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    • 10. 发明授权
    • Cross-linking of modified engineering thermoplastics
    • 改性工程热塑性塑料的交联
    • US06552135B2
    • 2003-04-22
    • US09760630
    • 2001-01-16
    • Werner SchnurnbergerJochen KerresWei Cui
    • Werner SchnurnbergerJochen KerresWei Cui
    • C08F834
    • B01J39/20C08G75/00
    • The present invention pertains to a process for the cross-linking of modified engineering thermoplastics, in particular, of polymeric sulfinic acids or sulfinic acid salts. In particular, the invention pertains to a process for the preparation of cross-linked polymers, characterized in that solutions of polymeric sulfinic acids or sulfinic acid salts (—SO2Me), optionally in the presence of organic di- or oligohalogeno compounds [R(Hal)x], are freed from solvent and cross-linked to polymers, wherein Me stands for a monovalent or polyvalent metal cation; R stands for an optionally substituted alkyl or aryl residue containing from 1 to 20 carbon atoms; and Hal stands for F, Cl, Br or I.
    • 本发明涉及改性工程热塑性塑料,特别是聚合亚磺酸或亚磺酸盐交联的方法。特别地,本发明涉及制备交联聚合物的方法,其特征在于: 聚合亚磺酸或亚磺酸盐(-SO 2 Me)的溶液,任选在有机二卤代或低卤代化合物[R(Hal)x]存在下,不溶于溶剂并与聚合物交联,其中Me代表单价或 多价金属阳离子; R代表含有1至20个碳原子的任选取代的烷基或芳基; 而H代表F,Cl,Br或I.