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    • 1. 发明授权
    • Soil release agents for granular laundry detergents
    • 颗粒状衣物洗涤剂用土壤脱模剂
    • US5599782A
    • 1997-02-04
    • US576263
    • 1995-12-21
    • Robert Y. L. PanEugene P. GosselinkEugene J. PancheriStephen W. Morrall
    • Robert Y. L. PanEugene P. GosselinkEugene J. PancheriStephen W. Morrall
    • C08G63/688C11D3/00C11D3/37C11D17/06C11D1/02
    • C08G63/6884C11D3/0036C11D3/3715
    • Improved soil release agents for granular laundry detergents, typically used at levels as low as about 1% of a fully-formulated anionic surfactant-containing granular detergent, are reaction products of transesterifying and oligomerizing mixtures of monomers having the functions MO.sub.3 SC.sub.6 H.sub.4 C(O)--, M'O.sub.3 SC.sub.6 H.sub.3 {C(O)O--}.sub.2, --(O)CC.sub.6 H.sub.4 C(O)-- and --OCH.sub.2 CH.sub.2 O-- wherein M and M' are independently selected from lithium, potassium and sodium, more preferably sodium; said mixtures having mole ratio of MO.sub.3 SC.sub.6 H.sub.4 C(O)-- to --(O)CC.sub.6 H.sub.4 C(O)-- of from about 0.2:1 to about 1.4:1, mole ratio of MO.sub.3 SC.sub.6 H.sub.4 C(O)-- to M'O.sub.3 SC.sub.6 H.sub.3 {C(O)O--}.sub.2 of from about 0.67:1 to about 20:1 and mole ratio of MO.sub.3 SC.sub.6 H.sub.4 C(O)-- to --OCH.sub.2 CH.sub.2 O-- of from about 0.007:1 to about 0.51:1 and being substantially free from monomers of formula HOROH wherein R is propylene or higher alkyl.
    • 用于粒状衣物洗涤剂的改进的去污剂通常以低至约1%的完全配制的含阴离子表面活性剂的颗粒洗涤剂的水平使用,是具有MO3SC6H4C(O) - , M'O3SC6H3 {C(O)O-} 2, - (O)C16H4C(O) - 和-OCH2CH2O-,其中M和M'独立地选自锂,钾和钠,更优选钠; 所述混合物的MO 3 SC 6 H 4 C(O) - (O)C 6 H 4 C(O)的摩尔比为约0.2:1至约1.4:1摩尔比的MO 3 SC 6 H 4 C(O) - 与M'O 3 SC 6 H 3 {C(O) 约为0.67:1至约20:1的摩尔比和MO 3 SC 6 H 4 C(O) - 至-OCH 2 CH 2 O的摩尔比为约0.007:1至约0.51:1,并且基本上不含式HOROH的单体,其中R 是丙烯或高级烷基。