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1. 发明授权

US06214885B1 Use of polymers containing &bgr;-hydroxyalkylvinylamine units as biocides 失效
标题翻译：使用含有β-羟基烷基乙烯基胺单元的聚合物作为杀生物剂
公开(公告)号：US06214885B1
公开(公告)日：2001-04-10
申请号：US09508058
申请日：2000-03-07
申请人： Jürgen Tropsch , Dieter Zeller , Anton Negele , Norbert Mahr , Jürgen Decker
发明人： Jürgen Tropsch , Dieter Zeller , Anton Negele , Norbert Mahr , Jürgen Decker
IPC分类号： A01N3308
CPC分类号： A01N33/08 , A01N2300/00
摘要： The use of polymers containing &bgr;-hydroxyalkylvinylamine units, as obtainable by reacting polymers containing vinylamine units with epoxides of the formula in which R is C2-C28 alkyl, phenyl, C1-C18 alkylphenyl or C2-C18 alkenyl, as biocides.
摘要翻译：使用含有β-羟基烷基乙烯基胺单元的聚合物，可通过使含有乙烯胺单元的聚合物与R为C 2 -C 28烷基，苯基，C 1 -C 18烷基苯基或C 2 -C 18烯基的环氧化物反应，作为杀生物剂获得。

2. 发明授权

US06458348B1 Use of water-soluble polymers as biocides 失效
标题翻译：使用水溶性聚合物作为杀生物剂
公开(公告)号：US06458348B1
公开(公告)日：2002-10-01
申请号：US09508001
申请日：2000-03-07
申请人： Jürgen Tropsch , Dieter Zeller , Anton Negele , Norbert Mahr , Jürgen Decker
发明人： Jürgen Tropsch , Dieter Zeller , Anton Negele , Norbert Mahr , Jürgen Decker
IPC分类号： A01N3718
CPC分类号： A01N37/36 , A01N43/80 , A01N2300/00
摘要： The use of polymers comprising as essential structural elements units of the formula I and/or II in which R1 is H, alkyl, cycloalkyl, aryl or aralkyl, R2 and R3 independently of one another are defined as for R1 or are selected from substituted alkyl, substituted cycloalkyl, substituted aryl or substituted aralkyl, the substituents being selected from OH, O-alkyl, O-aryl, SH, S-alkyl, S-aryl, NH2, NH-alkyl, NH-aryl, N(alkyl)2, in protonated form if desired, N(alkyl)3+Z31 , where Z is the radical of an organic or inorganic acid, COOH, COO-alkyl, CONH2, CONH-alkyl, CON(alkyl)2, CN and SO3H; and the indices x in each case independently of one another are an integer from 1 to 20, and their corresponding acid addition salts as biocides.
摘要翻译：使用包含作为基本结构单元的式I和/或IIin的单元，其中R 1为H，烷基，环烷基，芳基或芳烷基，R 2和R 3彼此独立地为R 1或选自取代的烷基，取代的环烷基，取代的芳基或取代的芳烷基，取代基选自OH，O-烷基，O-芳基，SH，S-烷基，S-芳基，NH 2，NH-烷基，NH-芳基，N（烷基）其中Z是有机或无机酸的基团，COOH，COO-烷基，CONH 2，CONH-烷基，CON（烷基）2，CN和SO 3 H; 并且每种情况下的指数x彼此独立地为1至20的整数，并且其相应的酸加成盐作为杀生物剂。

