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1. 发明授权

US09291390B2 Process for producing purified synthesis gas 有权
标题翻译：纯化合成气的制备方法
公开(公告)号：US09291390B2
公开(公告)日：2016-03-22
申请号：US14116142
申请日：2012-05-10
申请人： Jacobus Eilers , Arjan Allert Jonckers , Leendert Johannes Arie Zoetemeijer
发明人： Jacobus Eilers , Arjan Allert Jonckers , Leendert Johannes Arie Zoetemeijer
IPC分类号： B01D47/00 , B01D53/14 , F25J3/08 , C10J3/00 , C10K1/00 , C10K1/04 , C10K1/10
CPC分类号： F25J3/08 , C10J3/00 , C10J2300/1884 , C10J2300/1892 , C10K1/003 , C10K1/04 , C10K1/101
摘要： Process for producing purified synthesis gas from soot-containing synthesis gas having a temperature of at least 5° C. above its dew point comprising the steps of (a) cooling the soot-containing synthesis gas to a temperature below its dew point by indirect heat exchange in a shell-tube heat exchanger without removing the condensate formed, thereby forming a synthesis gas/condensate mixture; and (b) contacting the synthesis gas/condensate mixture with a scrubbing liquid to remove the condensate resulting in a purified synthesis gas and used scrubbing liquid, wherein the soot-containing synthesis gas in step (a) is passed through the shell-tube heat exchanger at the tube side.
摘要翻译：从含有至少5℃以上温度的含有烟灰的合成气生产纯化合成气的方法，包括以下步骤：（a）通过间接加热将含烟灰的合成气冷却至低于露点的温度在壳管式热交换器中进行交换而不去除形成的冷凝物，从而形成合成气/冷凝物混合物; 和（b）使合成气/冷凝物混合物与洗涤液接触以除去冷凝物，得到纯化的合成气和使用的洗涤液，其中步骤（a）中含烟灰的合成气通过壳管热交换器在管侧。

2. 发明申请

US20140331715A1 PROCESS FOR PRODUCING PURIFIED SYNTHESIS GAS 有权
标题翻译：生产纯化合成气的方法
公开(公告)号：US20140331715A1
公开(公告)日：2014-11-13
申请号：US14116142
申请日：2012-05-10
申请人： Jacobus Eilers , Arjan Allert Jonckers , Leendert Johannes Arie Zoetemeijer
发明人： Jacobus Eilers , Arjan Allert Jonckers , Leendert Johannes Arie Zoetemeijer
IPC分类号： F25J3/08
CPC分类号： F25J3/08 , C10J3/00 , C10J2300/1884 , C10J2300/1892 , C10K1/003 , C10K1/04 , C10K1/101
摘要： Process for producing purified synthesis gas from soot-containing synthesis gas having a temperature of at least 5° C. above its dew point comprising the steps of (a) cooling the soot-containing synthesis gas to a temperature below its dew point by indirect heat exchange in a shell-tube heat exchanger without removing the condensate formed, thereby forming a synthesis gas/condensate mixture; and (b) contacting the synthesis gas/condensate mixture with a scrubbing liquid to remove the condensate resulting in a purified synthesis gas and used scrubbing liquid, wherein the soot-containing synthesis gas in step (a) is passed through the shell-tube heat exchanger at the tube side.
摘要翻译：从含有至少5℃以上温度的含有烟灰的合成气生产纯化合成气的方法，包括以下步骤：（a）通过间接加热将含烟灰的合成气冷却至低于露点的温度在壳管式热交换器中进行交换而不去除形成的冷凝物，从而形成合成气/冷凝物混合物; 和（b）使合成气/冷凝物混合物与洗涤液接触以除去冷凝物，得到纯化的合成气和使用的洗涤液，其中步骤（a）中含烟灰的合成气通过壳管热交换器在管侧。

