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1. 发明授权

US07897673B2 Flexible high thermomechanical stress-resistant and fireproof halogen-free thermoplastic compositions 有权
标题翻译：柔软的高机械耐热和耐火无卤素热塑性组合物
公开(公告)号：US07897673B2
公开(公告)日：2011-03-01
申请号：US12303174
申请日：2007-06-01
申请人： Jean-Jacques Flat , Philippe Blondel , David Meslet
发明人： Jean-Jacques Flat , Philippe Blondel , David Meslet
IPC分类号： C08K3/32 , C08K3/34
CPC分类号： C09K21/12 , C08G81/028 , C08L23/02 , C09D5/18 , C09K21/04 , H01B7/295 , H01R13/527 , C08L2666/20
摘要： The invention concerns flexible high thermomechanical stress-resistant and fire retardant halogen-free thermoplastic compositions, comprising a polyamide block-graft copolymer consisting of a trunk and on average at least one polyamide graft, wherein the grafts are bound to the trunk by the residues of an unsaturated monomer (X) having a function capable of reacting with a polyamide at the amine-terminal, the unsaturated monomer residues (X) being bound on the trunk by grafting or copolymerization from the double bond thereof. The invention is characterized in that the compositions comprise a mixture: 50 to 70 wt. % of polyamide block copolymer, 25 to 35 wt. % of a flame-retardant agent selected among ammonium phosphates, phosphinates, pyrophosphates, and polyphosphates, about 2 wt. % of zeolite, or hydrotalcitemolecular sieves. Said compositions are particularly useful for making electric cables, electric components, for molding electrotechnical housings, or for making coating layers or thermal protection sleeves for fluid transfer lines in the automotive industry.
摘要翻译：本发明涉及柔性高的热机械应力阻力和阻燃无卤热塑性组合物，其包含由树干和平均至少一个聚酰胺接枝物组成的聚酰胺嵌段共聚物共聚物，其中移植物通过残留物具有能够在胺末端与聚酰胺反应的功能的不饱和单体（X），不饱和单体残基（X）通过从其双键接枝或共聚而结合在树干上。本发明的特征在于，所述组合物包含混合物：50至70wt。％的聚酰胺嵌段共聚物，25〜35重量％选自磷酸铵，次膦酸盐，焦磷酸盐和多磷酸盐的阻燃剂的百分比为约2重量％％的沸石或水分子分子筛。所述组合物特别可用于制造用于汽车工业中的流体输送线的电缆，用于模制电工技术外壳的电气部件或用于制造涂层或热保护套管。

2. 发明申请

US20090253836A1 FLEXIBLE HIGH THERMOMECHANICAL STRESS-RESISTANT AND FIREPROOF HALOGEN-FREE THERMOPLASTIC COMPOSITIONS 有权
标题翻译：柔性高温耐热耐火材料和无机无卤素热塑性组合物
公开(公告)号：US20090253836A1
公开(公告)日：2009-10-08
申请号：US12303174
申请日：2007-06-01
申请人： Jean-Jacques Flat , Philippe Blondel , David Meslet
发明人： Jean-Jacques Flat , Philippe Blondel , David Meslet
IPC分类号： C08L77/00 , C09K21/00 , C08K5/3492
CPC分类号： C09K21/12 , C08G81/028 , C08L23/02 , C09D5/18 , C09K21/04 , H01B7/295 , H01R13/527 , C08L2666/20
摘要： The present invention relates to flame-retarded flexible thermoplastic compositions of high thermomechanical strength, containing no halogen compound, comprising a graft copolymer containing polyamide blocks and composed of a polyolefin backbone and on average at least one polyamide graft, in which the grafts are attached to the backbone by the radicals of an unsaturated monomer (X) having a function capable of reacting with an amine-terminal polyamide, the radicals of the unsaturated monomer (X) being fixed to the backbone by grafting or copolymerization from its double bond, wherein said composition comprises, in a mixture: 50% to 70% by weight of the graft copolymer containing polyamide blocks, 25% to 35% by weight of a flame retardant selected from ammonium phosphates, phosphinates, pyrophosphates, and polyphosphates, approximately 2% by weight of molecular sieve, such as a zeolite, or of hydrotalcite(s). These compositions find favored application for the manufacture of electrical cables, electrical components, for molding cases in electrical engineering, or for producing protective layers or thermal protection sleeves for automotive fluid transfer lines.
摘要翻译：本发明涉及不含卤素化合物的具有高热机械强度的阻燃柔性热塑性组合物，其包含含有聚酰胺嵌段的接枝共聚物，由聚烯烃骨架和平均至少一个聚酰胺接枝物组成，其中移植物附着于具有能够与胺末端聚酰胺反应的功能的不饱和单体（X）的基团的主链，不饱和单体（X）的基团通过从其双键接枝或共聚而固定在主链上，其中所述组合物包含：含有50重量％至70重量％的含有聚酰胺嵌段的接枝共聚物，25重量％至35重量％的选自磷酸铵，次膦酸盐，焦磷酸盐和多磷酸盐的阻燃剂，约2重量％的分子筛，如沸石，或水滑石。这些组合物可用于制造电缆，电气部件，用于电气工程中的成型箱，或用于生产用于汽车流体输送管线的保护层或热保护套管。

