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1. 发明授权

US5200163A Removal of phosgene from off-gases 失效
标题翻译：从废气中去除磷灰石
公开(公告)号：US5200163A
公开(公告)日：1993-04-06
申请号：US785288
申请日：1991-10-30
申请人： Jochem Henkelmann , Thomas M. Kahl , Irene Troetsch-Schaller , Leopold Hupfer , Wolfgang Franzischka , Wolfgang Schwarz
发明人： Jochem Henkelmann , Thomas M. Kahl , Irene Troetsch-Schaller , Leopold Hupfer , Wolfgang Franzischka , Wolfgang Schwarz
IPC分类号： B01D53/70
CPC分类号： B01D53/70
摘要： To remove phosgene from off-gases, the former is reacted in a washing zone with a liquid which contains or is composed of compounds of the formula ##STR1## where R.sub.1 and R.sub.2 are identical or different and are each aliphatic or cycloaliphatic alkyl of 1 to 8 carbons, or R.sub.1 and R.sub.2 are --(CH.sub.2).sub.n -- where n is 4 or 5, R.sub.3 is hydrogen or aliphatic or cycloaliphatic alkyl of 1 to 6 carbon atoms, or R.sub.1 or R.sub.2 and R.sub.3 are --(CH.sub.2).sub.m -- where m is 3, 4 or 5.The liquid can be regenerated by the addition of water, and the regenerated liquid can be returned to the washing zone.
摘要翻译：为了从废气中除去光气，前者在洗涤区与液体反应，该液体含有或由式（Ⅰ）的化合物组成，其中R 1和R 2相同或不同，并且各自为脂族或脂环族烷基， 8个碳，或者R1和R2是 - （CH2）n-，其中n是4或5，R3是氢或1到6个碳原子的脂族或脂环族烷基，或者R1或R2和R3是 - （CH2）m-，其中 m为3,4或5.液体可以通过加水再生，再生液体可以返回到洗涤区。

2. 发明授权

US5200560A Preparation of carboxylic chlorides 失效
标题翻译：羧酸氯化物的制备
公开(公告)号：US5200560A
公开(公告)日：1993-04-06
申请号：US908439
申请日：1992-06-30
申请人： Thomas M. Kahl , Jochem Henkelmann , Leopold Hupfer , Wolfgang Franzischka , Wolfgang Schwarz
发明人： Thomas M. Kahl , Jochem Henkelmann , Leopold Hupfer , Wolfgang Franzischka , Wolfgang Schwarz
IPC分类号： C07C51/60
CPC分类号： C07C51/60
摘要： A process for the preparation of a carboxylic chloride of the general formula I ##STR1## in which R denotes C.sub.1 -C.sub.30 -alkyl, C.sub.2 -C.sub.30 -alkenyl or C.sub.2 -C.sub.30 -alkynyl, from a carboxylic acid of the general formula II ##STR2## in which R has the meanings stated, and phosgene COCl.sub.2 (III), in the presence of a catalyst adduct comprising phosgene and N,N-disubstituted formamide of the general formula IV ##STR3## in which R.sup.1 and R.sup.2 are independently C.sub.1 -C.sub.3 -alkyl or R.sup.1 and R.sup.2 together form a C.sub.4 - or C.sub.5 -alkylene chain which may or may not be interrupted by an oxygen atom or by a nitrogen atom carrying a C.sub.1 -C.sub.3 -alkyl group or CHO, the product being isolated by phase separation, wherein the amount of phosgene added to the formamide (IV) is from 20 to 70% molar, based on the formamide.
摘要翻译：由通式I（I）表示的羧酸的制备方法，其中R表示C 1 -C 30 - 烷基，C 2 -C 30 - 烯基或C 2 -C 30炔基，由通式（II）其中R具有所述的含义，和光气COCl 2（III），在包含光气和N，N-二取代的通式IV（IV）的甲酰胺的催化剂加合物的存在下，在其中R 1和R 2独立地是C 1 -C 3 - 烷基或R 1和R 2一起形成C4-或C5-亚烷基链，其可以被氧原子或可以不被氧原子中断或可以被携带C1-C3-烷基的氮原子或 CHO，通过相分离分离产物，其中加甲酰胺（IV）中的光气的量为甲酰胺为20-70％摩尔。

