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1. 发明授权

US06993911B2 System for power generation in a process producing hydrocarbons 有权
标题翻译：生产碳氢化合物的工艺发电系统
公开(公告)号：US06993911B2
公开(公告)日：2006-02-07
申请号：US10491701
申请日：2002-10-04
申请人： Joannes Ignatius Geijsel , Martijn De Heer , Koen Willem De Leeuw , Jan Volkert Zander
发明人： Joannes Ignatius Geijsel , Martijn De Heer , Koen Willem De Leeuw , Jan Volkert Zander
IPC分类号： F01K25/08
CPC分类号： C10G2/32 , C01B3/36 , C01B3/386 , C01B2203/0205 , C01B2203/0261 , C01B2203/06 , C01B2203/062 , C01B2203/0894 , C01B2203/1011 , C01B2203/1241 , C01B2203/148 , C01B2203/84
摘要： The invention relates to a system for power generation in a process for producing hydrocarbons by catalytic conversion of synthesis gas, involving: i. an oxidation unit for producing synthesis gas and oxidation unit steam by partial oxidation of a hydro-carbonaceous feed and oxygen containing gas; ii. a conversion unit for producing said hydrocarbons and conversion unit steam by catalytical conversion of said synthesis gas; and iii. means for super heating conversion unit steam and a unit for power generation using the super heated steam.
摘要翻译：本发明涉及通过催化转化合成气生产烃的方法中的发电系统

2. 发明授权

US06770191B2 Process for the preparation of linear olefins and use thereof to prepare linear alcohols 失效
标题翻译：制备直链烯烃的方法及其用途以制备直链醇
公开(公告)号：US06770191B2
公开(公告)日：2004-08-03
申请号：US10153955
申请日：2002-05-23
申请人： Joachim Ansorge , Hendrik Dirkzwager , Joannes Ignatius Geijsel , Abdul Razak Mohamad Ali , Timothy Michael Nisbet , Laurent Alain Michel Fenouil
发明人： Joachim Ansorge , Hendrik Dirkzwager , Joannes Ignatius Geijsel , Abdul Razak Mohamad Ali , Timothy Michael Nisbet , Laurent Alain Michel Fenouil
IPC分类号： C10G5102
CPC分类号： C07C11/02 , C07C29/16 , C07C45/50 , C10G69/06 , C10G2300/1022 , C10G2400/22 , C07C31/125 , C07C47/02
摘要： Process for the preparation of a mixture comprising C5+ linear olefins, which process comprises the steps of (a) reacting carbon monoxide and hydrogen in the presence of an effective amount of Fischer-Tropsch catalyst under Fischer-Tropsch reaction conditions; (b) separating from the hydrocarbon mixture thus prepared at least one hydrocarbon fraction, of which at least 95% by weight consists of hydrocarbons containing 15 carbon atoms or more; (c) contacting this hydrocarbon fraction with hydrogen in the presence of an effective amount of hydrogenation catalyst under hydrogenation conditions; (d) subjecting the hydrogenated hydrocarbon fraction thus obtained to a mild thermal cracking treatment; and (e) separating from the cracked product thus prepared the mixture comprising C5+ linear olefins.
摘要翻译：制备包含C 5 +线性烯烃的混合物的方法，该方法包括以下步骤：（a）在费 - 托反应条件下，在有效量的费 - 托催化剂存在下使一氧化碳和氢气反应;（b）由此制备至少一种烃馏分的烃混合物，其中至少95重量％由含有15个或更多个碳原子的烃组成;（c）在氢化作用下在有效量的氢化催化剂存在下使该烃馏分与氢气接触条件;（d）使由此获得的氢化烃馏分进行轻度热裂解处理; 和（e）从如此制备的裂化产物中分离出包含C5 +直链烯烃的混合物。

