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1. 发明授权

US06806297B2 Process for the production of liquid hydrocarbons 失效
标题翻译：液体烃的生产工艺
公开(公告)号：US06806297B2
公开(公告)日：2004-10-19
申请号：US10276615
申请日：2002-11-18
申请人： Hans Michiel Huisman , Koen Willem De Leeuw
发明人： Hans Michiel Huisman , Koen Willem De Leeuw
IPC分类号： C07C2700
CPC分类号： C10G2/30 , C01B3/386 , C01B2203/0261 , C01B2203/0405 , C01B2203/0415 , C01B2203/045 , C01B2203/0485 , C01B2203/062 , C01B2203/065 , C01B2203/0883 , C01B2203/0894 , C01B2203/1023 , C01B2203/1064 , C01B2203/1082 , C01B2203/1241 , C01B2203/127 , C07C1/0485 , C07C2521/06 , C07C2523/75
摘要： A process for producing normally liquid hydrocarbon products from a hydrocarbonaceous feedstock, especially from normally gaseous hydrocarbon feed, having the following steps: (a) partial oxidation of the normally gaseous hydrocarbon feed at elevated pressure using air or oxygen enriched air as oxidant, to obtain a syngas mixture having hydrogen, carbon monoxide and nitrogen; (b) converting hydrogen and carbon monoxide obtained in step (a) into a normally liquid hydrocarbon product and a normally gaseous hydrocarbon product; (c) separating from the reaction mixture obtained in step (b) an off-gas mixture having nitrogen, normally gaseous hydrocarbon product, and unconverted hydrogen, carbon monoxide and normally gaseous hydrocarbon feed, insofar as such unconverted components are present; (d) combusting at least a part of the off-gas mixture in a steam raising apparatus, producing steam of an elevated pressure; and (e) expanding the steam produced in step (d) for compressing the air or oxygen enriched air and/or the normally gaseous hydrocarbon feed used in step (a); and a plant having equipment in a line-up suitable for carrying out the process.
摘要翻译：一种从含烃原料，特别是通常气态烃进料生产常规烃类产物的方法，具有以下步骤：（a）使用空气或富氧空气作为氧化剂，在升高的压力下将常规气态烃进料部分氧化，以获得具有氢气，一氧化碳和氮气的合成气混合物; （b）将步骤（a）中获得的氢气和一氧化碳转化为通常为液体的烃产物和通常为气态烃产物; （c）与步骤（b）中获得的反应混合物分离出具有氮气，通常为气态烃产物和未转化氢气，一氧化碳和通常为气态烃进料的废气混合物，只要存在这种未转化的组分; （d）在蒸汽提升装置中燃烧至少一部分废气混合物，产生高压蒸汽; 和（e）扩大在步骤（d）中产生的用于压缩步骤（a）中使用的空气或富氧空气和/或常规气态烃进料的蒸汽; 以及具有适合于执行该过程的阵列中的设备的设备。

