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    • 2. 发明授权
    • Method of making a silver halide photographic material having enhanced light absorption and low fog
    • 制备具有增强的光吸收和低雾的卤化银照相材料的方法
    • US06790602B2
    • 2004-09-14
    • US10346745
    • 2003-01-17
    • David R. FosterStephen P. SingerWilliam J. HarrisonAlan R. Pitt
    • David R. FosterStephen P. SingerWilliam J. HarrisonAlan R. Pitt
    • G03C1005
    • G03C1/38G03C1/005G03C1/29G03C7/39216G03C7/39236G03C2001/0854
    • This invention relates to a method of spectrally sensitizing a silver halide emulsion comprising the following steps in the following order a) providing a silver halide emulsion comprising tabular silver halide grains having an inner dye layer adjacent to the silver halide grain, said dye layer comprising at least one dye (Dye 1) that is capable of spectrally sensitizing silver halide, b) adding to the emulsion at least one dye (Dye 2) capable of providing a second dye layer adjacent to the inner dye layer, and c) adding to the emulsion a non-cationic surfactant or a scavenger for oxidized developer, or a combination of the two, to form a silver halide emulsion comprising silver halide grains having associated therewith two dye layers, wherein the dye layers are held together by non-covalent forces or by in situ bond formation; the outer dye layer adsorbs light at equal or higher energy than the inner dye layer; and the energy emission wavelength of the outer dye layer overlaps with the energy absorption wavelength of the inner dye layer.
    • 本发明涉及一种使卤化银乳剂光谱增感的方法,包括以下顺序的以下步骤:a)提供包含具有与卤化银颗粒相邻的内染料层的片状卤化银颗粒的卤化银乳剂,所述染料层至少包含 能够使卤化银光谱增感的一种染料(染料1),b)向该乳液中加入至少一种能够提供与该内部染料层相邻的第二染料层的染料(染料2),以及c)向该乳液中添加 非阳离子表面活性剂或用于氧化显影剂的清除剂或两者的组合,以形成包含与其相关联的两个染料层的卤化银颗粒的卤化银乳剂,其中染料层通过非共价键或通过 原位结合; 外染料层以等于或高于内染料层的能量吸收光; 并且外部染料层的能量发射波长与内部染料层的能量吸收波长重叠。
    • 3. 发明授权
    • Method of making a silver halide photographic material having enhanced light absorption and low fog and containing a scavenger for oxidized developer
    • 制备具有增强的光吸收和低雾并且含有氧化显影剂的清除剂的卤化银照相材料的方法
    • US06794121B2
    • 2004-09-21
    • US10346961
    • 2003-01-17
    • David R. FosterStephen P. SingerWilliam J. HarrisonAlan R. Pitt
    • David R. FosterStephen P. SingerWilliam J. HarrisonAlan R. Pitt
    • G03C518
    • G03C1/29G03C1/005G03C1/38G03C7/39216G03C7/39236G03C2001/0854
    • This invention relates to a method of spectrally sensitizing a silver halide emulsion comprising the following steps in the following order a) providing a silver halide emulsion comprising tabular silver halide grains having an inner dye layer adjacent to the silver halide grain, said dye layer comprising at least one dye (Dye 1) that is capable of spectrally sensitizing silver halide, b) adding to the emulsion at least one dye (Dye 2) capable of providing a second dye layer adjacent to the inner dye layer, and c) adding to the emulsion a non-cationic surfactant or a scavenger for oxidized developer, or a combination of the two, to form a silver halide emulsion comprising silver halide grains having associated therewith two dye layers, wherein the dye layers are held together by non-covalent forces or by in situ bond formation; the outer dye layer adsorbs light at equal or higher energy than the inner dye layer; and the energy emission wavelength of the outer dye layer overlaps with the energy absorption wavelength of the inner dye layer.
