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1. 发明申请

US20060293544A1 Partially decomposed catalyst and hydrocarbon oxidation processes using the same 有权
标题翻译：部分分解的催化剂和烃氧化方法使用它们
公开(公告)号：US20060293544A1
公开(公告)日：2006-12-28
申请号：US11434717
申请日：2006-05-16
申请人： Jihad Dakka , Sabato Miseo , Stuart Soled , Jose Santiesteban , Joseph Baumgartner , Michiel Van Vliet , Roger Sheldon
发明人： Jihad Dakka , Sabato Miseo , Stuart Soled , Jose Santiesteban , Joseph Baumgartner , Michiel Van Vliet , Roger Sheldon
IPC分类号： C07C27/00
CPC分类号： B01J31/2243 , B01J23/76 , B01J2231/70 , B01J2531/16 , B01J2531/847 , C07C68/00 , C07C69/96
摘要： The present invention is related to a hydrocarbon oxidation process. The process comprises bringing one or more hydrocarbons into contact with a source of oxygen in the presence of a radical initiator and a catalyst. The catalyst comprises an organic metal complex located on a catalyst support, and is obtained by partial decomposition of the organic metal complex. For example, the process can be used to produce dimethyl carbonate from dimethoxy methane. The invention is also related to a partially decomposed catalyst that comprises a silica support and an organic metal complex, wherein at least 5% of the organic compound remains in the catalyst. The organic metal complex comprises an organic compound and a metal-based compound wherein the metal is selected from copper, nickel, and combinations thereof. The invention is also related to a process for manufacturing of a catalyst comprising mixing L-arginine, a Cu-based compound, water, and optionally another metal-based compound to form a solution; impregnating the solution onto a silica support to form a catalyst precursor; and partially decomposing the L-arginine to form the catalyst so that at least 5% of L-arginine remains in the catalyst.
摘要翻译：本发明涉及烃氧化方法。该方法包括在自由基引发剂和催化剂的存在下使一种或多种烃与氧源接触。催化剂包含位于催化剂载体上的有机金属络合物，并通过有机金属络合物的部分分解获得。例如，该方法可用于从二甲氧基甲烷生产碳酸二甲酯。本发明还涉及包含二氧化硅载体和有机金属络合物的部分分解的催化剂，其中至少5％的有机化合物保留在催化剂中。有机金属络合物包括有机化合物和金属基化合物，其中金属选自铜，镍及其组合。本发明还涉及制造催化剂的方法，其包括将L-精氨酸，Cu基化合物，水和任选的其它金属类化合物混合以形成溶液; 将溶液浸渍到二氧化硅载体上以形成催化剂前体; 并部分分解L-精氨酸以形成催化剂，使得至少5％的L-精氨酸保留在催化剂中。

2. 发明申请

US20060270881A1 Multi-component molecular sieve catalyst compositions and their use in aromatics reactions 有权
公开(公告)号：US20060270881A1
公开(公告)日：2006-11-30
申请号：US11392804
申请日：2006-03-29
申请人： Jihad Dakka , James Vartuli , John Buchanan , Jose Santiesteban , Doron Levin , Lorenzo DeCaul
发明人： Jihad Dakka , James Vartuli , John Buchanan , Jose Santiesteban , Doron Levin , Lorenzo DeCaul
IPC分类号： C07C2/68
CPC分类号： B01J37/0009 , B01J21/06 , B01J21/066 , B01J23/10 , B01J29/06 , B01J29/40 , B01J29/82 , B01J35/0006 , B01J35/002 , B01J37/03 , B01J2229/20 , B01J2229/32 , B01J2229/36 , B01J2229/42 , C07C2/864 , C07C2521/06 , C07C2523/10 , Y02P20/52 , C07C15/08
摘要： The invention relates to a process for producing alkylated aromatic hydrocarbons, preferably with an oxygen or sulfur containing alkylating agent, in the presence of a multi-component molecular sieve catalyst composition that includes a molecular sieve and an active metal oxide. The invention is also directed to methods of making and formulating the multi-component molecular sieve catalyst composition useful in producing alkylated aromatics.