3. 发明授权

US5196611A Preparation of alkyl, alkenyl, and alkynyl chlorides 失效
标题翻译：烷基，亚苄基和亚苄基氯化物的制备
公开(公告)号：US5196611A
公开(公告)日：1993-03-23
申请号：US879214
申请日：1992-05-06
申请人： Jochem Henkelmann , Irene Troetsch-Schaller , Thomas Wettling , Thomas-Michael Kahl , Leopold Hupfer , Wolfgang Franzischka , Hermann Koehler
发明人： Jochem Henkelmann , Irene Troetsch-Schaller , Thomas Wettling , Thomas-Michael Kahl , Leopold Hupfer , Wolfgang Franzischka , Hermann Koehler
IPC分类号： B01J31/02 , C07B39/00 , C07B61/00 , C07C17/16 , C07C19/01 , C07C21/02 , C07C21/22 , C07C41/22 , C07C43/225
CPC分类号： C07C17/16 , C07C41/22
摘要： The preparation of an alkyl, alkenyl, or alkynyl chloride by the reaction of a corresponding alcohol with phosgene or thionyl chloride in the presence of a phosphine oxide acting as catalyst, wherein the catalyst used is an aliphatic, cycloaliphatic, or cyclic/aliphatic phosphine oxide.
摘要翻译：在作为催化剂的氧化膦存在下，通过相应的醇与光气或亚硫酰氯的反应制备烷基，烯基或炔基氯，其中使用的催化剂是脂族，环脂族或环状/脂族氧化膦。

4. 发明授权

US5401873A Preparation of methyl formate 失效
标题翻译：甲酸甲酯的制备
公开(公告)号：US5401873A
公开(公告)日：1995-03-28
申请号：US208823
申请日：1994-03-11
申请人： Peter Zehner , Klaus Bittins , Wilhelm Haarde , Ulrich Eiden , Dietrich Wolff , Manfred Herr , Leopold Hupfer
发明人： Peter Zehner , Klaus Bittins , Wilhelm Haarde , Ulrich Eiden , Dietrich Wolff , Manfred Herr , Leopold Hupfer
IPC分类号： B01J31/02 , C07B61/00 , C07C67/36 , C07C69/06
CPC分类号： C07C67/36
摘要： Preparation of methyl formate by the reaction of carbon monoxide and methanol under conditions of elevated pressure and temperature in the presence of an alkali metal methylate, in whichA) the starting materials are mixed in a mixing zone, are allowed to react partially, and the reaction solution is saturated with CO andB) the reaction is allowed to reach completion in one or more secondary reaction zones without the addition of further starting materials.
摘要翻译：在甲醇酸碱金属（其中A）原料在混合区中混合的条件下，通过一氧化碳和甲醇在升高的压力和温度条件下反应制备甲酸甲酯，使其部分反应，反应溶液用CO饱和，B）使反应在一个或多个次级反应区中达到完成，而不添加进一步的起始原料。

