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    • 2. 发明授权
    • The production of polyurethane resins and laminates
    • 生产聚氨酯树脂和层压板
    • US4248930A
    • 1981-02-03
    • US107310
    • 1979-12-26
    • Peter HaasJohannes BlahakWerner MormannManfred Kapps
    • Peter HaasJohannes BlahakWerner MormannManfred Kapps
    • C08G18/00C08G18/18C08G18/28C08G18/32C08G18/14B32B27/40C08K5/20
    • C08G18/1808C08G18/1825C08G18/2865C08G18/3228Y10T428/249992Y10T428/3158
    • A process is disclosed for producing polyurethane resins using novel catalysts selected from the group consisting of a process for the production of cellular or non-cellular polyurethane resins comprising reacting:(a) polyisocyanates; with(b) compounds having at least 2 isocyanate reactive hydrogen atoms; in the presence of(c) tertiary amines as catalysts; optionally with the addition of(d) blowing agents, stabilizers and other known additives; characterized in that the substances used as component (c) comprise compounds selected from the group consisting of ##STR1## and mixtures thereof in which formulae: the symbols R may be the same or different and represent straight or branched-chain alkyl groups having from 1 to 4 carbon atoms;the symbols n may be the same or different and represent 2 or 3;the symbols m may be the same or different and represent 2 or 3; andk represents an integer of from 1 to 5.The process may also be carried out in the presence of other tertiary amine catalysts, particularly compounds containing one tertiary nitrogen atom and at least one amide group.The novel catalysts of the invention function as age-resistors and light-protective agents.
    • 公开了一种使用选自由生产细胞或非细胞聚氨酯树脂的方法组成的组的新型催化剂制备聚氨酯树脂的方法,其包括:(a)多异氰酸酯; 与(b)具有至少2个异氰酸酯反应性氢原子的化合物; 在(c)叔胺作为催化剂的存在下; 任选地加入(d)发泡剂,稳定剂和其它已知的添加剂; 其特征在于用作组分(c)的物质包括选自以下的化合物:其中式:(1) 符号R可以相同或不同,表示具有1至4个碳原子的直链或支链烷基; 符号n可以相同或不同,表示2或3; 符号m可以相同或不同,表示2或3; 并且k表示1至5的整数。该方法也可以在其它叔胺催化剂,特别是含有一个叔氮原子和至少一个酰胺基团的化合物的存在下进行。 本发明的新型催化剂用作耐老化剂和光保护剂。
    • 6. 发明授权
    • Process for silylizing carbohydrates, and use of the silylized
carbohydrates
    • 使碳水化合物甲硅烷基化的方法和使用甲硅烷基化的碳水化合物
    • US5410037A
    • 1995-04-25
    • US210877
    • 1994-03-18
    • Thomas WagnerWerner Mormann
    • Thomas WagnerWerner Mormann
    • C07F7/02C07F7/18C07H23/00C08B15/05C08B31/00C08B33/00D01F2/00D01F2/24
    • C07H23/00C08B15/05C08B31/00
    • There is described a process for silylizing carbohydrates in liquid nitrogen compounds,the carbohydrates being reacted under pressure in an autoclave at a tempperature of about 0.degree. to 200.degree. C. with a silylizing agent of the formula (I) ##STR1## in a liquid nitrogen compound of the formula (II) ##STR2## the respective radicals in the two formulas (I) and (II) being, independently of each other:hydrogen, a low alkyl group with 1 to 4 carbon atoms, a cycloalkyl group with 3 to 6 carbon atoms, an aryl group in the form of a phenyl or naphthyl radical, an aralkyl group with 7 to 18 carbon atoms, an alkylaryl group with 7 to 18 carbon atoms, or an O-, S- or N-containing heterocyclic group with 2 to 5 carbon atoms.An especially suitable silylizing agent is hexamethyl disilazane. As liquid nitrogen compound preferably ammonia is taken, which under the process conditions is liquid. The process according to the invention is of advantage ecologically and economically. The products obtained according to the invention are especially pure, making further processing possible.
    • 描述了在液氮化合物中甲酰化碳水化合物的方法,碳水化合物在高压釜中在约0至200℃的温度下与压力下的式(I)的甲硅烷基化剂在液体中反应 式(II)的氮化合物两个式(I)和(II)中的各个基团彼此独立地是氢,具有1至4个碳原子的低级烷基,具有3个 至6个碳原子,苯基或萘基形式的芳基,具有7至18个碳原子的芳烷基,具有7至18个碳原子的烷芳基,或O-,S-或N-杂环 具有2至5个碳原子的基团。 特别合适的甲硅烷基化剂是六甲基二硅氮烷。 作为液氮化合物,优选采用氨,其在工艺条件下为液体。 根据本发明的方法在生态和经济上是有利的。 根据本发明获得的产品是特别纯的,使得进一步的处理成为可能。