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1. 发明授权

US5200163A Removal of phosgene from off-gases 失效
标题翻译：从废气中去除磷灰石
公开(公告)号：US5200163A
公开(公告)日：1993-04-06
申请号：US785288
申请日：1991-10-30
申请人： Jochem Henkelmann , Thomas M. Kahl , Irene Troetsch-Schaller , Leopold Hupfer , Wolfgang Franzischka , Wolfgang Schwarz
发明人： Jochem Henkelmann , Thomas M. Kahl , Irene Troetsch-Schaller , Leopold Hupfer , Wolfgang Franzischka , Wolfgang Schwarz
IPC分类号： B01D53/70
CPC分类号： B01D53/70
摘要： To remove phosgene from off-gases, the former is reacted in a washing zone with a liquid which contains or is composed of compounds of the formula ##STR1## where R.sub.1 and R.sub.2 are identical or different and are each aliphatic or cycloaliphatic alkyl of 1 to 8 carbons, or R.sub.1 and R.sub.2 are --(CH.sub.2).sub.n -- where n is 4 or 5, R.sub.3 is hydrogen or aliphatic or cycloaliphatic alkyl of 1 to 6 carbon atoms, or R.sub.1 or R.sub.2 and R.sub.3 are --(CH.sub.2).sub.m -- where m is 3, 4 or 5.The liquid can be regenerated by the addition of water, and the regenerated liquid can be returned to the washing zone.
摘要翻译：为了从废气中除去光气，前者在洗涤区与液体反应，该液体含有或由式（Ⅰ）的化合物组成，其中R 1和R 2相同或不同，并且各自为脂族或脂环族烷基， 8个碳，或者R1和R2是 - （CH2）n-，其中n是4或5，R3是氢或1到6个碳原子的脂族或脂环族烷基，或者R1或R2和R3是 - （CH2）m-，其中 m为3,4或5.液体可以通过加水再生，再生液体可以返回到洗涤区。

2. 发明授权

US5200560A Preparation of carboxylic chlorides 失效
标题翻译：羧酸氯化物的制备
公开(公告)号：US5200560A
公开(公告)日：1993-04-06
申请号：US908439
申请日：1992-06-30
申请人： Thomas M. Kahl , Jochem Henkelmann , Leopold Hupfer , Wolfgang Franzischka , Wolfgang Schwarz
发明人： Thomas M. Kahl , Jochem Henkelmann , Leopold Hupfer , Wolfgang Franzischka , Wolfgang Schwarz
IPC分类号： C07C51/60
CPC分类号： C07C51/60
摘要： A process for the preparation of a carboxylic chloride of the general formula I ##STR1## in which R denotes C.sub.1 -C.sub.30 -alkyl, C.sub.2 -C.sub.30 -alkenyl or C.sub.2 -C.sub.30 -alkynyl, from a carboxylic acid of the general formula II ##STR2## in which R has the meanings stated, and phosgene COCl.sub.2 (III), in the presence of a catalyst adduct comprising phosgene and N,N-disubstituted formamide of the general formula IV ##STR3## in which R.sup.1 and R.sup.2 are independently C.sub.1 -C.sub.3 -alkyl or R.sup.1 and R.sup.2 together form a C.sub.4 - or C.sub.5 -alkylene chain which may or may not be interrupted by an oxygen atom or by a nitrogen atom carrying a C.sub.1 -C.sub.3 -alkyl group or CHO, the product being isolated by phase separation, wherein the amount of phosgene added to the formamide (IV) is from 20 to 70% molar, based on the formamide.
摘要翻译：由通式I（I）表示的羧酸的制备方法，其中R表示C 1 -C 30 - 烷基，C 2 -C 30 - 烯基或C 2 -C 30炔基，由通式（II）其中R具有所述的含义，和光气COCl 2（III），在包含光气和N，N-二取代的通式IV（IV）的甲酰胺的催化剂加合物的存在下，在其中R 1和R 2独立地是C 1 -C 3 - 烷基或R 1和R 2一起形成C4-或C5-亚烷基链，其可以被氧原子或可以不被氧原子中断或可以被携带C1-C3-烷基的氮原子或 CHO，通过相分离分离产物，其中加甲酰胺（IV）中的光气的量为甲酰胺为20-70％摩尔。