5. 发明授权

US5294740A Preparation of formic acid by thermal cleavage of quaternary ammonium formates 失效
标题翻译：通过季铵化合物的热裂解制备甲酸
公开(公告)号：US5294740A
公开(公告)日：1994-03-15
申请号：US41048
申请日：1993-03-31
申请人： Hans Kiefer , Leopold Hupfer , Ferdinand Lippert
发明人： Hans Kiefer , Leopold Hupfer , Ferdinand Lippert
IPC分类号： C07C51/02 , C07C51/09 , C07C51/44
CPC分类号： C07C51/02
摘要： A process for preparing formic acid by thermal cleavage of quaternary ammonium formates of the general formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are C.sub.1 - to C.sub.14 -alkyl, C.sub.3 - to C.sub.8 -cycloalkyl, aryl or C.sub.7 - to C.sub.16 -aralkyl, or together are 1,4- or 1,5-alkylene which is unsubstituted or substituted one to four times by C.sub.1 -to C.sub.4 -alkyl, with the proviso that the sum of the carbon atoms of R.sup.1, R.sup.2 and R.sup.3 in the quaternary ammonium formates I is 7 to 40,comprises carrying out the cleavage in the presence of secondary formamides of the general formula II ##STR2## where R.sup.4 and R.sup.5 are C.sub.2 - to C.sub.10 -alkyl, C.sub.3 - to C.sub.8 -cycloalkyl, aryl or C.sub.7 - to C.sub.16 -aralkyl, or together are 1,4- or 1,5-alkylene which is unsubstituted or substituted one to four times by C.sub.1 - to C.sub.4 -alkyl,which formamides boil 30.degree. to 150.degree. C. lower than the tertiary amine of the general formula III ##STR3## where R.sup.1, R.sup.2 and R.sup.3 have the abovementioned meanings, contained in the formate I.
摘要翻译：通式I（*化学结构*）（I）的季铵盐的热裂解制备甲酸的方法，其中R 1，R 2和R 3是C 1〜C 14烷基，C 3〜C 8环烷基，芳基或 C7-至C16-芳烷基，或一起为未取代或被C1至C4-烷基取代1-4次的1,4-或1,5-亚烷基，条件是R1，季铵盐I中的R 2和R 3为7至40，包括在通式II（*化学结构*）（II）的二级甲酰胺存在下进行裂解，其中R 4和R 5为C 2至C 10 - 烷基，C 3 -C 8 - 环烷基，芳基或C 7 - 至C 16 - 芳烷基，或者一起是未被取代或被C 1〜C 4 - 烷基取代1〜4次的1,4-或1,5-亚烷基，比通式III的叔胺（*化学结构*）（III）低30〜150℃，其中R1，R2和R3具有上述含义，含有i 在甲板上

6. 发明授权

US5130435A Preparation of vinyl ethers 失效
标题翻译：乙烯的制备
公开(公告)号：US5130435A
公开(公告)日：1992-07-14
申请号：US565180
申请日：1990-08-09
申请人： Wolfgang Hoelderich , Norbert Goetz , Leopold Hupfer
发明人： Wolfgang Hoelderich , Norbert Goetz , Leopold Hupfer
IPC分类号： C07C41/28
CPC分类号： C07C41/28 , Y02P20/582
摘要： Vinyl ethers of the formula ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are identical to or different from one another, each being hydrogen, straight-chain or branched alkyl or alkenyl of up to 12 carbon atoms, cycloalkyl or cycloalkylene of from 5 to 8 carbon atoms, aryl, alkylaryl, alkenylaryl, aralkyl and aralkenyl of from 6 to 16 carbon atoms, halogen-substituted aryl or heterocyclyl, and in addition the radicals R.sup.1 and R.sup.2 or R.sup.1 and R.sup.3, together with the carbon atom to which they are bonded, can form a cycloalkane, cycloalkene or a heterocycle, and R.sup.4 is alkyl, alkylaryl or aralkyl, are prepared by eliminating an alcohol from an acetal/ketal of the formula ##STR2## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each as defined above, in the presence of a phosphate of zeolite structure and/or a precipitated phosphate of the elements B, Zr, Ce or Fe and/or phosphoric acid or boric acid on carrier material and/or acidic undoped metal oxide as catalyst, the reaction being preferably carried out in the gas phase.
摘要翻译：式中，R 1，R 2和R 3彼此相同或不同的乙烯基醚，各自为氢，直至12个碳原子的直链或支链烷基或烯基，5至8的环烷基或亚环烷基碳原子，芳基，烷基芳基，烯基芳基，芳烷基和具有6至16个碳原子的芳烯基，卤素取代的芳基或杂环基，此外基团R 1和R 2或R 1和R 3与它们所键合的碳原子一起可以形成环烷烃，环烯烃或杂环，并且R 4是烷基，烷基芳基或芳烷基，通过从式（I）的缩醛/缩酮中除去醇来制备，其中R 1，R 2，R 3和R 4各自如上所定义在载体材料和/或酸性未掺杂的金属氧化物作为催化剂的沸石结构的磷酸盐和/或元素B，Zr，Ce或Fe和/或磷酸或硼酸的沉淀磷酸盐存在下，反应为优选在气相中进行。

