聚物衍生的新的分段聚氨酯树脂通过酯和/或氨基甲酸酯和/或脲基团连接在一起的方法
公开(公告)号：US4186257A
公开(公告)日：1980-01-29
申请号：US875646
申请日：1978-02-06
申请人： Johannes Blahak , Roland Gipp , Kuno Wagner , Erwin Muller , Jan Mazanek , Peter Haas
发明人： Johannes Blahak , Roland Gipp , Kuno Wagner , Erwin Muller , Jan Mazanek , Peter Haas
IPC分类号： C08G18/00 , C08G18/10 , C08G18/40 , C08G18/42 , C08G18/46 , C08G18/50
CPC分类号： C08G18/4615 , C08G18/10 , C08G18/4216 , C08G18/4244
摘要： This invention relates to new high molecular weight polyurethanes which contain a very small amount of urethane and urea groups. These new synthetic resins are built up as block copolymers and contain relatively high molecular weight segments which are derived from high melting and low melting polyols and linked together through ester and/or urethane and/or urea groups.
摘要翻译：本发明涉及含有非常少量的氨基甲酸酯和脲基团的新的高分子量聚氨酯。这些新的合成树脂被构建为嵌段共聚物并且含有相对高分子量链段，其衍生自高熔点和低熔点多元醇并通过酯和/或氨基甲酸酯和/或脲基团连接在一起。

2. 发明授权

US4228249A Segmented polyurethane resins 失效
标题翻译：分段聚氨酯树脂
公开(公告)号：US4228249A
公开(公告)日：1980-10-14
申请号：US26110
申请日：1979-04-02
申请人： Johannes Blahak , Roland Gipp , Kuno Wagner , Erwin Muller , Jan Mazanek , Peter Haas
发明人： Johannes Blahak , Roland Gipp , Kuno Wagner , Erwin Muller , Jan Mazanek , Peter Haas
IPC分类号： C08G18/00 , C08G18/10 , C08G18/40 , C08G18/42 , C08G18/46 , C08G18/14
CPC分类号： C08G18/4615 , C08G18/10 , C08G18/4216 , C08G18/4244
摘要： This invention relates to new high molecular weight polyurethanes which contain a very small amount of urethane and urea groups. These new synthetic resins are built up as block copolymers and contain relatively high molecular weight segments which are derived from high melting and low melting polyols and linked together through ester and/or urethane and/or urea groups.
摘要翻译：本发明涉及含有非常少量的氨基甲酸酯和脲基团的新的高分子量聚氨酯。这些新的合成树脂被构建为嵌段共聚物并且含有相对高分子量链段，其衍生自高熔点和低熔点多元醇并通过酯和/或氨基甲酸酯和/或脲基团连接在一起。

3. 发明授权

US4133943A Process for the production of polyurethane elastomers and foams 失效
标题翻译：生产聚氨酯弹性体和泡沫的方法
公开(公告)号：US4133943A
公开(公告)日：1979-01-09
申请号：US899431
申请日：1978-04-24
申请人： Johannes Blahak , Kuno Wagner , Jan Mazanek , Peter Haas
发明人： Johannes Blahak , Kuno Wagner , Jan Mazanek , Peter Haas
IPC分类号： C08G18/08 , C08G18/10 , C08G18/38 , C08G18/14 , C08G18/32
CPC分类号： C08G18/3855 , C08G18/0819 , C08G18/10 , C08G18/3821 , C08G2101/0008 , C08G2101/0083
摘要： The instant invention relates to an improved process for the production of cellular or non-cellular polyurethane urea elastomers, in which diamines which contain ester groups are used as chain lengthening agents. A characteristic feature of the process according to the invention is the use of salts of aromatic diaminocarboxylic or sulphonic acids as a portion of the chain lengthening component. Elastomers produced by this process are distinguished by their improved mechanical properties, in particular their increased tensile strength and tear propagation resistance as well as their reduced permanent elongation.
摘要翻译：本发明涉及用于生产细胞或非细胞聚氨酯脲弹性体的改进方法，其中含有酯基团的二胺用作链延长剂。根据本发明的方法的特征在于使用芳族二氨基羧酸或磺酸的盐作为链增长组分的一部分。通过该方法生产的弹性体的特征在于它们改进的机械性能，特别是它们增加的拉伸强度和抗撕裂蔓延性以及它们降低的永久伸长率。

