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    • 2. 发明授权
    • Process for the production of liquid hydrocarbons
    • 液体烃的生产工艺
    • US06806297B2
    • 2004-10-19
    • US10276615
    • 2002-11-18
    • Hans Michiel HuismanKoen Willem De Leeuw
    • Hans Michiel HuismanKoen Willem De Leeuw
    • C07C2700
    • C10G2/30C01B3/386C01B2203/0261C01B2203/0405C01B2203/0415C01B2203/045C01B2203/0485C01B2203/062C01B2203/065C01B2203/0883C01B2203/0894C01B2203/1023C01B2203/1064C01B2203/1082C01B2203/1241C01B2203/127C07C1/0485C07C2521/06C07C2523/75
    • A process for producing normally liquid hydrocarbon products from a hydrocarbonaceous feedstock, especially from normally gaseous hydrocarbon feed, having the following steps: (a) partial oxidation of the normally gaseous hydrocarbon feed at elevated pressure using air or oxygen enriched air as oxidant, to obtain a syngas mixture having hydrogen, carbon monoxide and nitrogen; (b) converting hydrogen and carbon monoxide obtained in step (a) into a normally liquid hydrocarbon product and a normally gaseous hydrocarbon product; (c) separating from the reaction mixture obtained in step (b) an off-gas mixture having nitrogen, normally gaseous hydrocarbon product, and unconverted hydrogen, carbon monoxide and normally gaseous hydrocarbon feed, insofar as such unconverted components are present; (d) combusting at least a part of the off-gas mixture in a steam raising apparatus, producing steam of an elevated pressure; and (e) expanding the steam produced in step (d) for compressing the air or oxygen enriched air and/or the normally gaseous hydrocarbon feed used in step (a); and a plant having equipment in a line-up suitable for carrying out the process.
    • 一种从含烃原料,特别是通常气态烃进料生产常规烃类产物的方法,具有以下步骤:(a)使用空气或富氧空气作为氧化剂,在升高的压力下将常规气态烃进料部分氧化,以获得 具有氢气,一氧化碳和氮气的合成气混合物; (b)将步骤(a)中获得的氢气和一氧化碳转化为通常为液体的烃产物和通常为气态烃产物; (c)与步骤(b)中获得的反应混合物分离出具有氮气,通常为气态烃产物和未转化氢气,一氧化碳和通常为气态烃进料的废气混合物,只要存在这种未转化的组分; (d)在蒸汽提升装置中燃烧至少一部分废气混合物,产生高压蒸汽; 和(e)扩大在步骤(d)中产生的用于压缩步骤(a)中使用的空气或富氧空气和/或常规气态烃进料的蒸汽; 以及具有适合于执行该过程的阵列中的设备的设备。
    • 4. 发明授权
    • Process for the production of liquid hydrocarbons
    • 液体烃的生产工艺
    • US06942839B2
    • 2005-09-13
    • US10931490
    • 2004-09-01
    • Hans Michiel HuismanKoen Willem De Leeuw
    • Hans Michiel HuismanKoen Willem De Leeuw
    • C01B3/38C07C1/04C10G2/00B01J10/00B01J8/04
    • C10G2/30C01B3/386C01B2203/0261C01B2203/0405C01B2203/0415C01B2203/045C01B2203/0485C01B2203/062C01B2203/065C01B2203/0883C01B2203/0894C01B2203/1023C01B2203/1064C01B2203/1082C01B2203/1241C01B2203/127C07C1/0485C07C2521/06C07C2523/75
    • A process for producing normally liquid hydrocarbon products from a hydrocarbonaceous feedstock, especially from normally gaseous hydrocarbon feed, having the following steps: (a) partial oxidation of the normally gaseous hydrocarbon feed at elevated pressure using air or oxygen enriched air as oxidant, to obtain a syngas mixture having hydrogen, carbon monoxide and nitrogen; (b) converting hydrogen and carbon monoxide obtained in step (a) into a normally liquid hydrocarbon product and a normally gaseous hydrocarbon product; (c) separating from the reaction mixture obtained in step (b) an off-gas mixture having nitrogen, normally gaseous hydrocarbon product, and unconverted hydrogen, carbon monoxide and normally gaseous hydrocarbon feed, insofar as such unconverted components are present; (d) combusting at least a part of the off-gas mixture in a steam raising apparatus, producing steam of an elevated pressure; and (e) expanding the steam produced in step (d) for compressing the air or oxygen enriched air and/or the normally gaseous hydrocarbon feed used in step (a); and a plant having equipment in a line-up suitable for carrying out the process.
    • 一种从含烃原料,特别是通常气态烃进料生产常规烃类产物的方法,具有以下步骤:(a)使用空气或富氧空气作为氧化剂,在升高的压力下将常规气态烃进料部分氧化,以获得 具有氢气,一氧化碳和氮气的合成气混合物; (b)将步骤(a)中获得的氢气和一氧化碳转化为通常为液体的烃产物和通常为气态烃产物; (c)与步骤(b)中获得的反应混合物分离出具有氮气,通常为气态烃产物和未转化氢气,一氧化碳和通常为气态烃进料的废气混合物,只要存在这种未转化的组分; (d)在蒸汽提升装置中燃烧至少一部分废气混合物,产生高压蒸汽; 和(e)扩大在步骤(d)中产生的用于压缩步骤(a)中使用的空气或富氧空气和/或常规气态烃进料的蒸汽; 以及具有适合于执行该过程的阵列中的设备的设备。