3. 发明申请

US20080085956A1 Fireproof Thermoplastic Compounds, Method for the Production Thereof 审中-公开
标题翻译：防火热塑性化合物，其生产方法
公开(公告)号：US20080085956A1
公开(公告)日：2008-04-10
申请号：US11630237
申请日：2005-07-01
申请人： Christelle Recoquille , Philippe Blondel , Jean-Jacques Flat , Jean-Claude Marais
发明人： Christelle Recoquille , Philippe Blondel , Jean-Jacques Flat , Jean-Claude Marais
IPC分类号： C08K5/3477 , C08L77/00
CPC分类号： C08L77/02 , C08K5/34928 , C08L2205/02 , C08L2666/20 , C08L77/00
摘要： The invention relates to flame-retardant thermoplastic compositions comprising a blend of PA-11 and PA-12 polyamide resins and melamine cyanurate, their method of preparation and their application in the manufacture of industrial articles.
摘要翻译：本发明涉及包含PA-11和PA-12聚酰胺树脂与氰尿酸三聚氰胺的共混物的阻燃热塑性组合物，其制备方法及其在制造工业制品中的应用。

4. 发明授权

US07235604B2 Polyamide- and polyolefin-based fire-retarded compositions 失效
标题翻译：聚酰胺和聚烯烃类阻燃组合物
公开(公告)号：US07235604B2
公开(公告)日：2007-06-26
申请号：US10602005
申请日：2003-06-24
申请人： Philippe Blondel , Benoît Brule , Nicolas Frenois , Jean-Jacques Flat
发明人： Philippe Blondel , Benoît Brule , Nicolas Frenois , Jean-Jacques Flat
IPC分类号： C08K5/523
CPC分类号： C08L77/00 , C08L23/02 , C08L23/04 , C08L23/06 , C08L23/08 , C08L23/0815 , C08L23/0853 , C08L23/10 , C08L51/06 , C08L77/02 , C08L77/06 , C08L2201/02 , C08L2205/03 , C08L2666/02 , C08L2666/14 , C08L2666/84 , C08L51/00 , C08L23/00
摘要： The present invention relates to fire-retarded compositions comprising, by weight, the total being 100 parts: 50 to 75 parts of a blend of a polyamide (A) and a polyolefin (B), 25 to 50 parts of a blend comprising: 0.1 to 48.8 parts of a fire retardant, 0.1 to 30 parts of a phosphorus-containing plasticizer, 0.1 to 10 parts of a zeolite, the total of these three products being between 25 and 50. These compositions have a V0 or V1 classification according to the UL94-VB test when a fire test is carried out on test specimens 1.6 mm in thickness. They have many advantages, in particular the elongation at break measured according to ISO R 527-1B exceeds 100%. As regards the impact strength, they have a non-brittle behaviour in multiaxial impact at room temperature according to ISO 6603-2 (at a rate of 7.7 m/s). They retain at least 50% of their mechanical properties after ageing for seven days at 120° C. in hot air. These compositions are useful for insulating and protecting electrical cables and optical fibres and for moulding electrical cases and connectors.
摘要翻译：本发明涉及阻燃组合物，其包含总重量为100份：50至75份聚酰胺（A）和聚烯烃（B）的共混物，25至50份共混物，其包含：0.1 至48.8份阻燃剂，0.1至30份含磷增塑剂，0.1至10份沸石，这三种产品的总量在25-50之间。这些组合物具有根据本发明的V0或V1分类对在1.6mm厚的试样进行耐火试验时，进行UL94-VB试验。它们具有许多优点，特别是根据ISO R 527-1B测量的断裂伸长率超过100％。关于冲击强度，根据ISO 6603-2（以7.7m / s的速率）在室温下在多轴冲击中具有非脆性。它们在120℃下在热空气中老化7天后，保持其机械性能的至少50％。这些组合物可用于绝缘和保护电缆和光纤以及用于模制电气外壳和连接器。

