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1. 发明申请

US20100151352A1 Composites and Composite Membranes 审中-公开
标题翻译：复合材料和复合膜
公开(公告)号：US20100151352A1
公开(公告)日：2010-06-17
申请号：US12636323
申请日：2009-12-11
申请人： Thomas Haring , Vladimir Linkov , Jochen Kerres , Andreas Ullrich , Chy-Ming Tang , Martin Hein , Wei Zhang
发明人： Thomas Haring , Vladimir Linkov , Jochen Kerres , Andreas Ullrich , Chy-Ming Tang , Martin Hein , Wei Zhang
IPC分类号： H01M8/10 , C25C7/04 , B01D61/42 , C08J5/22 , B05D3/02 , B01D61/36 , C02F1/44 , B01D61/02 , B01D53/22 , H01M6/18
CPC分类号： B01D67/0093 , B01D67/0006 , B01D67/0011 , B01D69/12 , B01D69/141 , B01D71/00 , B01D71/52 , B01D71/62 , B01D71/82 , B01D2323/30 , B01D2325/14 , C08J5/2275 , C08J2379/06 , C25B13/08 , H01B1/122 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1048 , H01M8/1051 , H01M8/1081 , H01M8/1088 , H01M10/05 , H01M10/0565 , Y02P70/56
摘要： The invention relates to the following types of composite membranes; composites or composite membranes obtained by adding a metal salt, e.g. from ZrOCl2, to a solvent, especially DMSO, for dissolving one or more polymers in an organic solvent or in aqueous systems, in addition to the subsequent precipitation in the matrix of the thus produced composite-membrane by post-treatment thereof in an acid or in a salt solution, especially phosphoric acid. The invention also relates to composites or composite membranes obtained by subsequent ion exchange of finished polymer membranes with a suitable salt cation, especially ZrO2+, wherein the polymer membrane is, optionally, swollen with an organic solvent or a mixture of organic solvent with water prior to the ion exchange and the subsequent precipitation of a low soluble salt, e.g. from Zr3(PO4)4, in the membrane by post-treatment thereof in an acid or in a salt solution, especially phosphoric acid. The invention further relates to composites or composite membranes obtained by adding nano-scaled Zr3(PO4)4 powder to a polymer solution, composites and composite membranes obtained according to the above-mentioned methods, wherein additional heteropoly acids are also incorporated into the polymer or membrane morphology, in addition to methods for producing said inventive polymers and membranes.
摘要翻译：本发明涉及以下类型的复合膜; 复合材料或复合膜，通过加入金属盐，从ZrOCl 2到溶剂，特别是DMSO中，用于将一种或多种聚合物溶解在有机溶剂或水性体系中，以及随后通过在酸中后处理由此制备的复合膜的基质中的沉淀，或在盐溶液中，特别是磷酸。本发明还涉及通过随后使用合适的盐阳离子，特别是ZrO 2 +离子交换成品聚合物膜而获得的复合材料或复合膜，其中聚合物膜任选地在有机溶剂或有机溶剂与水的混合物之前在水中溶胀离子交换和随后的低溶解盐沉淀，例如通过在酸或盐溶液，特别是磷酸中后处理，从Zr3（PO4）4中除去。本发明还涉及通过将纳米级Zr 3（PO 4）4粉末加入到根据上述方法获得的聚合物溶液，复合材料和复合膜中而获得的复合材料或复合膜，其中另外的杂多酸也被引入聚合物或膜形态，以及用于制备所述本发明聚合物和膜的方法。

