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1. 发明授权

US4684710A Half-amide reaction products of dioxalates and amino group containing materials 失效
标题翻译：二酰胺和含氨基的材料的半酰胺反应产物
公开(公告)号：US4684710A
公开(公告)日：1987-08-04
申请号：US892640
申请日：1986-08-04
申请人： Karl F. Schimmel , Thomas A. Ward , Jerome A. Seiner
发明人： Karl F. Schimmel , Thomas A. Ward , Jerome A. Seiner
IPC分类号： C09D5/18
CPC分类号： C09D5/18
摘要： An ungelled composition is prepared as the half-amide reaction product of a diester of oxalic acid and a material containing one or more primary and/or secondary amino groups and one or more different functional groups. The ungelled composition is useful as a crosslinking agent for amine group containing materials and as an intermediate in the preparation of resinous compositions for fire protective coatings.
摘要翻译：制备无凝胶组合物作为草酸二酯和含有一个或多个伯和/或仲氨基和一个或多个不同官能团的材料的半酰胺反应产物。无凝胶组合物可用作用于含胺基材料的交联剂和用作制备用于防火涂料的树脂组合物的中间体。

2. 发明授权

US4285849A Amidation reaction products of polyamines and polycarboxyl containing materials and coating compositions containing same 失效
标题翻译：多胺和含多羧基的材料的酰胺化反应产物和含有它们的涂料组合物
公开(公告)号：US4285849A
公开(公告)日：1981-08-25
申请号：US97619
申请日：1979-11-27
申请人： Rostyslaw Dowbenko , Karl F. Schimmel , Jerome A. Seiner
发明人： Rostyslaw Dowbenko , Karl F. Schimmel , Jerome A. Seiner
IPC分类号： C08G69/00 , C08F8/00 , C08F8/32 , C08G59/00 , C08G69/40 , C08G69/44 , C08G69/46 , C08G69/48 , C08G81/00 , C08G81/02 , C08L33/00 , C08L33/02 , C08L61/00 , C08L61/04 , C08L61/06 , C08L61/10 , C08L61/20 , C08L63/00 , C09D133/04 , C09D163/00 , C09D177/00 , C09D187/00
CPC分类号： C08G69/40 , C08G81/025 , C09D177/00 , Y10S525/939
摘要： Ungelled amidation reaction products of a polycarboxyl-containing material and a polyamine having at least one ether group are produced. The ungelled products can be mixed with a crosslinking resin to provide a coating composition having good durability and stain-resistance.
摘要翻译：制备含聚羧基的材料和具有至少一个醚基团的多胺的未凝胶化的酰胺化反应产物。未凝胶化产品可以与交联树脂混合，以提供具有良好的耐久性和耐污性的涂料组合物。

3. 发明授权

US4725457A Resinous compositions and their formulation into intumescent fire protective compositions 失效
标题翻译：树脂组合物及其制剂成膨胀性防火组合物
公开(公告)号：US4725457A
公开(公告)日：1988-02-16
申请号：US894168
申请日：1986-08-07
申请人： Thomas A. Ward , Karl F. Schimmel , Lois C. Trautvetter , Robert W. Heber , John P. Mikus , Jerome A. Seiner
发明人： Thomas A. Ward , Karl F. Schimmel , Lois C. Trautvetter , Robert W. Heber , John P. Mikus , Jerome A. Seiner
IPC分类号： C08G12/40 , C08G18/38 , C08G59/58 , C09D5/18 , C08G18/40
CPC分类号： C08G12/40 , C08G18/3825 , C08G59/58 , C09D5/185 , Y10T428/31551
摘要： A resinous composition is composed of the ungelled reaction product of(i) a diester of oxalic acid;(ii) a material containing one or more primary and/or secondary amino groups and one or more additional functional groups; and(iii) a material capable of coreacting with (i) or (ii).The resinous composition is useful in formulating intumescent fire protective compositions for fire protection of substrates.
摘要翻译：树脂组合物由（i）草酸二酯的未凝胶化反应产物组成; （ii）含有一个或多个伯和/或仲氨基和一个或多个另外的官能团的材料; 和（iii）能够与（i）或（ii）结合的材料。树脂组合物可用于配制用于底物防火的膨胀型防火组合物。

