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1. 发明授权

US4140621A Maintaining or increasing the isobutane content of a cut subjected to selective hydrogenolysis 失效
标题翻译：保持或提高经过选择性氢解的切割的异丁烷含量
公开(公告)号：US4140621A
公开(公告)日：1979-02-20
申请号：US835076
申请日：1977-09-20
申请人： Jean-Pierre Franck , Jean-Francois Le Page , Germain Martino , Jean Miquel
发明人： Jean-Pierre Franck , Jean-Francois Le Page , Germain Martino , Jean Miquel
IPC分类号： B01J23/00 , C07C1/00 , C07C4/06 , C07C11/09 , C07C67/00 , C10G47/14 , C07C9/08 , B01J27/04
CPC分类号： C07C4/06 , C07C2521/04 , C07C2521/08 , C07C2523/46 , C10G2400/26
摘要： A saturated hydrocarbon charge containing both butane and isobutane is subjected to selective hydrogenolysis in the presence of a catalyst comprising a specific carrier and 0.1 - 10 % b.w. of rhodium. Butane is thus selectively converted to ethane and propane, while isobutane is preserved or formed and can be recovered from the reaction product.
摘要翻译：在含有特定载体和0.1-10％b.w的催化剂存在下，将含有丁烷和异丁烷的饱和烃电荷进行选择性氢解。的铑。因此，丁烷选择性地转化为乙烷和丙烷，而异丁烷被保存或形成，并且可以从反应产物中回收。

2. 发明授权

US4092371A Process for manufacturing a catalyst comprising aluminum oxide and boron oxide, the resulting catalyst and the use thereof in alkylation reactions 失效
标题翻译：用于制造包含氧化铝和氧化硼的催化剂的方法，所得催化剂及其在烷基化反应中的用途
公开(公告)号：US4092371A
公开(公告)日：1978-05-30
申请号：US815350
申请日：1977-07-07
申请人： Jean-Pierre Franck , Jean-Francois Le Page
发明人： Jean-Pierre Franck , Jean-Francois Le Page
IPC分类号： B01J27/08 , B01J37/22 , C07C2/68 , C07C3/52
CPC分类号： C07C2/68 , B01J27/08 , B01J37/22 , C07C2521/02 , C07C2521/04 , C07C2527/126 , C07C2531/14 , Y02P20/582
摘要： A catalyst useful for the alkylation of aromatic hydrocarbons is produced by reacting a compound of the formula AlX.sub.y R.sub.(3 - y), where X is halogen, R is a hydrocarbon radical and y is 1, 3/2, 2 or 3, except 3 when X is fluorine, with a carrier comprising aluminum oxide and boron oxide.
摘要翻译：用于芳族烃烷基化的催化剂是通过使式AlXyR（3-y）的化合物（其中X是卤素，R是烃基）和y是1,3 / 2,2或3，除了3 当X是氟时，具有包含氧化铝和氧化硼的载体。

3. 发明授权

US4180453A Process for the steam-cracking of heavy feedstocks 失效
标题翻译：重质原料蒸汽裂解的工艺
公开(公告)号：US4180453A
公开(公告)日：1979-12-25
申请号：US876825
申请日：1978-02-10
申请人： Jean-Pierre Franck , Edouard Freund , Jean-Francois Le Page , Jean Miquel
发明人： Jean-Pierre Franck , Edouard Freund , Jean-Francois Le Page , Jean Miquel
IPC分类号： B01J27/00 , C10G65/06 , C10G69/06 , C10G37/00
CPC分类号： C10G65/06 , C10G2400/20
摘要： A fresh charge containing aromatic hydrocarbons is hydrotreated in admixture with a recycle fraction, in the presence of a bifunctional catalyst, a portion of the effluent is subjected to steam-cracking, thereby recovering a gas oil fraction which is subjected to hydrogenation and forms said recycle fraction. The mixture of recycle fraction and charge is advantageously treated with hydrogen in the presence of a monofunctional catalyst to hydrogenate olefins, at a lower temperature than the hydrotreatment, and then passed to the hydrotreatment zone.
摘要翻译：将含有芳烃的新鲜电荷与再循环部分混合加氢处理，在双官能催化剂存在下，将一部分流出物进行蒸汽裂化，从而回收粗制油馏分进行氢化并形成所述再循环分数。有利的是，在单官能催化剂存在下，用氢气处理再循环部分和装料的混合物，以在比加氢处理的温度更低的温度下氢化烯烃，然后通入加氢处理区。