2. 发明申请

US20060231484A1 Composites and composite membranes 审中-公开
标题翻译：复合材料和复合膜
公开(公告)号：US20060231484A1
公开(公告)日：2006-10-19
申请号：US10929648
申请日：2004-08-30
申请人： Thomas Haring , Vladimir Linkov , Jochen Kerres , Andreas Ullrich , Chy-Ming Tang , Martin Hein , Wei Zhang
发明人： Thomas Haring , Vladimir Linkov , Jochen Kerres , Andreas Ullrich , Chy-Ming Tang , Martin Hein , Wei Zhang
IPC分类号： B01D71/06
CPC分类号： B01D67/0093 , B01D67/0006 , B01D67/0011 , B01D69/12 , B01D69/141 , B01D71/00 , B01D71/52 , B01D71/62 , B01D71/82 , B01D2323/30 , B01D2325/14 , C08J5/2275 , C08J2379/06 , C25B13/08 , H01B1/122 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1048 , H01M8/1051 , H01M8/1081 , H01M8/1088 , H01M10/05 , H01M10/0565 , Y02P70/56
摘要： The invention relates to the following types of composite membranes; composites or composite membranes obtained by adding a metal salt, e.g. from ZrOCl2, to a solvent, especially DMSO, for dissolving one or more polymers in an organic solvent or in aqueous systems, in addition to the subsequent precipitation in the matrix of the thus produced composite-membrane by post-treatment thereof in an acid or in a salt solution, especially phosphoric acid. The invention also relates to composites or composite membranes obtained by subsequent ion exchange of finished polymer membranes with a suitable salt cation, especially ZrO2+, wherein the polymer membrane is, optionally, swollen with an organic solvent or a mixture of organic solvent with water prior to the ion exchange and the subsequent precipitation of a low soluble salt, e.g. from Zr3 (PO4)4, in the membrane by post-treatment thereof in an acid or in a salt solution, especially phosphoric acid. The invention further relates to composites or composite membranes obtained by adding nano-scaled Zr3(PO4)4 powder to a polymer solution, composites and composite membranes obtained according to the above-mentioned methods, wherein additional heteropoly acids are also incorporated into the polymer or membrane morphology, in addition to methods for producing said inventive polymers and membranes.
摘要翻译：本发明涉及以下类型的复合膜; 复合材料或复合膜，通过加入金属盐，从一种溶剂，特别是DMSO中，将一种或多种聚合物溶解在有机溶剂或水性体系中，除了随后通过如此制备的复合膜的基质沉淀，由在酸或盐溶液，特别是磷酸中进行后处理。本发明还涉及通过随后使用合适的盐阳离子离子交换完成的聚合物膜而获得的复合材料或复合膜，特别是ZrO 2 O + 在离子交换之前用有机溶剂或有机溶剂与水的混合物溶胀，随后沉淀低可溶性盐，例如通过在酸或盐溶液中，特别是磷酸中后处理，从Zr 3（PO 4）4 S 4 。本发明还涉及通过将纳米级Zr 3（PO 4）4 N 4）粉末添加到聚合物溶液中获得的复合材料或复合膜，复合材料以及根据上述方法获得的复合膜，其中除了制备所述本发明聚合物和膜的方法之外，还将其它杂多酸掺入聚合物或膜形态中。

3. 发明授权

US06982303B2 Covalently cross-linked polymers and polymer membranes via sulfinate alkylation 失效
公开(公告)号：US06982303B2
公开(公告)日：2006-01-03
申请号：US10173830
申请日：2002-06-19
申请人： Jochen Kerres , Wei Zhang , Chy-Ming Tang , Thomas Häring
发明人： Jochen Kerres , Wei Zhang , Chy-Ming Tang , Thomas Häring
IPC分类号： C08F283/00 , C08G75/00 , C08L81/00
CPC分类号： B01D67/0093 , B01D53/228 , B01D71/52 , B01D71/68 , B01D71/82 , B01D2323/30 , C08G75/00 , H01M2/1653 , H01M8/1025 , H01M8/1027 , H01M8/1032 , H01M8/1044 , H01M8/1051 , H01M8/1072 , H01M2300/0082 , Y02P70/56
摘要： A covalently cross-linked polymer or polymer membrane consisting of one or more polymers, which can bear the following functional groups (M=Hal(F, Cl, Br, I), OR, NR2; R=alkyl, hydroxyalkyl, aryl; (Me=H, Li, Na, K, Cs, or other metal cations or ammonium ions): a) precursors of cation exchange groups: SO2M and/or POM2 and/or COM b) sulphinate groups SO2Me and which can be covalently cross-linked using the following organic compounds: a) di-, tri- or oligofunctional haloalkanes or haloaromatics, which have been reacted with sulphinate groups SO2Me, whereby the following cross-linking bridges are present in the polymer/in the polymer blend/in the polymer membrane: (Y=cross-linking bridges, X=Hal (F, Cl, Br, I), OR, (CH2)x—; -arylene-; —(CH2)x-arylene-; CH2arylene-CH2—, x=3-12): polymer-SO2Y—SO2-polymer and/or b) compounds containing the following groups: Hal-(CH2)x—NHR, one side of which (Hal-) has been reacted with sulphinate groups SO2ME and the other side (—NHR) with SO2M groups, whereby the following cross-linking bridges are present in the polymer/in the polymer blend/in the polymer membrane: polymer-SO2—(CH2)x—NR—SO2 polymer and/or c) compounds containing the following groups: NHR—(CH2)x—NHR, which have been reacted with sulphinate groups SO2ME, whereby the following cross-linking bridges are present in the polymer/in the polymer blend/in the polymer membrane: polymer-SO2—NR—(CH2)x—NR—SO2-polymer.