    • 本发明涉及一种使卤化银乳剂光谱增感的方法,包括以下顺序的以下步骤:a)提供包含具有与卤化银颗粒相邻的内染料层的片状卤化银颗粒的卤化银乳剂,所述染料层至少包含 能够使卤化银光谱增感的一种染料(染料1),b)向该乳液中加入至少一种能够提供与该内部染料层相邻的第二染料层的染料(染料2),以及c)向该乳液中添加 非阳离子表面活性剂或用于氧化显影剂的清除剂或两者的组合,以形成包含与其相关联的两个染料层的卤化银颗粒的卤化银乳剂,其中染料层通过非共价键或通过 原位结合; 外染料层以等于或高于内染料层的能量吸收光; 并且外部染料层的能量发射波长与内部染料层的能量吸收波长重叠。
    • 4. 发明授权
    • Color photographic material with improved sensitivity
    • 彩色感光材料,灵敏度提高
    • US06811963B2
    • 2004-11-02
    • US10346582
    • 2003-01-17
    • Sharon G. JohnstonStephen P. SingerDrake M. MichnoJames A. FridayDavid R. Foster
    • Sharon G. JohnstonStephen P. SingerDrake M. MichnoJames A. FridayDavid R. Foster
    • G03C146
    • G03C7/39276G03C1/0051G03C1/29G03C7/3022G03C7/3029G03C7/3835G03C7/39244G03C2007/3034
    • This invention relates to a silver halide photographic element comprising a support bearing a cyan dye image-forming unit comprised of at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, and a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of the dye image forming units contains layers of differing sensitivities, and the layer of highest sensitivity contains a development promoting agent or a specific coupler as described herein, or a combination thereof, and a silver halide emulsion comprising tabular silver halide grains having associated therewith at least two dye layers comprising (a) an inner dye layer adjacent to the silver halide grain and comprising at least one dye, Dye 1, that is capable of spectrally sensitizing silver halide and (b) an outer dye layer adjacent to the inner dye layer and comprising at least one dye, Dye 2, wherein the dye layers are held together by more than one non-covalent force; the outer dye layer absorbs light at equal or higher energy than the inner dye layer; and the energy emission wavelength of the outer dye layer overlaps with the energy absorption wavelength of the inner dye layer.
    • 本发明涉及一种卤化银照相元件,其包括载体,该载体具有青色染料成像单元,该单元由至少一种与其相关的感红卤化银乳剂层组成,所述感红卤化银乳剂层具有至少一种形成青色染料的成色剂,品红色成像剂 包含至少一个具有与其相关联的至少一种品红色染料形成成色剂的感绿卤化银乳剂层的黄色染料成像单元和包含至少一种感蓝卤化银乳剂层的黄色染料影像形成单元,所述感蓝卤化银乳剂层具有至少一种黄色 染料形成成色剂,其中至少一种染料成像单元含有不同灵敏度的层,并且最高灵敏度层含有如本文所述的显影促进剂或特定成色剂或其组合,以及卤化银乳剂 包括具有与其相关联的至少两个染料层的片状卤化银颗粒,其包含(a)内部染料层a 与卤化银颗粒相邻并且包含至少一种能够使卤化银光谱增感的染料D染料1和(b)邻近内部染料层的外部染料层,并且包含至少一种染料染料2,染料2 染料层通过多于一种非共价力保持在一起; 外染料层以等于或高于内染料层的能量吸收光; 并且外部染料层的能量发射波长与内部染料层的能量吸收波长重叠。
    • 5. 发明授权
    • Color photographic material with improved sensitivity comprising a pyrazolotriazole coupler
    • 具有改进的灵敏度的彩色照相材料包括吡唑并三唑成色剂
    • US06699652B1
    • 2004-03-02
    • US10346273
    • 2003-01-17
    • Sharon G. JohnstonStephen P. SingerDrake M. MichnoJames A. FridayDavid R. Foster
    • Sharon G. JohnstonStephen P. SingerDrake M. MichnoJames A. FridayDavid R. Foster
    • G03C108
    • G03C1/29G03C1/0051G03C3/00G03C7/3022G03C7/3029G03C7/30541G03C7/30558G03C7/30594G03C7/3835G03C2003/006G03C2007/3034G03C2007/3039
    • This invention relates to a silver halide photographic element comprising a support bearing a cyan dye image-forming unit comprised of at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, and a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of the dye image forming units contains layers of differing sensitivities, and the layer of highest sensitivity contains a development promoting agent or a specific coupler as described herein, or a combination thereof, and a silver halide emulsion comprising tabular silver halide grains having associated therewith at least two dye layers comprising (a) an inner dye layer adjacent to the silver halide grain and comprising at least one dye, Dye 1, that is capable of spectrally sensitizing silver halide and (b) an outer dye layer adjacent to the inner dye layer and comprising at least one dye, Dye 2, wherein the dye layers are held together by more than one non-covalent force; the outer dye layer absorbs light at equal or higher energy than the inner dye layer; and the energy emission wavelength of the outer dye layer overlaps with the energy absorption wavelength of the inner dye layer.
