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    • 1. 发明授权
    • Light-sensitive material containing silver halide, reducing agent and
polymerizable compound
    • 含有卤化银,还原剂和可聚合化合物的感光材料
    • US4772531A
    • 1988-09-20
    • US23361
    • 1987-03-09
    • Jiro TsukaharaKozo Sato
    • Jiro TsukaharaKozo Sato
    • G03F7/004G03C1/498G03F7/028G03F7/06G03C1/68G03F7/26
    • G03F7/0285Y10S430/114Y10S430/116Y10S430/12
    • A light-sensitive material comprising a light-sensitive layer which contains silver halide, a reducing agent and a polymerizable compound provided on a support, characterized in that the reducing agent is a hydrazine derivative having the following formula (I) or (II): ##STR1## in which R.sup.1 is a monovalent group selected from the group consisting of hydrogen, an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an aryl group and a heterocyclic group, each of which may have one or more substituent groups; each of R.sup.2 and R.sup.3 independently is an aryl group which may have one or more substituent groups, or R.sup.2 and R.sup.3 form, together with the neighboring carbon, a condensed aromatic ring; R.sup.4 is a monovalent group selected from the group consisting of an alkyl group, an aryl group, an alkoxycarbonyl group and carbamoyl, each of which may have one or more substituent groups; (DEV) is a monovalent group having a function of reducing silver halide; and (LINK) is a divalent linkage group.
    • 一种感光材料,其包含含有卤化银的光敏层,还原剂和提供在载体上的可聚合化合物,其特征在于还原剂是具有下式(I)或(II)的肼衍生物: (I)其中R 1是选自氢,烷基,环烷基,烯基,炔基,芳烷基,芳基的一价基团 和杂环基,其各自可以具有一个或多个取代基; R 2和R 3各自独立地为可以具有一个或多个取代基的芳基,或者R 2和R 3与相邻的碳一起形成稠合芳香环; R4是选自烷基,芳基,烷氧基羰基和氨基甲酰基的一价基团,各自可以具有一个或多个取代基; (DEV)是具有还原卤化银功能的一价基团; 和(LINK)是二价连接基团。
    • 2. 发明授权
    • Process for formation of base and light-sensitive material
    • 形成基质和感光材料的方法
    • US4970307A
    • 1990-11-13
    • US84789
    • 1987-08-13
    • Keiji TakedaJiro TsukaharaKozo Sato
    • Keiji TakedaJiro TsukaharaKozo Sato
    • G03C1/61
    • G03C1/615
    • A process for formation of a base from a base precursor, which comprises decomposing the base precursor in the presence of a catalyst. The base precursor has the following formula (I) or (II):(R.sup.1 --C.tbd.C--CO.sub.2 H).sub.x .multidot.B (I)R.sup.2 (--C.tbd.C--CO.sub.2 H).sub.2 .multidot.B.sub.y (II)wherein R.sup.1 is a monovalent group selected from the group consisting of hydrogen, an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, an aralkyl group, an acyl group, an alkoxycarbonyl group, carbamoyl, --CO.sub.2 M (M is an alkali metal) and --CO.sub.2 H.B, each of which may have one or more substituent groups; R.sup.2 is a divalent group selected from the group consisting of an alkylene group, an arylene group and a divalent heterocyclic group, each of which may have one or more substituent groups; B is an organic base; x is 1 when B is a monoacidic base, and x is 2 when B is a diacidic base; and y is 2 when B is a monoacidic base, and y is 1 when B is a diacidic base. The catalyst is selected from the group consisting of silver, a silver compound, copper and a copper compound. A light-sensitive material containing the base precursor and the catalyst is also disclosed.
    • 从碱性前体形成碱的方法,其包括在催化剂存在下分解碱前体。 碱前体具有下式(I)或(II):(R1-C3B2C-CO2H)xxB(I)R2(-C3BcC-CO2H)2xBy(Ⅱ)其中R1是选自 由氢,烷基,环烷基,烯基,炔基,芳基,杂环基,芳烷基,酰基,烷氧基羰基,氨基甲酰基,-CO 2 M(M是碱 金属)和-CO 2 H B,其各自可以具有一个或多个取代基; R2是选自亚烷基,亚芳基和二价杂环基的二价基团,每个可以具有一个或多个取代基; B是有机碱; 当B是一元酸碱时x是1,当B是二酸基时x是2; 并且当B是一元酸碱时y是2,当B是二酸基时y是1。 催化剂选自银,银化合物,铜和铜化合物。 还公开了含有碱前体和催化剂的感光材料。
    • 4. 发明授权
    • Anti-trypanosomiasis agent
    • 抗锥虫病药
    • US07795285B2
    • 2010-09-14
    • US11576426
    • 2005-09-29
    • Masataka IharaKiyosei TakasuKhanitha PudhomHiroshi KitaguchiMasayuki KawakamiKozo Sato
    • Masataka IharaKiyosei TakasuKhanitha PudhomHiroshi KitaguchiMasayuki KawakamiKozo Sato
    • A01N43/78
    • C07D417/14A61K31/428A61K31/4439A61K31/4709Y02A50/414
    • The present invention is to provide an anti-trypanosomiasis agent having a high selective toxicity, and high preventing or treating effect against trypanosomiasis, comprising a compound shown by the following general formula (1) as an active ingredient (wherein R1 and R2 each independently represents a hydrogen atom, halogen atom, hydroxyl group, oxygen atom, C1-5 alkyl group, C1-5 alkoxy group, C5-8 aryl group, C5-8 aryloxy group, C2-6 alkoxycarbonyl group or C2-6 alkylaminocarbonyl group, and may be bound to each other; R3, R4, and R5 each independently represents a C1-5 alkyl group or C5-8 aryl group; R6 and R7 each independently represents a hydrogen atom, halogen atom, hydroxyl group, oxygen atom, C1-8 alkyl group, C1-5 alkoxy group, C5-8 aryl group, C5-8 aryloxy group, or C2-6 alkoxycarbonyl group, and may be bound to each other; Y and Z each independently represents an atom group necessary to form a 5- or 6-membered heterocycle; m and n each represent 0 or 1; Q represents a physiologically acceptable anion; k represents an integer of 0 to 2, necessary to make the electric charge of the whole molecule 0).