3. 发明授权

US5196611A Preparation of alkyl, alkenyl, and alkynyl chlorides 失效
标题翻译：烷基，亚苄基和亚苄基氯化物的制备
公开(公告)号：US5196611A
公开(公告)日：1993-03-23
申请号：US879214
申请日：1992-05-06
申请人： Jochem Henkelmann , Irene Troetsch-Schaller , Thomas Wettling , Thomas-Michael Kahl , Leopold Hupfer , Wolfgang Franzischka , Hermann Koehler
发明人： Jochem Henkelmann , Irene Troetsch-Schaller , Thomas Wettling , Thomas-Michael Kahl , Leopold Hupfer , Wolfgang Franzischka , Hermann Koehler
IPC分类号： B01J31/02 , C07B39/00 , C07B61/00 , C07C17/16 , C07C19/01 , C07C21/02 , C07C21/22 , C07C41/22 , C07C43/225
CPC分类号： C07C17/16 , C07C41/22
摘要： The preparation of an alkyl, alkenyl, or alkynyl chloride by the reaction of a corresponding alcohol with phosgene or thionyl chloride in the presence of a phosphine oxide acting as catalyst, wherein the catalyst used is an aliphatic, cycloaliphatic, or cyclic/aliphatic phosphine oxide.
摘要翻译：在作为催化剂的氧化膦存在下，通过相应的醇与光气或亚硫酰氯的反应制备烷基，烯基或炔基氯，其中使用的催化剂是脂族，环脂族或环状/脂族氧化膦。

4. 发明授权

US4814479A Preparation of aromatic nitriles 失效
标题翻译：芳香腈的制备
公开(公告)号：US4814479A
公开(公告)日：1989-03-21
申请号：US929829
申请日：1986-11-13
申请人： Heinz Engelbach , Roland Krokoszinski , Wolfgang Franzischka , Martin Decker
发明人： Heinz Engelbach , Roland Krokoszinski , Wolfgang Franzischka , Martin Decker
IPC分类号： C07B61/00 , B01J23/22 , C07C67/00 , C07C253/00 , C07C253/28 , C07C255/50 , C07C255/51 , C07C120/14
CPC分类号： C07C255/00 , C07C253/28
摘要： Aromatic nitriles, in particular phthalodinitriles, are prepared from an appropriately alkyl-substituted aromatic hydrocarbon by catalytic oxidation with oxygen or an oxygen-containing gas in the presence of ammonia at elevated temperatures in the vapor phase, in the presence of a catalyst which contains from 2 to 10% by weight of vanadium(V) oxide, from 1 to 10% by weight of antimony(III) oxide, from 0.02 to 2% by weight of an alkali metal oxide and alumina, by a process in which from 0.01 to 1.0% by weight of an alkaline earth metal, or of a compound of an alkaline earth metal, in particular barium or a barium compound, is added to the catalyst.
摘要翻译：芳族腈，特别是酞腈，通过在氨气存在下，在气相的高温下，在催化剂存在下，通过在氧气或含氧气体中进行催化氧化，由适当的烷基取代的芳烃制备， 2至10重量％的氧化钒（V），1至10重量％的氧化锑（III），0.02至2重量％的碱金属氧化物和氧化铝，其中从0.01至向催化剂中加入1.0重量％的碱土金属或碱土金属化合物，特别是钡或钡化合物。

5. 发明授权

US4895985A Preparation of cyclopentanone 失效
标题翻译：环戊酮的制备
公开(公告)号：US4895985A
公开(公告)日：1990-01-23
申请号：US236210
申请日：1988-08-25
申请人： Martin Decker , Harro Wache , Wolfgang Franzischka
发明人： Martin Decker , Harro Wache , Wolfgang Franzischka
IPC分类号： C07C45/48
CPC分类号： C07C45/48
摘要： The invention relates to a process for the preparation of cyclopentanone from adipic acid wherein adipic acid vapor in an inert gas at a temperature of from 250.degree. C. to 450.degree. C., possibly accompanied by water vapor, is passed over an oxygenous acidic or basic catalyst.
摘要翻译：本发明涉及一种从己二酸制备环戊酮的方法，其中惰性气体中的己二酸蒸气在250℃至450℃的温度下，可能伴随着水蒸汽，通过氧气酸性或碱性催化剂。

