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1. 发明授权

US4859591A Transamination process for producing amino acids 失效
标题翻译：生产氨基酸的氨基转移过程
公开(公告)号：US4859591A
公开(公告)日：1989-08-22
申请号：US83603
申请日：1987-08-07
申请人： James F. Walter , Martin B. Sherwin
发明人： James F. Walter , Martin B. Sherwin
IPC分类号： C12P13/04
CPC分类号： C12P13/04
摘要： A process is disclosed for catalyzing the transamination of an amino acid precursor to the corresponding L-amino acid by using aspartic acid as the amino donor and by adding certain multivalent metal ions, in the form of solid metal particles or pieces, to the system to catalyze the decomposition of oxalacetic acid, a by-product of the transamination.
摘要翻译：公开了一种通过使用天冬氨酸作为氨基供体催化氨基酸前体向相应的L-氨基酸的氨基转移的方法，并且以固体金属颗粒或片状的形式将某些多价金属离子加入到体系中催化草酰乙酸的分解，这是转氨酶的副产物。

2. 发明授权

US6071850A Multi-layer non-identical catalyst on metal substrate by electrophoretic deposition 失效
标题翻译：通过电泳沉积在金属基底上的多层不相同的催化剂
公开(公告)号：US6071850A
公开(公告)日：2000-06-06
申请号：US62307
申请日：1998-04-17
申请人： Semyon D. Friedman , Martin B. Sherwin , Rasto Brezny , Poovatholil F. Francis
发明人： Semyon D. Friedman , Martin B. Sherwin , Rasto Brezny , Poovatholil F. Francis
IPC分类号： B01J37/02 , B01J37/34 , C25D13/02 , B01J21/04
CPC分类号： C25D13/02 , B01J37/0225 , B01J37/0244 , B01J37/348
摘要： A method for producing by electrophoretic deposition multi-layer, polyfunctional, catalyst members for use in catalytic converters having a plurality of suitably porous and adherent catalyst support coatings of substantially uniform thickness, a plurality of non-identical catalytic agents imbued therein/on, and a flexible metal substrate, are disclosed. Such process involves maintaining electrical interaction between a metal substrate previously coated with catalyst-catalyst support material, the power source, and the electrodes disposed in the electrophoretic deposition ("EPD") cell containing a slurry of a second catalyst support material and a second catalyst composition non-identical to that found in the first catalytically-active layer.
摘要翻译：一种通过电泳沉积多层多功能催化剂构件制备的方法，用于催化转化器，其具有多个基本上均匀厚度的适当多孔和粘附的催化剂载体涂层，多个不相同的催化剂在其中/其上，以及公开了柔性金属基底。这种方法包括保持预先涂覆有催化剂 - 催化剂载体材料的金属基底，电源和设置在电泳沉积（“EPD”）电池中的电极之间的电相互作用，该电池含有第二催化剂载体材料和第二催化剂组成与在第一催化活性层中发现的组成不同。

3. 发明授权

US4404417A Isomerization 失效
标题翻译：异构化
公开(公告)号：US4404417A
公开(公告)日：1983-09-13
申请号：US286643
申请日：1981-07-24
申请人： John R. Adams , Abraham P. Gelbein , Robert Hansen , Jimmy Y. Peress , Martin B. Sherwin
发明人： John R. Adams , Abraham P. Gelbein , Robert Hansen , Jimmy Y. Peress , Martin B. Sherwin
IPC分类号： B01J21/04 , B01J23/00 , B01J27/00 , B01J31/00 , B01J35/10 , B01J37/24 , C07B61/00 , C07C1/00 , C07C5/27 , C07C11/02 , C07C67/00
CPC分类号： B01J37/24 , B01J21/04 , B01J35/10 , C07C5/2772 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J35/1085
摘要： A process is provided for the skeletal isomerization of straight chain olefins to branched chain olefins by contact at an elevated temperature with a chlorine- or fluorine-containing compound activated alumina catalyst, the alumina having an average particle size of from about 0.5.times.10.sup.-3 cm to about 160.times.10.sup.-3 cm and from 3 to 9% of the pore volume being attributable to pores having radii from about 100 to about 10,000 Angstroms.
摘要翻译：提供了一种通过在高温下与含氯或含氟化合物活性氧化铝催化剂接触将直链烯烃骨架异构化成支链烯烃的方法，该氧化铝的平均粒度为约0.5×10 -3 cm至约160×10 -3 cm和3至9％的孔体积可归因于具有约100至约10,000埃的半径的孔。