4. 发明授权

US4254294A Polymerization reactions in the presence of a catalyst containing aluminum oxide, boron oxide and halogen 失效
标题翻译：在含有氧化铝，氧化硼和卤素的催化剂存在下的聚合反应
公开(公告)号：US4254294A
公开(公告)日：1981-03-03
申请号：US096588
申请日：1979-11-21
申请人： Bernard Juguin , Jean-Pierre Franck , Jean-Francois Le Page , Gabriel de Gaudemaris
发明人： Bernard Juguin , Jean-Pierre Franck , Jean-Francois Le Page , Gabriel de Gaudemaris
IPC分类号： C08F4/00 , C07C1/00 , C07C2/22 , C07C11/02 , C07C67/00 , C08F4/06 , C08F8/04 , C08F10/00 , C08F240/00 , C10G50/00 , C08F4/52 , C08F4/12
CPC分类号： C08F240/00 , C08F10/00 , C08F8/04 , Y02P20/582
摘要： Process for polymerizing olefinic hydrocarbons at a temperature from 0.degree. to 90.degree. C., preferably from 20.degree. to 80.degree. C. in the presence of a catalyst containing aluminum oxide and, per part by weight thereof, boron oxide in a proportion of 0.01 to 1, preferably 0.07 to 0.15 part by weight and halogen in a proportion of 0.5 to 20%, preferably 4 to 12%, said catalyst resulting from the reaction of an aluminum compound of formula AlX.sub.y R.sub.(3-y) where X is halogen, R is a hydrocarbon radical and y is selected from 1, 3/2, 2 and 3, with a carrier containing aluminum oxide and boron oxide in a proportion to aluminum oxide from 1 to 100%.
摘要翻译：在含有氧化铝的催化剂存在下，在0〜90℃，优选20〜80℃的温度下使烯烃聚合的方法，按重量份计，氧化硼的比例为0.01 至1，优选0.07至0.15重量份，卤素以0.5至20重量％，优选4至12重量％的比例，由式AlXyR（3-y）的铝化合物（其中X为卤素， R是烃基，y选自1,3 / 2,2和3，其中含有氧化铝和氧化硼的载体与氧化铝的比例为1至100％。

5. 发明授权

US3951648A Process for recovering palladium, more particularly from alumina containing catalysts 失效
标题翻译：更具体地从含氧化铝的催化剂中回收钯的方法
公开(公告)号：US3951648A
公开(公告)日：1976-04-20
申请号：US455078
申请日：1974-03-27
申请人： Robert Stern , Jean-Pierre Franck , Jean-Francois Le Page
发明人： Robert Stern , Jean-Pierre Franck , Jean-Francois Le Page
IPC分类号： C22B11/00 , B01J37/24 , B01J38/00 , C01G55/00 , C22B11/02
CPC分类号： B01J37/24 , C22B11/026 , Y02P10/214
摘要： Process for recovering palladium from a catalyst having a palladium content of less than 5 %, comprising contacting said catalyst with a gaseous chlorinated organic compound at a temperature sufficient for vaporizing the palladium and cooling the gaseous phase so as to recover the formed chlorinated palladium derivative.
摘要翻译：从钯含量小于5％的催化剂中回收钯的方法，包括在足以汽化钯并冷却气相的温度下使所述催化剂与气态氯化有机化合物接触，以回收形成的氯化钯衍生物。

