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1. 发明授权

US06392041B1 Hydroxy-substituted N-alkoxy hindered amines and compositions stabilized therewith 有权
公开(公告)号：US06392041B1
公开(公告)日：2002-05-21
申请号：US09505529
申请日：2000-02-17
申请人： James Peter Galbo , Gerald A. Capocci , Nancy N. Cliff , Robert E. Detlefsen , Michael P. DiFazio , Ramanathan Ravichandran , Peter Solera , Christophe Bulliard
发明人： James Peter Galbo , Gerald A. Capocci , Nancy N. Cliff , Robert E. Detlefsen , Michael P. DiFazio , Ramanathan Ravichandran , Peter Solera , Christophe Bulliard
IPC分类号： C07D40114
CPC分类号： C07D211/94 , C07D211/98
摘要： Hindered amines substituted on the N-atom with an —O—E—OH moiety are particularly effective in stabilizing polyolefin and automotive coating compositions against the deleterious effects of oxidative, thermal and actinic radiation where the presence of the OH group on the compounds adds important properties not attainable by the use of normal —O—E moieties.

2. 发明授权

US06586507B2 Hydroxy-substituted N-alkoxy hindered amines and compositions stabilized therewith 有权
公开(公告)号：US06586507B2
公开(公告)日：2003-07-01
申请号：US09969737
申请日：2001-10-03
申请人： James Peter Galbo , Gerald A. Capocci , Nancy N. Cliff , Robert E. Detlefsen , Michael P. DiFazio , Ramanathan Ravichandran , Peter Solera , Christophe Bulliard
发明人： James Peter Galbo , Gerald A. Capocci , Nancy N. Cliff , Robert E. Detlefsen , Michael P. DiFazio , Ramanathan Ravichandran , Peter Solera , Christophe Bulliard
IPC分类号： C08K53435
CPC分类号： C07D211/94 , C07D211/98
摘要： Hindered amines substituted on the N-atom with an —O—E—OH moiety are particularly effective in stabilizing polyolefin and automotive coating compositions against the deleterious effects of oxidative, thermal and actinic radiation where the presence of the OH group on the compounds adds important properties not attainable by the use of normal —O—E moieties.

3. 发明授权

US06376584B1 Hydroxy-substituted N-alkoxy hindered amines and compositions stabilized therewith 有权
标题翻译：羟基取代的N-烷氧基受阻胺和用其稳定的组合物
公开(公告)号：US06376584B1
公开(公告)日：2002-04-23
申请号：US09794710
申请日：2001-02-27
申请人： James Peter Galbo , Gerald A. Capocci , Nancy N. Cliff , Robert E. Detlefsen , Michael P. DiFazio , Ramanathan Ravichandran , Peter Solera , Christophe Bulliard
发明人： James Peter Galbo , Gerald A. Capocci , Nancy N. Cliff , Robert E. Detlefsen , Michael P. DiFazio , Ramanathan Ravichandran , Peter Solera , Christophe Bulliard
IPC分类号： C08K534
CPC分类号： C07D211/98 , C07D211/94 , C08K5/3435 , C08K5/34926 , C08K5/5442
摘要： Hindered amines substituted on the N-atom with an hydroxy-substituted alkoxy moiety are particularly effective in stabilizing organic polymer compositions against the deleterious effects of oxidative, thermal and actinic radiation where the presence of the OH group on the compounds adds important properties not otherwise attainable.
摘要翻译：在N-原子上被羟基取代的烷氧基部分取代的受阻胺在稳定有机聚合物组合物中抵抗氧化，热和光化辐射的有害影响是特别有效的，其中化合物上的OH基团的存在增加了不可获得的重要性质。