3. 发明授权

US07034068B1 Aqueous dispersions of water-soluble polymers of N-vinyl carboxylic acid amides, method for the production and use thereof 有权
标题翻译： N-乙烯基羧酸酰胺的水溶性聚合物的水分散体，其制备方法和用途
公开(公告)号：US07034068B1
公开(公告)日：2006-04-25
申请号：US09830566
申请日：1999-10-30
申请人： Anton Negele , Werner Gauweiler , Hubert Meixner , Norbert Mahr , Martin Rübenacker
发明人： Anton Negele , Werner Gauweiler , Hubert Meixner , Norbert Mahr , Martin Rübenacker
IPC分类号： C08L29/04
CPC分类号： C08F26/02 , D21H17/37 , D21H21/10 , D21H21/18 , D21H21/20
摘要： Aqueous dispersions of water-soluble polymers of N-vinylcarboxamides contain, based on 100 parts of water, (A) from 5 to 80 parts by weight of water-soluble polymer containing N-vinylformamide units and/or N-vinylacetamide units and having particle sizes of from 50 nm to 2 μm and (B) from 1 to 50 parts by weight of at least one polymeric dispersant which is incompatible with the water-soluble polymers (A) in aqueous solution, which dispersions are prepared by polymerizing (A) from 5 to 80 parts by weight of N-vinylformamide and/or N-vinylacetamide, if desired together with other monoethylenically unsaturated monomers which form water-soluble polymers therewith, and (B) from 1 to 50 parts by weight of at least one polymeric dispersant which is incompatible with the polymers, formed from the monomers (A), in aqueous solution, in 100 parts by weight of water, at from 30 to 95° C. in the presence of from 0.001 to 5.0% by weight, based on the monomers used, and the aqueous dispersions of water-soluble polymers are used as drainage aids, flocculants and retention aids and as wet and dry strength agents and as fixing compositions in papermaking.
摘要翻译： N-乙烯基甲酰胺的水溶性聚合物的水性分散体含有100份水，（A）5至80份（重量）含有N-乙烯基甲酰胺单元和/或N-乙烯基乙酰胺单元的水溶性聚合物，并具有颗粒至少一种与水溶液中的水溶性聚合物（A）不相容的至少一种聚合物分散剂，（B）通过聚合（A）制备该分散体， 5至80重量份的N-乙烯基甲酰胺和/或N-乙烯基乙酰胺，如果需要，与其中形成水溶性聚合物的其它单烯属不饱和单体一起，和（B）1至50重量份的至少一种聚合物在100重量份水中，由单体（A）在水溶液中形成的与聚合物不相容的分散剂，在30至95℃，基于0.001至5.0重量％的存在下，基于使用的单体和水分散体水溶性聚合物被用作排水助剂，絮凝剂和助留剂以及湿和干强度剂和造纸中的固定组合物。

4. 发明授权

US07297733B2 Aqueous dispersions of water-soluble polymers of N-vinylcarboxamides, their preparation and their use 有权
标题翻译： N-乙烯基甲酰胺的水溶性聚合物的水分散体及其制备及其用途
公开(公告)号：US07297733B2
公开(公告)日：2007-11-20
申请号：US11328171
申请日：2006-01-10
申请人： Anton Negele , Werner Gauweiler , Hubert Meixner , Norbert Mahr , Martin Ruebenacker
发明人： Anton Negele , Werner Gauweiler , Hubert Meixner , Norbert Mahr , Martin Ruebenacker
IPC分类号： C08L29/04 , C08L89/00
CPC分类号： C08F26/02 , D21H17/37 , D21H21/10 , D21H21/18 , D21H21/20
摘要： Aqueous dispersions of water-soluble polymers of N-vinylcarboxamides contain, based on 100 parts of water, (A) from 5 to 80 parts by weight of water-soluble polymer containing N-vinylformamide units and/or N-vinylacetamide units and having particle sizes of from 50 nm to 2 μm and (B) from 1 to 50 parts by weight of at least one polymeric dispersant which is incompatible with the water-soluble polymers (A) in aqueous solution, which dispersions are prepared by polymerizing (A) from 5 to 80 parts by weight of N-vinylformamide and/or N-vinylacetamide, if desired together with other monoethylenically unsaturated monomers which form water-soluble polymers therewith, and (B) from 1 to 50 parts by weight of at least one polymeric dispersant which is incompatible with the polymers, formed from the monomers (A), in aqueous solution, in 100 parts by weight of water, at from 30 to 95° C. in the presence of from 0.001 to 5.0% by weight, based on the monomers used, and the aqueous dispersions of water-soluble polymers are used as drainage aids, flocculants and retention aids and as wet and dry strength agents and as fixing compositions in papermaking.
摘要翻译： N-乙烯基甲酰胺的水溶性聚合物的水性分散体含有100份水，（A）5至80份（重量）含有N-乙烯基甲酰胺单元和/或N-乙烯基乙酰胺单元的水溶性聚合物，并具有颗粒至少一种与水溶液中的水溶性聚合物（A）不相容的至少一种聚合物分散剂，（B）通过聚合（A）制备该分散体， 5至80重量份的N-乙烯基甲酰胺和/或N-乙烯基乙酰胺，如果需要，与其中形成水溶性聚合物的其它单烯属不饱和单体一起，和（B）1至50重量份的至少一种聚合物在100重量份水中，由单体（A）在水溶液中形成的与聚合物不相容的分散剂，在30至95℃，基于0.001至5.0重量％的存在下，基于使用的单体和水分散体水溶性聚合物被用作排水助剂，絮凝剂和助留剂以及湿和干强度剂和造纸中的固定组合物。