3. 发明授权

US5286455A Process for the preparation of hydrocarbons 失效
标题翻译：烃类制备方法
公开(公告)号：US5286455A
公开(公告)日：1994-02-15
申请号：US995120
申请日：1992-12-22
申请人： Jacobus Eilers , Sytze A. Posthuma , Pieter J. Hoek
发明人： Jacobus Eilers , Sytze A. Posthuma , Pieter J. Hoek
IPC分类号： B01J8/06 , C10G2/00 , G05D7/00 , B01S8/06
CPC分类号： C10G2/34 , B01J8/06
摘要： Hydrocarbons are prepared from a feed gas of hydrogen and carbon monoxide by feeding the feed gas into a reaction zone at an elevated temperature and pressure and allowing the hydrogen and carbon monoxide to react in the presence of a catalyst retained in the reaction zone to yield hydrocarbons. A reservoir of a hydrogen-rich gas is maintained at a pressure above the pressure of the feed gas, the reservoir and the reaction zone being connected in such a way that a continuous flow of hydrogen-rich gas is maintained from the reservoir into the reaction zone. A reactor in use in the preparation is shutdown by interrupting the feeding of the feed gas, thereby allowing hydrogen-rich gas to flow from the reservoir at increased rate and quench the reactions occurring in the reaction zone.
摘要翻译：通过将氢气和一氧化碳的进料气体通过将进料气体在升高的温度和压力下进料到反应区中并使氢气和一氧化碳在保留在反应区中的催化剂存在下反应以产生烃，从而制备碳氢化合物。富氢气体的储存器保持在高于进料气体压力的压力下，储存器和反应区域以这样的方式连接，使得从储存器保持连续的富氢气体流进入反应区。在制备中使用的反应器通过中断进料气体的进料来关闭，从而使富氢气体以增加的速率从储存器流出并淬灭在反应区域中发生的反应。

4. 发明申请

US20070213414A1 PROCESS TO PREPARE A FISCHER-TROPSCH SYNTHESIS PRODUCT 有权
标题翻译：制备FISCHER-TROPSCH SYNTHESIS产品的方法
公开(公告)号：US20070213414A1
公开(公告)日：2007-09-13
申请号：US11682351
申请日：2007-03-06
申请人： Jacobus Eilers , Robert Schouwenaar
发明人： Jacobus Eilers , Robert Schouwenaar
IPC分类号： C07C27/06
CPC分类号： C10G2/00 , C01B3/36 , C01B3/382 , C01B3/52 , C01B2203/0216 , C01B2203/0255 , C01B2203/0415 , C01B2203/0485 , C01B2203/062 , C01B2203/0827 , C01B2203/1241 , C01B2203/142 , C01B2203/148 , C01B2203/1614 , C01B2203/169 , C10G2300/1022 , C10G2300/4081 , C10G2400/06
摘要： The invention provides a process to prepare a Fischer-Tropsch synthesis product from a gaseous mixture of hydrocarbons comprising methane, ethane and optional higher carbon number hydrocarbons comprising the steps of: (a) pre-reforming the hydrocarbon mixture adiabatically, (b) heating the gaseous mixture obtained in step (a) to a temperature greater than 650° C., (c) performing a non-catalyzed partial oxidation by contacting the heated mixture of step (b) yielding a reactor effluent having a temperature of between 1100 and 1500 ° C., (d) performing a Fischer-Tropsch synthesis using the hydrogen- and carbon monoxide-containing gas as obtained in step (c) as feedstock and (e) wherein from the synthesis product obtained in step (d) a relatively light stream is separated and wherein a first part of the light stream is recycled to step (a) to be subjected to pre-reforming and wherein a second part of the light stream is recycled to the burner of step (c) to be subjected to partial oxidation and wherein the temperature in step (a) is controlled by the adjusting the amount of light stream that is recycled to step (a).
摘要翻译：本发明提供了一种从包含甲烷，乙烷和任选的较高碳数烃的烃的气体混合物制备费 - 托合成产物的方法，包括以下步骤：（a）绝热地预先重整烃混合物，（b）步骤（a）中获得的气态混合物至大于650℃的温度，（c）通过使加热的步骤（b）的混合物接触而进行非催化部分氧化，产生温度为1100至1500℃的反应器流出物 ℃，（d）使用步骤（c）中获得的含氢和一氧化碳的气体作为原料进行费 - 托合成，（e）其中从步骤（d）中获得的合成产物相对较轻流分离，并且其中轻流的第一部分被再循环到步骤（a）以进行预重整，并且其中轻流的第二部分被再循环到步骤（c）的燃烧器以进行部分氧化物离子，并且其中步骤（a）中的温度通过调节再循环到步骤（a）的轻质流量来控制。