4. 发明授权

US06767585B2 Ionically and covalently cross-linked polymers and polymer membranes 有权
标题翻译：离子和共价交联的聚合物和聚合物膜
公开(公告)号：US06767585B2
公开(公告)日：2004-07-27
申请号：US10275854
申请日：2003-05-12
申请人： Jochen Kerres , Wei Zhang , Chy-Ming Tang
发明人： Jochen Kerres , Wei Zhang , Chy-Ming Tang
IPC分类号： B05D302
CPC分类号： C08F8/44
摘要： The present invention relates to ionically and covalently cross-linked polymers and polymer membranes having recurrent units of the general formula (1), wherein Q is a link, oxygen, sulfur, (2) or (3) and the R radical is a divalent radical of an aromatic or heteroaromatic compound, and which are characterized in that a) R radical comprises at least partially substituents of general formula (4A), (4B), (4C), (4D), (4E), (4F), (4G) and/or (4H), b) R radical comprises at least partially substituents of the general formula (5A) and/or (5B) and/or the R radical is at least partially a group of the general formula (5C) and/or (5D) and c) the R radical comprises at least partially bridges of the general formula (6) linking at least to R radicals together, R1, R2, R3, R4, R5, M, X, Y, Z and m having the herein-mentioned meanings.
摘要翻译：本发明涉及具有通式（1）的复发单元的离子交换和共价交联的聚合物和聚合物膜，其中Q是连接，氧，硫，（2）或（3），R基是二价芳族或杂芳族化合物的基团，其特征在于a）R自由基至少部分包含通式（4A），（4B），（4C），（4D），（4E），（4F），（4G）和/或（4H），b）R自由基至少部分包含通式（5A）和/或（5B）的取代基和/或R基团至少部分为通式（5C ）和/或（5D）和c）R基团包含至少部分至少连接至R基团的通式（6）的桥，R 1，R 2，R 3，R 4，R 5，M，X，Y，Z 和m具有这里所述的含义。

5. 发明申请

US20090221759A1 Oligomers And Polymers Containing Sulfinate Groups And Method For The Production Thereof 有权
标题翻译：含有亚磺酸盐的低聚物和聚合物及其制备方法
公开(公告)号：US20090221759A1
公开(公告)日：2009-09-03
申请号：US12324320
申请日：2008-11-26
申请人： Thomas Haring , Jochen Kerres , Wei Zhang
发明人： Thomas Haring , Jochen Kerres , Wei Zhang
IPC分类号： C08F126/06 , C08G16/00
CPC分类号： H01M6/181 , C08C19/02 , C08F8/04 , C08J5/2243 , C08J2381/00 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/1072 , Y02P70/56
摘要： The invention relates to novel polymers or oligomers containing at least sulfinate groups (P-(SO2)nX, X=1-(n=1), 2-(n=2) or 3-(n=3) valent metal cation or H+ or ammonium ion NR4+ where R=alkyl, aryl, H), which are obtained by completely or partially reducing polymers or oligomers containing at least SO2Y-groups (Y═F, Cl, Br, I, OR, NR2 (R=alkyl and/or aryl and/or H), N-imidazolyL N-pyrazolyl) by means of suitable reducing agents in a suspension or in a solution formPolymer and polymer(blend)membranes which are obtained by further reacting the received sulfinated polymers, especially by alkylation of the sulfinate groups with mono- di- or oligo functional electrophiles. The invention further relates to methods for producing the sulfinated polymers and for further reacting the sulfinated polymers with electrophiles by S-alkylation.
摘要翻译：本发明涉及至少含有亚磺酸基团（P-（SO 2）n X，X = 1-（n = 1），2-（n = 2）或3-（n = 3）价金属阳离子或通过完全或部分还原含有至少SO 2 Y基团（YF，Cl，Br，I，OR，NR 2（R =烷基和/或烷基）的聚合物或低聚物）获得的H +或铵离子NR4 +，其中R =烷基，芳基，H）或芳基和/或H），N-咪唑并吡唑基），通过合适的还原剂以悬浮液或溶液形式聚合物和聚合物（共混物）膜，其通过进一步使所接收的磺化聚合物反应而获得，特别是通过烷基化的亚硫酸酯基团与单 - 或寡功能亲电试剂。本发明还涉及用于生产硫化聚合物的方法，以及通过S-烷基化进一步使硫化聚合物与亲电体反应。