4. 发明授权

US06451887B1 Benzotriazoles containing &agr;-cumyl groups substituted by heteroatoms and compositions stabilized therewith 失效
标题翻译：含有被杂原子取代的α-异丙苯基的苯并三唑和用其稳定的组合物
公开(公告)号：US06451887B1
公开(公告)日：2002-09-17
申请号：US09632216
申请日：2000-08-03
申请人： Mervin G. Wood , Joseph Suhadolnik , Ramanathan Ravichandran , Jacqueline Lau , Carmen Hendricks-Guy , Christophe Bulliard
发明人： Mervin G. Wood , Joseph Suhadolnik , Ramanathan Ravichandran , Jacqueline Lau , Carmen Hendricks-Guy , Christophe Bulliard
IPC分类号： C08K53475
CPC分类号： C08K5/3475 , C07D249/20
摘要： 2H-Benzotriazole UV absorbers substituted at the 3-position and/or the 5-position of the phenyl ring by &agr;-cumyl moiety which is substituted by a heteroatom are particularly photostable in automotive coatings, and are of low color and exhibit low volatility in thermoplastic compositions.
摘要翻译：在苯环的3-位和/或5-位取代的2-苯并三唑UV吸收剂被被杂原子取代的α-枯基部分特别是在汽车涂料中是稳定的，并且颜色低，表现出低挥发性热塑性组合物。

5. 发明授权

US06723846B1 Triazinylaminostilbene derivative as fluorescent whitening agents 失效
标题翻译：三嗪基氨基芪衍生物作为荧光增白剂
公开(公告)号：US06723846B1
公开(公告)日：2004-04-20
申请号：US10070525
申请日：2002-03-06
申请人： Georges Metzger , Serge Hauger , Fabienne Cuesta , Christophe Bulliard , Peter Rohringer , Marc Roger Grienenberger
发明人： Georges Metzger , Serge Hauger , Fabienne Cuesta , Christophe Bulliard , Peter Rohringer , Marc Roger Grienenberger
IPC分类号： C07D25168
CPC分类号： C07D251/68 , Y10S8/919
摘要： The present invention relates to compounds having formula (1): wherein each R1 represents, independently, a linear C1-C4-alkylene residue which is unsubstituted or substituted by hydroxy, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-hydroxy- or alkoxy-alkoxy, —OCOM, —OCOC1-C4-alkyl, or an amino acid residue from which a hydrogen atom on the amino group has been removed; each R2 represents, independently, a linear C1-C4-alkylene residue which is unsubstituted or substituted by hydroxy, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-hydroxy- or alkoxy-alkoxy, —OCOM, —OCOC1-C4-alkyl, —CO2M, CO2C1-C4-alkyl SO3M or phenoxy which is unsubstituted or substituted by halogen, C1-C4-alkyl or C1-C4-alkoxy, —CO2M or CO2C1-C4-alkyl, NH3 or mono- or disubstituted amino; or phenyl which is unsubstituted or substituted by 1 to 3 SO3M, SO2NHC1-C4-alkyl, —SO2NH2, —CO2M, —CO2M, —CO2C1-C4-alkyl, —CONH2, —CONHC1-C4-alkyl, —NHCOC1-C4-alkyl or mono- or disubstituted amino groups; each R3 represents independently, hydrogen, C1-C4-alkyl, halogen, cyano, SO3M, —SO2NH2, SO2NHC1-C4-alkyl, —CO2M, —CO2C1-C4-alkyl, —CONH2, —CONHC1-C4-alkyl, or —NHCOC1-C4-alkyl; M is hydrogen, an alkali metal atom, ammonium or a cation formed from an amine and m is an integer of 1 to 3, a process for their preparation and use of the compounds as optical brightening agents for synthetic or natural organic materials or for removing stain in photographic materials.
摘要翻译：本发明涉及具有式（1）的化合物：其中每个R 1独立地表示未被取代或被羟基，C 1 -C 4烷基，C 1 -C 4烷氧基，C 1 -C 4烷基取代的直链C 1 -C 4亚烷基 - 羟基 - 或烷氧基 - 烷氧基，-OCOM，-OCOC1-C4-烷基或氨基上氨基的氢原子被除去的氨基酸残基; 每个R 2独立地表示未被取代或被羟基，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 羟基 - 或烷氧基 - 烷氧基取代的直链C 1 -C 4 - 亚烷基残基，-OCOM，-OCOC 1 -C 1-4烷基，-CO 2 M，CO 2 C 1 -C 4 - 烷基SO 3 M或苯氧基，其未被取代或被卤素，C 1 -C 4 - 烷基或C 1 -C 4 - 烷氧基，-CO 2 M或CO 2 C 1 -C 4烷基，NH 3或单 - 或二取代氨基; 或未被取代或被1至3个SO 3 M，SO 2 NHC 1 -C 4烷基，-SO 2 NH 2，-CO 2 M，-CO 2 M，-CO 2 C 1 -C 4 - 烷基，-CONH 2，-CONHC 1 -C 4烷基，-NHCOC 1 -C 4 - 烷基或单或二取代的氨基; 每个R 3独立地表示氢，C 1 -C 4 - 烷基，卤素，氰基，SO 3 M，-SO 2 NH 2，SO 2 NHC 1 -C 4烷基，-CO 2 M，