5. 发明授权

US08052864B2 Process to prepare a sweet crude 有权
标题翻译：制备甜味原油的过程
公开(公告)号：US08052864B2
公开(公告)日：2011-11-08
申请号：US11947641
申请日：2007-11-29
申请人： Jacobus Eilers , Johannes Cornelis De Jong , Franciscus Johanna Arnoldus Martens
发明人： Jacobus Eilers , Johannes Cornelis De Jong , Franciscus Johanna Arnoldus Martens
IPC分类号： C10G67/04 , C10G1/02
CPC分类号： C10G67/04 , C01B3/36 , C01B3/48 , C01B2203/0255 , C01B2203/0283 , C01B2203/043 , C01B2203/0475 , C01B2203/0485 , C01B2203/049 , C01B2203/06 , C01B2203/0877 , C01B2203/0894 , C01B2203/1252 , C01B2203/127 , C01B2203/84 , C01B2203/86 , C10J3/485 , C10J3/66 , C10J3/721 , C10J3/76 , C10J3/845 , C10J2300/1223 , C10J2300/1621 , C10J2300/165 , C10J2300/1678 , C10K1/004 , C10K1/02 , C10K1/08 , C10K1/101 , C10K3/04 , Y02P30/30
摘要： A process to prepare a sweet crude from an ash containing and heavy fraction of a tar sand oil comprising supplying an atmospheric distillation bottoms of a tar sands originated feed to a vacuum distillation to obtain a vacuum gas oil and a vacuum bottoms and contacting the vacuum gas oil with hydrogen to obtain a sweet synthetic crude. The vacuum bottoms obtained are separated into an asphalt fraction comprising between 0.1 and 4 wt % ash and a de-asphalted oil and the asphalt fraction is fed to a burner of a gasification reactor to obtain a mixture of hydrogen and carbon monoxide on which a water gas shift reaction is performed. Hydrogen sulphide and carbon dioxide are separated from the shifted gas in an acid removal unit thereby obtaining crude hydrogen which is purified and used to obtain the sweet synthetic crude. The asphalt fraction is provided to the burner in a liquid state and wherein in case the separation step fails to provide sufficient feed for the gasification reactor, vacuum bottoms from the first step are fed to the burner in a liquid state.
摘要翻译：一种从含灰分和重馏分的焦油砂油中制备甜味粗品的方法，包括将来自焦油砂原料的进料的常压蒸馏塔底物进行真空蒸馏以获得真空瓦斯油和真空塔底，并使真空气体油与氢气获得甜味的合成原油。将获得的真空塔底物分离成包含0.1至4重量％灰分和脱沥青油的沥青部分，并将沥青部分进料至气化反应器的燃烧器以获得氢和一氧化碳的混合物，其上加入水进行气体转换反应。在除酸单元中将硫化氢和二氧化碳与转移的气体分离，从而获得纯化的粗氢，并用于获得甜的合成原油。将沥青馏分以液态提供给燃烧器，并且其中在分离步骤不能为气化反应器提供足够的进料的情况下，来自第一步骤的真空塔底物以液态进料到燃烧器。

