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    • 2. 发明授权
    • High-capacity optical storage media
    • 大容量光存储介质
    • US07754863B2
    • 2010-07-13
    • US11659993
    • 2005-07-06
    • Jean-Pierre BacherGisèle BaudinFrédérique WendebornJean-Marie AdamUrs LehmannJean-Luc Birbaum
    • Jean-Pierre BacherGisèle BaudinFrédérique WendebornJean-Marie AdamUrs LehmannJean-Luc Birbaum
    • C09B45/34C09B69/02G11B7/24
    • G11B7/2467C09B45/20C09B45/34C09B69/045G11B7/246G11B7/247G11B7/2472G11B7/2492G11B7/2495G11B7/2498G11B7/2531G11B7/2533G11B7/2534G11B7/2535G11B7/256G11B7/2575G11B7/259G11B2007/25706G11B2007/2571G11B2007/25713G11B2007/25715G11B2007/25716
    • The invention accordingly relates to an optical recording medium comprising a substrate, a reflecting layer and a recording layer, wherein the recording layer comprises a compound of formula (I) or a mesomeric or a tautomeric form thereof, wherein M1 is a metal cation in the oxidation state +3, a hydroxy or halogeno metal group wherein the metal is in the oxidation state +4, or an oxo metal group wherein the metal is in the oxidation state +5; (III) and (IV)are each independently of the other (V), (VI) or (VII); (VIII) is (IX), (X), (XI), (XII), (XIII), or (XIV); (XV) is (XVI) or C2-C8heteroaryl unsubstituted or mono- or poly-substituted by R10, R11, R12 and/or R13; Q1 is N or CR18, Q2 is N or CR19, Q3, Q5 and Q7 are each independently of the other CR20R21, O, S or NR22, Q4 is CR16 or N and Q6 is CR17 or N; and R2 and/or R6 are O, S or NR33. Please see the disclosure for the other substituents which are less relevant. The compounds of formula (I) are novel and also claimed, as well as the compound of formula (II), or a mesomer or tautomer thereof, wherein R38 is halogen , CF3, NO2, CN, COR22, COOR23, SO3R23, NCO or SCN, G1, G2M1, R1R2, R4, R5, R6, R8, R22 and R23 are as defined in formula (I), M2m+ is a cation with m positive charges, and m is an integer 1, 2 or 3. The optical recording media are remarkably suitable for DVD±R (658 nm), especially at high recording speeds.
    • 因此,本发明涉及一种包括基底,反射层和记录层的光学记录介质,其中记录层包含式(I)化合物或其互变异构体或互变异构体,其中M1是金属阳离子 氧化态+3,其中金属处于氧化态+4的羟基或卤代金属基团,或其中金属处于氧化态+5的氧代金属基团; (III)和(IV)各自独立于另一个(V),(VI)或(VII); (VIII)为(IX),(X),(XI),(XII),(XIII)或(XIV); (XV)是(XVI)或未被取代或被R10,R11,R12和/或R13单取代或多取代的C 2 -C 8杂芳基; Q1是N或CR18,Q2是N或CR19,Q3,Q5和Q7各自独立于另一个CR20R21,O,S或NR22,Q4是CR16或N,Q6是CR17或N; 且R 2和/或R 6为O,S或NR 33。 请参阅其他不太相关的其他取代基的披露。 式(I)化合物是新的,也要求保护的,以及式(II)化合物或其互变异构体或互变异构体,其中R38是卤素,CF3,NO2,CN,COR22,COOR23,SO3R23,NCO或 SCN,G1,G2M1,R1R2,R4,R5,R6,R8,R22和R23如式(I)中所定义,M2m +是具有m个正电荷的阳离子,m是整数1,2或3.光学 记录介质非常适合于DVD±R(658nm),特别是在高记录速度下。
    • 5. 发明授权
    • Anionic acid dyes, processes for their preperation and their use
    • 阴离子染料,其制备方法及其用途
    • US5859216A
    • 1999-01-12
    • US811450
    • 1997-03-03
    • Jean-Marie AdamJean-Pierre Bacher
    • Jean-Marie AdamJean-Pierre Bacher
    • C09B1/34C09B43/16
    • C09B43/16C09B1/343
    • Anionic acid dyes of the formula ##STR1## in which R.sub.1 and R.sub.2 independently of one another are hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl,X.sub.1 is C.sub.1 -C.sub.8 alkyl, substituted or unsubstituted C.sub.5 -C.sub.7 cycloalkyl, phenyl or naphthyl which are unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.4 alkanoylamino, amino, hydroxyl, ureido, halogen, carboxyl or sulfo,or the radical of the formula --N(R.sub.2)--X.sub.1 is a ring, which may contain further heteroatoms,Y.sub.1 is a radical of the formula ##STR2## in which B.sub.1 is a colourless organic bridge member,R.sub.3 is hydrogen or C.sub.1 -C.sub.4 alkyl and R.sub.4 is hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl,W.sub.1 is hydrogen or a radical of the formula --CO--R, in whichR is substituted or unsubstituted C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.7 cycloalkyl, phenyl or naphthyl and A.sub.1 is as defined in claim 1.The dyes of the formula (1) are particularly suitable for dyeing or printing natural or synthetic polyamide fibre materials.