6. 发明授权

US6117997A Hydroxyphenyltriazines 有权
标题翻译：羟基苯基三嗪
公开(公告)号：US6117997A
公开(公告)日：2000-09-12
申请号：US312799
申请日：1999-05-17
申请人： Christophe Bulliard , Thomas Schafer , Christian Zumwald
发明人： Christophe Bulliard , Thomas Schafer , Christian Zumwald
IPC分类号： A61K8/49 , A61Q17/04 , C07D251/24
CPC分类号： C07D251/24 , A61K8/4966 , A61Q17/04
摘要： A description is given of compounds of the formula wherein R and R' independently are H, methyl or ethyl.The novel compounds are effective as stabilizers for organic material against the damaging effect of light, oxygen and heat; they are also suitable for use in skin or hair protection preparations.
摘要翻译：给出下式化合物的描述，其中R和R'独立地是H，甲基或乙基。新型化合物有效地作为有机材料的稳定剂，防止光，氧和热的破坏作用; 它们也适用于皮肤或护发制剂。

7. 发明申请

US20050169859A1 Naphthyltriazines as stabilizers for organic material 有权
标题翻译：萘基三嗪作为有机材料的稳定剂
公开(公告)号：US20050169859A1
公开(公告)日：2005-08-04
申请号：US11098640
申请日：2005-04-04
申请人： Vien Toan , Georges Metzger , Thomas Schafer , Stephane Biry , Christophe Bulliard , Dieter Reinehr , Peter Michaelis
发明人： Vien Toan , Georges Metzger , Thomas Schafer , Stephane Biry , Christophe Bulliard , Dieter Reinehr , Peter Michaelis
IPC分类号： A61K8/00 , A61K8/49 , A61Q5/00 , A61Q19/00 , C07D251/24 , C09K15/30 , A61K7/42 , C07D251/48 , G03C1/005 , G03C1/494
CPC分类号： C07D251/24
摘要： Novel compounds of formula I are described wherein E corresponds to the formula or to the formula and the radicals R1, R2, R11, R22, R′22, R′33 and R′33 are as defined in claim 1. Compounds of formula I are suitable for stabilising organic material, especially plastics materials, surface-coatings, cosmetic preparations, sun protection agents or photographic material, against damage by light, oxygen and/or heat.
摘要翻译：描述了新的式I化合物，其中E对应于式或式，基团R 1，R 2，R 11， R 22，R 22，R 33a和R 33如权利要求1中所定义。式I化合物适用于稳定化有机材料，特别是塑料材料，表面涂层，化妆品制剂，防晒剂或照相材料，防止光，氧和/或热的损害。

