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    • 3. 发明授权
    • Soil release agents for granular laundry detergents
    • 颗粒状衣物洗涤剂用土壤脱模剂
    • US5599782A
    • 1997-02-04
    • US576263
    • 1995-12-21
    • Robert Y. L. PanEugene P. GosselinkEugene J. PancheriStephen W. Morrall
    • Robert Y. L. PanEugene P. GosselinkEugene J. PancheriStephen W. Morrall
    • C08G63/688C11D3/00C11D3/37C11D17/06C11D1/02
    • C08G63/6884C11D3/0036C11D3/3715
    • Improved soil release agents for granular laundry detergents, typically used at levels as low as about 1% of a fully-formulated anionic surfactant-containing granular detergent, are reaction products of transesterifying and oligomerizing mixtures of monomers having the functions MO.sub.3 SC.sub.6 H.sub.4 C(O)--, M'O.sub.3 SC.sub.6 H.sub.3 {C(O)O--}.sub.2, --(O)CC.sub.6 H.sub.4 C(O)-- and --OCH.sub.2 CH.sub.2 O-- wherein M and M' are independently selected from lithium, potassium and sodium, more preferably sodium; said mixtures having mole ratio of MO.sub.3 SC.sub.6 H.sub.4 C(O)-- to --(O)CC.sub.6 H.sub.4 C(O)-- of from about 0.2:1 to about 1.4:1, mole ratio of MO.sub.3 SC.sub.6 H.sub.4 C(O)-- to M'O.sub.3 SC.sub.6 H.sub.3 {C(O)O--}.sub.2 of from about 0.67:1 to about 20:1 and mole ratio of MO.sub.3 SC.sub.6 H.sub.4 C(O)-- to --OCH.sub.2 CH.sub.2 O-- of from about 0.007:1 to about 0.51:1 and being substantially free from monomers of formula HOROH wherein R is propylene or higher alkyl.
    • 用于粒状衣物洗涤剂的改进的去污剂通常以低至约1%的完全配制的含阴离子表面活性剂的颗粒洗涤剂的水平使用,是具有MO3SC6H4C(O) - , M'O3SC6H3 {C(O)O-} 2, - (O)C16H4C(O) - 和-OCH2CH2O-,其中M和M'独立地选自锂,钾和钠,更优选钠; 所述混合物的MO 3 SC 6 H 4 C(O) - (O)C 6 H 4 C(O)的摩尔比为约0.2:1至约1.4:1摩尔比的MO 3 SC 6 H 4 C(O) - 与M'O 3 SC 6 H 3 {C(O) 约为0.67:1至约20:1的摩尔比和MO 3 SC 6 H 4 C(O) - 至-OCH 2 CH 2 O的摩尔比为约0.007:1至约0.51:1,并且基本上不含式HOROH的单体,其中R 是丙烯或高级烷基。
    • 7. 发明授权
    • Cationic polymers having clay soil removal/anti-redeposition properties
useful in detergent compositions
    • 具有洗涤剂组合物中有用的粘土去除/抗再沉积性质的阳离子聚合物
    • US4551506A
    • 1985-11-05
    • US452655
    • 1982-12-23
    • Eugene P. Gosselink
    • Eugene P. Gosselink
    • C08G65/26C08G73/04C11D1/40C11D1/62C11D3/37C11D3/48
    • C11D3/3723C08G65/2624C11D1/40C11D1/62
    • Water-soluble cationic polymers having clay soil removal/anti-redeposition properties, which comprise a polymer backbone, at least two M groups and at least one L-X group, wherein M is a cationic group attached to or integral with the backbone and contains an N+ positively charged center; X is a nonionic group selected from the group consisting of H, C.sub.1 -C.sub.4 alkyl or hydroxyalkyl ester or ether groups, or mixtures thereof; and L is a hydrophilic chain connecting groups M and X or connecting X to the polymer backbone. L also contains the polyoxyalkylene moiety --[(R'O).sub.m (CH.sub.2 CH.sub.2 O).sub.n ]--, wherein R' is C.sub.3 -C.sub.4 alkylene or hydroxyalkylene, m and n are numbers such that the moiety --(CH.sub.2 CH.sub.2 O).sub.n -- is at least about 50% by weight of said polyoxyalkylene moiety, and n is at least about 3. These cationic polymers are useful in detergent compositions.
    • 具有粘土去除/抗再沉积性质的水溶性阳离子聚合物,其包含聚合物主链,至少两个M基团和至少一个LX基团,其中M是与骨架连接或与骨架一体并含有N + 带正电的中心; X是选自H,C 1 -C 4烷基或羟烷基酯或醚基的非离子基团,或其混合物; L是连接基团M和X或将X连接到聚合物骨架的亲水链。 L还含有聚氧化烯部分 - [(R'O)m(CH 2 CH 2 O)n] - ,其中R'是C 3 -C 4亚烷基或羟基亚烷基,m和n是数个这样的数字,使得部分 - (CH 2 CH 2 O)n-至少 约50重量%的所述聚氧化烯部分,n为至少约3.这些阳离子聚合物可用于洗涤剂组合物中。