4. 发明授权

US4225480A Addition interpolymers having improved stability and two-package compositions comprising such interpolymers and polyepoxides 失效
标题翻译：具有改进的稳定性的加成互聚物和包含这种互聚物和聚环氧化物的双组分组合物
公开(公告)号：US4225480A
公开(公告)日：1980-09-30
申请号：US929882
申请日：1978-07-31
申请人： Karl F. Schimmel , Roger M. Christenson , Jerome A. Seiner , James A. Claar
发明人： Karl F. Schimmel , Roger M. Christenson , Jerome A. Seiner , James A. Claar
IPC分类号： C08L33/02 , C08L63/00 , C09D133/02 , C09D157/04 , C08F8/30 , C08F8/32 , C08F8/44 , C08L31/02
CPC分类号： C09D133/02 , C08L33/02 , C08L63/00 , C09D157/04
摘要： Amine group-containing addition interpolymers having improved stability under conditions of storage and use are prepared by interpolymerizing at least one polymerizable ethylenically unsaturated carboxylic acid monomer and at least one polymerizable ethylenically unsaturated aminolysis-resistant organic monomer to form an addition interpolymer containing carboxyl groups pendent to the polymer chain and aminolysis-resistant organic groups pendent to the polymer chain, following which a portion of the pendent carboxyl groups of the addition interpolymer are reacted with an alkylenimine to form pendent amine groups and a portion of the pendent carboxyl groups of the addition interpolymer are neutralized with a basic compound to form pendent anionic salt groups. The addition interpolymer is preferably reducible with organic solvents, water or a mixture thereof, and can be utilized as pigment grinding vehicles or they can be formulated with conventional additives to form useful coating compositions. A preferred use for these interpolymers is in combination with a polyepoxide to provide two-package cocurable polymeric compositions for coatings and other uses.
摘要翻译：通过将至少一种可聚合的烯键式不饱和羧酸单体和至少一种可聚合的烯属不饱和的抗氨基有机单体共聚以形成含有羧基的加成互聚物来制备在储存和使用条件下具有改进的稳定性的含胺基的加成互聚物，聚合物链和耐氨基的有机基团聚合到聚合物链上，随后将一部分加成互聚物的侧基羧基与亚烷基亚胺反应以形成侧挂胺基团和一部分加成互聚物的侧挂羧基用碱性化合物中和以形成悬垂的阴离子盐基团。添加互聚物优选可以用有机溶剂，水或其混合物还原，并且可以用作颜料研磨载体，或者可以用常规添加剂配制以形成有用的涂料组合物。这些互聚物的优选用途是与聚环氧化物组合，以提供用于涂料和其它用途的双包封可共聚的聚合物组合物。

5. 发明授权

US4221885A Addition interpolymers having improved stability and two-package compositions comprising such interpolymers and polyepoxides 失效
标题翻译：具有改进的稳定性的加成互聚物和包含这种互聚物和聚环氧化物的双组分组合物
公开(公告)号：US4221885A
公开(公告)日：1980-09-09
申请号：US939950
申请日：1978-09-06
申请人： Karl F. Schimmel , Roger M. Christenson , Jerome A. Seiner , James A. Claar
发明人： Karl F. Schimmel , Roger M. Christenson , Jerome A. Seiner , James A. Claar
IPC分类号： C08F8/32 , C08F8/44 , C08F8/30
CPC分类号： C08F8/32 , C08F8/44
摘要： Amine group-containing addition interpolymers having improved stability under conditions of storage and use are prepared by interpolymerizing at least one polymerizable ethylenically unsaturated carboxylic acid monomer and at least one polymerizable ethylenically unsaturated aminolysis-resistant organic monomer to form an addition interpolymer containing carboxyl groups pendent to the polymer chain and aminolysis-resistant organic groups pendent to the polymer chain, following which a portion of the pendent carboxyl groups of the addition interpolymer are reacted with an alkylenimine to form pendent amine groups and a portion of the pendent carboxyl groups of the addition interpolymer are neutralized with a basic compound to form pendent anionic salt groups.
摘要翻译：通过将至少一种可聚合的烯键式不饱和羧酸单体和至少一种可聚合的烯属不饱和的抗氨基有机单体共聚以形成含有羧基的加成互聚物来制备在储存和使用条件下具有改进的稳定性的含胺基的加成互聚物，聚合物链和耐氨基的有机基团聚合到聚合物链上，随后将一部分加成互聚物的侧基羧基与亚烷基亚胺反应以形成侧挂胺基团和一部分加成互聚物的侧挂羧基用碱性化合物中和以形成悬垂的阴离子盐基团。