6. 发明授权

US07202327B2 Oligomers and polymers containing sulfonite groups and method for the production thereof 有权
标题翻译：含有亚磺酸基团的低聚物和聚合物及其制备方法
公开(公告)号：US07202327B2
公开(公告)日：2007-04-10
申请号：US10488420
申请日：2002-09-02
申请人： Thomas Häring , Jochen Kerres , Wei Zhang
发明人： Thomas Häring , Jochen Kerres , Wei Zhang
IPC分类号： C08G75/00 , C08F28/02 , A61K7/06 , A61K7/11
CPC分类号： H01M6/181 , C08C19/02 , C08F8/04 , C08J5/2243 , C08J2381/00 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/1072 , Y02P70/56
摘要： The invention relates to novel polymers or oligomers containing at least sulfonite groups (P-(SO2)nX, X=1−(n=1), 2−(n=2) or 3−(n=3) valent metal cation or H+ or ammonium ion NR4+ wherein R=alkyl, aryl, H), which are obtained by completely or partially reducing polymers or oligomers containing at least SO2Y-groups (Y=F, Cl, Br, I, OR, NR2 (R=alkyl and/or aryl and/or H), N-imidazolyl, N-pyrazolyl) by means of suitable reducing agents in a suspension or in a solution form. The invention also relates to polymers and polymer(blend) membranes which are obtained by further reacting the obtained sulfinated polymers, especially by alkylation of the sulfinate groups with mono- di- or oligo functional electrophiles. The invention further relates to methods for producing the sulfinated polymers and for further reacting the sulfinated polymers with electrophiles by S-alkylation.
摘要翻译：本发明涉及至少含有亚磺酸基团的新型聚合物或低聚物（X-1-（n = 1），2-（ n = 2）或3-（n = 3）价金属阳离子或H +或铵离子NR 4 +其中R =烷基，芳基，H），其通过完全或部分还原含有至少SO 2 Y-基团（Y = F，Cl，Br，I，OR，NR 2）的聚合物或低聚物而获得，（R =烷基和/或芳基和/或H），N-咪唑基，N-吡唑基），通过合适的还原剂以悬浮液或溶液形式存在。本发明还涉及聚合物和聚合物（共混物）膜，其通过进一步使得到的硫化聚合物反应而获得，特别是通过亚磺酸基团与单 - 或寡官能亲电体的烷基化。本发明还涉及用于生产硫化聚合物的方法，以及通过S-烷基化进一步使硫化聚合物与亲电体反应。

7. 发明授权

US08030414B2 Oligomers and polymers containing sulfinate groups and method for the production thereof 有权
标题翻译：含有亚磺酸盐基团的低聚物和聚合物及其制备方法
公开(公告)号：US08030414B2
公开(公告)日：2011-10-04
申请号：US12324320
申请日：2008-11-26
申请人： Thomas Haring , Jochen Kerres , Wei Zhang
发明人： Thomas Haring , Jochen Kerres , Wei Zhang
IPC分类号： C08F8/00 , C08F14/00 , C08F114/00 , C08F214/00
CPC分类号： H01M6/181 , C08C19/02 , C08F8/04 , C08J5/2243 , C08J2381/00 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/1072 , Y02P70/56
摘要： The invention relates to novel polymers or oligomers containing at least sulfinate groups (P—(SO2)nX, X=1-(n=1), 2-(n=2) or 3-(n=3) valent metal cation or H+ or ammonium ion NR4+ where R=alkyl, aryl, H), which are obtained by completely or partially reducing polymers or oligomers containing at least SO2Y-groups (Y═F, Cl, Br, I, OR, NR2 (R=alkyl and/or aryl and/or H), N-imidazolyl, N-pyrazolyl) by means of suitable reducing agents in a suspension or in a solution form.Polymer and polymer(blend)membranes which are obtained by further reacting the received sulfinated polymers, especially by alkylation of the sulfinate groups with mono- di- or oligo functional electrophiles. The invention further relates to methods for producing the sulfinated polymers and for further reacting the sulfinated polymers with electrophiles by S-alkylation.
摘要翻译：本发明涉及至少含有亚磺酸基团（P-（SO 2）n X，X = 1-（n = 1），2-（n = 2）或3-（n = 3）价金属阳离子或 H +或铵离子NR4 +，其中R =烷基，芳基，H），其通过完全或部分还原含有至少SO 2 Y基团（Y = F，Cl，Br，I，OR，NR 2（R = 和/或芳基和/或H），N-咪唑基，N-吡唑基），通过合适的还原剂以悬浮液或溶液形式存在。聚合物和聚合物（共混物）膜，其通过进一步使所接收的磺化聚合物反应而获得，特别是通过亚硫酸酯基团与单 - 或寡功能亲电体的烷基化。本发明还涉及用于生产硫化聚合物的方法，以及通过S-烷基化进一步使硫化聚合物与亲电体反应。