6. 发明授权

US4062805A Process for manufacturing a catalyst comprising aluminum oxide and boron oxide, the resulting catalyst and the use thereof in alkylation reactions 失效
标题翻译：用于制造包含氧化铝和氧化硼的催化剂的方法，所得催化剂及其在烷基化反应中的用途
公开(公告)号：US4062805A
公开(公告)日：1977-12-13
申请号：US699454
申请日：1976-06-24
申请人： Jean-Pierre Franck , Jean-Francois Le Page
发明人： Jean-Pierre Franck , Jean-Francois Le Page
IPC分类号： B01J27/08 , B01J31/14 , B01J37/22 , C07B61/00 , C07C1/00 , C07C2/66 , C07C2/68 , C07C15/02 , C07C67/00 , B01J21/02
CPC分类号： B01J37/22 , B01J27/08 , C07C2/66 , C07C2/68 , C07C2521/02 , C07C2521/04 , C07C2527/126 , C07C2531/14 , Y02P20/582
摘要： A catalyst useful for the alkylation of aromatic hydrocarbons is produced by reacting a compound of the formula AlX.sub.y R.sub.(3 - y) , where X is halogen, R is a hydrocarbon radical and y is 1, 3/2, or 2, except, with a carrier comprising aluminum oxide and boron oxide.
摘要翻译：可用于芳族烃烷基化的催化剂是通过使式AlXyR（3-y）化合物（其中X是卤素，R是烃基，y是1,3/2或2）与式包含氧化铝和氧化硼的载体。

7. 发明授权

US4145276A Process for the 3-step catalytic treatment of highly unsaturated heavy fractions under hydrogen pressure 失效
$Process for the 3-step catalytic treatment of highly unsaturated heavy fractions under hydrogen pressure$
标题翻译：三次催化处理氢压下高度不稳定重力分段的方法
公开(公告)号：US4145276A
公开(公告)日：1979-03-20
申请号：US862324
申请日：1977-12-20
申请人： Jean Cosyns , Jean-Pierre Franck
发明人： Jean Cosyns , Jean-Pierre Franck
IPC分类号： C10G65/08 , B01J23/00 , B01J27/00 , C07B61/00 , C07C1/00 , C07C5/02 , C07C7/163 , C07C9/00 , C07C15/02 , C07C67/00 , C10G45/52 , C10G65/04 , C10G23/04
CPC分类号： C10G45/52 , C10G65/04
摘要： An unstable heavy hydrocarbon fraction obtained by pyrosis is reacted with hydrogen in contact with three successive catalysts: (a) a group VIII metal catalyst (b) a catalyst comprising nickel and tungsten compounds, and (c) a catalyst comprising alumina, a group VIII noble metal and fluorine or chlorine.

8. 发明授权

US4019976A Process for hydrogenating highly unsaturated heavy hydrocarbon cuts 失效
标题翻译：氢化高度不饱和重烃馏分的方法
公开(公告)号：US4019976A
公开(公告)日：1977-04-26
申请号：US569788
申请日：1975-04-21
申请人： Jean Cosyns , Jean-Pierre Franck , Jean-Claude Guibet , Yves Jacquin
发明人： Jean Cosyns , Jean-Pierre Franck , Jean-Claude Guibet , Yves Jacquin
IPC分类号： B01J23/85 , C10G45/50 , C10G65/08 , C10G23/02
CPC分类号： C10G45/50 , B01J23/85 , C10G65/08
摘要： Process for hydrogenating a highly unsaturated hydrocarbon cut, boiling above 200.degree. C under atmospheric pressure, comprising passing said cut successively over two catalysts, each of which contains an alumina carrier, (a) at least one molybdenum and/or tungsten compound and (b) at least one nickel and/or cobalt compound, the ratio b/a expressed in gram-atoms of metals, being from 1.5:1 to 10:1 for the first catalyst and from 0.1:1 to 1:1 for the second catalyst and the alumina carrier of the first catalyst having a heat of neutralization by ammonia absorption lower than 10 calories per gram under an ammonia pressure of 300 mmHg.
摘要翻译：在大气压下沸腾高于200℃的高度不饱和烃馏分的方法，包括将所述切割依次通过两个催化剂，每个催化剂含有氧化铝载体，（a）至少一种钼和/或钨化合物和（b ）至少一种镍和/或钴化合物，对于第一催化剂，以金属的克原子表示的比率b / a为第一催化剂的1.5:1至10:1，对于第二催化剂为0.1:1至1:1 并且在氨压力为300mmHg下，第一催化剂的氧化铝载体具有通过氨吸收低于10卡路里/克的中和热。

