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1. 发明授权

US08680183B2 Liquid stabilizer mixture 有权
标题翻译：液体稳定剂混合物
公开(公告)号：US08680183B2
公开(公告)日：2014-03-25
申请号：US13362281
申请日：2012-01-31
申请人： Simon Schambony , Jochen Fink , Bernd Bruchmann
发明人： Simon Schambony , Jochen Fink , Bernd Bruchmann
IPC分类号： C08K5/00 , C08K5/16 , C08K5/34 , C08G18/28 , C08G67/02
CPC分类号： C08K5/101 , C08K5/315 , C08K5/3492 , C08L21/00
摘要： A mixture comprising (a) one or more liquid UV absorbers, with the proviso that Tinuvin 384-2 as a liquid UV absorber is excluded, (b) one or more branched polymers comprising stabilizing groups, (c) optionally one or more further additions. Use of such a mixture for stabilizing inanimate organic materials against the effect of light, oxygen and/or heat. Inanimate organic materials comprising at least one such mixture, and also articles produced from such inanimate organic materials. Methods of stabilizing inanimate organic materials against the effect of light, oxygen and/or heat by adding to said inanimate organic materials at least one such mixture in an effective amount.
摘要翻译：包含（a）一种或多种液体UV吸收剂的混合物，条件是不包括作为液体UV吸收剂的Tinuvin 384-2，（b）一种或多种包含稳定基团的支链聚合物，（c）任选的一种或多种另外的添加剂。使用这种混合物来抵抗光，氧和/或热的影响来稳定无生命的有机材料。包含至少一种这样的混合物的无生命有机材料，以及由这些无生命的有机材料制成的制品。通过向所述无生命的有机材料中加入有效量的至少一种这样的混合物来稳定无生命有机材料抵抗光，氧和/或热的影响的方法。

2. 发明申请

US20090306294A1 Method of producing comb block-copolymers from epoxy-functionalized nitroxylethers and anionically polymerizable monomers 审中-公开
标题翻译：由环氧官能化硝酰基醚和阴离子聚合单体生产梳形嵌段共聚物的方法
公开(公告)号：US20090306294A1
公开(公告)日：2009-12-10
申请号：US11919604
申请日：2006-04-24
申请人： Jochen Fink , Rudolf Pfaendner
发明人： Jochen Fink , Rudolf Pfaendner
IPC分类号： C08L53/00
CPC分类号： C08F283/06 , C08F293/00 , C08G65/22 , C08L71/02 , C08L2666/04
摘要： The invention pertains to a method of producing comb block copolymers from epoxy-functionalized nitroxylethers and further monomers by anionic polymerization followed by nitroxyl mediated controlled free radical polymerization. The block copolymer backbone has defined initiating points where radical grafting of ethylenically unsaturated monomers can take place. Further aspects of the invention are comb block copolymers obtained by this process and the use of such polymers for plastic applications.
摘要翻译：本发明涉及一种由环氧官能化硝酰基醚制备梳形嵌段共聚物的方法，还涉及通过阴离子聚合，然后进行硝酰基介导的受控自由基聚合的其它单体。嵌段共聚物主链已经定义了可以发生烯键式不饱和单体的自由基接枝的引发点。本发明的其它方面是通过该方法获得的梳形嵌段共聚物和这种聚合物在塑料应用中的用途。

3. 发明申请

US20090299013A1 Process for the Preparation of Star and Block-Copolymers Via Epoxy-Functionalized Alkoxyamines 审中-公开
标题翻译：通过环氧官能化烷氧基胺制备星形和嵌段共聚物的方法
公开(公告)号：US20090299013A1
公开(公告)日：2009-12-03
申请号：US11887497
申请日：2006-03-27
申请人： Jochen Fink , Rudolf Pfaendner , Andreas Kramer , Francesco Fuso
发明人： Jochen Fink , Rudolf Pfaendner , Andreas Kramer , Francesco Fuso
IPC分类号： C08F112/08 , C08F2/38
CPC分类号： C08F12/08 , C08F283/124 , C08F293/005 , C08F2438/03 , C08G65/22 , C08G65/26 , C08G65/329 , C08L53/00 , C08L2666/02 , C09J153/00 , C08F2/38 , C08F4/00 , C08F220/60
摘要： The instant invention relates to a process for the preparation of star and block-copolymers, which are prepared by controlled free radical polymerization using epoxy-functionalized alkoxyamines and multifunctional compounds capable of reacting with the epoxy group.
摘要翻译：本发明涉及通过使用环氧官能化烷氧基胺和能与环氧基反应的多官能化合物的控制自由基聚合制备星形和嵌段共聚物的方法。