8. 发明授权

US06890706B2 Process for removing stain in a photographic material 失效
标题翻译：去除摄影材料污点的方法
公开(公告)号：US06890706B2
公开(公告)日：2005-05-10
申请号：US10301226
申请日：2002-11-20
申请人： Christophe Bulliard , Georges Metzger , Sonia Megert
发明人： Christophe Bulliard , Georges Metzger , Sonia Megert
IPC分类号： G03C7/00 , C07D251/68 , G03C1/775 , G03C1/79 , G03C1/815 , G03C5/305 , G03C7/30 , G03C7/407 , G03C7/413 , G03C7/42 , G03C11/00
CPC分类号： G03C7/413 , G03C1/775 , G03C1/815 , G03C1/8155 , G03C5/305 , G03C7/421 , Y10S430/134
摘要： A process for removing stain in a photographic material is described which process comprises incorporation of at least one compound of the formula (I) wherein X is O or NH; n is 1 or 2, p is 0, 1 or 2, M is hydrogen, an alkali metal atom, ammonium or a cation formed from an amine; each R1, independently, is an aminoacid residue from which a hydrogen atom on the amino group has been removed; each R2, independently, is hydrogen, C1-C8alkyl, C1-C8alkoxy, halogen, cyano, COOR, wherein R is hydrogen or C1-C3alkyl, CONH—R in which R has its previous significance, SO2NH—R in which R has its previous significance, NH—COR in which R has its previous significance, or SO3M, wherein M has its previous significance, or, if n is 1, R2 can also be CO—R3 in which R3 is C1-C3alkyl or phenyl, in that photographic material.
摘要翻译：描述了去除照相材料中污点的方法，该方法包括加入至少一种其中X为O或NH的式（I）化合物; n为1或2，p为0,1或2，M为氢，由胺形成的碱金属原子，铵或阳离子; 每个R 1独立地是氨基上的氢原子被除去的氨基酸残基; 每个R 2独立地是氢，C 1 -C 8烷基，C 1 -C 3 烷氧基，卤素，氰基，COOR，其中R是氢或C 1 -C 3烷基，其中R具有其先前含义的CONH-R ，其中R具有其先前含义的SO 2 NH-R，其中R具有其先前含义的NH-COR，或其中M具有其先前的含义，或者如果n是1，R 2也可以是其中R 3是C 1 H 2的CO-R 3，在这种照相材料中，C 1 -C 3烷基或苯基。

9. 发明授权

US07087753B2 Naphthyltriazines as stabilizers for organic material 有权
标题翻译：萘基三嗪作为有机材料的稳定剂
公开(公告)号：US07087753B2
公开(公告)日：2006-08-08
申请号：US11098640
申请日：2005-04-04
申请人： Vien Van Toan , Georges Metzger , Thomas Schäfer , Stéphane Biry , Christophe Bulliard , Dieter Reinehr , Peter Michaelis
发明人： Vien Van Toan , Georges Metzger , Thomas Schäfer , Stéphane Biry , Christophe Bulliard , Dieter Reinehr , Peter Michaelis
IPC分类号： C07D251/24 , A61K7/42 , G03C1/005
CPC分类号： C07D251/24
摘要： Novel compounds of formula I are described wherein E corresponds to the formula or to the formula and the radicals R1, R2, R11, R22, R′22, R′33 and R′33 are as defined in claim 1. Compounds of formula I are suitable for stabilizing organic material, especially plastics materials, surface-coatings, cosmetic preparations, sun protection agents or photographic material, against damage by light, oxygen and/or heat.
摘要翻译：描述了新的式I化合物，其中E对应于式或式，基团R 1，R 2，R 11， R 22，R 22，R 33和R 33如权利要求1中所定义。式I化合物适用于稳定有机材料，特别是塑料材料，表面涂层，化妆品制剂，防晒剂或照相材料，以防止光，氧和/或热的损害。

