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1. 发明授权

US06818586B2 Hexacoordinated ruthenium or osmium metal carbene metathesis catalysts 有权
标题翻译：六配位钌或锇金属卡宾复分解催化剂
公开(公告)号：US06818586B2
公开(公告)日：2004-11-16
申请号：US10172765
申请日：2002-06-14
申请人： Robert H. Grubbs , Melanie S. Sanford , Jason L. Moore , Jennifer A. Love , Tina M. Trnka
发明人： Robert H. Grubbs , Melanie S. Sanford , Jason L. Moore , Jennifer A. Love , Tina M. Trnka
IPC分类号： B01J3100
CPC分类号： C07C6/04 , B01J23/462 , B01J23/466 , B01J31/181 , B01J31/1815 , B01J31/182 , B01J31/1825 , B01J31/183 , B01J31/2273 , B01J31/28 , B01J2231/14 , B01J2231/543 , B01J2531/821 , B01J2531/825 , C07C6/06 , C07C2531/22 , C07F15/002 , C07F15/0046 , C08G61/06
摘要： The present invention relates to novel hexacoordinated metathesis catalysts and to methods for making and using the same. The inventive catalysts are of the formula wherein: M is ruthenium or osmium; X and X1 are the same or different and are each independently an anionic ligand; L, L1′ and L2 are the same or different and are each independently a neutral electron donor ligand; and, R and R1 are each independently hydrogen or a substituent selected from the group consisting of C1-C20 alkyl, C2-C20 alkenyl, C2-C20 alkynyl, aryl, C1-C20 carboxylate, C1-C20 alkoxy, C2-C20 alkenyloxy, C2-C20 alkynyloxy, aryloxy, C2-C20 alkoxycarbonyl, C1-C20 alkylthio, C1-C20 alkylsulfonyl and C1-C20 alkylsulfinyl and silyl. Optionally, each of the R or R1 substituent group may be substituted with one or more moieties selected from the group consisting of C1-C10 alkyl, C1-C10 alkoxy, and aryl which in turn may each be further substituted with one or more groups selected from a halogen, a C1-C5 alkyl, C1-C5 alkoxy, and phenyl. Moreover, any of the catalyst ligands may further include one or more functional groups. Examples of suitable functional groups include but are not limited to: hydroxyl, thiol, thioether, ketone, aldehyde, ester, ether, amine, imine, amide, nitro, carboxylic acid, disulfide, carbonate, isocyanate, carbodiimide, carboalkoxy, carbamate, halogen, alcohol, sulfonic acid, phosphine, imide, acetal, ketal, boronate, cyano, cyanohydrin, hydrazine, enamine, sulfone, sulfide, and sulfenyl. In certain embodiments, at least one of L, L1′ and L2 is an N-heterocyclic carbene ligand.
摘要翻译：本发明涉及新型六配位复分解催化剂及其制备和使用方法。本发明的催化剂为糠醛：M是钌或锇; X和X 1相同或不同，各自独立地为阴离子配位体; L，L 1和L 2相同或不同并且各自独立地为中性电子给体配体; 和R 1和R 2各自独立地为氢或选自C 1 -C 20烷基，C 2 -C 20烯基，C 2 -C 20炔基，芳基，C 1 -C 20羧酸酯，C 1 -C 20烷氧基， C20链烯氧基，C2-C20炔氧基，芳氧基，C2-C20烷氧基羰基，C1-C20烷硫基，C1-C20烷基磺酰基和C1-C20烷基亚磺酰基和甲硅烷基。任选地，R或R 1取代基中的每一个可以被一个或多个选自以下的部分取代：C 1 -C 10烷基，C 1 -C 10烷氧基和芳基，其又可以进一步被一个或多个更多选自卤素，C 1 -C 5烷基，C 1 -C 5烷氧基和苯基的基团。此外，任何催化剂配体还可以包括一个或多个官能团。合适的官能团的实例包括但不限于：羟基，硫醇，硫醚，酮，醛，酯，醚，胺，亚胺，酰胺，硝基，羧酸，二硫化物，碳酸酯，异氰酸酯，碳二亚胺，碳烷氧基，氨基甲酸酯，卤素醇，磺酸，膦，酰亚胺，缩醛，缩酮，硼酸酯，氰基，氰醇，肼，烯胺，砜，硫化物和亚磺酰基。在某些实施方案中，L，L'和L 2中的至少一个是N-杂环卡宾配体。