3. 发明申请

US20070004944A1 Process and catalyst for oxidation of hydrocarbons 有权
标题翻译：碳氢化合物的氧化工艺和催化剂
公开(公告)号：US20070004944A1
公开(公告)日：2007-01-04
申请号：US11173594
申请日：2005-07-01
申请人： Bi-Zeng Zhan , Bjorn Moden , Jihad Dakka , Jose Santiesteban , Sebastian Reyes , Enrique Iglesia
发明人： Bi-Zeng Zhan , Bjorn Moden , Jihad Dakka , Jose Santiesteban , Sebastian Reyes , Enrique Iglesia
IPC分类号： C07C27/00
CPC分类号： C07C29/50 , B01J29/064 , B01J29/076 , B01J29/48 , B01J29/7253 , B01J29/7292 , B01J29/7853 , B01J29/7892 , B01J2229/186 , C07C45/33 , C07C45/36 , C07C51/215 , C07C51/265 , Y02P20/582 , C07C49/04 , C07C53/00 , C07C63/06 , C07C31/125
摘要： A process for the oxidation of hydrocarbons comprises contacting the hydrocarbon with an oxygen-containing gas in the presence of a catalyst comprising a microporous solid support, preferably a zeolite, having from 8- to 12-ring open windows and comprising non-framework metal cations selected from manganese, iron, cobalt, vanadium, chromium, copper, nickel, and ruthenium, and mixtures thereof, providing that the oxygen-containing gas does not contain significant amounts of added hydrogen. The catalyst is novel and forms part of the invention. The process may be used for oxidation of alkanes, cycloalkanes, benzene and alkylbenzenes, and is suitable for use in regioselective terminal oxidation of straight chain alkanes and for selective oxidation/separation of p-dialkylbenzenes from an alkylbenzene mixture, for example, p-xylene from an isomeric mixture of xylenes.
摘要翻译：烃的氧化方法包括使烃与含氧气体在催化剂存在下接触，所述催化剂包含微孔固体载体，优选沸石，具有8-至12-环开放的窗口并且包含非骨架金属阳离子选自锰，铁，钴，钒，铬，铜，镍和钌，以及它们的混合物，条件是含氧气体不含显着量的加氢。该催化剂是新颖的并且构成本发明的一部分。该方法可用于烷烃，环烷烃，苯和烷基苯的氧化，并且适用于直链烷烃的区域选择性末端氧化和用于从烷基苯混合物中选择性氧化/分离对二烷基苯，例如对二甲苯来自异构体的二甲苯混合物。

4. 发明授权

US07868201B2 Process and catalyst for oxidation of hydrocarbons 有权
标题翻译：碳氢化合物的氧化工艺和催化剂
公开(公告)号：US07868201B2
公开(公告)日：2011-01-11
申请号：US11173594
申请日：2005-07-01
申请人： Bi-Zeng Zhan , Bjorn Moden , Jihad Dakka , Jose Santiesteban , Sebastian C. Reyes , Enrique Iglesia
发明人： Bi-Zeng Zhan , Bjorn Moden , Jihad Dakka , Jose Santiesteban , Sebastian C. Reyes , Enrique Iglesia
IPC分类号： C07C51/00 , C07C45/00 , C07C27/10 , B01J29/06 , B01J29/068 , B01J29/072
CPC分类号： C07C29/50 , B01J29/064 , B01J29/076 , B01J29/48 , B01J29/7253 , B01J29/7292 , B01J29/7853 , B01J29/7892 , B01J2229/186 , C07C45/33 , C07C45/36 , C07C51/215 , C07C51/265 , Y02P20/582 , C07C49/04 , C07C53/00 , C07C63/06 , C07C31/125
摘要： A process for the oxidation of hydrocarbons comprises contacting the hydrocarbon with an oxygen-containing gas in the presence of a catalyst comprising a microporous solid support, preferably a zeolite, having from 8- to 12-ring open windows and comprising non-framework metal cations selected from manganese, iron, cobalt, vanadium, chromium, copper, nickel, and ruthenium, and mixtures thereof, providing that the oxygen-containing gas does not contain significant amounts of added hydrogen. The catalyst is novel and forms part of the invention.The process may be used for oxidation of alkanes, cycloalkanes, benzene and alkylbenzenes, and is suitable for use in regioselective terminal oxidation of straight chain alkanes and for selective oxidation/separation of p-dialkylbenzenes from an alkylbenzene mixture, for example, p-xylene from an isomeric mixture of xylenes.
摘要翻译：烃的氧化方法包括使烃与含氧气体在催化剂存在下接触，所述催化剂包含微孔固体载体，优选沸石，具有8-至12-环开放的窗口并且包含非骨架金属阳离子选自锰，铁，钴，钒，铬，铜，镍和钌，以及它们的混合物，条件是含氧气体不含显着量的加氢。该催化剂是新颖的并且构成本发明的一部分。该方法可用于烷烃，环烷烃，苯和烷基苯的氧化，并且适用于直链烷烃的区域选择性末端氧化和用于从烷基苯混合物中选择性氧化/分离对二烷基苯，例如对二甲苯来自异构体的二甲苯混合物。