10. 发明授权

US06284821B1 Hydroxyphenyltriazines 有权
标题翻译：羟基苯基三嗪
公开(公告)号：US06284821B1
公开(公告)日：2001-09-04
申请号：US09715799
申请日：2000-11-17
申请人： Dietmar Hüglin , Vien Van Toan , Helmut Luther , Christophe Bulliard , Gerhard Rytz
发明人： Dietmar Hüglin , Vien Van Toan , Helmut Luther , Christophe Bulliard , Gerhard Rytz
IPC分类号： C08K534
CPC分类号： A61Q17/04 , A61K8/4966 , C07D251/24 , C09K15/30 , G03C1/8155
摘要： A description is given of compounds of the formula I in which R1 is C1-C18alkyl; C5-C12cycloalkyl; C3-C6alkenyl; phenyl; C1-C18alkyl which is substituted by phenyl, OH, C1-C18alkoxy, C5-C12cycloalkoxy, C3-C18alkenyloxy, halogen, —COOH, —COOR4, —O—CO—R5, —O—CO—O—R6, —CO—NH2, —CO—NHR7, —CO—N(R7)(R8), CN, NH2, NHR7, —N(R7)(R8), —NH—CO—R5, phenoxy, C1-C18alkyl-substituted phenoxy, phenyl-C1-C4alkoxy, C6-C15bicycloalkoxy, C6-C15bicycloalkylalkoxy, C6-C15bicycloalkenylalkoxy, or C6-C15tricycloalkoxy; C5-C12cycloalkyl which is substituted by OH, C1-C4alkyl, C2-C6alkenyl or —O—CO—R5; glycidyl; —CO—R9 or —SO2—R10; or R1 is C3-C50alkyl which is interrupted by one or more oxygen atoms and/or substituted by OH, phenoxy or C7-C18alkylphenoxy; or R1 denotes the specific polymerizable radicals indicated in claim 1; R2 is C6-C18alky1; C2-C6alkenyl; phenyl; C7-C11phenylalkyl; COOR4; CN; NH—CO—R5; halogen; trifluoromethyl; —O—R3; R3 embraces the definitions given for R1; the radicals R11 independently of one another are H; C1-C18alkyl; C3-C6alkenyl; phenyl; C7-C11phenylalkyl; halogen or C1-C18alkoxy, and the remaining radicals embrace the definitions given in claim 1, at least one of the radicals R1, R2 and R11 containing 4 or more carbon atoms. The novel compounds are effective as stabilizers for organic material against the damaging effect of light, oxygen and heat; they are also suitable for use in skin or hair protection preparations.
摘要翻译：给出式Iin化合物的描述，其中R 1是C 1 -C 18烷基; C5-C12环烷基; C 3 -C 6烯基; 苯基; 被苯基，OH，C1-C18烷氧基，C5-C12环烷氧基，C3-C18链烯氧基，卤素，-COOH，-COOR4，-O-CO-R5，-O-CO-O-R6，-CO- NH，-CO-NHR7，-CO-N（R7）（R8），CN，NH2，NHR7，-N（R7）（R8），-NH-CO-R5，苯氧基，C1-C18烷基取代的苯氧基，苯基 C 1 -C 4烷氧基，C 6 -C 15双环烷氧基，C 6 -C 15双环烷基烷氧基或C 6 -C 15三环烷氧基; 被OH，C 1 -C 4烷基，C 2 -C 6烯基或-O-CO-R 5取代的C 5 -C 12环烷基; 缩水甘油基 -CO-R 9或-SO 2 -R 10; 或R1是被一个或多个氧原子中断和/或被OH，苯氧基或C 7 -C 18烷基苯氧基取代的C 3 -C 50烷基;或R 1表示权利要求1所示的特异性可聚合基团; R 2是C 6 -C 18烷基; C 2 -C 6烯基; 苯基; C7-C11苯基烷基; COOR4; CN; NH-CO-R5; 卤素; 三氟甲基 -O-R3; R3包含给定的R 1的定义;基团R 11彼此独立地是H; C1-C18烷基; C 3 -C 6烯基; 苯基; C7-C11苯基烷基; 卤素或C 1 -C 18烷氧基，其余基团包括权利要求1中给出的定义，含有4个或更多个碳原子的基团R 1，R 2和R 11中的至少一个。新型化合物有效地作为有机材料的稳定剂，防止光，氧和热的破坏作用; 它们也适用于皮肤或护发制剂。

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