2. 发明授权

US06759537B2 Hexacoordinated ruthenium or osmium metal carbene metathesis catalysts 有权
标题翻译：六配位钌或锇金属卡宾复分解催化剂
公开(公告)号：US06759537B2
公开(公告)日：2004-07-06
申请号：US10017489
申请日：2001-12-14
申请人： Robert H. Grubbs , Jennifer A. Love , Melanie S. Sanford , Tina M. Trnka , Jason L. Moore
发明人： Robert H. Grubbs , Jennifer A. Love , Melanie S. Sanford , Tina M. Trnka , Jason L. Moore
IPC分类号： C07D22706
CPC分类号： C08G61/06 , B01J31/181 , B01J31/1815 , B01J31/182 , B01J31/1825 , B01J31/183 , B01J31/2273 , B01J2231/14 , B01J2231/543 , B01J2531/821 , B01J2531/825 , C07C6/04 , C07C6/06 , C07C2531/22 , C07F15/002 , C07F15/0046
摘要： The present invention relates to novel hexacoordinated metathesis catalysts and to methods for making and using the same. The inventive catalysts are of the formula wherein: M is ruthenium or osmium; X and X1 are the same or different and are each independently an anionic ligand; L, L1′ and L2 are the same or different and are each independently a neutral electron donor ligand, wherein at least one L, L1′ and L2 is an N-heterocyclic carbene ligand; and, R and R1 are each independently hydrogen or a substituent selected from the group consisting of C1-C20 alkyl, C2-C20 alkenyl, C2-C20 alkynyl, aryl, C1-C20 carboxylate, C1-C20 alkoxy, C2-C20 alkenyloxy, C2-C20 alkynyloxy, aryloxy, C2-C20 alkoxycarbonyl, C1-C20 alkylthio, C1-C20 alkylsulfonyl and C1-C20 alkylsulfinyl. Optionally, each of the R or R1 substituent group may be substituted with one or more moieties selected from the group consisting of C1-C10 alkyl, C1-C10 alkoxy, and aryl which in turn may each be further substituted with one or more groups selected from a halogen, a C1-C5 alkyl, C1-C5 alkoxy, and phenyl. Moreover, any of the catalyst ligands may further include one or more functional groups. Examples of suitable functional groups include but are not limited to: hydroxyl, thiol, thioether, ketone, aldehyde, ester, ether, amine, imine, amide, nitro, carboxylic acid, disulfide, carbonate, isocyanate, carbodiimide, carboalkoxy, carbamate, and halogen.
摘要翻译：本发明涉及新型六配位复分解催化剂及其制备和使用方法。本发明的催化剂为糠醛：M是钌或锇; X和X 1相同或不同，各自独立地为阴离子配位体; L，L 1和L 2相同或不同并且各自独立地为中性电子给体配体，其中至少一个L，L 1和L 2为N-杂环卡宾配体; 和R 1和R 2各自独立地为氢或选自C 1 -C 20烷基，C 2 -C 20烯基，C 2 -C 20炔基，芳基，C 1 -C 20羧酸酯，C 1 -C 20烷氧基， C20链烯氧基，C2-C20炔氧基，芳氧基，C2-C20烷氧基羰基，C1-C20烷硫基，C1-C20烷基磺酰基和C1-C20烷基亚磺酰基。任选地，R或R 1取代基中的每一个可以被一个或多个选自以下的部分取代：C 1 -C 10烷基，C 1 -C 10烷氧基和芳基，其又可以进一步被一个或多个更多选自卤素，C 1 -C 5烷基，C 1 -C 5烷氧基和苯基的基团。此外，任何催化剂配体还可以包括一个或多个官能团。合适的官能团的实例包括但不限于羟基，硫醇，硫醚，酮，醛，酯，醚，胺，亚胺，酰胺，硝基，羧酸，二硫化物，碳酸酯，异氰酸酯，碳二亚胺，碳烷氧基，氨基甲酸酯和卤素。