4. 发明授权

US4517393A Preparation of nitro compounds by vapor phase nitration of ketones 失效
标题翻译：通过气相硝化酮制备硝基化合物
公开(公告)号：US4517393A
公开(公告)日：1985-05-14
申请号：US563208
申请日：1983-12-19
申请人： Shu-Shieh P. Wang , Martin B. Sherwin
发明人： Shu-Shieh P. Wang , Martin B. Sherwin
IPC分类号： C07C45/29 , C07C201/14 , C07C201/16 , C07C205/02 , C07C79/02
CPC分类号： C07C45/29 , C07C201/14 , C07C201/16
摘要： A process for selectively forming nitro compounds by contacting, at elevated temperature and pressure and in a homogeneous gas phase, a ketone having from three to ten carbon atoms with nitrogen dioxide alone or in the presence of oxygen and/or water.
摘要翻译：通过在升高的温度和压力下，均匀气相中将具有3至10个碳原子的酮与单独的二氧化氮或在氧气和/或水的存在下接触来选择性地形成硝基化合物的方法。

5. 发明授权

US4469904A Preparation of nitro compounds by vapor phase nitration of carboxylic acids 失效
标题翻译：通过气相硝化羧酸制备硝基化合物
公开(公告)号：US4469904A
公开(公告)日：1984-09-04
申请号：US510858
申请日：1983-07-05
申请人： Shu-Chieh P. Wang , Martin B. Sherwin
发明人： Shu-Chieh P. Wang , Martin B. Sherwin
IPC分类号： C07C201/14 , C07C205/02 , C07C205/06 , C07C76/02 , C07C79/10
CPC分类号： C07C201/06
摘要： A process for selectively forming nitro compounds by contacting, at elevated temperature and pressure and in a homogeneous gas phase, an organic carboxylic acid having from two to ten carbon atoms with NO.sub.2 or HNO.sub.3 alone or in the presence of oxygen and/or water.
摘要翻译：在升高的温度和压力下，在均相气相中，将具有2-10个碳原子的有机羧酸与NO 2或HNO 3单独或在氧和/或水的存在下接触来选择性地形成硝基化合物的方法。

6. 发明授权

US5288907A Hydrogenation of nitroalkanes to hydroxylamines 失效
标题翻译：硝基烷烃氢化成羟胺
公开(公告)号：US5288907A
公开(公告)日：1994-02-22
申请号：US784850
申请日：1991-10-30
申请人： Martin B. Sherwin , Puvin Pichaichanarong
发明人： Martin B. Sherwin , Puvin Pichaichanarong
IPC分类号： C02F1/20 , C07C239/10 , C23F11/14 , C07C239/08
CPC分类号： C23F11/147 , C02F1/20 , C07C239/10
摘要： Catalytic hydrogenation of nitroalkane to N-alkylhydroxylamine free base in the absence of transition metal ions, and omission of acid and the resultant free base is storage stable, permitting shipment and storage of 15% aqueous solution for use as oxygen scavenger in boiler feed water treatment.
摘要翻译：在不存在过渡金属离子的情况下将硝基烷烃催化氢化为N-烷基羟胺游离碱，省略酸和得到的游离碱保存稳定，允许运输和储存15％水溶液，用作锅炉给水处理中的除氧剂。

7. 发明授权

US5023371A Synthesis of thioglycolic acid 失效
标题翻译：巯基乙酸的合成
公开(公告)号：US5023371A
公开(公告)日：1991-06-11
申请号：US53976
申请日：1987-05-26
申请人： Mosum E. Tsui , Martin B. Sherwin
发明人： Mosum E. Tsui , Martin B. Sherwin
IPC分类号： C07C319/02 , C07C319/06 , C07C323/52
CPC分类号： C07C319/02 , C07C319/06
摘要： A process for forming thioglycolic acid by contacting in a reaction zone at elevated pressure of at least 250 psig a mixture of monochloroacetic acid and dichloroacetic acid with a molar excess of an alkali metal hydrosulfide to form the alkali metal salt of thioglycolic acid, acidifying said salt and removing the free thioglycolic acid. A preferred process further requires separating any formed thiodiglycolic acid from the resultant liquid phase materials and recycling said acid to the reaction zone.
摘要翻译：通过在反应区中以至少250psig的升高的压力使一氯乙酸和二氯乙酸的混合物与摩尔过量的碱金属氢硫化物接触以形成巯基乙酸的方法以形成巯基乙酸的碱金属盐，酸化所述盐并除去游离巯基乙酸。优选的方法还需要从所得液相材料中分离任何形成的硫二甘醇酸并将所述酸再循环到反应区。

