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1. 发明申请

US20100029844A1 Liquid polymeric phosphites and phosphonites as stabilizers 审中-公开
标题翻译：液体聚合亚磷酸酯和亚膦酸酯作为稳定剂
公开(公告)号：US20100029844A1
公开(公告)日：2010-02-04
申请号：US12310698
申请日：2007-08-30
申请人： Jochen Fink , Rudolf Pfaendner , Roswell Easton King , Sai Ping Shum , Stanley J. Padegimas
发明人： Jochen Fink , Rudolf Pfaendner , Roswell Easton King , Sai Ping Shum , Stanley J. Padegimas
IPC分类号： C08L85/02 , C08G79/04
CPC分类号： C08K5/5393 , C07F9/145 , C08G79/02 , C08G79/025 , C08G79/04 , C08K5/526
摘要： Novel liquid polymeric compounds of the formula (I) wherein the general symbols are as defined in claim 1, are disclosed as stabilizers for protecting organic materials against oxidative, thermal or light-induced degradation.
摘要翻译：公开了通式（I）的新型液体聚合物，其中通式为如权利要求1所定义，作为保护有机材料免受氧化，热或光诱导降解的稳定剂。

2. 发明授权

US07468410B2 Stabilization of polyolefins with liquid tris-(mono-alkyl)phenyl phosphites 有权
标题翻译：用液体三（单烷基）苯基亚磷酸酯稳定聚烯烃
公开(公告)号：US07468410B2
公开(公告)日：2008-12-23
申请号：US11487839
申请日：2006-07-17
申请人： Laura F. Chafin , Walid Al-Akhdar , Sai Ping Shum , Stanley J. Padegimas , Roswell Easton King
发明人： Laura F. Chafin , Walid Al-Akhdar , Sai Ping Shum , Stanley J. Padegimas , Roswell Easton King
IPC分类号： C08K5/524
CPC分类号： C07F9/145 , C08K5/526 , C08K2201/014 , C08L23/02
摘要： The present invention discloses a process for stabilizing polyolefin compositions against the deleterious effects of melt processing, heat aging and exposure to combustion products of natural gas, which process comprises incorporating or applying to a polyolefin an effective stabilizing amount of a tris-(mono-alkyl)phenyl phosphite ester of the formula I, or a mixture of phosphite esters of formula I, where each R is the same or different and is straight or branched chain alkyl of from 1 to 8 carbon atoms, and where said phosphite ester or phosphite ester mixture is in the liquid state at 25° C. and 1 atm of pressure. Also disclosed is a stabilized composition comprising polyolefin and a present phosphite ester or phosphite ester mixture as well as certain mixtures of tris-(mono-alkyl)phenyl phosphite. The present liquid phosphite ester stabilizers are especially compatible with low density polyethylene.
摘要翻译：本发明公开了一种用于稳定聚烯烃组合物以抵抗熔体加工，热老化和暴露于天然气燃烧产物的有害影响的方法，该方法包括将有效稳定量的三 - （单烷基））式I的亚磷酸苯酯或式I的亚磷酸酯的混合物，其中每个R相同或不同，是具有1至8个碳原子的直链或支链烷基，并且其中所述亚磷酸酯或亚磷酸酯混合物在25℃和1atm的压力下处于液态。还公开了包含聚烯烃和本发明的亚磷酸酯或亚磷酸酯混合物以及三（单烷基）苯基亚磷酸酯的某些混合物的稳定化组合物。本发明的液体亚磷酸酯稳定剂与低密度聚乙烯特别相容。