3. 发明授权

US06838489B2 High activity metal carbene metathesis catalysts generated using a thermally activated N-heterocyclic carbene precursor 失效
标题翻译：使用热活化的N-杂环卡宾前体产生的高活性金属卡宾复分解催化剂
公开(公告)号：US06838489B2
公开(公告)日：2005-01-04
申请号：US10107531
申请日：2002-03-25
申请人： Andrew Bell , Robert H. Grubbs , John P Morgan , Jason L. Moore
发明人： Andrew Bell , Robert H. Grubbs , John P Morgan , Jason L. Moore
IPC分类号： B01J23/46 , B01J31/18 , B01J31/22 , B01J31/24 , B01J31/28 , C07C6/04 , C07C6/06 , C07F15/00 , C08F2/48 , C08F4/44 , C08F4/80 , C08G61/06 , C08F2/46
CPC分类号： C08G61/06 , B01J23/462 , B01J23/466 , B01J31/2265 , B01J31/2273 , B01J31/24 , B01J31/2404 , B01J31/28 , B01J2231/543 , B01J2531/821 , B01J2531/825 , C07C6/04 , C07C6/06 , C07C2531/22 , C07F15/002 , C07F15/0046
摘要： The invention provides a method for converting a less active or slower to initiate system to a higher activity system so that at the end of a polymerization the most active species is present in the system. The invention generally relates to a process for converting a less active or slower to initiate catalyst system to a higher activity catalyst system wherein the process comprises contacting a protected N-heterocyclic carbene with a metathesis catalyst and an olefin in the presence of energy. One of the benefits of the invention is that the amount of catalyst required is less than or lowered in the presence of the protected N-heterocyclic carbene as compared to the amount of catalyst required in the absence of the protected N-heterocyclic carbene. The protected N-heterocyclic carbene can be unsaturated or saturated. In addition, the invention describes novel ruthenium initiators and methods of making the same.
摘要翻译：本发明提供了一种将较少活性或较慢的引发体系转化为较高活性体系的方法，使得在聚合结束时，最活泼的物质存在于体系中。本发明一般涉及将较不活泼或较慢的引发催化剂体系转化为较高活性的催化剂体系的方法，其中该方法包括在能量存在下使受保护的N-杂环卡宾与易位催化剂和烯烃接触。本发明的优点之一是与不存在受保护的N-杂环卡宾所需的催化剂的量相比，在保护的N-杂环卡宾的存在下所需的催化剂的量小于或降低。受保护的N-杂环卡宾可以是不饱和的或饱和的。此外，本发明描述了新颖的钌引发剂及其制备方法。

4. 发明申请

US20140238713A1 Interactive Tools 审中-公开
标题翻译：互动工具
公开(公告)号：US20140238713A1
公开(公告)日：2014-08-28
申请号：US14269176
申请日：2014-05-04
申请人： Jason L. Moore
发明人： Jason L. Moore
IPC分类号： B23Q17/00
CPC分类号： B23Q17/007 , B25F5/00
摘要： A method includes receiving a first alignment state indication at a portable handheld tool from an alignment tool. The first alignment state indication indicating an alignment state of a workpiece relative to a reference that is independent and distinct from the portable handheld tool. The method also includes, based on the first alignment state indication, enabling a first selectable drive state of a drive system of the portable handheld tool. The method further includes actuating the drive system responsive to user input, where the drive system is limited based, on the first selectable drive state.
摘要翻译：一种方法包括从便携式手持工具从对准工具接收第一对准状态指示。第一对准状态指示指示工件相对于与便携式手持工具独立且不同的参考的对准状态。该方法还包括基于第一对准状态指示，实现便携式手持式工具的驱动系统的第一可选驱动状态。该方法还包括响应于在第一可选驱动状态下基于驱动系统进行限制的用户输入来致动驱动系统。

