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    • 3. 发明授权
    • Stabilization of polyolefins with liquid tris-(mono-alkyl)phenyl phosphites
    • 用液体三(单烷基)苯基亚磷酸酯稳定聚烯烃
    • US07468410B2
    • 2008-12-23
    • US11487839
    • 2006-07-17
    • Laura F. ChafinWalid Al-AkhdarSai Ping ShumStanley J. PadegimasRoswell Easton King
    • Laura F. ChafinWalid Al-AkhdarSai Ping ShumStanley J. PadegimasRoswell Easton King
    • C08K5/524
    • C07F9/145C08K5/526C08K2201/014C08L23/02
    • The present invention discloses a process for stabilizing polyolefin compositions against the deleterious effects of melt processing, heat aging and exposure to combustion products of natural gas, which process comprises incorporating or applying to a polyolefin an effective stabilizing amount of a tris-(mono-alkyl)phenyl phosphite ester of the formula I, or a mixture of phosphite esters of formula I, where each R is the same or different and is straight or branched chain alkyl of from 1 to 8 carbon atoms, and where said phosphite ester or phosphite ester mixture is in the liquid state at 25° C. and 1 atm of pressure. Also disclosed is a stabilized composition comprising polyolefin and a present phosphite ester or phosphite ester mixture as well as certain mixtures of tris-(mono-alkyl)phenyl phosphite. The present liquid phosphite ester stabilizers are especially compatible with low density polyethylene.
    • 本发明公开了一种用于稳定聚烯烃组合物以抵抗熔体加工,热老化和暴露于天然气燃烧产物的有害影响的方法,该方法包括将有效稳定量的三 - (单烷基) )式I的亚磷酸苯酯或式I的亚磷酸酯的混合物,其中每个R相同或不同,是具有1至8个碳原子的直链或支链烷基,并且其中所述亚磷酸酯或亚磷酸酯 混合物在25℃和1atm的压力下处于液态。 还公开了包含聚烯烃和本发明的亚磷酸酯或亚磷酸酯混合物以及三(单烷基)苯基亚磷酸酯的某些混合物的稳定化组合物。 本发明的液体亚磷酸酯稳定剂与低密度聚乙烯特别相容。