7. 发明授权

US4891451A Preparation of vinyl ethers 失效
标题翻译：乙烯基醚的制备
公开(公告)号：US4891451A
公开(公告)日：1990-01-02
申请号：US213589
申请日：1988-06-30
申请人： Wolfgang Hoelderich , Norbert Goetz , Leopold Hupfer
发明人： Wolfgang Hoelderich , Norbert Goetz , Leopold Hupfer
IPC分类号： C07C41/28
CPC分类号： C07C41/28 , C07C2101/14 , Y02P20/582
摘要： Vinyl ethers of the formula (I) ##STR1## where R.sup.1 to R.sup.3 are identical or different and are each hydrogen, a straight-chain or branched alkyl or alkenyl radical of not more than 12 carbon atoms, halogen-substituted alkyl, a cycloalkyl or cycloalkenyl radical of 5 to 8 carbon atoms, an aryl, alkylaryl, alkenylaryl, aralkyl or aralkenyl radical of 6 to 16 carbon atoms, halogen-substituted aryl or a heterocyclic radical and furthermore R.sup.1 and R.sup.2 or R.sup.1 and R.sup.3, together with the carbon atom to which they are bonded, may form a cycloalkane, cycloalkene or heterocyclic structure, and R.sup.4 is alkyl, alkylaryl or aralkyl, are prepared by a process in which an alcohol is eliminated from an acetal or ketal of the formula (II) ##STR2## where R.sup.1 to R.sup.4 have the above meanings, in the presence of borosilicate and/or iron silicate zeolites as catalysts.
摘要翻译：式（I）的乙烯基醚其中R 1至R 3相同或不同并且各自为氢，不超过12个碳原子的直链或支链烷基或烯基，卤素取代的烷基， 5至8个碳原子的环烷基或环烯基，6至16个碳原子的芳基，烷基芳基，烯基芳基，芳烷基或芳烯基，卤素取代的芳基或杂环基，此外R1和R2或R1和R3连同其键合的碳原子可以通过其中从式（II）的缩醛或缩酮中除去醇的方法制备环烷烃，环烯烃或杂环结构，并且R 4是烷基，烷基芳基或芳烷基，在有硼硅酸盐和/或铁硅酸盐沸石作为催化剂的情况下，R1至R4具有上述含义的图像（II）。

8. 发明授权

US4885395A Preparation of alpha, beta-unsaturated ketones 失效
标题翻译：制备α，β-不饱和酮
公开(公告)号：US4885395A
公开(公告)日：1989-12-05
申请号：US100846
申请日：1987-09-25
申请人： Wolfgang Hoelderich , Kurt Schneider , Leopold Hupfer
发明人： Wolfgang Hoelderich , Kurt Schneider , Leopold Hupfer
IPC分类号： B01J29/04 , B01J29/40 , B01J29/85 , C07C45/66 , C07C45/67
CPC分类号： B01J29/85 , B01J29/04 , B01J29/40 , C07C45/66 , C07C45/673 , C07C45/676 , Y02P20/582
摘要： Alpha,beta-unsaturated ketones of the formula (I) ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each hydrogen, alkyl, alkenyl of 1 to 12 carbon atoms, cycloalkyl, aryl, aralkyl or alkylaryl, are prepared by converting the corresponding .alpha.-hydroxy, alkoxy or carboxy compound in the presence of an acidic catalyst.Preferred starting materials are 3-methyl-3-hydroxy-butan-2-one, 3-methyl-3-hydroxypentan-2-one and 3-pentamethylene-3-hydroxypropan-2-one, and preferred catalysts are zeolites of the pentasil type.
摘要翻译：式（I）的α，β-不饱和酮其中R 1，R 2和R 3各自为氢，具有1至12个碳原子的烷基，烯基，环烷基，芳基，芳烷基或烷芳基，其通过转化在酸性催化剂存在下，相应的α-羟基，烷氧基或羧基化合物。优选的原料是3-甲基-3-羟基 - 丁-2-酮，3-甲基-3-羟基戊-2-酮和3-五亚甲基-3-羟基丙-2-酮，优选的催化剂是pentasil的沸石类型。