3. 发明授权

US07250450B2 Process for the production of hydrocarbons from gaseous hydrocarbonaceous feed 失效
标题翻译：从气态烃类饲料生产烃的方法
公开(公告)号：US07250450B2
公开(公告)日：2007-07-31
申请号：US10516805
申请日：2003-06-05
申请人： Laurent Alain Fenouil , Joannes Ignatius Geijsel , Abdul Razak Mohamad Ali
发明人： Laurent Alain Fenouil , Joannes Ignatius Geijsel , Abdul Razak Mohamad Ali
IPC分类号： C07C27/00 , C10G47/00
CPC分类号： C10G2/32 , C10G2/332
摘要： A process for the production of hydrocarbons from gaseous hydrocarbonaceous feed involving the steps of: i) partial oxidation conversion of the gaseous hydrocarbonaceous feed and oxygen containing gas at elevated temperature and pressure into synthesis gas; ii) catalytical conversion of synthesis gas of step i) using a cobalt based Fischer-Tropsch catalyst into a hydrocarbons comprising stream; iii) separating the hydrocarbons comprising stream of step ii) into a hydrocarbons product stream and a recycle stream; and, iv) removing carbon dioxide from the recycle stream and recycle of carbon dioxide depleted recycle stream to step i).
摘要翻译：一种用于从气态烃类原料生产烃的方法，包括以下步骤：i）将气态烃类进料和含氧气体在升高的温度和压力下部分氧化转化成合成气; ii）步骤i）的合成气的催化转化使用基于钴的费 - 托催化剂转化为包含烃的物流; iii）将包含步骤ii）的物流的烃分离成烃产物流和循环流; 以及iv）从再循环流中除去二氧化碳并再循环二氧化碳贫化循环物流至步骤i）。

4. 发明授权

US07282474B2 Process for the preparation of detergents 有权
标题翻译：洗涤剂的制备方法
公开(公告)号：US07282474B2
公开(公告)日：2007-10-16
申请号：US10541169
申请日：2003-12-29
申请人： Hendrik Dirkzwager , Joannes Ignatius Geijsel
发明人： Hendrik Dirkzwager , Joannes Ignatius Geijsel
IPC分类号： C11D17/00 , C07C27/00 , C07C1/00
CPC分类号： C10G67/02 , C07C1/0485 , C10G2/00 , C10G65/04 , C10G69/123
摘要： A process for the preparation of detergents involving separating the hydrocarbonaceous product stream from a Fischer-Tropsch process producing normally liquid and normally solid hydrocarbons into a light fraction and one or more heavy fractions, hydrogenating at least part of the light fraction to convert unsaturated hydrocarbons and/or oxygenates into saturated hydrocarbons, distilling product thus obtained into at least one fraction comprising detergent hydrocarbons, dehydrogenating at least part of the detergent hydrocarbons to obtain a detergent hydrocarbon stream having mono-olefins and converting the mono-olefins into detergents. The invention further concerns a process for the preparation of detergents in which process a hydrogenated product, which is obtained according to the above process, is dehydrogenated to obtain a detergent hydrocarbon stream of mono-olefins, followed by conversion of the mono-olefins into detergents. Further, the invention relates to the combined production of detergents or detergent hydrocarbons and fuels from Fischer-Tropsch hydrocarbonaceous reaction product.
摘要翻译：一种用于制备洗涤剂的方法，其包括将费 - 托法中的烃类产物流分离，从而产生通常为液体和通常为固体烃的轻馏分和一种或多种重馏分，将至少部分轻馏分氢化以转化不饱和烃和 /或将含氧化合物转化成饱和烃，将由此获得的产物蒸馏成至少一部分包含洗涤剂烃，将至少部分洗涤剂烃脱氢得到具有单烯烃的洗涤剂烃流并将单烯烃转化为洗涤剂。本发明还涉及制备洗涤剂的方法，其中根据上述方法获得的氢化产物被脱氢以获得单烯烃的洗涤剂烃流，然后将单烯烃转化为洗涤剂。此外，本发明涉及从费 - 托含烃反应产物组合生产洗涤剂或洗涤剂烃和燃料。