6. 发明授权

US4327008A Urethane rheology modifiers and coating compositions containing same 失效
标题翻译：聚氨酯流变改性剂和含有它们的涂料组合物
公开(公告)号：US4327008A
公开(公告)日：1982-04-27
申请号：US221146
申请日：1980-12-29
申请人： Karl F. Schimmel , Jerome A. Seiner , Roger M. Christenson , Rostyslaw Dowbenko
发明人： Karl F. Schimmel , Jerome A. Seiner , Roger M. Christenson , Rostyslaw Dowbenko
IPC分类号： C08G18/28 , C08G18/30 , C08G18/66 , C08G18/71 , C08G18/72 , C09D7/00 , C08G18/12 , C08G18/48
CPC分类号： C08G18/6666 , C08G18/2805 , C08G18/302 , C08G18/6677 , C08G18/71 , C08G18/721 , C09D7/002 , C08L75/04
摘要： Rheology modifiers useful in water-based and organic solvent-based compositions are derived from the reaction of polyalkylene oxide, polyfunctional material, diisocyanate, water and a monofunctional active hydrogen-containing compound or monoisocyanate. The modifiers are characterized by having a branched structure, urea linkages and terminal hydrophobic groups.
摘要翻译：可用于水基和有机溶剂基组合物的流变改性剂衍生自聚环氧烷，多官能材料，二异氰酸酯，水和单官能活性氢化合物或单异氰酸酯的反应。改性剂的特征在于具有支链结构，脲键和末端疏水基团。

7. 发明授权

US4298511A Urethane rheology modifiers and compositions containing same 失效
标题翻译：聚氨酯流变改性剂和含有它的组合物
公开(公告)号：US4298511A
公开(公告)日：1981-11-03
申请号：US174479
申请日：1980-08-01
申请人： Karl F. Schimmel , Jerome A. Seiner , Rostyslaw Dowbenko , Roger M. Christenson
发明人： Karl F. Schimmel , Jerome A. Seiner , Rostyslaw Dowbenko , Roger M. Christenson
IPC分类号： C09K3/00 , B01F17/52 , C08G18/00 , C08G18/30 , C08G18/65 , C08G18/66 , C08G18/72 , C09D7/00 , C09D7/12 , C08G18/48
CPC分类号： C09D7/002 , C08G18/302 , C08G18/6666 , C08G18/6677 , C08G18/721 , C08L75/04
摘要： Rheology modifiers useful in water-and organic solvent-based compositions are derived from the reaction of polyalkylene oxide, polyfunctional material, diisocyanate and water. The modifiers are characterized by having a branched structure and containing substantially no terminal hydrophobic groups.
摘要翻译：用于水和有机溶剂基组合物的流变改性剂衍生自聚环氧烷，多官能物质，二异氰酸酯和水的反应。改性剂的特征在于具有支链结构并且基本上不含末端疏水基团。