5. 发明申请

US20060116448A1 Aqueous dispersions of water-soluble polymers of N-vinylcarboxamides, their preparation and their use 有权
标题翻译： N-乙烯基甲酰胺的水溶性聚合物的水分散体及其制备及其用途
公开(公告)号：US20060116448A1
公开(公告)日：2006-06-01
申请号：US11328171
申请日：2006-01-10
申请人： Anton Negele , Werner Gauweiler , Hubert Meixner , Norbert Mahr , Martin Rubenacker
发明人： Anton Negele , Werner Gauweiler , Hubert Meixner , Norbert Mahr , Martin Rubenacker
IPC分类号： D21H19/60
CPC分类号： C08F26/02 , D21H17/37 , D21H21/10 , D21H21/18 , D21H21/20
摘要： Aqueous dispersions of water-soluble polymers of N-vinylcarboxamides contain, based on 100 parts of water, (A) from 5 to 80 parts by weight of water-soluble polymer containing N-vinylformamide units and/or N-vinylacetamide units and having particle sizes of from 50 nm to 2 μm and (B) from 1 to 50 parts by weight of at least one polymeric dispersant which is incompatible with the water-soluble polymers (A) in aqueous solution, which dispersions are prepared by polymerizing (A) from 5 to 80 parts by weight of N-vinylformamide and/or N-vinylacetamide, if desired together with other monoethylenically unsaturated monomers which form water-soluble polymers therewith, and (B) from 1 to 50 parts by weight of at least one polymeric dispersant which is incompatible with the polymers, formed from the monomers (A), in aqueous solution, in 100 parts by weight of water, at from 30 to 95° C. in the presence of from 0.001 to 5.0% by weight, based on the monomers used, and the aqueous dispersions of water-soluble polymers are used as drainage aids, flocculants and retention aids and as wet and dry strength agents and as fixing compositions in papermaking.
摘要翻译： N-乙烯基甲酰胺的水溶性聚合物的水性分散体含有100份水，（A）5至80份（重量）含有N-乙烯基甲酰胺单元和/或N-乙烯基乙酰胺单元的水溶性聚合物，并具有颗粒至少一种与水溶液中的水溶性聚合物（A）不相容的至少一种聚合物分散剂，（B）通过聚合（A）制备该分散体， 5至80重量份的N-乙烯基甲酰胺和/或N-乙烯基乙酰胺，如果需要，与其中形成水溶性聚合物的其它单烯属不饱和单体一起，和（B）1至50重量份的至少一种聚合物在100重量份水中，由单体（A）在水溶液中形成的与聚合物不相容的分散剂，在30至95℃，基于0.001至5.0重量％的存在下，基于使用的单体和水分散体水溶性聚合物被用作排水助剂，絮凝剂和助留剂以及湿和干强度剂和造纸中的固定组合物。

6. 发明授权

US06716311B1 Modified cationic polymers, their preparation and their use in papermaking 失效
标题翻译：改性阳离子聚合物，其制备及其在造纸中的应用
公开(公告)号：US06716311B1
公开(公告)日：2004-04-06
申请号：US09807996
申请日：2001-05-04
申请人： Jürgen Decker , Norbert Mahr , Anton Esser , Hubert Meixner , Rainer Dyllick-Brenzinger , Martin aus dem Kahmen , Martin Gercke
发明人： Jürgen Decker , Norbert Mahr , Anton Esser , Hubert Meixner , Rainer Dyllick-Brenzinger , Martin aus dem Kahmen , Martin Gercke
IPC分类号： D21H1100
CPC分类号： D21H21/02 , C08F8/00 , C08G73/0206 , C08G73/028 , D21C5/022 , D21H17/54 , Y02W30/648 , C08F26/02
摘要： The invention relates to modified cationic polymers which can be obtained by reacting (a) water-soluble, polymeric compounds containing NH groups with (b) compounds which are at least bifunctional with regard to NH groups, which contain at least one alkyl radical or alkenyl radical having at least 8 C atoms, and which contain, as a functional group, a halohydrin, epoxide, carboxyl, chloroformate or isocyanate group or a halogen atom. The invention also relates to a method for producing the polymers by reacting the compounds of groups (a) and (b), and to the use of the modified cationic polymers during the production of paper as fixing agents for papermaking stock containing interfering substances.
摘要翻译：本发明涉及改性阳离子聚合物，其可以通过使（a）含有NH基团的水溶性聚合物与（b）至少对NH基团具有双官能团的化合物反应获得，所述NH基团含有至少一个烷基或链烯基具有至少8个C原子的基团，并且其含有卤代醇，环氧化物，羧基，氯甲酸酯或异氰酸酯基或卤素原子作为官能团。本发明还涉及通过使基团（a）和（b）的化合物反应制备聚合物的方法，以及在制造纸作为含有干扰物质的造纸原料的固定剂时使用改性阳离子聚合物的方法。

