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1. 发明授权

US4789620A Liquid photosensitive resin composition containing carboxylated epoxy acrylates or methacrylates 失效
标题翻译：含羧基环氧丙烯酸酯或甲基丙烯酸酯的液体感光性树脂组合物
公开(公告)号：US4789620A
公开(公告)日：1988-12-06
申请号：US880738
申请日：1986-07-01
申请人： Isao Sasaki , Kenji Kushi , Ken-ichi Inukai
发明人： Isao Sasaki , Kenji Kushi , Ken-ichi Inukai
IPC分类号： G03F7/027 , G03F7/032 , H05K3/28 , G03C1/68
CPC分类号： G03F7/032 , G03F7/027 , H05K3/287 , H05K2203/0793
摘要： Disclosed is a liquid photosensitive resin composition comprising(a) an at least partially carboxyl-modified multifunctional epoxy acrylate and/or multifunctional epoxy methacrylate having an average acid value of 4 to 150 and a number average molecular weight of not greater than 5,000,(b) an acrylic and/or methacrylic cross-linking monomer and/or oligomer other than the epoxy acrylate and/or epoxy methacrylate,(c) an acrylic and/or methacrylic monoethylenically vinyl monomer,(d) an inorganic filler, and(e) a photo-initiator and/or photosensitizer.This liquid photosensitive resin composition has excellent alkali developability, yields a cured coating film having good adhesion and good electrical insulating properties under high-humidity conditions, and is suitable for use as a solder resist in the fabrication of printed circuit boards.
摘要翻译：公开了一种液体感光性树脂组合物，其包含（a）至少部分羧基改性的多官能环氧丙烯酸酯和/或平均酸值为4〜150，数均分子量为5000以下的多官能环氧丙烯酸酯（b ）丙烯酸和/或甲基丙烯酸单烯属乙烯基单体以外的丙烯酸和/或甲基丙烯酸交联单体和/或低聚物，（d）无机填料，和（e）丙烯酸和/ 光引发剂和/或光敏剂。该液体感光性树脂组合物具有优异的碱显影性，得到在高湿度条件下具有良好的粘合性和良好的电绝缘性的固化涂膜，适用于制造印刷电路板的阻焊剂。

2. 发明授权

US4689243A Heat-resistant resin molded article with excellent abrasion resistance and process for producing the same 失效
标题翻译：具有优异耐磨性的耐热树脂成型体及其制造方法
公开(公告)号：US4689243A
公开(公告)日：1987-08-25
申请号：US783227
申请日：1985-09-24
申请人： Isao Sasaki , Kozi Nishida , Masaru Morimoto , Kenji Kushi
发明人： Isao Sasaki , Kozi Nishida , Masaru Morimoto , Kenji Kushi
IPC分类号： C08J7/04 , C08L33/24 , C09D4/00 , B05D3/06
CPC分类号： C08L33/24 , C08J7/047 , C09D4/00 , C08J2423/00 , C08J2433/00 , Y10T428/261 , Y10T428/264 , Y10T428/265 , Y10T428/269 , Y10T428/31721 , Y10T428/31928
摘要： A heat-resistant resin molded article excellent in abrasion resistance, surface smoothness, solvent resistance, durability and adhesiveness between base material and cured film, consisting of (1) a resin molded article composed of 2% by weight or more of a structural unit represented by the following structural formula ##STR1## (wherein R is a hydrogen atom, an alkyl group, an aryl group or an alicyclic group of 1 to 20 carbon atoms) and 98% by weight or less of an ethylenic monomer unit and (2) a cured film formed on the surface of said resin molded article by curing a crosslinking-curable resin material containing 30% by weight or more of at least one monomer having three or more (meth)acryloyloxy groups in one molecule, as well as a process for producing said heat-resistant resin molded article.
摘要翻译： PCT No.PCT / JP85 / 00071 Sec。 371日期：1985年9月24日 102（e）1985年9月24日PCT 1985年2月20日PCT PCT。出版物WO85 / 03670 日本1985年8月29日。耐磨性，表面平滑性，耐溶剂性，耐久性和基材与固化膜之间的粘合性优异的耐热性树脂成型体，由（1）由2重量％以下结构式表示的结构单元，其中R为氢原子，烷基，芳基或碳原子数为1〜20的脂环族基），98重量％以下的结构单元乙烯性单体单元和（2）通过将包含30重量％以上的至少一种具有三个以上（甲基）丙烯酰氧基的单体的交联固化性树脂材料固化在一个上形成在所述树脂成型体的表面上的固化膜分子，以及制造所述耐热树脂模塑制品的方法。