4. 发明申请

US20050124814A1 Open-chain alkoxyamines and their corresponding nitroxides for controlled low temperature radical polymerization 失效
标题翻译：开链烷氧基胺及其相应的氮氧化物用于控制低温自由基聚合
公开(公告)号：US20050124814A1
公开(公告)日：2005-06-09
申请号：US10506700
申请日：2003-02-25
申请人： Tobias Hintermann , Peter Nesvadba , Andreas Kramer , Jochen Fink
发明人： Tobias Hintermann , Peter Nesvadba , Andreas Kramer , Jochen Fink
IPC分类号： C07D333/40 , C07C219/22 , C07C239/20 , C07C291/00 , C07C321/28 , C07D265/32 , C07D265/34 , C08F4/00 , C07D401/00
CPC分类号： C08F4/00
摘要： The present invention relates to open chain alkoxyamine compounds, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) at least one open chain alkoxyamine compound. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of open chain alkoxyamine compounds for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator X, as well as a process and their use for polymerization are also subjects of the present invention.
摘要翻译：本发明涉及开链烷氧基胺化合物，可聚合组合物，其包含a）至少一种烯键式不饱和单体和b）至少一种开链烷氧基胺化合物。本发明的另外的方面是用于聚合烯键式不饱和单体的方法，以及使用开链烷氧基胺化合物用于受控聚合。中间体N-氧基衍生物，具有烯键式不饱和单体的N-氧基衍生物和自由基引发剂X的组合物以及其聚合的方法和用途也是本发明的主题。

5. 发明申请

US20120129987A1 LIQUID STABILIZER MIXTURE 有权
标题翻译：液体稳定剂混合物
公开(公告)号：US20120129987A1
公开(公告)日：2012-05-24
申请号：US13362281
申请日：2012-01-31
申请人： Simon Schambony , Jochen Fink , Bernd Bruchmann
发明人： Simon Schambony , Jochen Fink , Bernd Bruchmann
IPC分类号： C08K5/3475 , C09K15/22
CPC分类号： C08K5/101 , C08K5/315 , C08K5/3492 , C08L21/00
摘要： A mixture comprising (a) one or more liquid UV absorbers, with the proviso that Tinuvin 384-2 as a liquid UV absorber is excluded, (b) one or more branched polymers comprising stabilizing groups, (c) optionally one or more further additions. Use of such a mixture for stabilizing inanimate organic materials against the effect of light, oxygen and/or heat. Inanimate organic materials comprising at least one such mixture, and also articles produced from such inanimate organic materials. Methods of stabilizing inanimate organic materials against the effect of light, oxygen and/or heat by adding to said inanimate organic materials at least one such mixture in an effective amount.
摘要翻译：包含（a）一种或多种液体UV吸收剂的混合物，条件是不包括作为液体UV吸收剂的Tinuvin 384-2，（b）一种或多种包含稳定基团的支链聚合物，（c）任选的一种或多种另外的添加剂。使用这种混合物来抵抗光，氧和/或热的影响来稳定无生命的有机材料。包含至少一种这样的混合物的无生命有机材料，以及由这些无生命的有机材料制成的制品。通过向所述无生命的有机材料中加入有效量的至少一种这样的混合物来稳定无生命有机材料抵抗光，氧和/或热的影响的方法。