5. 发明授权

US07071237B2 Method to start a process for hydrocarbons 失效
标题翻译：开始碳氢化合物工艺的方法
公开(公告)号：US07071237B2
公开(公告)日：2006-07-04
申请号：US10477743
申请日：2002-05-29
申请人： Joachim Ansorge , Joannes Ignatius Geijsel
发明人： Joachim Ansorge , Joannes Ignatius Geijsel
IPC分类号： C07C27/00 , C10G65/00
CPC分类号： C10G2/32 , B01J2208/00716 , B01J2219/00006 , C01B3/36 , C01B2203/0255 , C01B2203/062 , C01B2203/1235
摘要： The invention relates to a method to start a process for producing normally gaseous, normally liquid and optionally normally solid hydrocarbons from a hydrocarbonaceous feed, which process involves the steps of: (i) compressing and optionally separating an oxygen containing gas; (ii) partial oxidation of the hydrocarbonaceous feed at elevated temperature and pressure using the compressed oxygen containing gas of step (i) to obtain synthesis gas and steam; (iii) catalytically converting the synthesis gas of step (ii) at elevated temperature and pressure to obtain the normally liquid and/or gaseous hydrocarbons and steam; and (iv) using steam obtained in step (ii) and/or step (iii) and optionally combusting of hydrocarbons for generating power for providing the pressurized oxygen containing gas for step (i), which method starts with using a hydrocarbonaceous feed fired boiler for providing steam for the generation of power for step (i) for compressing and optionally separating the pressurized oxygen containing gas until step (iv) takes over for providing the power for step (i).
摘要翻译：本发明涉及一种从烃类原料中开始生产常态气态，通常为液态和任选通常为固体烃的方法，该方法包括以下步骤：（i）压缩和任选分离含氧气体; （ii）使用步骤（i）的压缩含氧气体在升高的温度和压力下部分氧化烃原料以获得合成气和蒸汽; （iii）在升高的温度和压力下催化转化步骤（ii）的合成气，以获得常规的和/或气态的烃和蒸汽; 和（iv）使用在步骤（ii）和/或步骤（iii）中获得的蒸汽，并任选地燃烧用于产生用于步骤（i）的加压含氧气体的动力的烃，该方法开始于使用含烃进料燃烧锅炉用于提供用于产生用于步骤（i）的功率的蒸汽，用于压缩和任选地分离加压含氧气体，直到步骤（iv）接管以提供步骤（i）的功率。

6. 发明授权

US07674940B2 Process for the preparation of detergent compounds 有权
标题翻译：洗涤剂化合物的制备方法
公开(公告)号：US07674940B2
公开(公告)日：2010-03-09
申请号：US10546281
申请日：2004-02-19
申请人： Henk Dirkzwager , Robert Martijn Van Hardeveld , Arend Hoek , Peter William Lednor , Joannes Ignatius Geijsel
发明人： Henk Dirkzwager , Robert Martijn Van Hardeveld , Arend Hoek , Peter William Lednor , Joannes Ignatius Geijsel
IPC分类号： C07C2/00 , C07C4/00 , C07C6/00 , C11D17/00
CPC分类号： C10G67/02 , C07C1/0485 , C10G2/00 , C10G65/04 , C10G69/123 , C10G2300/1022 , C10G2300/301
摘要： A process for the preparation of detergents containing a relatively low amount of isoparaffins, involving separating a hydrocarbonaceous product stream from a Fischer-Tropsch process using a cobalt based catalyst and producing normally liquid and normally solid hydrocarbons into a light fraction boiling below an intermediate fraction having detergent hydrocarbons, an intermediate boiling fraction having detergent hydrocarbons and a heavy fraction boiling above the intermediate boiling fraction having detergent hydrocarbons, followed by conversion of the detergent hydrocarbons present in the intermediate boiling fraction into detergents, the Fischer-Tropsch process being carried out at a relatively high pressure.
摘要翻译：一种用于制备含有相对低量的异链烷烃的洗涤剂的方法，包括使用钴基催化剂从费 - 托法中分离烃产物流，并将通常为液态的和通常为固体的烃生产成沸点低于具有洗涤剂烃，具有洗涤剂烃的中间沸点馏分和在具有洗涤剂烃的中间沸点馏分以上沸腾的重馏分，随后将存在于中间沸点馏分中的洗涤剂烃转化为洗涤剂，费 - 托方法在比较高的压力。