5. 发明授权

US08584619B2 Electronic livestock feeding station with integral scale assembly 有权
标题翻译：电子家畜饲养站具有一体化秤装配
公开(公告)号：US08584619B2
公开(公告)日：2013-11-19
申请号：US13219595
申请日：2011-08-26
申请人： George R. Eakin , Jason L. Moore , Ronald M. Thibault
发明人： George R. Eakin , Jason L. Moore , Ronald M. Thibault
IPC分类号： A01K1/10
CPC分类号： A01K29/00 , A01K5/0266 , A01K5/0275
摘要： A livestock feeding station includes an entrance raceway, an exit raceway arranged at an angle relative to the entrance raceway, and a feeder located at an intersection between the entrance and exit raceways. A feed dispensing mechanism selectively dispenses an allotted amount of feed into the feeder. A scale assembly having a platform located in the entrance raceway is used to individually weigh animals within the feeding station. The scale assembly includes a hinged scale platform to allow for easy cleaning, and a cantilevered scale platform extension that extends past an end of the entrance raceway and the feeder to provide a weighing platform assembly that continues to hold an entire animal during normal feeding functions. The scale assembly also includes a basket assembly construction to ensure that an accurate weight measurement can be made even if an animal is leaning against a back or front side of the station.
摘要翻译：家畜饲养站包括入口滚道，相对于入口滚道成一定角度布置的出口滚道，以及位于入口和出口滚道之间交叉点处的进料器。进料分配机构选择性地将分配的进料量分配到进料器中。使用具有位于入口滚道中的平台的刻度组件来单独地称重给料台内的动物。标尺组件包括铰链秤台，以便于清洁;以及悬臂式秤台平台延伸部，其延伸越过入口滚道和进料器的端部，以提供在正常进给功能期间继续保持整个动物的称重平台组件。标尺组件还包括篮组件结构，以确保即使动物靠在车站的后侧或前侧也能进行精确的重量测量。

6. 发明申请

US20120241250A1 Aerial Work Platforms and Aerial Work Platform Assemblies Comprised of Polymerized Cycloolefin Monomers 审中-公开
标题翻译：高空作业平台和由聚合环烯烃单体组成的高空作业平台组件
公开(公告)号：US20120241250A1
公开(公告)日：2012-09-27
申请号：US13430608
申请日：2012-03-26
申请人： George R. Eakin , Jason L. Moore
发明人： George R. Eakin , Jason L. Moore
IPC分类号： B66F11/04
CPC分类号： B66F11/044 , B29C37/0032 , B29C2037/0035 , C08G61/08 , C08G2261/3324 , C08G2261/418
摘要： An aerial work platform assembly includes: a) a platform shaft retaining assembly; b) a mounting bracket connected to the platform shaft retaining assembly; and c) a platform connected to the mounting bracket. The platform shaft retaining assembly includes two concentric apertures for installation of a pivot shaft therein; the mounting bracket having an upper gusset member and a center gusset member that are bonded together and that include horizontal portions to which the pivot shaft is bonded; upper and lower platform pins; a valve bracket; a platform bracket; and upper platform pins that provide for pivoting on a lower platform pin and tilting down of the platform thereby. At least one of the platform shaft retaining assembly, the mounting bracket, the platform, the upper and lower platform pins, and the valve bracket are molded from at least one monomer having at least one norbornene functionality, such as polydicyclopentadiene.
摘要翻译：空中工作平台组件包括：a）平台轴保持组件; b）连接到平台轴保持组件的安装支架; 和c）连接到安装支架的平台。平台轴保持组件包括用于在其中安装枢轴的两个同心孔; 所述安装支架具有接合在一起并且包括所述枢转轴所接合的水平部分的上部角撑构件和中心角撑构件; 上下平台销; 阀支架; 平台支架; 以及上平台销，其提供在下平台销上的枢转并且由此平台向下倾斜。平台轴保持组件，安装支架，平台，上下平台销和阀支架中的至少一个由至少一种具有降冰片烯官能团的单体（例如聚二环戊二烯）模制而成。