7. 发明授权

US06310261B1 Method for the production of aldehydes 失效
标题翻译：醛的生产方法
公开(公告)号：US06310261B1
公开(公告)日：2001-10-30
申请号：US09582780
申请日：2000-07-03
申请人： Bernhard Geissler , Michael Röper , Edgar Zeller , Rocco Paciello , Jürgen Decker , Hartwig Voss , Norbert Mahr
发明人： Bernhard Geissler , Michael Röper , Edgar Zeller , Rocco Paciello , Jürgen Decker , Hartwig Voss , Norbert Mahr
IPC分类号： C07C4550
CPC分类号： C08G73/0206 , B01J31/1658 , B01J31/1805 , B01J2231/321 , B01J2531/80 , B01J2531/822 , C07C45/50 , Y02P20/584 , C07C47/02
摘要： The invention relates to a method for the production of aldehydes or aldehydes and alcohols by hydroformylation of olefins in the presence of a complexing catalyst homogeneously dissolved in a reaction mixture, containing a metal of Group VIIIa of the periodic table of the elements and a phosphorus-free, polydentate nitrogen compound suitable for complex formation as ligand at temperatures ranging from 50 to 100° C. and pressures from 20 to 1,000 bar and recirculating the catalyst complex in the hydroformylation reaction, wherein a) derivatized polyamines are used that are substantially non-water soluble and suitable for complex formation and have a mean molecular weight of more than 1,000 Dalton and at least 10 nitrogen atoms; b) the catalyst complex remaining in the bottom of the distillation column and the excess ligands obtained from the reaction mixture are recirculated totally or partially in the hydroformylation once the hydroformylation reaction and the separation or partial separation by distillation of the aldehydes and the alcohols has been completed; c) continues or at least batchwise evacuation of at least part of the high boiler from the bottom of the distillation of the reaction mixture is then carried out.
摘要翻译：本发明涉及通过在均匀溶解在含有元素周期表第Ⅷa族金属的反应混合物的络合催化剂存在下烯烃的加氢甲酰化生产醛或醛和醇的方法，在50至100℃的温度和20至1,000巴的压力下适合于络合物形成配位体的多余的多齿氮化合物，并且在加氢甲酰基化反应中再循环催化剂配合物，其中a）使用基本上不相容的衍生的多胺，水溶性且适合于络合物形成，并且具有大于1,000道尔顿和至少10个氮原子的平均分子量; b）一旦加氢甲酰化反应和通过蒸馏醛和醇的分离或部分分离已经被残留在蒸馏塔底部的催化剂络合物和从反应混合物中得到的过量配体在加氢甲酰化反应中被全部或部分再循环完成 c）然后执行从反应混合物的蒸馏底部继续或至少间歇抽出高锅炉的至少一部分。

8. 发明授权

US07084200B2 Aqueous dispersions of water-soluble polymers of N-vinyl carboxylic acid amides, method for the production thereof and their use 失效
标题翻译： N-乙烯基羧酸酰胺的水溶性聚合物的水分散体，其制造方法及其用途
公开(公告)号：US07084200B2
公开(公告)日：2006-08-01
申请号：US10495111
申请日：2002-11-19
申请人： Marc Leduc , Stefan Frenzel , Norbert Mahr
发明人： Marc Leduc , Stefan Frenzel , Norbert Mahr
IPC分类号： C08F2/16 , C08L11/02
CPC分类号： C08F283/06 , C02F1/56 , C02F2209/09 , C08F26/02 , C08F285/00 , D21H21/10 , D21H21/18 , C08F226/02
摘要： Aqueous dispersions of water-soluble polymers of N-vinylcarboxamides, which contain, as a stabilizer, water-soluble, crosslinked graft polymers which are obtainable by free radical polymerization of compounds having at least two ethylenically unsaturated double bonds in the presence of polyalkylene glycols, are prepared by free radical polymerization of N-vinylcarboxamides in an aqueous medium in the presence of said stabilizers and are used as drainage aids, flocculants and retention aids, as wet and dry strength agents and as fixing agents in papermaking.
摘要翻译： N-乙烯基甲酰胺的水溶性聚合物的水分散体，其含有作为稳定剂的水溶性交联接枝聚合物，其可通过在聚亚烷基二醇存在下具有至少两个烯属不饱和双键的化合物的自由基聚合而获得，通过在所述稳定剂的存在下在水性介质中的N-乙烯基甲酰胺的自由基聚合制备，并且作为湿法和干燥强度剂以及作为造纸中的固定剂用作排水助剂，絮凝剂和助留剂。