8. 发明授权

US4895971A Process for the production of iminodiacetonitrile 失效
标题翻译：亚氨基乙腈生产工艺
公开(公告)号：US4895971A
公开(公告)日：1990-01-23
申请号：US264413
申请日：1988-10-31
申请人： Jow-Lih Su , Martin B. Sherwin
发明人： Jow-Lih Su , Martin B. Sherwin
IPC分类号： C07C255/25
CPC分类号： C07C255/25 , Y02P20/125
摘要： This invention relates to the production of iminodiacetonitrile, and more specifically to an integrated process wherein a crude, unpurified reactor gas stream from a hydrogen cyanide reactor and optionally, a crude, unpurified reactor gas stream from a formaldehyde process reactor are fed directly to a reactive absorber together with additional ammonia and acidified water to produce iminodiacetonitrile in high yields. This process provides improved economics for producing iminodiacetonitrile by eliminating costly intermediate recovery and purification processes associated with conventional hydrogen cyanide and formaldehyde production processes.

9. 发明授权

US4158100A Process for the preparation of .beta.-phenylethyl alcohol via homologation 失效
标题翻译：通过同系制备{62-苯基乙醇的方法
公开(公告)号：US4158100A
公开(公告)日：1979-06-12
申请号：US850209
申请日：1977-11-10
申请人： Martin B. Sherwin , Arthur M. Brownstein
发明人： Martin B. Sherwin , Arthur M. Brownstein
IPC分类号： B01J23/89 , B01J27/08 , B01J31/00 , C07B61/00 , C07C27/00 , C07C29/32 , C07C33/22 , C07C67/00 , C07C29/00
CPC分类号： B01J27/08 , B01J23/8913 , C07C29/32
摘要： .beta.-Phenylethyl alcohol is prepared by the homologation of benzyl alcohol with hydrogen and carbon monoxide in the presence of a cobalt catalyst promoted with ruthenium and iodine compounds, in the presence of water at a temperature from 100.degree. to 165.degree. C. High yields and selectivity of the .beta.-phenylethyl alcohol are obtained.
摘要翻译：在100℃至165℃的温度存在下，在用钌和碘化合物促进的钴催化剂的存在下，通过与氢气和一氧化碳同时化苄基醇制备β-苯乙醇。高产率和得到β-苯乙醇的选择性。

10. 发明授权

US4012424A Cracking of mixtures containing hydroxyesters 失效
标题翻译：含羟基酯的混合物开裂
公开(公告)号：US4012424A
公开(公告)日：1977-03-15
申请号：US602738
申请日：1975-08-07
申请人： Martin B. Sherwin , Jimmy Peress
发明人： Martin B. Sherwin , Jimmy Peress
IPC分类号： C07D301/02
CPC分类号： C07D301/02
摘要： This invention concerns the preparation of oxirane compounds by the vapor phase cracking of hydroxyesters in the presence of a basic material. Specifically, it has been discovered that the aforesaid reaction may be carried out without the prior separation of vicinal glycols, vicinal diesters or both. This is particularly advantageous because vicinal hydroxyesters are frequently formed in combination with these latter materials and the separation thereof is most difficult. Preferably, mixtures of the hydroxyesters, glycols and diesters are first hydrolyzed or esterified in order to increase the hydroxyester content.
摘要翻译：本发明涉及在碱性物质存在下通过羟基酯的气相裂解来制备环氧乙烷化合物。具体地说，已经发现上述反应可以在没有先前分离连二醇，连位二酯或两者的情况下进行。这是特别有利的，因为邻位羟基酯经常与这些后者材料组合形成，并且其分离是最困难的。优选地，羟基酯，二醇和二酯的混合物首先水解或酯化以增加羟基酯含量。

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