5. 发明申请

US20080086018A1 Process For Producing Phenol And Methyl Ethyl Ketone 失效
标题翻译：生产苯酚和甲基乙基酮的方法
公开(公告)号：US20080086018A1
公开(公告)日：2008-04-10
申请号：US11660065
申请日：2005-08-05
申请人： Jane Cheng , John Buchanan , Doron Levin , Michael Steckel , Jihad Dakka , James Stokes , John Robbins , Jon Stanat , Charles Smith , Jose Santiesteban
发明人： Jane Cheng , John Buchanan , Doron Levin , Michael Steckel , Jihad Dakka , James Stokes , John Robbins , Jon Stanat , Charles Smith , Jose Santiesteban
IPC分类号： C07C45/00
CPC分类号： C07C37/08 , C07C45/53 , C07C409/08 , C07C2529/70 , Y02P20/127 , Y02P20/52 , C07C49/10 , C07C39/04
摘要： A process for producing phenol and methyl ethyl ketone comprises contacting benzene with a C4 alkylating agent under alkylation conditions with catalyst comprising zeolite beta or a molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom to produce an alkylation effluent comprising sec-butylbenzene. The sec-butylbenzene is then oxidized to produce a hydroperoxide and the hydroperoxide is decomposed to produce phenol and methyl ethyl ketone.
摘要翻译：一种生产苯酚和甲基乙基酮的方法包括在烷基化条件下使苯与C 4烷基化试剂在含沸石β的催化剂或具有包括d间距最大值的X射线衍射图谱的分子筛上接触 12.4±0.25,6.9±0.15,3.57±0.07和3.42±0.07埃，以产生包含仲丁基苯的烷基化流出物。然后将仲丁基苯氧化生成氢过氧化物，氢过氧化物分解生成苯酚和甲基乙基酮。