8. 发明申请

US20070185305A1 Oligomers and polymers containing sulfinate groups and method for the production thereof 审中-公开
标题翻译：含有亚磺酸盐基团的低聚物和聚合物及其制备方法
公开(公告)号：US20070185305A1
公开(公告)日：2007-08-09
申请号：US11602481
申请日：2006-11-20
申请人： Thomas Haring , Jochen Kerres , Wei Zhang
发明人： Thomas Haring , Jochen Kerres , Wei Zhang
IPC分类号： C08G75/00
CPC分类号： H01M6/181 , C08C19/02 , C08F8/04 , C08J5/2243 , C08J2381/00 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/1072 , Y02P70/56
摘要： The invention relates to novel polymers or oligomers containing at least sulfonite groups (P—(SO2)nX, X=1−(n=1), 2−(n=2) or 3−(n=3) valent metal cation or H+ or ammonium ion NR4+ where R=alkyl, aryl, H), which are obtained by completely or partially reducing polymers or oligomers containing at least SO2Y-groups (Y═F, Cl, Br, I, OR, NR2 (R=alkyl and/or aryl and/or H), N-imidazolyl, N-pyrazolyl) by means of suitable reducing agents in a suspension or in a solution form. The invention also relates to polymers and polymer(blend) membranes which are obtained by further reacting the obtained sulfinated polymers, especially by alkylation of the sulfinate groups with mono- di- or oligo functional electrophiles. The invention further relates to methods for producing the sulfinated polymers and for further reacting the sulfinated polymers with electrophiles by S-alkylation.
摘要翻译：本发明涉及至少含有亚磺酸基团的新型聚合物或低聚物（X-1-（n = 1），2-（ n = 2）或3-（n = 3）价金属阳离子或H +或铵离子NR 4 +，其中R =烷基，芳基，H），其通过完全或部分还原含有至少SO 2 Y基（YF，Cl，Br，I，OR，NR 2）的聚合物或低聚物而获得（R =烷基和/或芳基和/或H），N-咪唑基，N-吡唑基），通过合适的还原剂以悬浮液或溶液形式。本发明还涉及聚合物和聚合物（共混物）膜，其通过进一步使得到的硫化聚合物反应而获得，特别是通过亚磺酸基团与单 - 或寡官能亲电体的烷基化。本发明还涉及用于生产硫化聚合物的方法，以及通过S-烷基化进一步使硫化聚合物与亲电体反应。

9. 外观设计

USD1004162S1 Outdoor lamp 有权
公开(公告)号：USD1004162S1
公开(公告)日：2023-11-07
申请号：US29743460
申请日：2020-07-22
申请人： Bruce Pi , Wei Kang , Zhixiang Chen , Wei Zhang
设计人： Bruce Pi , Wei Kang , Zhixiang Chen , Wei Zhang
摘要： FIG. 1 is a perspective view of an outdoor lamp showing our new design.
FIG. 2 is a front elevation view thereof;
FIG. 3 is a rear elevation view thereof;
FIG. 4 is a left side elevation view thereof;
FIG. 5 is a right side elevation view thereof;
FIG. 6 is a top plan view thereof; and,
FIG. 7 is a bottom plan view thereof.

10. 发明申请

US20220110303A1 APPARATUS AND METHODS FOR EXPANDING AND COLLAPSING A ROD 有权
公开(公告)号：US20220110303A1
公开(公告)日：2022-04-14
申请号：US17067711
申请日：2020-10-11
申请人： Wei Zhang
发明人： Wei Zhang
IPC分类号： A01K87/02
摘要： Methods and apparatus for expanding a rod from a collapsed position to a formed position are disclosed. One such apparatus includes a plurality of segments for forming the body of the collapsible rod including with each segment coupled to each immediately adjacent segment of the plurality of segments. The apparatus may include a coupler for coupling each segment of the plurality of segments to each immediately adjacent segment of the plurality of segments. The coupler may stretch from a base segment to the tip of the apparatus and may be biased to apply a force to hold the plurality of segments in a formed position and to urge the plurality of segments into a formed position from a collapsed position. In the formed position, the plurality of segments may be aligned end-to-end to form a rod and in the collapsed position, the plurality of segments may be folded against each other such that cylindrical walls of each of the plurality of segments are positioned adjacent each other.

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