6. 发明申请

US20100267893A1 LIQUID STABILIZER MIXTURE 审中-公开
标题翻译：液体稳定剂混合物
公开(公告)号：US20100267893A1
公开(公告)日：2010-10-21
申请号：US12743071
申请日：2008-11-24
申请人： Simon Schambony , Jochen Fink , Bernd Bruchmann
发明人： Simon Schambony , Jochen Fink , Bernd Bruchmann
IPC分类号： C08L75/04 , F21V9/06 , C08L69/00 , C07C255/00 , C07C69/73
CPC分类号： C08K5/101 , C08K5/315 , C08K5/3492 , C08L21/00
摘要： A mixture comprising (a) one or more liquid UV absorbers, with the proviso that Tinuvin 384-2 as a liquid UV absorber is excluded, (b) one or more branched polymers comprising stabilizing groups, (c) optionally one or more further additions. Use of such a mixture for stabilizing inanimate organic materials against the effect of light, oxygen and/or heat. Inanimate organic materials comprising at least one such mixture, and also articles produced from such inanimate organic materials. Methods of stabilizing inanimate organic materials against the effect of light, oxygen and/or heat by adding to said inanimate organic materials at least one such mixture in an effective amount.
摘要翻译：包含（a）一种或多种液体UV吸收剂的混合物，条件是不包括作为液体UV吸收剂的Tinuvin 384-2，（b）一种或多种包含稳定基团的支链聚合物，（c）任选的一种或多种另外的添加剂。使用这种混合物来抵抗光，氧和/或热的影响来稳定无生命的有机材料。包含至少一种这样的混合物的无生命有机材料，以及由这些无生命的有机材料制成的制品。通过向所述无生命的有机材料中加入有效量的至少一种这样的混合物来稳定无生命有机材料抵抗光，氧和/或热的影响的方法。

7. 发明授权

US07253232B2 Thermoplastic compositions with enhanced melt flow and compatibility 失效
标题翻译：具有增强的熔体流动性和相容性的热塑性组合物
公开(公告)号：US07253232B2
公开(公告)日：2007-08-07
申请号：US10527610
申请日：2003-09-18
申请人： Rudolf Pfaendner , Jochen Fink , Wiebke Wunderlich-Wippert , Andreas Kramer
发明人： Rudolf Pfaendner , Jochen Fink , Wiebke Wunderlich-Wippert , Andreas Kramer
IPC分类号： C08L83/10 , C08L53/00
CPC分类号： C08L51/00 , C07D211/94 , C08L23/02 , C08L27/06 , C08L33/06 , C08L53/00 , C08L67/00 , C08L71/12 , C08L77/00 , C08L2666/02
摘要： The instant invention relates to a composition of a thermoplastic polymer and a triblock-copolymer or grafted comb copolymer, with enhanced melt flow during processing. Further aspects of the invention are the triblock-copolymers or grafted comb polymers itself, a method for their production and their use as compatibilizers and meltflow enhancing additives. Yet another aspect of the invention are functional alkoxyamines, which are useful for the preparation of the triblock-copolymers or grafted comb polymers.
摘要翻译：本发明涉及热塑性聚合物和三嵌段共聚物或接枝梳状共聚物的组合物，其在加工过程中具有增强的熔体流动性。本发明的另外的方面是三嵌段共聚物或接枝的梳状聚合物本身，它们的生产方法以及它们作为增容剂和熔融流动增强添加剂的用途。本发明的另一方面是功能性烷氧基胺，其可用于制备三嵌段共聚物或接枝梳状聚合物。

8. 发明申请

US20060194053A1 Comb copolymers with defined side chains and process for their manufacture 失效
公开(公告)号：US20060194053A1
公开(公告)日：2006-08-31
申请号：US10543427
申请日：2004-02-02
申请人： Jochen Fink , Michael Roth , Rudolf Pfaendner
发明人： Jochen Fink , Michael Roth , Rudolf Pfaendner
IPC分类号： C08G59/32 , C08L71/02
CPC分类号： C08F255/023 , C08F255/02 , C08F257/02 , C08F265/00 , C08F285/00 , C08F287/00 , C08F291/00 , C08F293/005 , Y10T428/2978
摘要： The present invention relates to the modification of copolymers, in particular of grafted copolymers into comb copolymers. The modification comprises the steps (i) of controlled radical polymerization of a polymer or copolymer bearing a epoxide group at one end resulting from the initiation step, and (ii) a heating step of the polymer prepared under (i) and a copolymer bearing a functional group either in the backbone or attached to a side chain, which is able to react with the epxide group. The result is a comb copolymer with well controlled chain length of the grafted side arms expressed for example by a low polydispersity.