6. 发明授权

US5371308A Process for the preparation of lower olefins 失效
标题翻译：低级烯烃的制备方法
公开(公告)号：US5371308A
公开(公告)日：1994-12-06
申请号：US111797
申请日：1993-08-25
申请人： John W. Gosselink , Jacobus Eilers
发明人： John W. Gosselink , Jacobus Eilers
IPC分类号： B01J23/74 , C07B61/00 , C07C1/04 , C07C4/04 , C07C11/02 , C10G2/00 , C10G9/36 , C10G69/06
CPC分类号： C07C1/0485 , C10G2400/20 , Y10S208/95 , Y10S585/93
摘要： A process for preparing lower olefins from a hydrocarbon feed having at least a fraction boiling above the boiling point range of the lower olefins, which process includes thermal cracking of the hydrocarbon feed, wherein at least part of the hydrocarbon feed is a hydroprocessed synthetic oil fraction. The hydroprocessed synthetic oil fraction may be prepared by hydrogenation and/or hydroconversion and/or hydrocracking of a synthetic oil fraction.
摘要翻译：从具有至少沸点高于低级烯烃的沸点范围的馏分的烃原料制备低级烯烃的方法，该方法包括烃进料的热裂解，其中至少部分烃进料是加氢合成油馏分。加氢合成油馏分可以通过合成油馏分的氢化和/或加氢转化和/或加氢裂化来制备。

7. 发明申请

US20090224209A1 PROCESS TO PREPARE A MIXTURE OF HYDROGEN AND CARBON MONOXIDE 审中-公开
标题翻译：制备氢氧化镁和一氧化碳混合物的方法
公开(公告)号：US20090224209A1
公开(公告)日：2009-09-10
申请号：US12274227
申请日：2008-11-19
申请人： Jacobus Eilers , Martin John Fernie , Herman Pieter Charles Eduard Kuipers
发明人： Jacobus Eilers , Martin John Fernie , Herman Pieter Charles Eduard Kuipers
IPC分类号： C01B3/36 , C09C1/48
CPC分类号： C01B3/36 , C10K1/024
摘要： A process to prepare a mixture of hydrogen and carbon monoxide from a methane containing gaseous feed by performing the following steps, (a) performing a partial oxidation by contacting the feed with an oxygen containing gas to prepare a gaseous mixture comprising hydrogen, carbon monoxide, steam, carbon dioxide, methane and soot particles said mixture having an elevated temperature, (b) passing the gaseous mixture of step (a) through a filter where the soot particles are retained on the filter and a mixture comprising hydrogen, carbon monoxide, carbon dioxide, methane poor in soot is obtained wherein the filter is a ceramic foam filter or a ceramic wall-flow filter, and (c) converting the retained soot particles at the elevated temperature to carbon oxide.
摘要翻译：一种通过进行以下步骤从含甲烷的气态原料制备氢气和一氧化碳的混合物的方法，（a）通过使进料与含氧气体接触来进行部分氧化，以制备包含氢气，一氧化碳，蒸汽，二氧化碳，甲烷和烟灰颗粒，所述混合物具有升高的温度，（b）使步骤（a）的气体混合物通过过滤器，其中烟灰颗粒保留在过滤器上，并且包含氢，一氧化碳，碳二氧化碳，得到烟灰不足的甲烷，其中过滤器是陶瓷泡沫过滤器或陶瓷壁流过滤器，和（c）将高温下保留的烟灰颗粒转化为碳氧化物。

8. 发明授权

US4397734A Process for reducing ramsbottom carbon test of short residues 失效
标题翻译：用于减少短残留物的短片碳测试的方法
公开(公告)号：US4397734A
公开(公告)日：1983-08-09
申请号：US388778
申请日：1982-06-15
申请人： Jacobus Eilers , Willem H. J. Stork
发明人： Jacobus Eilers , Willem H. J. Stork
IPC分类号： C10G45/08 , C10G67/04
CPC分类号： C10G45/08 , C10G2300/107
摘要： Process for the preparation of a heavy oil with a low Ramsbottom Carbon Test (RCT) from a short residue by (a) catalytic hydrotreatment for RCT reduction at such severity that the C.sub.4.sup.- gas production per percentage RCT reduction is kept between defined limits, followed by (b) solvent deasphalting of the (vacuum or atmospheric) distillation residue of the hydrotreated product.
摘要翻译：通过（a）用于RCT降低的催化加氢处理，以使得每单位RCT降低的C4气体产量保持在确定的限度之间的严重程度，从短残留物制备具有低Ramsbottom碳测试（RCT）的重油的方法，随后通过（b）加氢处理产物的（真空或大气）蒸馏残余物的溶剂脱沥青。