2. 发明授权

US06942839B2 Process for the production of liquid hydrocarbons 失效
标题翻译：液体烃的生产工艺
公开(公告)号：US06942839B2
公开(公告)日：2005-09-13
申请号：US10931490
申请日：2004-09-01
申请人： Hans Michiel Huisman , Koen Willem De Leeuw
发明人： Hans Michiel Huisman , Koen Willem De Leeuw
IPC分类号： C01B3/38 , C07C1/04 , C10G2/00 , B01J10/00 , B01J8/04
CPC分类号： C10G2/30 , C01B3/386 , C01B2203/0261 , C01B2203/0405 , C01B2203/0415 , C01B2203/045 , C01B2203/0485 , C01B2203/062 , C01B2203/065 , C01B2203/0883 , C01B2203/0894 , C01B2203/1023 , C01B2203/1064 , C01B2203/1082 , C01B2203/1241 , C01B2203/127 , C07C1/0485 , C07C2521/06 , C07C2523/75
摘要： A process for producing normally liquid hydrocarbon products from a hydrocarbonaceous feedstock, especially from normally gaseous hydrocarbon feed, having the following steps: (a) partial oxidation of the normally gaseous hydrocarbon feed at elevated pressure using air or oxygen enriched air as oxidant, to obtain a syngas mixture having hydrogen, carbon monoxide and nitrogen; (b) converting hydrogen and carbon monoxide obtained in step (a) into a normally liquid hydrocarbon product and a normally gaseous hydrocarbon product; (c) separating from the reaction mixture obtained in step (b) an off-gas mixture having nitrogen, normally gaseous hydrocarbon product, and unconverted hydrogen, carbon monoxide and normally gaseous hydrocarbon feed, insofar as such unconverted components are present; (d) combusting at least a part of the off-gas mixture in a steam raising apparatus, producing steam of an elevated pressure; and (e) expanding the steam produced in step (d) for compressing the air or oxygen enriched air and/or the normally gaseous hydrocarbon feed used in step (a); and a plant having equipment in a line-up suitable for carrying out the process.
摘要翻译：一种从含烃原料，特别是通常气态烃进料生产常规烃类产物的方法，具有以下步骤：（a）使用空气或富氧空气作为氧化剂，在升高的压力下将常规气态烃进料部分氧化，以获得具有氢气，一氧化碳和氮气的合成气混合物; （b）将步骤（a）中获得的氢气和一氧化碳转化为通常为液体的烃产物和通常为气态烃产物; （c）与步骤（b）中获得的反应混合物分离出具有氮气，通常为气态烃产物和未转化氢气，一氧化碳和通常为气态烃进料的废气混合物，只要存在这种未转化的组分; （d）在蒸汽提升装置中燃烧至少一部分废气混合物，产生高压蒸汽; 和（e）扩大在步骤（d）中产生的用于压缩步骤（a）中使用的空气或富氧空气和/或常规气态烃进料的蒸汽; 以及具有适合于执行该过程的阵列中的设备的设备。

3. 发明授权

US07563745B2 Shaped catalyst particles for hydrocarbon synthesis 失效
标题翻译：用于烃合成的成型催化剂颗粒
公开(公告)号：US07563745B2
公开(公告)日：2009-07-21
申请号：US10517098
申请日：2003-06-06
申请人： Arend Hoek , Hans Michiel Huisman , Carolus Matthias Anna Maria Mesters
发明人： Arend Hoek , Hans Michiel Huisman , Carolus Matthias Anna Maria Mesters
IPC分类号： B01J23/00 , B01J21/00 , B01J20/00 , B01J29/00 , B01J37/00 , C01B3/38 , C07C1/02 , C01B3/26 , C10G47/00 , C10G47/02 , C10G47/04 , C10G11/00 , C10G35/06
CPC分类号： C10G2/332 , B01J23/75 , B01J23/8892 , B01J35/026 , B01J37/0009 , C10G2/33 , C10G49/00
摘要： The invention relates to a shaped catalyst or catalyst precursor containing a catalytically active component or a precursor therefore, the component selected from elements of Group VIII of the Periodic Table of the Elements, supported on a carrier, which catalyst or catalyst precursor is an elongated shaped particle having three protrusions each extending from and attached to a central position, wherein the central position is aligned along the longitudinal axis of the particle, the cross-section of the particle occupying the space encompassed by the outer edges of six circles around a central circle, each of the six circles touching two neighboring circles while three alternating circles are equidistant to the central circle and may be attached to the central circle, minus the space occupied by the three remaining outer circles and including the six interstitial regions.The invention further relates to a process to prepare the catalyst or catalyst precursor from a shapeable dough, to the die-plate used for the preparation of an extruded catalyst or catalyst precursor, to the use of the catalysts, as well as to hydrocarbons prepared by using the catalyst.The invention further relates to a process to obtain fuels and optionally base oils, by hydrogenation, hydroisomerisation and/or hydrocracking of the hydrocarbons prepared by using the catalyst.
摘要翻译：本发明涉及含有催化活性组分或前体的成型催化剂或催化剂前体，所述催化剂或催化剂前体包含负载在载体上的选自元素周期表第Ⅷ族元素的组分，该催化剂或催化剂前体是细长形状具有从中心位置延伸并连接到中心位置的三个突起的颗粒，其中中心位置沿着颗粒的纵向轴线对准，颗粒的横截面占据由围绕中心圆的六个圆的外边缘包围的空间，六个圆中的每一个接触两个相邻的圆，而三个交替的圆与中心圆相等，并且可以附接到中心圆，减去三个剩余外圆所占据的空间并且包括六个间隙区。本发明还涉及一种从可成型面团制备催化剂或催化剂前体的方法，用于制备挤出的催化剂或催化剂前体的模板，使用催化剂以及由使用催化剂。本发明还涉及通过使用催化剂制备的烃的氢化，加氢异构化和/或加氢裂化来获得燃料和任选的基础油的方法。