    • 式(1)的阴离子染料其中R 1和R 2彼此独立地是氢或取代或未取代的C 1 -C 4烷基,X 1是C 1 -C 8烷基,取代或未取代的C 5 -C 7环烷基,苯基或萘基,其是未取代的 或被C 1 -C 4烷基,C 1 -C 4烷氧基,C 2 -C 4烷酰基氨基,氨基,羟基,脲基,卤素,羧基或磺基取代,或者式-N(R 2)-X 1的基团是环,其可以含有其它杂原子, Y1是下式的基团:其中B1是无色有机桥连构件,R 3是氢或C 1 -C 4烷基,R 4是氢或被取代的 未取代的C1-C4烷基,W1是氢或式-CO-R的基团,其中R是取代或未取代的C1-C8烷基,C5-C7环烷基,苯基或萘基,A1如权利要求1所定义。 式(1)特别适用于染色或印花天然或合成聚酰胺纤维材料。
    • 7. 发明申请
    • New heterocyclic compounds, a process for their preparation and their use as dyes and pigments
    • 新的杂环化合物,其制备方法及其作为染料和颜料的用途
    • US20060124014A1
    • 2006-06-15
    • US10548358
    • 2004-03-10
    • Jean-Marie AdamPramod DalviVadiraj EkkundiJean-Pierre BacherRamaswami SreenivasanDeepak Rane
    • Jean-Marie AdamPramod DalviVadiraj EkkundiJean-Pierre BacherRamaswami SreenivasanDeepak Rane
    • B41F31/00
    • C09D11/32C09D5/028C09D5/035C09D11/037
    • Compounds of formula (I) wherein R1 is hydrogen, hydroxy, halogen, nitro, cyano, amino, carboxy, carboxylic ester, sulfo, sulfonic ester, carboxylic amide, sulfonic amide, alkylthio, arylthio, alkoxy or aryloxy, R′1 is hydrogen, hydroxy, halogen, nitro, cyano, amino, carboxy, carboxylic ester, sulfo, sulfonic ester, carboxylic amide, sulfonic amide, alkylthio, arylthio, alkoxy or aryloxy, X is —O—, —S—, —NH— or —N(alkyl)-, X′ is —O—, —S—, —NH— or —N(alkyl)-, Y is hydrogen or carboxylic ester, Y′ is hydrogen or carboxylic ester, Z is ═C— or ═N—, Z′ is ═C— or ═N—, x is 0 or 1, when Z is ═N—, then x is 0, y is 0 or 1, when Z′ is ═N—, then y is 0, A is a conjugated linking bridge of the formulae (II), (III), (IV), (V), or (VI), wherein n is 0, 1, 2 or 3, m is 0, 1, 2 or 3, B is a phenyl ring, T is ═C(R3)— or ═N—, wherein R3 is hydrogen, C1-C12alkyl or CN, W is a heterocyclic, or linear or polycondensed aromatic group which is unsubstituted or substituted by alkyl, halogen, hydroxy, alkoxy, alkylthio or amino, G is —CH═ or —N═, and R2 is hydrogen, alkyl, halogen, hydroxy, alkoxy, alkylthio or amino, their preparation and their use in the production of coloured plastics or polymeric color particles.