9. 发明申请

US20050288435A1 Thermoplastic compositions with enhanced melt flow and compatibility 失效
标题翻译：具有增强的熔体流动性和相容性的热塑性组合物
公开(公告)号：US20050288435A1
公开(公告)日：2005-12-29
申请号：US10527610
申请日：2003-09-18
申请人： Rudolf Pfaendner , Jochen Fink , Wiebke Wunderlich-Wippert , Andreas Kramer
发明人： Rudolf Pfaendner , Jochen Fink , Wiebke Wunderlich-Wippert , Andreas Kramer
IPC分类号： C07D211/94 , C08F4/00 , C08L23/02 , C08L27/06 , C08L33/06 , C08L51/00 , C08L51/08 , C08L53/00 , C08L67/00 , C08L71/12 , C08L77/00 , C08L83/10 , C08L51/04
CPC分类号： C08L51/00 , C07D211/94 , C08L23/02 , C08L27/06 , C08L33/06 , C08L53/00 , C08L67/00 , C08L71/12 , C08L77/00 , C08L2666/02
摘要： The instant invention relates to a composition of a thermoplastic polymer and a triblock-copolymer or grafted comb copolymer, with enhanced melt flow during processing. Further aspects of the invention are the triblock-copolymers or grafted comb polymers itself, a method for their production and their use as compatibilizers and meltflow enhancing additives. Yet another aspect of the invention are functional alkoxyamines, which are useful for the preparation of the triblock-copolymers or grafted comb polymers.
摘要翻译：本发明涉及热塑性聚合物和三嵌段共聚物或接枝梳状共聚物的组合物，其在加工过程中具有增强的熔体流动性。本发明的另外的方面是三嵌段共聚物或接枝的梳状聚合物本身，它们的生产方法以及它们作为增容剂和熔融流动增强添加剂的用途。本发明的另一方面是功能性烷氧基胺，其可用于制备三嵌段共聚物或接枝梳状聚合物。

10. 发明申请

US20050215720A1 Grafting of nitroxyl terminated oligomers or polymers onto thermoplastic polymers 失效
标题翻译：将硝酰基封端的低聚物或聚合物接枝到热塑性聚合物上
公开(公告)号：US20050215720A1
公开(公告)日：2005-09-29
申请号：US10518873
申请日：2003-06-12
申请人： Jochen Fink , Michael Roth , Rudolf Pfaendner
发明人： Jochen Fink , Michael Roth , Rudolf Pfaendner
IPC分类号： C08F4/00 , C08F8/00 , C08F8/30 , C08F10/00 , C08F293/00 , C08G81/02 , C08F2/00
CPC分类号： C08F293/005 , C08F4/00 , C08F8/30 , C08F10/00 , C08F2438/02 , C08G81/021 , C08F2/38
摘要： The instant invention relates to a process for the preparation of grafted polymers wherein in a first step A) a oligomer or polymer is prepared by controlled radical polymerization in the presence of a stable free nitroxyl radical or a nitroxylether to obtain a nitroxyl terminated oligomer or polymer and in a second step B) the nitroxyl terminated oligomer or polymer is mixed and reacted with a thermoplastic or elastomeric polymer or copolymer in its molten state at a temperature at which cleavage of the nitroxyl-polymer/oligomer bond occurs, whereby the nitroxyl terminated oligomer or polymer is grafted onto the thermoplastic or elastomeric polymer. A further subject of the present invention is a grafted polymer prepared by said process.
摘要翻译：本发明涉及一种制备接枝聚合物的方法，其中在第一步骤A）中，通过在稳定的游离硝酰基或硝酰基醚的存在下通过可控自由基聚合制备低聚物或聚合物，得到硝酰基封端的低聚物或聚合物并且在第二步骤B）中，将硝酰基封端的低聚物或聚合物与其熔融状态下的热塑性或弹性体聚合物或共聚物在发生硝酰基聚合物/低聚物键断裂的温度下反应，由此将硝酰基封端的低聚物或聚合物接枝到热塑性或弹性聚合物上。本发明的另一个主题是通过所述方法制备的接枝聚合物。

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