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    • 3. 发明申请
    • PHOTOSENSITIVE RESIN COMPOSITION AND METHOD FOR PRODUCING RESIST PATTERN
    • 光敏树脂组合物及其制造方法
    • US20150185604A1
    • 2015-07-02
    • US14580902
    • 2014-12-23
    • JSR Corporation
    • Hisanori AKIMARUHirokazu SakakibaraHidefumi IshikawaShingo Naruse
    • G03F7/027G03F7/30G03F7/038
    • G03F7/031G03F7/027G03F7/0388G03F7/30
    • The present invention provides a photosensitive resin composition comprising: an alkali-soluble resin (A); a compound having at least one ethylenically unsaturated double bond per molecule (B); a photo radical polymerization initiator having a keto oxime ester structure (C); and a compound represented by the Formula (1) or (2) below (D); wherein the content of the photo radical polymerization initiator (C) is 0.5 to 5 times the content of the compound (D), and the content of the photo radical polymerization initiator (C) with respect to 100 parts by mass of the compound (B) is 3 to 20 parts by mass. In Formula (1), the six R1s each independently represent a hydrogen atom or an electron-donating group, and n represents 0 or 1. In Formula (2), the six R2s each independently represent a hydrogen atom or an electron-donating group, and m represents 0 or 1. By use of the photosensitive resin composition of the present invention, formation of a resist pattern having excellent resolution is possible even without using an oxygen inhibition layer. By the method for producing a resist pattern of the present invention, formation of a resist pattern having excellent resolution is possible even without using an oxygen inhibition layer.
    • 本发明提供一种感光性树脂组合物,其含有:碱溶性树脂(A) 每分子具有至少一个烯属不饱和双键的化合物(B); 具有酮肟酯结构(C)的光自由基聚合引发剂; 和由下式(1)或(2)表示的化合物(D)表示的化合物。 其中光自由基聚合引发剂(C)的含量为化合物(D)的含量的0.5〜5倍,光自由基聚合引发剂(C)的含量相对于化合物(B)100质量份 )为3〜20质量份。 在式(1)中,六个R 1各自独立地表示氢原子或给电子基团,n表示0或1.在式(2)中,六个R 2各自独立地表示氢原子或给电子基团 m表示0或1.通过使用本发明的感光性树脂组合物,即使不使用氧抑制层,也可以形成具有优异的分辨率的抗蚀剂图案。 通过本发明的抗蚀剂图案的制造方法,即使不使用氧抑制层,也可以形成具有优异的分辨率的抗蚀剂图案。