7. 发明申请

US20120048206A1 ELECTRONIC LIVESTOCK FEEDING STATION WITH INTEGRAL SCALE ASSEMBLY 有权
标题翻译：具有整体尺寸装配的电子畜牧饲料站
公开(公告)号：US20120048206A1
公开(公告)日：2012-03-01
申请号：US13219595
申请日：2011-08-26
申请人： George R. Eakin , Jason L. Moore , Ronald M. Thibault
发明人： George R. Eakin , Jason L. Moore , Ronald M. Thibault
IPC分类号： A01K5/02 , A01K15/04 , A01K5/00
CPC分类号： A01K29/00 , A01K5/0266 , A01K5/0275
摘要： A livestock feeding station includes an entrance raceway, an exit raceway arranged at an angle relative to the entrance raceway, and a feeder located at an intersection between the entrance and exit raceways. A feed dispensing mechanism selectively dispenses an allotted amount of feed into the feeder. A scale assembly having a platform located in the entrance raceway is used to individually weigh animals within the feeding station. The scale assembly includes a hinged scale platform to allow for easy cleaning, and a cantilevered scale platform extension that extends past an end of the entrance raceway and the feeder to provide a weighing platform assembly that continues to hold an entire animal during normal feeding functions. The scale assembly also includes a basket assembly construction to ensure that an accurate weight measurement can be made even if an animal is leaning against a back or front side of the station.
摘要翻译：家畜饲养站包括入口滚道，相对于入口滚道成一定角度布置的出口滚道，以及位于入口和出口滚道之间交叉点处的进料器。进料分配机构选择性地将分配的进料量分配到进料器中。使用具有位于入口滚道中的平台的刻度组件来单独地称重给料台内的动物。标尺组件包括铰链秤台，以便于清洁;以及悬臂式秤台平台延伸部，其延伸越过入口滚道和进料器的端部，以提供在正常进给功能期间继续保持整个动物的称重平台组件。标尺组件还包括篮组件结构，以确保即使动物靠在车站的后侧或前侧也能进行精确的重量测量。

8. 发明授权

US06610626B2 Highly active metathesis catalysts generated in situ from inexpensive and air stable precursors 有权
标题翻译：由廉价和空气稳定的前体原位产生的高活性复分解催化剂
公开(公告)号：US06610626B2
公开(公告)日：2003-08-26
申请号：US09948115
申请日：2001-09-05
申请人： Robert H. Grubbs , Janis Louie , John P. Morgan , Jason L. Moore
发明人： Robert H. Grubbs , Janis Louie , John P. Morgan , Jason L. Moore
IPC分类号： B01J3100
CPC分类号： B01J31/2295 , B01J23/462 , B01J23/466 , B01J31/2265 , B01J31/2273 , B01J2231/14 , B01J2231/543 , B01J2531/821 , B01J2531/825 , C07C6/04 , C07C6/06 , C07C2531/22 , C07F15/002 , C07F15/0046 , C08G61/06
摘要： The invention provides a process for the in-situ generation of a metathesis active catalyst of the formula: comprising contacting an NHC carbene with a dimer of the formula [(arene)MX1X]2 and an alkyne of the formula RC≡CR1 or wherein M is ruthenium or osmium; X and X1 are the same or different and are each independently an anionic ligand; NHC is any N-heterocyclic carbene ligand; R, R1 and R2 are each independently hydrogen or a substituted or unsubstituted substituent selected from the group consisting of C1-C20 alkyl, C2-C20 alkenyl, C2-C20 alkynyl, aryl, C1-C20 carboxylate, C1-C20 alkoxy, C2-C20 alkenyloxy, C2-C20 alkynyloxy, aryloxy, C2-C20 alkoxycarbonyl, C1-C20 alkylthio, C1-C20 alkylsulfonyl and C1-C20 alkylsulfinyl; and R3 is OH. Preferably, the NHC is an s-IMES or IMES carbene ligand; the arene is preferably p-cymene and the alkyne is preferably acetylene. The invention further provides a process for ROMP and RCM reactions using the metathesis active catalysts.
摘要翻译：本发明提供了一种用于原位产生下式的复分解活性催化剂的方法：包括使NHC卡宾与式[（芳烃）MX1X] 2的二聚体和式RC = CR1或其中M是钌的咔啉接触或锇; X和X 1相同或不同，各自独立地为阴离子配体; NHC为任何N-杂环卡宾配体; R 1，R 2和R 2各自独立地为氢或取代或未取代的取代基，所述取代基选自C1 -C 20烷基，C 2 -C 20烯基，C 2 -C 20炔基，芳基，C 1 -C 20羧酸酯，C 1 -C 20烷氧基，C 2 -C 20链烯氧基，C 2 -C 20炔氧基，芳氧基，C 2 -C 20烷氧基羰基，C 1 -C 20烷硫基， C20烷基磺酰基和C1-C20烷基亚磺酰基; 并且R 3是OH。优选地，NHC是s-IMES或IMES卡宾配体; 芳烃优选为对甲基异丙基苯并且炔优选为乙炔。本发明还提供使用复分解活性催化剂的ROMP和RCM反应的方法。

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