9. 发明授权

US4737262A Process for the catalytic reforming of a charge passing through at least two catalyst beds 失效
标题翻译：用于催化重整通过至少两个催化剂床的电荷的方法
公开(公告)号：US4737262A
公开(公告)日：1988-04-12
申请号：US10596
申请日：1987-02-03
申请人： Jean-Pierre Franck , Jean-Paul Bournonville
发明人： Jean-Pierre Franck , Jean-Paul Bournonville
IPC分类号： B01J27/00 , B01J27/13 , B01J31/00 , B01J31/12 , B01J31/22 , C10G35/04 , C10G35/085 , C10G35/09 , C10G50/00 , C10G59/02
CPC分类号： C10G35/09 , C10G59/02
摘要： A process for the catalytic reforming of a hydrocarbon charge wherein the charge passes successively through at least two catalyst beds, the first one being a bed of a first catalyst whose carrier contains platinum, rhenium and at least one halogen, at least the last bed being a moving bed of a second catalyst whose carrier contains platinum, at least one additional metal M selected from the group consisting of tin, gallium, germanium, indium, lead and thallium and at least one halogen, said metal M being introduced onto this carrier by means of an organometallic compound and the proportion by weight of said second catalyst being from 25 to 55% of the total catalyst mass used in all the catalyst beds. The charge preferably passes through at least two fixed beds of the first catalyst and at least one moving bed of the second catalyst, the carrier of the two catalysts being preferably alumina.By this process high grade gasolines (of Research Octane Number higher than 95) are produced over long periods.
摘要翻译：一种用于烃电荷的催化重整的方法，其中电荷依次通过至少两个催化剂床，第一个是载体包含铂，铼和至少一个卤素的第一催化剂的床，至少最后一个床是载体包含铂的第二催化剂的移动床，选自锡，镓，锗，铟，铅和铊的至少一种另外的金属M和至少一种卤素，所述金属M通过有机金属化合物的手段和所述第二催化剂的重量比例在所有催化剂床中使用的总催化剂质量的25-55％。电荷优选通过第一催化剂的至少两个固定床和第二催化剂的至少一个移动床，两种催化剂的载体优选为氧化铝。通过这种方法，高品质汽油（研究辛烷值高于95）长期生产。

10. 发明授权

US4588495A Catalytic reforming process 失效
标题翻译：催化重整过程
公开(公告)号：US4588495A
公开(公告)日：1986-05-13
申请号：US704456
申请日：1985-02-22
申请人： Jean-Pierre Franck , Jean-Paul Bournonville
发明人： Jean-Pierre Franck , Jean-Paul Bournonville
IPC分类号： C10G35/09 , B01J21/04 , B01J27/00 , B01J27/13 , B01J27/135 , C10G59/02 , C10G35/06
CPC分类号： C10G59/02
摘要： In a catalytic reforming process wherein a charge is circulated successively through a first catalyst bed and then at least one further catalyst bed, the improvement wherein the catalyst of the first bed comprises a carrier of alumina base and, by weight in proportion to the carrier, 0.05-0.6% of platinum, 0.005-3% of rhenium and 0.1-15% of at least one halogen and wherein each catalyst of the other beds contains a carrier of alumina base and, by weight with respect to the carrier, 0.05-0.6% of platinum, 0.05-3% of at least one metal promoter selected from the group consisting of tin, thallium and indium and 0.1-15% of at least one halogen, the proportion by weight of the catalyst containing platinum and rhenium ranging from 8 to 40% with respect to the total catalyst mass used in all the catalyst beds.
摘要翻译：在催化重整过程中，其中电荷依次通过第一催化剂床和至少一个另外的催化剂床循环，其中第一床的催化剂包含氧化铝碱的载体，并且按载体的重量比例， 0.05-0.6％的铂，0.005-3％的铼和0.1-15％的至少一种卤素，其中每个催化剂的其它床层含有氧化铝基质的载体，相对于载体的重量比为0.05-0.6 铂的含量为0.05-3％，选自锡，铊和铟的至少一种金属促进剂和0.1-15％的至少一种卤素，含有铂和铼的催化剂的重量比为8 相对于在所有催化剂床中使用的总催化剂质量至40％。

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