9. 发明授权

US4396493A Process for reducing ramsbottom test of short residues 失效
标题翻译：用于减少短残留物的短裤试验的方法
公开(公告)号：US4396493A
公开(公告)日：1983-08-02
申请号：US391810
申请日：1982-06-24
申请人： Jacobus Eilers , Willem H. J. Stork
发明人： Jacobus Eilers , Willem H. J. Stork
IPC分类号： C10G67/04
CPC分类号： C10G67/0463 , C10G2300/107
摘要： In the preparation of a heavy oil with a low Ramsbottom Carbon Test (RCT) from a short residue by a two-stage process comprising catalytic hydrotreatment followed by solvent deasphalting and recycle of the asphalt to the first stage, the catalytic hydrotreatment for RCT reduction in the first stage is carried out at such severity that the C.sub.4.sup.- production per percent RCT reduction is kept between defined limits.
摘要翻译：在通过包括催化加氢处理，然后溶剂脱沥青和沥青再循环到第一阶段的两阶段方法从短的残留物制备具有低残留量的Ramsbottom碳测试（RCT）的重油的情况下，用于RCT降低的催化加氢处理第一阶段的进行情况使得C4生产每百分比RCT降低保持在限定的限度之间。

10. 发明授权

US07795317B2 Process to prepare a Fischer-Tropsch synthesis product 有权
标题翻译：制备费 - 托合成产物的方法
公开(公告)号：US07795317B2
公开(公告)日：2010-09-14
申请号：US11682351
申请日：2007-03-06
申请人： Jacobus Eilers , Robert Schouwenaar
发明人： Jacobus Eilers , Robert Schouwenaar
IPC分类号： C07C27/00
CPC分类号： C10G2/00 , C01B3/36 , C01B3/382 , C01B3/52 , C01B2203/0216 , C01B2203/0255 , C01B2203/0415 , C01B2203/0485 , C01B2203/062 , C01B2203/0827 , C01B2203/1241 , C01B2203/142 , C01B2203/148 , C01B2203/1614 , C01B2203/169 , C10G2300/1022 , C10G2300/4081 , C10G2400/06
摘要： The invention provides a process to prepare a Fischer-Tropsch synthesis product from a gaseous mixture of hydrocarbons comprising methane, ethane and optional higher carbon number hydrocarbons comprising the steps of: (a) pre-reforming the hydrocarbon mixture adiabatically, (b) heating the gaseous mixture obtained in step (a) to a temperature greater than 650° C., (c) performing a non-catalyzed partial oxidation by contacting the heated mixture of step (b) yielding a reactor effluent having a temperature of between 1100 and 1500° C., (d) performing a Fischer-Tropsch synthesis using the hydrogen- and carbon monoxide-containing gas as obtained in step (c) as feedstock and (e) wherein from the synthesis product obtained in step (d) a relatively light stream is separated and wherein a first part of the light stream is recycled to step (a) to be subjected to pre-reforming and wherein a second part of the light stream is recycled to the burner of step (c) to be subjected to partial oxidation and wherein the temperature in step (a) is controlled by the adjusting the amount of light stream that is recycled to step (a).
摘要翻译：本发明提供了一种从包含甲烷，乙烷和任选的较高碳数烃的烃的气体混合物制备费 - 托合成产物的方法，包括以下步骤：（a）绝热地预重整烃混合物，（b）步骤（a）中获得的气态混合物至大于650℃的温度，（c）通过使加热的步骤（b）的混合物接触而进行非催化部分氧化，产生温度为1100至1500℃的反应器流出物 ℃，（d）使用步骤（c）中获得的含氢和一氧化碳的气体作为原料进行费 - 托合成，（e）其中从步骤（d）中获得的合成产物相对较轻流分离，并且其中轻流的第一部分被再循环到步骤（a）以进行预重整，并且其中轻流的第二部分被再循环到步骤（c）的燃烧器以进行部分氧化物并且其中步骤（a）中的温度通过调节再循环到步骤（a）的轻流量来控制。

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