7. 发明申请

US20090301131A1 METHOD AND APPARATUS FOR TREATING A HYDROCARBON STREAM 审中-公开
标题翻译：处理油气田的方法和装置
公开(公告)号：US20090301131A1
公开(公告)日：2009-12-10
申请号：US12301182
申请日：2007-05-16
申请人： Hillegonda Bakker , Joannes Ignatius Geijsel , Mark Antonius Kevenaar
发明人： Hillegonda Bakker , Joannes Ignatius Geijsel , Mark Antonius Kevenaar
IPC分类号： F25J1/02 , F25J3/00
CPC分类号： F25J1/0087 , F25J1/0022 , F25J1/0035 , F25J1/0042 , F25J1/0052 , F25J1/0214 , F25J1/0216 , F25J1/0279 , F25J1/0283 , F25J1/0287 , F25J1/029 , F25J1/0292 , F25J2205/02 , F25J2220/62 , F25J2220/64 , F25J2230/20 , F25J2230/30 , F25J2230/60
摘要： A method of treating a hydrocarbon stream such as natural gas from a feed stream (10) comprising at least the steps of: a) passing the feed stream (10) through a distillation column (12) to provide a gaseous stream (20) and a C2+ liquid stream (30); b) compressing at least part of the gaseous stream (20) through one or more feed compressors (14, 16) to provide a compressed stream (40); and c) commonly driving (28) at least one of the feed compressors with one or more separate refrigerant compressors for one or more separate refrigerant circuits, by mechanically interconnecting said compressors.
摘要翻译：一种从进料流（10）处理烃流如天然气的方法，包括至少步骤：a）使进料流（10）通过蒸馏塔（12）以提供气流（20）和 C2 +液体流（30）; b）通过一个或多个进料压缩机（14,16）压缩至少部分气流（20）以提供压缩流（40）; 和c）通过机械地互连所述压缩机，一个或多个单独制冷剂回路中的至少一个进料压缩机与一个或多个单独的制冷剂压缩机共同驱动（28）。

8. 发明授权

US06861450B2 Process for the preparation of a highly linear alcohol composition 失效
标题翻译：制备高度线性醇组合物的方法
公开(公告)号：US06861450B2
公开(公告)日：2005-03-01
申请号：US10621816
申请日：2003-07-17
申请人： Hendrik Dirkzwager , Laurent Alain Fenouil , Joannes Ignatius Geijsel , Arend Hoek , Frederik Hendrik Van Der Steen
发明人： Hendrik Dirkzwager , Laurent Alain Fenouil , Joannes Ignatius Geijsel , Arend Hoek , Frederik Hendrik Van Der Steen
IPC分类号： C07C1/04 , C07B61/00 , C07C29/16 , C07C29/80 , C07C31/125 , C10G2/00 , A61K31/045 , A01N31/00 , A61K31/047
CPC分类号： C10G2/32 , C07C29/16 , C07C31/125 , C10G2/332
摘要： Process for the preparation of a highly linear alcohol composition is provided comprising the steps of: (a) reacting carbon monoxide with hydrogen under Fischer-Tropsch reaction conditions in the presence of a Fischer-Tropsch catalyst comprising cobalt; (b) separating from the product of step (a) at least one hydrocarbon fraction comprising between 10 and 50% by weight of olefins containing 6 or more carbon atoms; (c) contacting one or more of the hydrocarbon fractions obtained in step (b) with carbon monoxide and hydrogen under hydroformylation conditions in the presence of a hydroformylation catalyst based on a source of cobalt and one or more alkyl phosphines; and (d) recovering the alcohol composition.
摘要翻译：提供了制备高度线性的醇组合物的方法，包括以下步骤：（a）在费 - 托反应条件下，在包含钴的费 - 托催化剂的存在下使一氧化碳与氢反应;（b）步骤（a）至少一种含有10至50重量％的含有6个或更多个碳原子的烯烃的烃馏分;（c）使步骤（b）中获得的一种或多种烃馏分与一氧化碳和氢气接触，在基于钴源和一种或多种烷基膦的加氢甲酰化催化剂存在下，加氢甲酰化条件; 和（d）回收醇组合物。