3. 发明授权

US07230042B2 Flame retardant polymer compositions containing hydroxylamine esters 有权
标题翻译：含有羟胺酯的阻燃聚合物组合物
公开(公告)号：US07230042B2
公开(公告)日：2007-06-12
申请号：US10511853
申请日：2003-04-10
申请人： Michael Roth , Dirk Simon , Grant Leslie , Peter Nesvadba , Roswell Easton King , Nikolas Kaprinidis
发明人： Michael Roth , Dirk Simon , Grant Leslie , Peter Nesvadba , Roswell Easton King , Nikolas Kaprinidis
IPC分类号： C08K5/34 , C08K5/51 , C08K5/17 , C08K5/18
CPC分类号： C08K5/3435
摘要： The instant invention pertains to a thermoplastic organic polymer containing a conventional flame retardant and a hydroxylamine ester, in particular a tetraalkyl piperidine hydroxylamine ester. Further aspects of the invention are the use of hydroxylamine esters as flame retardants and a method for improving flame retardancy of a thermoplastic organic polymer.
摘要翻译：本发明涉及含有常规阻燃剂和羟胺酯，特别是四烷基哌啶羟胺酯的热塑性有机聚合物。本发明的其它方面是使用羟胺酯作为阻燃剂和改进热塑性有机聚合物的阻燃性的方法。

4. 发明授权

US07084196B2 Flame retardant compositions 有权
标题翻译：阻燃组合物
公开(公告)号：US07084196B2
公开(公告)日：2006-08-01
申请号：US10471947
申请日：2002-03-12
申请人： Malisa V. Troutman , Ramanathan Ravichandran , Rangarajan Srinivsan , Roswell Easton King , Douglas Wayn Horsey
发明人： Malisa V. Troutman , Ramanathan Ravichandran , Rangarajan Srinivsan , Roswell Easton King , Douglas Wayn Horsey
IPC分类号： C08K5/3415 , C08K5/3432
CPC分类号： C08K5/0066 , C08K5/3435
摘要： Polymeric substrates, for example polyolefins such as polypropylene, can be made flame retardant by the incorporation therein of a synergistic mixture of (i.) at least one compound selected from the group consisting of nitroxyl stabilizers, hydroxylamine stabilizers, nitrone stabilizers, substituted hydroxylamine stabilizers, amine oxide stabilizers, benzofuranone stabilizers phosphite and phosphonite stabilizers, quinone methide stabilizers and monoacrylate esters of 2,2′-alkylidenebisphenol stabilizers and (ii.) at least one compound selected from the group consisting of brominated flame retardants, phosphorus containing flame retardants and inorganic flame retardants such as ammonium polyphosphate or decabromodiphenyl oxide; wherein the amount of organic or inorganic flame retardant of component (ii.) required to achieve an acceptable level of flame retardancy is significantly reduced compared to that needed when component (i.) is not present.
摘要翻译：聚合物基材，例如聚烯烃如聚丙烯，可以通过在其中加入协同混合物（即，选自硝酰基稳定剂，羟胺稳定剂，硝酮稳定剂，取代的羟胺稳定剂，，氧化胺稳定剂，苯并呋喃酮稳定剂亚磷酸酯和亚膦酸酯稳定剂，醌甲基稳定剂和2,2'-亚烷基双酚稳定剂的单丙烯酸酯，和（ii）至少一种选自溴化阻燃剂，含磷阻燃剂和无机阻燃剂如聚磷酸铵或十溴二苯醚; 其中与不存在组分（i）时所需的量相比，实现可接受水平的阻燃性所需的组分（ii。）的有机或无机阻燃剂的量显着降低。