8. 发明授权

US4373083A Process of making urethane rheology modifiers 失效
标题翻译：制备聚氨酯流变改性剂的工艺
公开(公告)号：US4373083A
公开(公告)日：1983-02-08
申请号：US220886
申请日：1980-12-29
申请人： Jerome A. Seiner , Karl F. Schimmel
发明人： Jerome A. Seiner , Karl F. Schimmel
IPC分类号： C08G18/00 , C08G18/08 , C08G18/12 , C08G18/30 , C08G18/65 , C08G18/66 , C08G18/71 , C08G18/72 , C08G18/83 , C09D7/00 , C09K3/00 , C08G18/48
CPC分类号： C08G18/721 , C08G18/0852 , C08G18/12 , C08G18/302 , C08G18/6666 , C08G18/6677 , C08G18/71
摘要： Rheology modifiers useful in water and organic solvent-based compositions are derived from the reaction of polyalkylene oxide, polyfunctional material, diisocyanate, water and end-capping compounds in an organic solvent. The organic solvent is compatible with latex coating compositions.
摘要翻译：用于水和有机溶剂基组合物的流变改性剂衍生自聚环氧烷，多官能材料，二异氰酸酯，水和封端化合物在有机溶剂中的反应。有机溶剂与胶乳涂料组合物相容。

9. 发明授权

US4337184A Urethane rheology modifiers substantially free of terminal hydrophobic groups and compositions containing same 失效
标题翻译：基本上不含末端疏水基团的聚氨酯流变改性剂和含有它们的组合物
公开(公告)号：US4337184A
公开(公告)日：1982-06-29
申请号：US220617
申请日：1980-12-29
申请人： Karl F. Schimmel , Jerome A. Seiner , Rostyslaw Dowbenko , Roger M. Christenson
发明人： Karl F. Schimmel , Jerome A. Seiner , Rostyslaw Dowbenko , Roger M. Christenson
IPC分类号： C08G18/30 , C08G18/66 , C08G18/72 , C09D7/00 , C08K5/29
CPC分类号： C08G18/6677 , C08G18/302 , C08G18/6666 , C08G18/721 , C09D7/002 , C08L75/04
摘要： Rheology modifiers useful in water-based and organic solvent-based compositions are derived from the reaction of polyalkylene oxide, polyfunctional material, diisocyanate and little or no water. The modifiers are characterized by having a branched structure and containing substantially no terminal hydrophobic groups.
摘要翻译：用于水基和有机溶剂基组合物的流变改性剂衍生自聚环氧烷，多官能材料，二异氰酸酯和少量或不含水的反应。改性剂的特征在于具有支链结构并且基本上不含末端疏水基团。

10. 发明授权

US4126596A Two package polymeric epoxy compositions having improved potlife 失效
标题翻译：两种包装聚合物环氧组合物具有改善的适用期
公开(公告)号：US4126596A
公开(公告)日：1978-11-21
申请号：US771276
申请日：1977-02-23
申请人： Karl F. Schimmel , James A. Claar , Jerome A. Seiner , Marco Wismer
发明人： Karl F. Schimmel , James A. Claar , Jerome A. Seiner , Marco Wismer
IPC分类号： C08L33/02 , C08L63/00 , C08L63/02
CPC分类号： C08L33/02 , C08L63/00 , Y10S524/906 , Y10T428/31529 , Y10T428/31699
摘要： Two-package polymeric compositions which form cured products having excellent stain and solvent resistance and having improved potlife comprise a polyepoxide and an addition interpolymer containing pendent salt groups formed by reacting carboxyl groups with a hindered amine and pendent amine groups formed by reacting carboxyl groups with an alkylenimine. The addition interpolymer when mixed with the polyepoxide reacts to form a cured, hard, stain and solvent resistant material. The stability of the mixed compositions, i.e., its potlife, is lengthened by utilizing a sterically-hindered tertiary amine to form the salt groups of the interpolymer.Stability of the addition interpolymer prior to mixing is improved by utilizing therein monomers which provide aminolysis-resistant groups in the interpolymer.
摘要翻译：形成具有优异的耐污染和耐溶剂性并且具有改善的适用期的固化产物的双组分聚合物组合物包括聚环氧化物和加成互聚物，其包含通过使羧基与受阻胺反应形成的侧挂盐基团和通过羧基与亚烷基亚胺。当与聚环氧化物混合时，加成互聚物反应形成固化的，硬的，耐污染和耐溶剂的材料。混合组合物的稳定性，即其适用期，通过利用空间位阻叔胺形成互聚物的盐基来延长。混合前的加成互聚物的稳定性通过在其中利用提供抗氨基酸的单体而得到改善互聚物中的基团。

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