6. 发明授权

US4786727A Preparation of hexamethyleneimine 失效
标题翻译：六亚甲基亚胺的制备
公开(公告)号：US4786727A
公开(公告)日：1988-11-22
申请号：US608447
申请日：1984-05-09
申请人： Wolfgang Schroeder , Wolfgang Franzischka , Herbert Mueller
发明人： Wolfgang Schroeder , Wolfgang Franzischka , Herbert Mueller
IPC分类号： C07D295/023 , C07D295/02
CPC分类号： C07D295/023
摘要： Hexamethylenemine is obtained by hydrogenating .epsilon.-caprolactam, the latter being vaporized and hydrogenated under a working pressure of less than 10 bar, the gas phase being unsaturated in respect of caprolactam, and the residence time being short.
摘要翻译：六亚甲基胺是通过氢化ε-己内酰胺得到的，ε-己内酰胺在小于10巴的工作压力下蒸发和氢化，气相在己内酰胺方面是不饱和的，停留时间短。

7. 发明授权

US4745228A Preparation of cyclic ketones 失效
标题翻译：环酮的制备
公开(公告)号：US4745228A
公开(公告)日：1988-05-17
申请号：US65959
申请日：1987-06-24
申请人： Martin Decker , Rolf Fischer , Wolfgang Franzischka , Rudolf Kummer , Heinz-Walter Schneider , Uwe Vagt
发明人： Martin Decker , Rolf Fischer , Wolfgang Franzischka , Rudolf Kummer , Heinz-Walter Schneider , Uwe Vagt
IPC分类号： C07C45/48 , C07C45/00 , C07C45/51
CPC分类号： C07C45/48
摘要： Cyclic ketones of the formula ##STR1## where n is an integer from 4 to 6, are prepared by converting an aliphatic dicarboxylate of the formulaR.sup.1 OCC--(CH.sub.2).sub.n --COOR.sup.2 IIwhere n has the above meaning, R.sup.1 and R.sup.2 are each alkyl, cycloalkyl, aralkyl or aryl and R.sup.2 may furthermore be hydrogen, at from 150.degree. to 450.degree. C. over a solid oxide catalyst.
摘要翻译：通过将式R 1 OCC-（CH 2）n -COOR 2 II的脂肪族二羧酸酯转化为其中n具有上述含义，R1和R2各自为烷基，其中n为4-6的整数，其中n为4至6的整数的式，环烷基，芳烷基或芳基，R2可以为氢，在固体氧化物催化剂上为150-450℃。

8. 发明授权

US6037381A Preparation of polytetrahydrofuran with terminal hydroxyl groups using ion exchangers 有权
标题翻译：使用离子交换剂制备具有末端羟基的聚四氢呋喃
公开(公告)号：US6037381A
公开(公告)日：2000-03-14
申请号：US220776
申请日：1998-12-28
申请人： Wulfrich Friedemann Beer , Klaus Beiser , Jurgen Ciprian , Lothar Franz , Wolfgang Franzischka , Christof Palm , Frank-Friedrich Pape , Axel Paul , Ulrich-Dieter Pessel , Alexander Weck
发明人： Wulfrich Friedemann Beer , Klaus Beiser , Jurgen Ciprian , Lothar Franz , Wolfgang Franzischka , Christof Palm , Frank-Friedrich Pape , Axel Paul , Ulrich-Dieter Pessel , Alexander Weck
IPC分类号： B01J39/04 , B01J47/02 , B01J49/00 , C08G65/20 , C08G65/30 , C08G65/331 , C08J5/20 , C08F6/08
CPC分类号： C08G65/3311 , B01J39/043 , B01J47/026 , B01J49/0008 , C08G65/20
摘要： The invention relates to a process for preparing hydroxyl-containing polymers, in particular for preparing polytetrahydrofuran with terminal hydroxyl groups, from the corresponding acyloxy-containing polymers by transesterification with alcohols in the presence of a sodium-containing catalyst. In this process the polytetrahydrofuiran solution is passed in the presence of a catalytic amount of water directly through at least one ion exchanger following the transesterification in order to remove the sodium cations.The novel process makes it possible to remove the sodium cations from the sodium-containing catalyst in an economic manner and with little complexity. The residual sodium content can be reduced to values of less than 0.5 ppm.
摘要翻译：本发明涉及一种通过在含钠催化剂存在下与醇进行酯交换来制备含羟基聚合物的方法，特别是通过与相应的含酰氧基的聚合物一起制备具有末端羟基的聚四氢呋喃。在该方法中，聚四氢呋喃溶液在催化量的存在下直接通过至少一个离子交换剂进行酯交换反应以除去钠阳离子。该新颖的方法使得可以经济地并且几乎没有复杂性从含钠催化剂中除去钠阳离子。剩余的钠含量可以降低到小于0.5ppm的值。