4. 发明授权

US6019953A Process for gas incineration 失效
标题翻译：气体焚烧工艺
公开(公告)号：US6019953A
公开(公告)日：2000-02-01
申请号：US899368
申请日：1997-07-23
申请人： Peter John Van Den Brink , Hans Michiel Huisman , Inge Roos , Thoms Stanley Vermeulen
发明人： Peter John Van Den Brink , Hans Michiel Huisman , Inge Roos , Thoms Stanley Vermeulen
IPC分类号： B01J27/19 , B01D53/52 , B01D53/86 , B01J23/18 , B01J23/24 , B01J23/843 , B01D53/48
CPC分类号： B01D53/8612 , B01J23/18 , B01J23/24
摘要： There is provided a process for the incineration of gases containing sulphur compounds by contacting these gases with an oxygen-containing gas in the presence of a catalyst composition comprising (i) a metal selected from bismuth, molybdenum and chromium as a first metal component and (ii) at least one Group IIA metal as a second metal component, supported on a refractory oxide carrier not being a carrier comprising both aluminum and phosphorus.
摘要翻译：提供了一种通过在含有（i）选自铋，钼和铬的金属作为第一金属组分的催化剂组合物存在下使这些气体与含氧气体接触来焚烧含硫化合物的方法， ii）至少一种IIA族金属作为第二金属组分，负载在不是包含铝和磷的载体的难熔氧化物载体上。

5. 发明申请

US20090124711A1 Fischer-tropsch process and reactor assembly 有权
标题翻译：费 - 托法和反应器组装
公开(公告)号：US20090124711A1
公开(公告)日：2009-05-14
申请号：US11988970
申请日：2006-07-14
申请人： Arend Hoek , Hans Michiel Huisman
发明人： Arend Hoek , Hans Michiel Huisman
IPC分类号： C10G2/00 , B01J19/00
CPC分类号： C10G2/32 , B01J8/0278 , B01J8/065 , B01J8/067 , B01J8/22 , B01J2219/00038 , B01J2219/00202 , B01J2219/00211 , B01J2219/00231 , B01J2219/00238 , C10G2/34 , C10G2400/02 , C10G2400/06 , C10G2400/08 , C10G2400/10 , C10G2400/18
摘要： A method of accommodating a reduction in production capacity of one or more reactors in a multi-reactor assembly adapted for the production of hydrocarbon products from syngas, the syngas being provided by a syngas manufacturing facility and provided to an entry stream system providing syngas to each of the reactors, and having an exit stream system taking at least hydrocarbon products from the reactors, wherein the method comprises the steps of: redistributing the syngas from the one or more said reactors to one or more other reactors, and increasing the temperature in the said one or more other reactors to at least partially take over the reduction in production capacity of the one or more reactors.
摘要翻译：一种在适合从合成气生产碳氢化合物产品的多反应器组合中容纳一个或多个反应器的生产能力降低的方法，合成气由合成气制造设施提供并提供给进入流系统，其将合成气提供给每个的反应器，并且具有至少从反应器中取出烃产物的出口流系统，其中所述方法包括以下步骤：将来自所述一个或多个所述反应器的合成气重新分配到一个或多个其它反应器，并且增加所述反应器中的温度所述一个或多个其它反应器至少部分地承担一个或多个反应器的生产能力的降低。