9. 发明授权

US4812593A Preparation of bifunctional compounds 失效
标题翻译：双功能化合物的制备
公开(公告)号：US4812593A
公开(公告)日：1989-03-14
申请号：US82127
申请日：1987-08-06
申请人： Wolfgang Hoelderich , Norbert Goetz , Leopold Hupfer
发明人： Wolfgang Hoelderich , Norbert Goetz , Leopold Hupfer
IPC分类号： C07C45/51 , C07C45/67 , C07C45/71 , C07C47/198 , C07C47/277 , C07C49/175 , C07C49/255 , C07C67/327 , C07C69/708 , C07C69/734 , C07C69/73
CPC分类号： C07C45/71 , C07C45/515 , C07C45/673 , C07C47/198 , C07C47/277 , C07C49/175 , C07C49/255 , C07C67/327
摘要： Bifunctional compounds of the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each alkyl of 1 to 6 carbon atoms, R.sup.2 and R.sup.3 may furthermore be hydrogen, R.sup.2 is furthermore alkoxy and R.sup.4 is hydrogen, alkyl of 1 to 6 carbon atoms or alkoxy, and a double bond may be present between carbon atoms 2 and 3, are prepared by converting a tetraalkoxyalkane or a dialkoxyalkanoate of the formulae ##STR2## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 have the above meanings, in the presence of a catalyst, such as a zeolite, in particular one of the pentasil type, and/or a phosphate and/or phosphoric acid on a carrier.
摘要翻译：其中R 1，R 2和R 3各自为1至6个碳原子的烷基，R 2和R 3可以另外为氢，R 2为烷氧基，且R 4为氢，具有1-6个碳原子的烷基或烷氧基，并且碳原子2和3之间可以存在双键，通过在催化剂存在下，将式Ia，R2，R3和R4具有上述含义的四烷氧基烷烃或二烷氧基烷酸酯进行转化来制备，例如沸石，特别是pentasil类中的一种，和/或载体上的磷酸盐和/或磷酸。

10. 发明授权

US4594461A Preparation of trimethylolalkanes from alkanals and formaldehyde 失效
标题翻译：从链烷和甲醛制备三羟甲基烷烃
公开(公告)号：US4594461A
公开(公告)日：1986-06-10
申请号：US668026
申请日：1984-11-05
申请人： Franz Merger , Peter Hettinger , Leopold Hupfer , Juergen Paetsch
发明人： Franz Merger , Peter Hettinger , Leopold Hupfer , Juergen Paetsch
IPC分类号： B01J23/00 , C07B61/00 , C07C27/00 , C07C29/141 , C07C29/38 , C07C31/22 , C07C67/00 , C07C29/14 , C07C29/80
CPC分类号： C07C29/38
摘要： Trimethylolalkanes are prepared by reacting an n-alkanal with formaldehyde and a trialkylamine in aqueous solution and then hydrogenating the product, by a method in which from 2.2 to 4.5 moles of formaldehyde and from 0.6 to 3 moles of trialkylamine are used per mole of the alkanal, and the reaction mixture is worked up by distillation either before or after the hydrogenation.
摘要翻译：通过使正链烷醛与甲醛和三烷基胺在水溶液中反应然后使产物氢化，通过使用每摩尔烷烃使用2.2至4.5摩尔甲醛和0.6至3摩尔三烷基胺的方法制备三羟甲基烷烃，并且在氢化之前或之后通过蒸馏处理反应混合物。

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