    • 式(I)化合物,其中R 1是氢,羟基,卤素,硝基,氰基,氨基,羧基,羧酸酯,磺基,磺酸酯,羧酸酰胺,磺酰胺,烷硫基,芳硫基,烷氧基 或芳氧基,R'1是氢,羟基,卤素,硝基,氰基,氨基,羧基,羧酸酯,磺基,磺酸酯,羧酸酰胺,磺酰胺,烷硫基,芳硫基,烷氧基或芳氧基, X是-O - , - S-,-NH-或-N(烷基) - ,X'是-O - , - S-,-NH-或-N(烷基) - ,Y是氢或羧酸酯, Y'是氢或羧酸酯,Z是-C-或-N-,Z'是-C-或-N-,x是0或1,当Z是-N-时,x是0,y是0 或者当Z'为-N-时,y为0,A为式(II),(III),(IV),(V)或(VI)的共轭连接桥,其中n为0 ,1,2或3,m为0,1,2或3,B为苯环,T为-C(R 3) - 或-N-,其中R 3 N是氢,C 1 -C 12烷基或CN,W是杂环或直链或缩聚芳族基,其中i 未取代或被烷基,卤素,羟基,烷氧基,烷硫基或氨基取代,G是-CH-或-N-,R 2是氢,烷基,卤素,羟基,烷氧基,烷硫基或 氨基,它们的制备及其在生产有色塑料或聚合物着色颗粒中的应用。
    • 8. 发明授权
    • Method of mass-coloring synthetic materials
    • 合成材料的大量着色方法
    • US07018430B2
    • 2006-03-28
    • US10484356
    • 2002-07-18
    • Jean-Marie AdamJean-Pierre Bacher
    • Jean-Marie AdamJean-Pierre Bacher
    • C08K5/00C07D491/048
    • C07D491/16C08K5/0041C08K5/3447C09B57/12D01F1/04
    • The present invention relates to a method of mass-coloring synthetic materials, which comprises using at least one pigment dye of formula (1) wherein R and R1 together form a phenyl or heteroaryl radical and R2 is hydrogen, or R1 and R2 together form a phenyl or heteroaryl radical and R is hydrogen, and the rings A and B may each independently of the other be substituted by C1-C4?alkyl, C1–C4alkoxy, halogen, —COOR3, —CONHR4 and/or by —SR5, wherein R3, R4 and R5 are each independently of the others hydrogen, C1–C4alkyl, C6–C12aryl or heteroaryl, to synthetic materials colored with such pigment dyes, and to novel pigment dyes of formula (3), wherein R6 is hydrogen or bromine
    • 本发明涉及一种大量着色合成材料的方法,其包括使用至少一种式(1)的颜料染料,其中R和R 1一起形成苯基或杂芳基,R SUB > 2是氢,或者R 1和R 2一起形成苯基或杂芳基并且R是氢,并且环A和B可以各自独立地 的另一个被C 1 -C 4烷基,C 1 -C 4烷氧基,卤素,-COOR 3取代 和/或-SR 5,其中R 3,R 4,和/或-SR 5,其中R 3,R 4, 和R 5各自独立地为氢,C 1 -C 4烷基,C 6 -C 对于用这种颜料染料着色的合成材料和式(3)的新型颜料染料,其中R 6是氢或溴
    • 10. 发明授权
    • Process for dyeing natural or synthetic polyamide fiber materials
    • 天然或合成聚酰胺纤维材料染色工艺
    • US5922865A
    • 1999-07-13
    • US089141
    • 1998-06-02
    • Jean-Marie AdamJean-Pierre BacherFrancine Casi
    • Jean-Marie AdamJean-Pierre BacherFrancine Casi
    • C09B1/34C09B43/16D06P1/39D06P1/642D06P3/16D06P3/24D06P5/06C07D251/50C07D251/54
    • D06P1/39C09B1/34C09B43/16D06P1/6426D06P3/16D06P3/241D06P5/06Y10S8/917Y10S8/924
    • Process for dyeing natural or synthetic polyamide fibre materials, which comprises dyeing these fibre materials with at least one anionic acid dye of the formula ##STR1## and treating the fibre material mentioned, during or after the dyeing process, with a colourless fixing agent which contains sulfo or sulfato groups and contains at least two fibre-reactive groups, whereR.sub.1 and R.sub.2 independently of one another are hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl,X.sub.1 is substituted or unsubstituted C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.7 cycloalkyl, phenyl or naphthyl,or the radical of the formula --N(R.sub.2)--X.sub.1 is a ring, which may contain further heteroatoms,Y.sub.1 is a radical of the formula ##STR2## in which B.sub.1 is a colourless organic bridge member,R.sub.3 is hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl andR.sub.4 is hydrogen or substituted or unsubstituted C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.7 cycloalkyl, phenyl or naphthyl, andA.sub.1 is as defined in claim 1.
    • 用于染色天然或合成聚酰胺纤维材料的方法,其包括用至少一种下式的阴离子酸性染料染色这些纤维材料,并在染色过程中或之后用含有磺基或硫酸酯的无色固色剂处理所述纤维材料 并且包含至少两个纤维反应性基团,其中R 1和R 2彼此独立地是氢或取代或未取代的C 1 -C 4烷基,X 1是取代或未取代的C 1 -C 8烷基,C 5 -C 7环烷基,苯基或萘基或 式-N(R2)-X1是可以含有其它杂原子的环,Y1是下式的基团,其中B1是无色有机桥连构件,R3是氢或取代或未取代的C1-C4烷基,R4是氢 或取代或未取代的C1-C8烷基,C5-C7环烷基,苯基或萘基,A1如权利要求1所定义。