6. 发明申请

US20050143613A1 Process for aromatic alkylation 有权
标题翻译：芳烃烷基化方法
公开(公告)号：US20050143613A1
公开(公告)日：2005-06-30
申请号：US10987324
申请日：2004-11-12
申请人： Jihad Dakka , John Buchanan , Robert Crane , Christine Elia , Xiaobing Feng , Larry Iaccino , Gary Mohr , Brenda Raich , Jose Santiesteban , Lei Zhang
发明人： Jihad Dakka , John Buchanan , Robert Crane , Christine Elia , Xiaobing Feng , Larry Iaccino , Gary Mohr , Brenda Raich , Jose Santiesteban , Lei Zhang
IPC分类号： B01J29/40 , B01J29/44 , B01J31/02 , C07C2/86 , C07C15/08 , C07C2/68
CPC分类号： C07C2/864 , B01J29/40 , B01J29/44 , B01J2229/12 , B01J2229/32 , B01J2229/42 , C07C2521/10 , C07C2523/42 , C07C2523/46 , C07C2527/14 , C07C2529/40 , Y02P20/52 , Y10S585/906 , C07C15/08 , C07C15/00
摘要： This invention relates to a process for the selective alkylation of toluene and/or benzene with an oxygen-containing alkylation agent. In particular, the process uses a selectivated molecular sieve which has been modified by the addition of a hydrogenation component, wherein at least one of the following conditions is met: (a) the selectivated molecular sieve has an alpha value of less than 100 prior to the addition of the hydrogenation component, or (b) the selectivated and hydrogenated catalyst has an alpha value of less than 100. The process of this invention provides high selectivity for the alkylated product while reducing catalyst degradation.
摘要翻译：本发明涉及用含氧烷基化剂选择性烷基化甲苯和/或苯的方法。特别地，该方法使用已经通过加入氢化组分进行了改性的选择性分子筛，其中符合以下条件中的至少一个：（a）选择性分子筛之前的α值小于100，氢化组分的添加，或（b）选择和氢化的催化剂具有小于100的α值。本发明的方法在减少催化剂降解的同时，对烷基化产物提供高选择性。

7. 发明申请

US20120022197A2 PROCESS FOR MAKING MIXED TRIGLYCERIDE PLASTICIZER FROM BENZOIC AND TOLUIC ACID 审中-公开
标题翻译：从苯甲酸和柠檬酸制备混合的TRIGLYCERIDE PLASTICZER的方法
公开(公告)号：US20120022197A2
公开(公告)日：2012-01-26
申请号：US12878166
申请日：2010-09-09
申请人： Jihad Dakka , Edmund Mozeleski , Lisa Baugh , Allen Godwin , Manika Varma-Nair
发明人： Jihad Dakka , Edmund Mozeleski , Lisa Baugh , Allen Godwin , Manika Varma-Nair
IPC分类号： C08K5/101 , C09K3/00 , C07C69/76 , C08K5/12 , C08K5/11
CPC分类号： C11C3/02 , C07C67/08 , C08K5/0016 , C07C69/78
摘要： Provided are compositions, processes for making, and processes for using mixed triglycerides as plasticizers. Triglyceride plasticizers can be produced by recovery of linear or branched C4 to C13 aldehydes from a hydroformylation product, oxidation to linear or branched C4 to C13 acids with oxygen and/or air, recovery of the resulting acids, combining the linear or branched C4 to C13 acid with benzoic acid, toluic acid or a combination thereof to form a mixed acid blend, and esterification of the mixed acid blend with glycerol, wherein the total carbon number of the triester groups ranges from 20 to 25 and includes from 1 to 2 aryl groups for greater than or equal to 45 wt % of the plasticizer. Such plasticizers can be phthalate-free and provide outstanding properties including a suitable melting or pour point, glass transition temperature, low volatility, increased compatibility, increased hydrolytic stability, and excellent low temperature properties in a range of polymeric resins.
摘要翻译：提供组合物，制备方法和使用混合甘油三酸酯作为增塑剂的方法。甘油三酯增塑剂可以通过从加氢甲酰化产物中回收线性或分支的C4至C13醛，通过用氧和/或空气氧化成直链或支链C 4至C 13酸，回收所得酸，将直链或支链C4与C13 酸与苯甲酸，甲苯甲酸或其组合形成混合酸混合物，并将混合酸共混物与甘油酯化，其中三酯基团的总碳数为20-25，包括1至2个芳基大于或等于45重量％的增塑剂。这种增塑剂可以是无邻苯二甲酸酯，并且提供突出的性能，包括合适的熔点或倾点，玻璃化转变温度，低挥发性，增加的相容性，增加的水解稳定性和在一系列聚合物树脂中的优异的低温性能。