    • 本发明涉及一种卤化银照相元件,其包括载体,该载体具有青色染料成像单元,该单元由至少一种与其相关的感红卤化银乳剂层组成,所述感红卤化银乳剂层具有至少一种形成青色染料的成色剂,品红色成像剂 包含至少一个具有与其相关联的至少一种品红色染料形成成色剂的感绿卤化银乳剂层的黄色染料成像单元和包含至少一种感蓝卤化银乳剂层的黄色染料影像形成单元,所述感蓝卤化银乳剂层具有至少一种黄色 染料形成成色剂,其中至少一种染料成像单元含有不同灵敏度的层,并且最高灵敏度层含有如本文所述的显影促进剂或特定成色剂或其组合,以及卤化银乳剂 包括具有与其相关联的至少两个染料层的片状卤化银颗粒,其包含(a)内部染料层a 与卤化银颗粒相邻并且包含至少一种能够使卤化银光谱增感的染料D染料1和(b)邻近内部染料层的外部染料层,并且包含至少一种染料染料2,染料2 染料层通过多于一种非共价力保持在一起; 外染料层以等于或高于内染料层的能量吸收光; 并且外部染料层的能量发射波长与内部染料层的能量吸收波长重叠。
    • 9. 发明申请
    • COLOR PHOTOGRAPHIC MATERIALS WITH IMPROVED BLUE SENSITIZATION
    • 具有改善蓝色感光度的彩色摄影材料
    • US20110236838A1
    • 2011-09-29
    • US12732328
    • 2010-03-26
    • David R. FosterDrake M. Michno
    • David R. FosterDrake M. Michno
    • G03C7/32G03C7/26
    • G03C7/3022G03C1/29G03C7/39224G03C2001/0055G03C2001/03558G03C2001/091G03C2001/096G03C2007/3034G03C2200/59
    • Color silver halide photographic elements having a yellow dye image-forming unit comprises at least one blue-sensitive silver iodobromide emulsion layer that has silver iodobromide grains. The silver iodobromide grains have initially associated therewith at least two blue spectral sensitizing dye layers comprising: (a) an inner dye layer adjacent the silver iodobromide grains comprising at least one anionic blue spectral sensitizing Dye 1, and (b) an outer dye layer adjacent to the inner dye layer comprising at least one cationic blue spectral sensitizing Dye 2. Dye 2 absorbs light at equal or higher energy than Dye 1. The maximum energy emission wavelength of Dye 2 overlaps but is not exactly corresponding to the maximum energy absorption wavelength of Dye 1. The silver iodobromide grains also have initially associated therewith an amine borane compound and a thiosulfonate compound.
    • 具有黄色染料影像形成单元的彩色卤化银照相元件包括至少一种具有碘溴化银颗粒的蓝色感光性碘溴化银乳剂层。 碘溴化银颗粒最初与其相关联的至少两个蓝色光谱增感染料层包括:(a)与包含至少一种阴离子蓝光谱增感染料1的碘溴化银颗粒相邻的内部染料层,和(b)邻近的染料层 包含至少一种阳离子蓝光谱增感染料2的内染料层。染料2以等于或高于染料1的能量吸收光。染料2的最大能量发射波长重叠但不完全对应于最大能量吸收波长 染料1.碘溴化银颗粒也最初与胺硼烷化合物和硫代磺酸盐化合物相关联。