5. 发明授权

US06432548B1 Compositions based on polyolefins and low-melting-point polyamides 有权
标题翻译：基于聚烯烃和低熔点聚酰胺的组合物
公开(公告)号：US06432548B1
公开(公告)日：2002-08-13
申请号：US09585429
申请日：2000-06-02
申请人： Patrick Alex , Jean-Jacques Flat , Philippe Blondel , Gérard Reignier
发明人： Patrick Alex , Jean-Jacques Flat , Philippe Blondel , Gérard Reignier
IPC分类号： B32B2732
CPC分类号： B32B27/08 , B32B27/306 , B32B27/308 , B32B27/32 , B32B27/34 , B32B2323/04 , B32B2377/00 , B32B2439/00 , C08J5/18 , C08J2377/00 , C08L77/00 , C08L77/02 , C08L77/06 , Y10T428/31743 , Y10T428/31746 , Y10T428/31913 , C08L2666/04 , C08L23/00 , C08L51/00
摘要： The invention relates to compositions containing a polyamide matrix (A) and a polyolefin dispersed phase (B), in which compositions the polyamide has a melting point below that of PA-6 and the dispersed phase consists of at least one polyolefin (B) chosen from functionalized polyolefins (B1) and non-functionalized polyolefins (B2). Advantageously, (A) is PA-6/12 or PA-6/6,6. These compositions are useful for making monolayer or multilayer films by extrusion with EVA or PE.
摘要翻译：本发明涉及含有聚酰胺基质（A）和聚烯烃分散相（B）的组合物，其中聚酰胺的熔点低于PA-6的组成，分散相由至少一种所选择的聚烯烃（B）组成来自官能化聚烯烃（B1）和非官能化聚烯烃（B2）。有利地，（A）是PA-6/12或PA-6 / 6,6。这些组合物可用于通过EVA或PE挤出制备单层或多层膜。

6. 发明申请

US20060008604A1 Multilayer structure having a layer based on polyamide and on HDPE 审中-公开
标题翻译：具有基于聚酰胺和HDPE层的多层结构
公开(公告)号：US20060008604A1
公开(公告)日：2006-01-12
申请号：US11154422
申请日：2005-06-16
申请人： Jean-Jacques Flat , Gaelle Bellet , Benoit Brule , Philippe Blondel
发明人： Jean-Jacques Flat , Gaelle Bellet , Benoit Brule , Philippe Blondel
IPC分类号： B65D1/00
CPC分类号： B32B27/32 , Y10T428/1341 , Y10T428/1383
摘要： The present invention relates to a structure successively comprising: a first layer of high density polyethylene (HDPE), a tie layer, a second layer of EVOH or of a blend based on EVOH, optionally a tie layer, a third layer of a blend comprising, by weight, the total being 100%: 50 to 90% of polyamide (A) having a conversion temperature of at most 230° C., 1 to 30% of high density polyethylene (HDPE), 5 to 30% of an impact modifier chosen from elastomers and very low density polyethylenes, at least one of the HDPE and of the impact modifier being functionalized, in all or part, the layers being coextrudable. The present invention also relates to devices for the transfer or storage of fluids and more particularly to pipes, tanks, conduits, bottles and containers composed of the above structure in which the layer of the blend of polyamide (A) and of HDPE is in direct contact with the fluid present or transported
摘要翻译：本发明涉及一种结构，其连续包括：第一层高密度聚乙烯（HDPE），粘结层，第二层EVOH或基于EVOH的共混物，任选的粘结层，第三层共混物，包括，总重量为100％：转化温度为230℃以下的聚酰胺（A）为50〜90％，高密度聚乙烯（HDPE）为1〜30％，冲击强度为5〜30％选自弹性体和非常低密度聚乙烯的改性剂，HDPE和抗冲改性剂中的至少一种在全部或部分中被共同挤出。本发明还涉及用于转移或储存流体的装置，更具体地涉及由上述结构组成的管，罐，导管，瓶和容器，其中聚酰胺（A）和HDPE的共混物层直接与存在或运输的液体接触