6. 发明授权

US06977237B2 Catalyst and process for the preparation of hydrocarbons 有权
标题翻译：用于制备烃的催化剂和方法
公开(公告)号：US06977237B2
公开(公告)日：2005-12-20
申请号：US10851596
申请日：2004-05-21
申请人： Jacobus Johannes Cornelis Geerlings , Hans Michiel Huisman
发明人： Jacobus Johannes Cornelis Geerlings , Hans Michiel Huisman
IPC分类号： B01J23/889 , B01J23/89 , C07C1/04 , C10G2/00 , B01J23/32 , B01J23/00 , B01J23/40
CPC分类号： C10G2/332 , B01J23/889 , B01J23/8896 , B01J23/8986 , C07C1/0435 , C07C2521/06 , C07C2523/34 , C07C2523/36 , C07C2523/46 , C07C2523/75 , C07C2523/889 , C10G2/333
摘要： The invention provides a process for the production of mainly C5+ hydrocarbons, which process involves contacting carbon monoxide and hydrogen at a temperature in the range of from about 180° C. to about 270° C. and elevated pressure in the presence of a catalyst composition having cobalt, manganese and at least one of rhenium and/or ruthenium on a titania carrier. The invention also relates to a catalyst composition having cobalt, manganese and rhenium on a titania carrier.
摘要翻译：本发明提供了主要生产C 5+烃的方法，该方法包括在约180℃至约270℃的温度范围内接触一氧化碳和氢气，在具有钴，锰和铼和/或钌中的至少一种的催化剂组合物的存在下，在二氧化钛载体上存在高压。本发明还涉及在二氧化钛载体上具有钴，锰和铼的催化剂组合物。

7. 发明授权

US5958985A Process for the preparation of hydrocarbons 失效
标题翻译：烃类制备方法
公开(公告)号：US5958985A
公开(公告)日：1999-09-28
申请号：US989430
申请日：1997-12-12
申请人： Jacobus Johannes Cornelis Geerlings , Arend Hoek , Hans Michiel Huisman , Peter William Lednor
发明人： Jacobus Johannes Cornelis Geerlings , Arend Hoek , Hans Michiel Huisman , Peter William Lednor
IPC分类号： B01J23/889 , C07C1/04 , C10G2/00 , C07C27/00 , B01J23/00 , B01J23/32
CPC分类号： C10G2/332 , B01J23/8892 , C07C1/0435 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/34 , C07C2523/75 , C07C2523/889
摘要： A process for the preparation of hydrocarbons by catalytic reaction of carbon monoxide with hydrogen in which reaction a feed comprising hydrogen and carbon monoxide is contacted at elevated temperature and pressure with a catalyst comprising cobalt and manganese in which catalyst the cobalt/manganese molar ratio is between 14:1 and 7:1 and the GHSV is at least 1600 N1/1/h. Preferably the cobalt/manganese molar ratio is between 13:1 and 9:1 and the GHSV is between 2700 and 25,000 N1/1/h. The reaction is especially carried out in a slurry phase regime.
摘要翻译：通过一氧化碳与氢的催化反应制备烃的方法，其中使包含氢和一氧化碳的进料在高温和高压下与包含钴和锰的催化剂接触，其中催化剂的钴/锰摩尔比介于 14：1和7：1，GHSV至少为1600N1 / 1 / h。优选钴/锰的摩尔比为13:1至9:1，GHSV为2700至25,000N1 / 1 / h。反应特别是在淤浆相状态下进行。

8. 发明授权

US07855234B2 Fischer-tropsch process and reactor assembly 有权
标题翻译：费 - 托法和反应器组装
公开(公告)号：US07855234B2
公开(公告)日：2010-12-21
申请号：US11988970
申请日：2006-07-14
申请人： Arend Hoek , Hans Michiel Huisman
发明人： Arend Hoek , Hans Michiel Huisman
IPC分类号： C07C27/00
CPC分类号： C10G2/32 , B01J8/0278 , B01J8/065 , B01J8/067 , B01J8/22 , B01J2219/00038 , B01J2219/00202 , B01J2219/00211 , B01J2219/00231 , B01J2219/00238 , C10G2/34 , C10G2400/02 , C10G2400/06 , C10G2400/08 , C10G2400/10 , C10G2400/18
摘要： A method of accommodating a reduction in production capacity of one or more reactors in a multi-reactor assembly adapted for the production of hydrocarbon products from syngas, the syngas being provided by a syngas manufacturing facility and provided to an entry stream system providing syngas to each of the reactors, and having an exit stream system taking at least hydrocarbon products from the reactors, wherein the method comprises the steps of: redistributing the syngas from the one or more said reactors to one or more other reactors, and increasing the temperature in the said one or more other reactors to at least partially take over the reduction in production capacity of the one or more reactors.
摘要翻译：一种在适合从合成气生产碳氢化合物产品的多反应器组合中容纳一个或多个反应器的生产能力降低的方法，合成气由合成气制造设施提供并提供给进入流系统，其将合成气提供给每个的反应器，并且具有至少从反应器中取出烃产物的出口流系统，其中所述方法包括以下步骤：将来自所述一个或多个所述反应器的合成气重新分配到一个或多个其它反应器，并且增加所述反应器中的温度所述一个或多个其它反应器至少部分地承担一个或多个反应器的生产能力的降低。