9. 发明申请

US20090095018A1 METHOD FOR LIQUEFYING A HYDROCARBON STREAM 审中-公开
标题翻译：用于液化石油气流的方法
公开(公告)号：US20090095018A1
公开(公告)日：2009-04-16
申请号：US12118165
申请日：2008-05-09
申请人： Hillegonda Bakker , Joannes Ignatius Geijsel , Marco Dick Jager , Mark Antonius Kevenaar
发明人： Hillegonda Bakker , Joannes Ignatius Geijsel , Marco Dick Jager , Mark Antonius Kevenaar
IPC分类号： F25J1/00
CPC分类号： F25J1/0022 , F25J1/004 , F25J1/0042 , F25J1/0264 , F25J2210/06 , F25J2220/62
摘要： A hydrocarbon stream is liquefied in a method wherein a feed stream is provided, from which feed stream a first stream and a second stream are produced. The first stream is liquefied in a main liquefaction system to provide a first liquefied stream, while the second stream is cooled separately to provide a cooled second stream. The first liquefied stream is combined with the cooled second stream to produce a combined stream, which is separated in a gas/liquid separator into a liquefied hydrocarbon product stream and a gaseous stream. The gaseous stream is warmed to a temperature of above −40° C. by heat exchanging against any other stream used in the method, wherein the warming of the gaseous stream employs at least heat exchanging against the second stream to provide at least part of the cooling of the second stream.
摘要翻译：烃流在其中提供进料流的方法中液化，从其中产生进料流第一流和第二流。第一流在主液化系统中液化以提供第一液化流，而第二流被单独冷却以提供冷却的第二流。将第一液化流与冷却的第二物流组合以产生组合流，其在气/液分离器中分离成液化烃产物流和气流。通过与该方法中使用的任何其它流热交换将气流升温至高于-40℃的温度，其中气流的升温至少使用与第二流的热交换以提供至少部分冷却第二流。

10. 发明授权

US07227045B2 Process for the preparation of linear olefins and use thereof to prepare linear alcohols 失效
标题翻译：制备直链烯烃的方法及其用途以制备直链醇
公开(公告)号：US07227045B2
公开(公告)日：2007-06-05
申请号：US10842403
申请日：2004-05-10
申请人： Joachim Ansorge , Hendrik Dirkzwager , Joannes Ignatius Geijsel , Abdul Razak Mohamad Ali , Timothy Michael Nisbet , Laurent Alain Michel Fenouil
发明人： Joachim Ansorge , Hendrik Dirkzwager , Joannes Ignatius Geijsel , Abdul Razak Mohamad Ali , Timothy Michael Nisbet , Laurent Alain Michel Fenouil
IPC分类号： C07C45/00 , C07C27/00 , C07C1/00 , C10G51/02 , C10G47/00
CPC分类号： C07C11/02 , C07C29/16 , C07C45/50 , C10G69/06 , C10G2300/1022 , C10G2400/22 , C07C31/125 , C07C47/02
摘要： Process for the preparation of a mixture comprising C5+ linear olefins, which process comprises the steps of (a) reacting carbon monoxide and hydrogen in the presence of an effective amount of Fischer-Tropsch catalyst under Fischer-Tropsch reaction conditions; (b) separating from the hydrocarbon mixture thus prepared at least one hydrocarbon fraction, of which at least 95% by weight consists of hydrocarbons containing 15 carbon atoms or more; (c) contacting this hydrocarbon fraction with hydrogen in the presence of an effective amount of hydrogenation catalyst under hydrogenation conditions; (d) subjecting the hydrogenated hydrocarbon fraction thus obtained to a mild thermal cracking treatment; and (e) separating from the cracked product thus prepared the mixture comprising C5+ linear olefins.
摘要翻译：制备包含C 5+直链烯烃的混合物的方法，该方法包括以下步骤：（a）在有费量的费 - 托催化剂存在下，在Fischer- 托反应条件; （b）从如此制备的烃混合物中分离出至少一个烃馏分，其中至少95重量％由含有15个或更多个碳原子的烃组成; （c）在氢化条件下，在有效量的氢化催化剂存在下，使该烃馏分与氢气接触; （d）将由此获得的氢化烃馏分进行轻度热裂解处理; 和（e）从如此制备的裂化产物中分离出包含C 5+直链烯烃的混合物。

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