7. 发明授权

US08883899B2 Flame-retarded thermoplastic compositions of high thermomechanical strength, in particular for electric cables 有权
标题翻译：具有高热机械强度的阻燃热塑性组合物，特别是电缆
公开(公告)号：US08883899B2
公开(公告)日：2014-11-11
申请号：US13881491
申请日：2011-10-18
申请人： Dominique Jousset , Jean-Jacques Flat , Pierre Georlette
发明人： Dominique Jousset , Jean-Jacques Flat , Pierre Georlette
IPC分类号： H01B3/44 , F16L57/04 , C08L53/00 , C08G81/02 , C08L87/00 , C08L33/16
CPC分类号： H01B3/447 , C08G81/028 , C08L33/16 , C08L53/00 , C08L87/005 , F16L57/04
摘要： A flame-retarded thermoplastic composition including a graft copolymer containing polyamide blocks and composed of a polyolefin backbone and on average at least one polyamide graft, in which the grafts are attached to the backbone by the residues of an unsaturated monomer (X) having a function capable of reacting with a polyamide, the residues of the unsaturated monomer (X) are attached to the backbone by grafting or copolymerization from its double bond, wherein the composition includes: —between 60% and 70% by weight of the graft copolymer containing polyamide blocks, —between 22% and 28% by weight of poly(pentabromobenzyl acrylate), —between 4% and 8% by weight of a synergistic flame retardant chosen from antimony trioxide, derivatives of tin, of molybdenum and/or bismuth and also boron and zinc oxides, calcium borates, calcium sulphate and/or zinc stannate, between 0.5% and 5% by weight of organophilic treated clay.
摘要翻译：一种阻燃热塑性组合物，其包含含有聚酰胺嵌段的接枝共聚物，由聚烯烃骨架和平均至少一个聚酰胺接枝物组成，其中移植物通过具有功能的不饱和单体（X）的残基连接到主链上能够与聚酰胺反应，不饱和单体（X）的残基通过从其双键接枝或共聚而连接到主链上，其中组合物包括：含有聚酰胺的接枝共聚物的60重量％至70重量％（聚丙烯酸五溴苄酯）的22重量％至28重量％，4重量％至8重量％的协同阻燃剂，其选自三氧化锑，锡，钼和/或铋的衍生物，以及硼和氧化锌，硼酸钙，硫酸钙和/或锡酸锌，占亲水处理粘土的0.5重量％至5重量％。

8. 发明申请

US20100099817A1 FLEXIBLE THERMOPLASTIC COMPOSITION WITH IMPROVED RESISTANCE TO THE EFFECT OF OILS, AND USE OF SUCH A COMPOSITION 有权
标题翻译：具有改善耐油性的柔性热塑性组合物，以及这些组合物的使用
公开(公告)号：US20100099817A1
公开(公告)日：2010-04-22
申请号：US12526097
申请日：2008-02-06
申请人： Stephane Bizet , Jean-Jacques Flat
发明人： Stephane Bizet , Jean-Jacques Flat
IPC分类号： C08L77/00 , C08F287/00
CPC分类号： C08L51/08 , C08F255/00 , C08F255/02 , C08G81/028 , C08L23/0861 , C08L51/06 , C08L2666/24 , C08L2666/20 , C08L2666/02 , C08L2666/04
摘要： The invention relates to a flexible thermoplastic composition resistant to the ageing effects of oil, said composition comprising a grafted copolymer containing polyamide blocks and consisting of a polyolefin backbone and at least one polyamide graft. According to the invention, the grafts are attached to the core by the residues of an unsaturated monomer (X) having a function that can react with a polyamide comprising an amine end or a carboxylic acid end; the residues of the unsaturated monomer (X) are attached to the backbone by grafting or copolymerisation from the double bond thereof; and the composition comprises between 40 to 90 wt % of the polyolefin core comprising the unsaturated monomer (X); between 5 to 40 wt % of polyamide grafts; and between 5 to 40% of at least one polymer selected from a saponified ethylene/vinyl acetate copolymer and a polyamide.
摘要翻译：本发明涉及耐油性的老化作用的柔性热塑性组合物，所述组合物包含含聚酰胺嵌段的接枝共聚物，由聚烯烃骨架和至少一种聚酰胺接枝物组成。根据本发明，移植物通过具有可与包含胺末端或羧酸端的聚酰胺反应的功能的不饱和单体（X）的残基连接到芯上; 不饱和单体（X）的残基通过从其双键接枝或共聚而连接到主链上; 并且所述组合物包含40-90重量％的包含不饱和单体（X）的聚烯烃芯; 5〜40重量％的聚酰胺接枝物; 和5至40％的至少一种选自皂化乙烯/乙酸乙烯酯共聚物和聚酰胺的聚合物。