4. 发明授权

US4260754A Hexahydrotriazine carboxylates and the use thereof as catalysts in the production of polyisocyanurate plastics 失效
标题翻译：六氢三嗪羧酸盐及其在制备聚异氰脲酸酯塑料中作为催化剂的用途
公开(公告)号：US4260754A
公开(公告)日：1981-04-07
申请号：US51789
申请日：1979-06-25
申请人： Peter Haas , Johannes Blahak , Rolf Wiedermann
发明人： Peter Haas , Johannes Blahak , Rolf Wiedermann
IPC分类号： C07D251/04 , C08G18/02 , C08G18/20 , C08G18/22
CPC分类号： C08G18/225 , C07D251/04 , C08G18/022 , C08G18/2036 , C08G2105/02 , Y10S521/902
摘要： The instant invention is directed to hexahydrotriazine carboxylates, a method for their preparation, and their use as catalysts in the production of polyisocyanurate plastics.
摘要翻译：本发明涉及六氢三嗪羧酸盐，其制备方法及其在制备聚异氰脲酸酯塑料中作为催化剂的用途。

5. 发明授权

US4143003A Polyurethanes made with linear polyamines 失效
标题翻译：聚氨酯用线性聚氨酯制成
公开(公告)号：US4143003A
公开(公告)日：1979-03-06
申请号：US801451
申请日：1977-05-27
申请人： Peter Haas , Johannes Blahak , Hans-Joachim Meiners , Werner Mormann
发明人： Peter Haas , Johannes Blahak , Hans-Joachim Meiners , Werner Mormann
IPC分类号： C08G18/18 , C08G18/20 , C08L9/00
CPC分类号： C08G18/20 , C08G18/1808
摘要： This invention relates to a process for the production of polyurethane resins (more particularly foam resins) in which linear polyamines containing at least four tertiary nitrogen atoms are used as catalysts. The compounds correspond to the general formula: ##STR1## wherein the groups R, which may be the same or different, represent methyl or ethyl groups; m represents an integer of from 2 to 7; and the integers n, which may be the same or different, represent 2 or 3.

6. 发明授权

US4310633A Hexahydrotriazine carboxylates and the use thereof as catalysts in the production of polyisocyanurate plastics 失效
标题翻译：六氢三嗪羧酸盐及其在制备聚异氰脲酸酯塑料中作为催化剂的用途
公开(公告)号：US4310633A
公开(公告)日：1982-01-12
申请号：US206112
申请日：1980-11-12
申请人： Peter Haas , Johannes Blahak , Rolf Wiedermann
发明人： Peter Haas , Johannes Blahak , Rolf Wiedermann
IPC分类号： C07D251/04 , C08G18/02 , C08G18/20 , C08G18/22 , C08G18/14
CPC分类号： C08G18/225 , C07D251/04 , C08G18/022 , C08G18/2036 , C08G2105/02 , Y10S521/902
摘要： The instant invention is directed to hexahydrotriazine carboxylates, a method for their preparation, and their use as catalysts in the production of polyisocyanurate plastics.
摘要翻译：本发明涉及六氢三嗪羧酸盐，其制备方法及其在制备聚异氰脲酸酯塑料中作为催化剂的用途。

7. 发明授权

US4248930A The production of polyurethane resins and laminates 失效
标题翻译：生产聚氨酯树脂和层压板
公开(公告)号：US4248930A
公开(公告)日：1981-02-03
申请号：US107310
申请日：1979-12-26
申请人： Peter Haas , Johannes Blahak , Werner Mormann , Manfred Kapps
发明人： Peter Haas , Johannes Blahak , Werner Mormann , Manfred Kapps
IPC分类号： C08G18/00 , C08G18/18 , C08G18/28 , C08G18/32 , C08G18/14 , B32B27/40 , C08K5/20
CPC分类号： C08G18/1808 , C08G18/1825 , C08G18/2865 , C08G18/3228 , Y10T428/249992 , Y10T428/3158
摘要： A process is disclosed for producing polyurethane resins using novel catalysts selected from the group consisting of a process for the production of cellular or non-cellular polyurethane resins comprising reacting:(a) polyisocyanates; with(b) compounds having at least 2 isocyanate reactive hydrogen atoms; in the presence of(c) tertiary amines as catalysts; optionally with the addition of(d) blowing agents, stabilizers and other known additives; characterized in that the substances used as component (c) comprise compounds selected from the group consisting of ##STR1## and mixtures thereof in which formulae: the symbols R may be the same or different and represent straight or branched-chain alkyl groups having from 1 to 4 carbon atoms;the symbols n may be the same or different and represent 2 or 3;the symbols m may be the same or different and represent 2 or 3; andk represents an integer of from 1 to 5.The process may also be carried out in the presence of other tertiary amine catalysts, particularly compounds containing one tertiary nitrogen atom and at least one amide group.The novel catalysts of the invention function as age-resistors and light-protective agents.
摘要翻译：公开了一种使用选自由生产细胞或非细胞聚氨酯树脂的方法组成的组的新型催化剂制备聚氨酯树脂的方法，其包括：（a）多异氰酸酯; 与（b）具有至少2个异氰酸酯反应性氢原子的化合物; 在（c）叔胺作为催化剂的存在下; 任选地加入（d）发泡剂，稳定剂和其它已知的添加剂; 其特征在于用作组分（c）的物质包括选自以下的化合物：其中式：（1）符号R可以相同或不同，表示具有1至4个碳原子的直链或支链烷基; 符号n可以相同或不同，表示2或3; 符号m可以相同或不同，表示2或3; 并且k表示1至5的整数。该方法也可以在其它叔胺催化剂，特别是含有一个叔氮原子和至少一个酰胺基团的化合物的存在下进行。本发明的新型催化剂用作耐老化剂和光保护剂。