    • 本发明提供具有高选择性毒性和对锥虫病的高预防或治疗作用的抗锥虫病药,其包含由以下通式(1)表示的化合物作为活性成分(其中R 1和R 2各自独立地表示 氢原子,卤素原子,羟基,氧原子,C 1-5烷基,C 1-5烷氧基,C 5-8芳基,C 5-8芳氧基,C 2-6烷氧基羰基或C 2-6烷基氨基羰基, 可以相互结合; R3,R4和R5各自独立地表示C1-5烷基或C5-8芳基; R6和R7各自独立地表示氢原子,卤素原子,羟基,氧原子,C1- 8个烷基,C 1-5烷氧基,C 5-8芳基,C 5-8芳氧基或C 2-6烷氧基羰基,并且可以彼此结合; Y和Z各自独立地表示形成 5-或6-元杂环; m和n各自表示0或1; Q表示物理 生理上可接受的阴离子 k表示0〜2的整数,使整个分子的电荷为0)。
    • 9. 发明授权
    • Dye forming couplers and silver halide color photosensitive material
containing the same
    • 染料形成成色剂和含有卤化银色光敏材料
    • US5401624A
    • 1995-03-28
    • US145630
    • 1993-11-04
    • Kozo SatoYoshio IshiiKatsuyoshi Yamakawa
    • Kozo SatoYoshio IshiiKatsuyoshi Yamakawa
    • C07D487/04G03C7/38
    • C07D487/04G03C7/3825G03C7/383
    • A silver halide color photosensitive material which forms a cyan dye that has superior heat resistance and that will not readily fade in a reducing atmosphere. The silver halide color photosensitive material contains in at least one layer on a support at least one coupler represented by formula (I): ##STR1## wherein R.sup.1 represents hydrogen atom or a substituent; R.sup.2 represents a substituent; X represents hydrogen atom or a group releasable on a coupling reaction with an oxidation product of a color developing agent; Z.sup.1 represents a nonmetallic atom group necessary for forming a nitrogen-containing, six-membered, heterocyclic ring which has at least one dissociative group: Z.sup.1 cannot be --C(.dbd.O)--N(R)--C(.dbd.O)--NH--; and R represents a substituent.Also disclosed is a novel dye forming coupler which exhibits a high coupling activity and which gives a dye having a large molar extinction coefficient and superior stability, the coupler being represented by the following formula (XX) or (XXI). Also disclosed is a silver halide color photosensitive material which contains at least one of the dye forming couplers of formulae (XX) and (XXI) and which provides sharp dye images with high fastness properties. ##STR2## wherein EWG represents an electron withdrawing group having a Hammett's .sigma..sub.p value of not less than 0.3; R.sub.1 and R.sub.2 each represent a substituent; and X represents hydrogen atom or a group releasable on a coupling reaction with an oxidation product of an aromatic primary amine developing agent.
    • 一种卤化银色感光材料,其形成具有优异耐热性且不易在还原气氛中褪色的青色染料。 卤化银色感光材料在载体上至少一层中含有至少一个由式(I)表示的成色剂:汤姆或取代基; R2表示取代基; X表示氢原子或可与显色剂的氧化产物偶联反应脱离的基团; Z1表示形成具有至少一个解离基团的含氮六元杂环所必需的非金属原子团:Z1不能为-C(= O)-N(R)-C(= O)-NH - ; R表示取代基。 还公开了一种新型的染料形成成色剂,其显示出高的偶联活性,并且得到具有大的摩尔吸光系数和优异的稳定性的染料,所述成色剂由下式(XX)或(XXI)表示。 还公开了含有式(XX)和(XXI)的染料形成成色剂中的至少一种的卤化银色感光材料,并提供具有高坚牢度性质的清晰的染料图像。 (XXI)(XXI)其中EWG表示哈米特σp值不小于0.3的吸电子基团; R1和R2各自表示取代基; X表示氢原子或可与芳族伯胺显影剂的氧化产物偶联反应脱离的基团。