9. 发明授权

US09579838B2 Method for extruding a polymer in the presence of water 有权
标题翻译：在水存在下挤出聚合物的方法
公开(公告)号：US09579838B2
公开(公告)日：2017-02-28
申请号：US13976640
申请日：2011-12-23
申请人： Frederic Malet , Jean-Jacques Flat , Francois Touchaleaume , Jacques Devaux , Patricia Krawczak , Michel Sclavons , Jeremie Soulestin
发明人： Frederic Malet , Jean-Jacques Flat , Francois Touchaleaume , Jacques Devaux , Patricia Krawczak , Michel Sclavons , Jeremie Soulestin
IPC分类号： B29C47/00 , B29C47/10 , B29C47/80 , C08G63/91 , C08G69/40 , B29C47/76 , B29K77/00 , B29K105/00 , B29K105/16
CPC分类号： B29C47/0071 , B29C47/0004 , B29C47/0011 , B29C47/0019 , B29C47/0023 , B29C47/1045 , B29C47/1063 , B29C47/762 , B29C47/805 , B29K2077/00 , B29K2105/0005 , B29K2105/16 , C08G63/916 , C08G69/40
摘要： The invention relates to a method for converting a polycondensed elastomeric thermoplastic polymer, including a step of extruding the polycondensed elastomeric thermoplastic polymer in the presence of water. The polycondensed elastomeric thermoplastic polymer is in particular chosen from copolymer block amides, copolyethers or copolyester block urethanes, copolyether block esters and the mixtures thereof, and is preferably a copolyether block amide.
摘要翻译：本发明涉及一种用于转化聚缩聚弹性体热塑性聚合物的方法，包括在水存在下挤出缩聚的弹性体热塑性聚合物的步骤。聚缩聚弹性体热塑性聚合物特别地选自共聚物嵌段酰胺，共聚醚或共聚酯嵌段聚氨酯，共聚醚嵌段酯及其混合物，并且优选为共聚醚嵌段酰胺。

10. 发明授权

US08227543B2 Flexible thermoplastic composition with improved resistance to the effect of oils, and use of such a composition 有权
标题翻译：柔性热塑性组合物具有改善的耐油性能，以及使用这种组合物
公开(公告)号：US08227543B2
公开(公告)日：2012-07-24
申请号：US12526097
申请日：2008-02-06
申请人： Stephane Bizet , Jean-Jacques Flat
发明人： Stephane Bizet , Jean-Jacques Flat
IPC分类号： C08G63/48
CPC分类号： C08L51/08 , C08F255/00 , C08F255/02 , C08G81/028 , C08L23/0861 , C08L51/06 , C08L2666/24 , C08L2666/20 , C08L2666/02 , C08L2666/04
摘要： The invention relates to a flexible thermoplastic composition resistant to the ageing effects of oil, said composition comprising a grafted copolymer containing polyamide blocks and consisting of a polyolefin backbone and at least one polyamide graft. According to the invention, the grafts are attached to the core by the residues of an unsaturated monomer (X) having a function that can react with a polyamide comprising an amine end or a carboxylic acid end; the residues of the unsaturated monomer (X) are attached to the backbone by grafting or copolymerization from the double bond thereof; and the composition comprises between 40 to 90 wt % of the polyolefin core comprising the unsaturated monomer (X); between 5 to 40 wt % of polyamide grafts; and between 5 to 40% of at least one polymer selected from a saponified ethylene/vinyl acetate copolymer and a polyamide.
摘要翻译：本发明涉及耐油性的老化作用的柔性热塑性组合物，所述组合物包含含聚酰胺嵌段的接枝共聚物，由聚烯烃骨架和至少一种聚酰胺接枝物组成。根据本发明，移植物通过具有可与包含胺末端或羧酸端的聚酰胺反应的功能的不饱和单体（X）的残基连接到芯上; 不饱和单体（X）的残基通过从其双键接枝或共聚而连接到主链上; 并且所述组合物包含40-90重量％的包含不饱和单体（X）的聚烯烃芯; 5〜40重量％的聚酰胺接枝物; 和5至40％的至少一种选自皂化乙烯/乙酸乙烯酯共聚物和聚酰胺的聚合物。

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