9. 发明申请

US20050247420A1 Production of paper, board and cardboard 失效
标题翻译：生产纸张，纸板和纸板
公开(公告)号：US20050247420A1
公开(公告)日：2005-11-10
申请号：US10523417
申请日：2003-07-23
申请人： Rainer Blum , Ralf Hemel , Norbert Mahr , Rudolf Lorz
发明人： Rainer Blum , Ralf Hemel , Norbert Mahr , Rudolf Lorz
IPC分类号： D21H23/10 , D21H17/37 , D21H17/45 , D21H17/68 , D21H21/10 , D21H23/18
CPC分类号： D21H23/18 , D21H17/375 , D21H17/455 , D21H17/68 , D21H21/10
摘要： Paper, board and cardboard are produced by shearing the paper stock, adding a microparticle system comprising a cationic polymer and a finely divided inorganic component to the paper stock after the last shearing stage before the head box, draining the paper stock with sheet formation and drying the sheets, by a process in which cationic polyacrylamides, polymers containing vinylamine units and/or polydiallyldimethylammonium chloride having an average molar mass Mw of in each case at least 500 000 Dalton and a charge density of in each case not more than 4.0 meq/g are used as cationic polymers of the microparticle system.
摘要翻译：纸，纸板和纸板是通过剪切纸原料制成的，在头箱前的最后剪切阶段之后，将含有阳离子聚合物和细碎无机成分的微粒体系添加到纸料中，将纸料排出并形成干燥通过其中阳离子聚丙烯酰胺，含有乙烯胺单元的聚合物和/或聚二烯丙基二甲基氯化铵的平均摩尔质量Mw在每种情况下至少为500000道尔顿，电荷密度在每种情况下不超过4.0meq / g的方法，用作微粒系统的阳离子聚合物。

10. 发明申请

US20080210394A1 Polymer-Pigment Hybrids For Use in Papermaking 有权
标题翻译：用于造纸的聚合物 - 颜料混合物
公开(公告)号：US20080210394A1
公开(公告)日：2008-09-04
申请号：US11915682
申请日：2006-05-24
申请人： Norbert Mahr , Dieter Meck , Rainer Blum , Ralf Hemel , Norbert Gispert , Jurgen Schmidt-Thummes , Christoph Hamers
发明人： Norbert Mahr , Dieter Meck , Rainer Blum , Ralf Hemel , Norbert Gispert , Jurgen Schmidt-Thummes , Christoph Hamers
IPC分类号： D21H17/63
CPC分类号： C09C1/021 , C01P2004/61 , C01P2004/62 , C01P2004/80 , C01P2006/60 , D21H17/675 , D21H17/69
摘要： Process for the production of filler-containing papers and filler-containing paper products by addition of an aqueous suspension of at least one finely divided polymer-pigment hybrid to a paper stock and drainage of the paper stock with sheet formation, the polymer-pigment hybrid being obtainable by milling an aqueous suspension of at least one inorganic pigment in the presence of at least one binder and, if appropriate, by drying the aqueous suspension thus obtainable and redispersing the dried polymer-pigment hybrid in water, and the use of the polymer-pigment hybrids thus obtainable as a filler for the production of filler-containing paper or filler-containing paper products.
摘要翻译：通过将至少一种细分散的聚合物 - 颜料混合物的水性悬浮液加入到纸料中并通过片材形成纸浆的排出来生产含填料的纸和含填料的纸产品的方法，聚合物 - 颜料混合物可通过在至少一种粘合剂的存在下研磨至少一种无机颜料的水性悬浮液，并且如果合适的话，通过干燥由此获得的水性悬浮液并将干燥的聚合物 - 颜料杂化物再分散在水中，以及使用聚合物因此可以将其作为用于生产含填料的纸或含有填料的纸制品的填料获得。

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