9. 发明授权

US07282467B2 Catalysts support, a supported group VIII metal catalyst and precursor thereof, processes for their preparations, and use of the supported group VIII metal catalyst 失效
标题翻译：催化剂载体，负载的VIII族金属催化剂及其前体，其制备方法和使用负载的VIII族金属催化剂
公开(公告)号：US07282467B2
公开(公告)日：2007-10-16
申请号：US10332094
申请日：2001-07-10
申请人： Hans Michiel Huisman , Gerardus Petrus Lambertus Niesen , Johannes Jacobus Maria Van Vlaanderen
发明人： Hans Michiel Huisman , Gerardus Petrus Lambertus Niesen , Johannes Jacobus Maria Van Vlaanderen
IPC分类号： B01J23/00 , B01J21/00
CPC分类号： C10G2/332 , B01J23/74 , B01J23/8892 , B01J37/0045 , B01J37/0236
摘要： A process for preparing a catalyst support or a supported Group VIII metal catalyst or a precusor of the supported Group VIII metal catalyst, which process comprises (a) exerting mechanical power on a mixture comprising a refractory oxide and a first liquid to obtain a dough, (b) admixing the dough with a second liquid to obtain a slurry, (c) shaping and drying the slurry, and (d) calcining.
摘要翻译：制备催化剂载体或负载的VIII族金属催化剂或负载的VIII族金属催化剂的前体的方法，该方法包括（a）在包含难熔氧化物和第一液体的混合物上施加机械动力以获得面团，（b）将面团与第二液体混合以获得浆料，（c）成型并干燥浆料，和（d）煅烧。

10. 发明授权

US06572787B1 Evacuation of hydrogen and carbon monoxide from a hydrocarbonaceous feedstock 失效
标题翻译：从烃类原料中排出氢和一氧化碳
公开(公告)号：US06572787B1
公开(公告)日：2003-06-03
申请号：US09600066
申请日：2000-07-10
申请人： Hans Michiel Huisman , Patrick Dennis Lawrence Mercera , Coen Willem Johannes Pieterse , David Schaddenhorst , Ronald Jan Schoonebeek
发明人： Hans Michiel Huisman , Patrick Dennis Lawrence Mercera , Coen Willem Johannes Pieterse , David Schaddenhorst , Ronald Jan Schoonebeek
IPC分类号： C07C104
CPC分类号： C01B3/386 , B01J23/46 , B01J23/56 , C01B3/40 , C01B2203/0261 , C01B2203/0495 , C01B2203/061 , C01B2203/062 , C01B2203/066 , C01B2203/1005 , C01B2203/1064 , C01B2203/1082 , C01B2203/1088 , C01B2203/1241 , C01B2203/1247 , C01B2203/1676 , Y02P20/52
摘要： A catalyst comprising a catalytically active metal, selected from Ru, Rh, Os and Ir, associated with at least one inorganic metal cation or precursor thereof, wherein the inorganic metal cation or precursor thereof is present in intimate association supported on or with the catalytically active metal, a process for the preparation of the catalyst, and a process for the preparation of carbon monoxide and/or hydrogen from a hydrocarbonaceous feedstock using the catalyst.
摘要翻译：一种催化剂，其包含与至少一种无机金属阳离子或其前体相关的选自Ru，Rh，Os和Ir的催化活性金属，其中无机金属阳离子或其前体以与催化活性金属，制备催化剂的方法，以及使用该催化剂从烃原料制备一氧化碳和/或氢的方法。

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