9. 发明授权

US5981688A Continuous preparation of polytetrahydrofuran by a transesterification cascade with specific destruction of foam 失效
标题翻译：通过酯交换级联连续制备聚四氢呋喃，特别破坏泡沫
公开(公告)号：US5981688A
公开(公告)日：1999-11-09
申请号：US159086
申请日：1998-09-23
申请人： Heinz Auer , Klaus Beiser , Jurgen Ciprian , Lothar Franz , Wolfgang Franzischka , Ulrich-Dieter Pessel , Werner Weinle
发明人： Heinz Auer , Klaus Beiser , Jurgen Ciprian , Lothar Franz , Wolfgang Franzischka , Ulrich-Dieter Pessel , Werner Weinle
IPC分类号： B01J19/18 , C08G65/20 , C08G65/30 , C08G65/331 , C08G63/00
CPC分类号： B01J19/1862 , B01J19/1881 , C08G65/20 , C08G65/30 , C08G65/3312 , B01J2219/0025
摘要： A process for preparing hydroxyl-containing polymers and, in particular, a process for preparing polytetrahydrofuran with terminal hydroxyl groups from the corresponding acyloxy-containing polymers by transesterification with alcohols is carried out continuously in at least one stirred vessel, with the foam produced in the transesterification being fed tangentially to a cylindrical container, preferably a cyclone separator, at an adequate velocity to destroy the foam. The liquid phase which separates out is recycled through a line to the at least one stirred vessel.This continuous process is preferably carried out in a cascade of stirred vessels, in which each stirred vessel or a subunit of at least two stirred vessels can in each case be coupled to a cylindrical container, preferably in the form of a cyclone separator.
摘要翻译：特别是制备含羟基聚合物的方法，特别是通过与醇的酯交换反应，由相应的含酰氧基的聚合物制备具有末端羟基的聚四氢呋喃的方法在至少一个搅拌容器中连续进行，其中在酯交换反应以适当的速度切向地进料到圆柱形容器，优选旋风分离器以破坏泡沫。分离出的液相通过管线再循环至至少一个搅拌容器。这种连续方法优选在级联的搅拌容器中进行，其中每个搅拌容器或至少两个搅拌容器的亚单位可以在每种情况下联接到圆柱形容器，优选以旋风分离器的形式。

10. 发明授权

US5623082A Preparation of acyl chlorides 失效
标题翻译：酰氯的制备
公开(公告)号：US5623082A
公开(公告)日：1997-04-22
申请号：US488923
申请日：1995-07-11
申请人： Martin Decker , Wolfgang Franzischka , Rudolf Irnich, deceased , Manfred Sauerwald
发明人： Martin Decker , Wolfgang Franzischka , Rudolf Irnich, deceased , Manfred Sauerwald
IPC分类号： B01J31/04 , C07B61/00 , C07C51/00 , C07C51/60 , C07C53/38 , C07C53/42 , C07C67/00 , C07C51/58
CPC分类号： C07C51/60
摘要： Acyl chlorides are prepared by reacting a carboxylic acid or its anhydride with carbonyl chloride in the presence of a carboxamide of the formula I ##STR1## where R.sup.1 is a radical of the formula ##STR2## R.sup.2 and R.sup.3 are each alkyl of 1 to 9 carbon atoms, R.sup.4 and R.sup.5 are each hydrogen or alkyl of 1 to 9 carbon atoms and the two radicals R.sup.1 and R.sup.2 may furthermore be a hydrocarbon radical which completes the moiety ##STR3## to form a heterocyclic structure, and the stated alkyl and hydrocarbon radicals may furthermore contain substituents which are inert under the reaction conditions.
摘要翻译：酰基氯通过羧酸或其酸酐与碳酰氯在式I酮原子的羧酰胺存在下反应制备，R 4和R 5各自为氢或1至9个碳原子的烷基，并且两个基团R 1和R 2可以此外是完成部分“IMAGE”以形成杂环结构的烃基，并且所述烷基和烃基还可以含有在反应条件下为惰性的取代基。

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