8. 发明授权

US4331778A Process for the production of polyurethane plastics 失效
标题翻译：聚氨酯塑料生产工艺
公开(公告)号：US4331778A
公开(公告)日：1982-05-25
申请号：US102162
申请日：1979-12-10
申请人： Claus-Dieter Sommerfeld , Peter Haas , Kuno Wagner , Manfred Kapps
发明人： Claus-Dieter Sommerfeld , Peter Haas , Kuno Wagner , Manfred Kapps
IPC分类号： C08G18/00 , C08G18/18 , C08G18/14
CPC分类号： C08G18/1833 , C08G18/1808
摘要： The present invention relates to a process for the production of polyurethane plastics by reacting compounds containing at least two isocyanate-reactive hydrogen atoms and having a molecular weight in the range of from 400 to 10,000, polyisocyanates and, optionally, chain extenders having a molecular weight of from 32 to 400, foam stabilizers, water and/or organic blowing agents in the presence of catalysts containing tertiary nitrogen. These catalysts are characterized in that mixtures of (a) one or more cross-linking catalysts corresponding to the following general formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 which may be the same or different, represent C.sub.1 -C.sub.5 -alkyl radicals, preferably CH.sub.3 -- or C.sub.2 H.sub.5 radicals,R' and R" represent hydrogen or the same or different C.sub.1 -C.sub.3 -alkyl radicals, preferably CH.sub.3 -- or C.sub.2 H.sub.5 -- radicals, andn represents an integer of from 1 to 10, preferably from 4 to 8,(b) blowing catalysts corresponding to the following general formula: ##STR2## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4, are as defined above andX represents oxygen or ##STR3## where R'" represents a C.sub.1 -C.sub.5 alkyl radical, preferably a CH.sub.3 -- or C.sub.2 H.sub.5 -- radical,p represents an integer of from 2 to 4 andr represents an integer of from 1 to 3, andm and o which may be the same or different, represent numbers ranging from 1 to 10, preferably from 1 to 3 in value.
摘要翻译：本发明涉及通过使包含至少两个异氰酸酯反应性氢原子的化合物与分子量范围为400至10,000的多异氰酸酯和任选的具有分子量的扩链剂来生产聚氨酯塑料的方法的32至400，泡沫稳定剂，水和/或有机发泡剂在含有叔氮的催化剂存在下。这些催化剂的特征在于：（a）一种或多种交联催化剂的混合物，其对应于以下通式：其中R1，R2，R3和R4可以相同或不同，表示C1-C5-烷基自由基，优选CH 3 - 或C 2 H 5基团，R'和R“表示氢或相同或不同的C 1 -C 3 - 烷基，优选CH 3 - 或C 2 H 5 - 基，n表示1至10的整数，优选 4至8，（b）对应于以下通式的发泡催化剂：其中R 1，R 2，R 3和R 4如上所定义，X代表氧或者其中R“'表示C1-C5 烷基，优选CH 3 - 或C 2 H 5 - 基，p表示2〜4的整数，r表示1〜3的整数，m和o可以相同或不同，表示1〜 10，优选为1〜3。