8. 发明申请

US20070093683A1 Manufacture of xylenes using reformate 有权
公开(公告)号：US20070093683A1
公开(公告)日：2007-04-26
申请号：US11637574
申请日：2006-12-12
申请人： Larry Iaccino , Jeevan Abichandani , John Buchanan , Robert Crane , Jihad Dakka , Xiaobing Feng , Shifang Luo , Gary Mohr
发明人： Larry Iaccino , Jeevan Abichandani , John Buchanan , Robert Crane , Jihad Dakka , Xiaobing Feng , Shifang Luo , Gary Mohr
IPC分类号： C07C2/68
CPC分类号： C10G63/02 , C07C2/66 , C07C2/86 , C07C15/08 , C07C2521/02 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/18 , C07C2523/02 , C07C2523/10 , C07C2523/18 , C07C2523/34 , C07C2523/40 , C07C2523/42 , C07C2523/74 , C07C2527/14 , C07C2529/40 , C07C2529/60 , C07C2529/65 , C07C2529/70 , C07C2529/85 , C10G9/00 , C10G11/00 , C10G35/09 , C10G35/095 , C10G2300/1044 , C10G2300/4018 , C10G2400/30 , Y02P20/52
摘要： A process is provided for the production of xylenes from reformate. The process is carried out by methylating under conditions effective for the methylation, the benzene/toluene present in the reformate outside the reforming loop, to produce a resulting product having a higher xylenes content than the reformate. Greater than equilibrium amounts of para-xylene can be produced by the process.

9. 发明申请

US20050014630A1 Process for the oligomerization of olefins 有权
标题翻译：烯烃低聚方法
公开(公告)号：US20050014630A1
公开(公告)日：2005-01-20
申请号：US10492705
申请日：2002-10-23
申请人： Jihad Dakka , Hans Goris , Georges Mathys , Roger Eijkhoudt , Marc Puttemans , Stephen Brown
发明人： Jihad Dakka , Hans Goris , Georges Mathys , Roger Eijkhoudt , Marc Puttemans , Stephen Brown
IPC分类号： B01J29/70 , C01B39/46 , C07B61/00 , C07C2/12 , C07C11/02 , C07C29/141 , C07C31/125 , B01J29/04
CPC分类号： B01J29/7042 , B01J29/7026 , B01J29/80 , B01J37/20 , B01J2229/186 , B01J2229/34 , C07C2/12 , C07C2529/70
摘要： Sulphur-containing olefinic feedstocks are oligomerized over zeolite catalysts.
摘要翻译：含硫烯烃原料在沸石催化剂上低聚。

10. 发明授权

US4853479A Process for the manufacture of aromatic dicarboxylic acids and derivatives thereof 失效
标题翻译：用于制备芳族二羧酸及其衍生物的方法
公开(公告)号：US4853479A
公开(公告)日：1989-08-01
申请号：US266820
申请日：1988-11-03
申请人： Jihad Dakka , Amikam Zoran , Yoel Sasson
发明人： Jihad Dakka , Amikam Zoran , Yoel Sasson
IPC分类号： B01J31/26 , C07B61/00 , C07C51/265 , C07C63/24 , C07C63/26 , C07C67/00 , C07C67/39 , C07C69/80 , C07C69/82
CPC分类号： C07C51/265 , C07C67/39
摘要： An improved process for the manufacture of aromatic dicarboxylic acids and derivatives thereof is described. The process is based on the reaction of a corresponding aromatic hydrocarbon in a liquid phase oxidation with an oxygen-containing gas in the presence of a phase-transfer catalyst (a) a transition metal salt (b) and traces of a polar solvent, such as water, the molar ratio between (a) and (b) being in the range of between 0.25:1 to 1.5:1. The phase-transfer catalyst is selected from the quaternary ammonium and phosphonium salts having a total carbon atoms in the range of 17 to 58, the anion bound thereto being selected from Br.sup.-, F.sup.-, Cl.sup.-, OH.sup.-, CH.sub.3 COO.sup.- and HSO.sub.4. Among the aromatic dicarboxylic acids and derivatives thereof the following are mentioned: terephthalic acid; isophthalic acid and methyl terephthalate. The process is characterized by the very high conversion of the respective aromatic hydrocarbon reaching even 100%.

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