5. 发明申请

US20110196082A1 STORAGE-STABLE AQUEOUS EMULSIONS AND LIQUID BLENDS WITH LOW VISCOSITY AS STABILIZERS 审中-公开
标题翻译：存储稳定的水性乳液和具有低粘度作为稳定剂的液体混合物
公开(公告)号：US20110196082A1
公开(公告)日：2011-08-11
申请号：US13002849
申请日：2009-06-23
申请人： Karl-Heinz Hornbach , Roswell Easton King , Arpad Major , Jean-Roch Pauquet , Alex Wegmann , Thomas Wehrle , Philipp Walter , Andreas Cendra , Walid Al-akhdar
发明人： Karl-Heinz Hornbach , Roswell Easton King , Arpad Major , Jean-Roch Pauquet , Alex Wegmann , Thomas Wehrle , Philipp Walter , Andreas Cendra , Walid Al-akhdar
IPC分类号： C08K5/103 , C09K15/08 , C08L23/12
CPC分类号： C08K5/005 , C08K5/1345
摘要： The invention describes a storage-stable aqueous emulsion comprising a) a compound of the formula (I); wherein n is 4 to 23, b) a surfactant, and c) water, and describes a storage-stable liquid blend with low viscosity, which is not an aqueous emulsion, comprising a) a compound of the formula I d) at least a stabilizer selected from the group consisting of phosphites, phosphonites, aminic antioxidants, hydroxylamines, benzofuran-2-ones, thiosynergists, plasticizers, acid scavengers, lubricants, dispersing aids, sterically hindered amines, UV absorbers and sterically hindered phenols other than the compounds of the formula I according to component a). These emulsions and blends are useful as stabilizers for organic materials.
摘要翻译：本发明描述了一种储存稳定的水乳液，其包含a）式（I）化合物; 其中n为4至23，b）表面活性剂和c）水，并且描述了低粘度的储存稳定的液体共混物，其不是水性乳液，其包含a）式I的化合物，d）至少一种选自亚磷酸酯，亚膦酸酯，氨基抗氧化剂，羟胺，苯并呋喃-2-酮，硫代增效剂，增塑剂，除酸剂，润滑剂，分散助剂，空间位阻胺，UV吸收剂和位阻酚之外的稳定剂，配方Ⅰ根据组分a）。这些乳液和共混物可用作有机材料的稳定剂。

6. 发明授权

US07470734B2 Flame retardant compositions 有权
标题翻译：阻燃组合物
公开(公告)号：US07470734B2
公开(公告)日：2008-12-30
申请号：US11296686
申请日：2005-12-07
申请人： Malisa V. Troutman , Ramanathan Ravichandran , Rangarajan Srinivsan , Roswell Easton King , Douglas Wayne Horsey
发明人： Malisa V. Troutman , Ramanathan Ravichandran , Rangarajan Srinivsan , Roswell Easton King , Douglas Wayne Horsey
IPC分类号： C08K5/3415 , C08K5/3432
CPC分类号： C08K5/0066 , C08K5/3435
摘要： Polymeric substrates, for example polyolefins such as polypropylene, can be made flame retardant by the incorporation therein of a synergistic mixture of (i.) at least one compound selected from the group consisting of nitroxyl stabilizers, hydroxylamine stabilizers, nitrone stabilizers, substituted hydroxylamine stabilizers, amine oxide stabilizers, benzofuranone stabilizers, phosphite and phosphonite stabilizers, quinone methide stabilizers and monoacrylate esters of 2,2′-alkylidenebisphenol stabilizers and (ii.) at least one compound selected from the group consisting of brominated flame retardants, phosphorus containing flame retardants and inorganic flame retardants such as ammonium polyphosphate or decabromodiphenyl oxide; wherein the amount of organic or inorganic flame retardant of component (ii.) required to achieve an acceptable level of flame retardancy is significantly reduced compared to that needed when component (i.) is not present.
摘要翻译：聚合物基材，例如聚烯烃如聚丙烯，可以通过在其中加入协同混合物（即，选自硝酰基稳定剂，羟胺稳定剂，硝酮稳定剂，取代的羟胺稳定剂，，氧化胺稳定剂，苯并呋喃酮稳定剂，亚磷酸酯和亚膦酸酯稳定剂，醌甲基稳定剂和2,2'-亚烷基双酚稳定剂的单丙烯酸酯，和（ii）至少一种选自溴化阻燃剂，含磷阻燃剂的化合物和无机阻燃剂如聚磷酸铵或十溴二苯醚; 其中与不存在组分（i）时所需的量相比，实现可接受水平的阻燃性所需的组分（ii。）的有机或无机阻燃剂的量显着降低。

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