9. 发明授权

US4328321A Dialkoxy-phosphonyl-N-alkyl-formic acid amides and their use as additives for the production of polyurethane foams which are capable of being flame laminated and high frequency welded 失效
标题翻译：二烷氧基 - 膦酰基-N-烷基 - 甲酸酰胺及其作为生产能够被火焰层压和高频焊接的聚氨酯泡沫的添加剂的用途
公开(公告)号：US4328321A
公开(公告)日：1982-05-04
申请号：US185870
申请日：1980-09-11
申请人： Peter Haas , Heinz Muller , Peter Seifert , Kuno Wagner , Kurt Findeisen , Klaus Konig
发明人： Peter Haas , Heinz Muller , Peter Seifert , Kuno Wagner , Kurt Findeisen , Klaus Konig
IPC分类号： C08G18/00 , C07F9/40 , C08J9/00 , C08L75/00 , C08L75/04 , C08G18/14
CPC分类号： C08J9/0038 , C07F9/4065 , C08J2375/04
摘要： The present invention relates to a process for the preparation of polyurethane foams capable of being flame laminated and high frequency welded, comprising reacting:(a) polyisocyanate,(b) a compound having a molecular weight of from 400 to 10,000 containing at least two isocyanate-reactive hydrogen atoms and(c) a dialkoxy-phosphonyl-N-alkyl-formic acid amide of the formula: ##STR1## wherein m represents an integer of from 1 to 3,n represents an integer of from 0 to 8,X represents halogen, hydrogen, C.sub.1 to C.sub.6 alkyl, --OR, or ##STR2## R represents C.sub.1 to C.sub.6 alkyl, R.sub.1 represents hydrogen, C.sub.1 to C.sub.10 alkyl, C.sub.1 to C.sub.10 alkylene, C.sub.6 to C.sub.10 aryl or C.sub.6 to C.sub.10 arylene, andR.sub.2 and R.sub.3, which may be the same or different, represent C.sub.1 to C.sub.10 alkyl in the presence of water and/or blowing agent.The present invention also relates to dialkoxy-phosphonyl-N-formic acid amides.
摘要翻译：本发明涉及一种制备能够进行火焰层压和高频焊接的聚氨酯泡沫体的方法，包括使（a）多异氰酸酯，（b）分子量为400至10,000的含有至少两种异氰酸酯的化合物 - 反应性氢原子和（c）下式的二烷氧基膦酰基-N-烷基 - 甲酸酰胺其中m表示1至3的整数，n表示0至8的整数，X表示卤素，氢，C1至C6烷基，-OR或R表示C1至C6烷基，R1表示氢，C1至C10烷基，C1至C10亚烷基，C6至C10芳基或C6至C10亚芳基，R2和 R 3可以相同或不同，在水和/或发泡剂的存在下表示C1至C10烷基。本发明还涉及二烷氧基 - 膦酰基-N-甲酸酰胺。

10. 发明授权

US4400331A Dialkoxy-phosphonyl-N-alkyl-formic acid amides 失效
标题翻译：二烷氧基 - 膦酰基-N-烷基 - 甲酸酰胺
公开(公告)号：US4400331A
公开(公告)日：1983-08-23
申请号：US342544
申请日：1982-01-25
申请人： Peter Haas , Heinz Muller , Peter Seifert , Kuno Wagner , Kurt Findeisen , Klaus Konig
发明人： Peter Haas , Heinz Muller , Peter Seifert , Kuno Wagner , Kurt Findeisen , Klaus Konig
IPC分类号： C08G18/00 , C07F9/40 , C08J9/00 , C08L75/00 , C08L75/04
CPC分类号： C08J9/0038 , C07F9/4065 , C08J2375/04
摘要： The present invention relates to a process for the preparation of polyurethane foams capable of being flame laminated and high frequency welded, comprising reacting:(a) polyisocyanate,(b) a compound having a molecular weight of from 400 to 10,000 containing at least two isocyanate-reactive hydrogen atoms and(c) a dialkoxy-phosphonyl-N-alkyl-formic acid amide of the formula: ##STR1## wherein m represents an integer of from 1 to 3,n represents an integer of from 0 to 8,X represents halogen, hydrogen, C.sub.1 to C.sub.6 alkyl, -OR, or ##STR2## R represents C.sub.1 to C.sub.6 alkyl, R.sub.1 represents hydrogen, C.sub.1 to C.sub.10 alkyl, C.sub.1 to C.sub.10 alkylene, C.sub.6 to C.sub.10 aryl or C.sub.6 to C.sub.10 arylene, andR.sub.2 and R.sub.3, which may be the same or different, represent C.sub.1 to C.sub.10 alkyl in the presence of water and/or blowing agent.The present invention also relates to dialkoxy-phosphonyl-N-formic acid amides.
摘要翻译：本发明涉及一种制备能够进行火焰层压和高频焊接的聚氨酯泡沫体的方法，包括使（a）多异氰酸酯，（b）分子量为400至10,000的含有至少两种异氰酸酯的化合物 - 反应性氢原子和（c）下式的二烷氧基膦酰基-N-烷基 - 甲酸酰胺其中m表示1至3的整数，n表示0至8的整数，X表示卤素，氢，C1至C6烷基，-OR或R表示C1至C6烷基，R1表示氢，C1至C10烷基，C1至C10亚烷基，C6至C10芳基或C6至C10亚芳基，R2和 R 3可以相同或不同，在水和/或发泡剂的存在下表示C1至C10烷基。本发明还涉及二烷氧基 - 膦酰基-N-甲酸酰胺。

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