3. 发明授权

US4518472A Delustering coating composition excellent in abrasion resistance 失效
标题翻译：具有优异耐磨性的清漆涂料组合物
公开(公告)号：US4518472A
公开(公告)日：1985-05-21
申请号：US525895
申请日：1983-08-24
申请人： Kazuo Kishida , Isao Sasaki , Kenji Kushi , Masahiro Sugimori
发明人： Kazuo Kishida , Isao Sasaki , Kenji Kushi , Masahiro Sugimori
IPC分类号： C08F2/48 , C08F285/00 , C08J7/04 , C09D4/06 , C08F220/00 , C09D3/00
CPC分类号： C08J7/047 , C08F285/00 , C09D4/06 , C08J2333/06 , C08J2433/00
摘要： A coating composition curable by an activation energy ray, which comprises (a) 100 parts by weight of a monomer mixture (A) comprising at least 30% by weight of a compound having at least 3 acryloyloxy and/or methacryloyloxy groups in the molecule and up to 70% by weight of a compound having 1 to 2 .alpha.,.beta.-ethylenically unsaturated bonds in the molecule, (b) 0.01 to 6.0 parts by weight of at least one photosensitizer and (c) 0.5 to 30 parts by weight of an emulsion type crosslinked polymer or copolymer of a reactive monomer having one .alpha.,.beta.-ethylenically unsaturated bond in the molecule and a reactive monomer having at least two .alpha.,.beta.-ethylenically unsaturated bonds in the molecule.
摘要翻译：一种由活化能射线固化的涂料组合物，其包含（a）100重量份的包含至少30重量％的分子中具有至少3个丙烯酰氧基和/或甲基丙烯酰氧基的化合物的单体混合物（A），和至多70重量％的分子中具有1至2个α，β-烯属不饱和键的化合物，（b）0.01至6.0重量份的至少一种光敏剂和（c）0.5至30重量份的分子中具有一个α，β-烯属不饱和键的反应性单体的乳液型交联聚合物或共聚物，以及在分子中具有至少两个α，β-烯属不饱和键的反应性单体。

4. 发明授权

US4367245A Coating composition and process for preparing synthetic resin shaped articles by using same 失效
标题翻译：涂料组合物及其制备方法
公开(公告)号：US4367245A
公开(公告)日：1983-01-04
申请号：US246942
申请日：1981-03-24
申请人： Kazuo Kishida , Isao Sasaki , Kenji Kushi , Misao Tamura
发明人： Kazuo Kishida , Isao Sasaki , Kenji Kushi , Misao Tamura
IPC分类号： C08F20/00 , B05D3/06 , B05D7/02 , C08F2/48 , C08F20/10 , C08F20/26 , C08F22/10 , C08F220/28 , C08F290/00 , C08F299/02 , C08J7/04 , C09D4/00 , C09D133/04
CPC分类号： C08F22/105 , C09D4/00
摘要： A coating composition for the preparation of synthetic resin shaped articles excellent in abrasion resistance and weatherability is described. This composition comprises (a) a polyfunctional monomer mixture comprising (i) 25-75 wt. % of at least one polyfunctional monomer of the formula (I): ##STR1## wherein at least three of X.sub.11, X.sub.12, X.sub.13, X.sub.22, X.sub.23 -X.sub.n2, X.sub.n3 and X.sub.14 are CH.sub.2 .dbd.CH.C00-- and the remaining groups are --OH, and n is an integer of 1-5, (ii) 25-75 wt. % of at least one polyfunctional monomer of the formula (II): ##STR2## wherein at least three of the R groups are CH.sub.2 .dbd.CH COO-- and each of the remaining is H or --OH, n.sub.1, n.sub.2, n.sub.3, n.sub.4, m.sub.1, m.sub.2, m.sub.3 and m.sub.4 are integers of 0, 1 or 2, and X is an integer of 1 to 10 and (iii) 0 to 50 wt. % of a monomer containing one acryloyloxy group and having a boiling point of at least 150.degree. C. at normal pressure and a viscosity of not higher than 20 cps/20.degree. C., and (b) 0.01-6.0 wt. parts, based on 100 wt. parts of the polyfunctional monomer mixture, of at least one photosensitizer. The coating composition is coated on a synthetic resin shaped article and then, irradiated with utraviolet rays in air to form a crosslinked coating film having a thickness of 1-30 microns.
摘要翻译：描述了用于制备耐磨性和耐候性优异的合成树脂成型制品的涂料组合物。该组合物包含（a）多官能单体混合物，其包含（i）25-75wt。％的至少一种式（I）的多官能单体：其中X11，X12，X13，X22，X23-Xn2，Xn3和X14中的至少三个是CH2 = CH。 C00-，其余基团为-OH，n为1-5的整数，（ii）25-75wt。％的至少一种式（II）的多官能单体：其中至少三个R基团是CH 2 = CH COO-，并且其中每一个是H或-OH， n1，n2，n3，n4，m1，m2，m3和m4为0,1或2的整数，X为1〜10的整数，（iii）0〜50重量％％的含有1个丙烯酰氧基的单体，沸点在常压下为至少150℃，粘度不高于20cps / 20℃，（b）0.01-6.0wt。基于100wt。部分多官能单体混合物，至少一种光敏剂。将涂料组合物涂布在合成树脂成型制品上，然后在空气中用紫外线照射，形成厚度为1-30微米的交联涂膜。

5. 发明授权

US4737409A Heat-resistant resin molded article with excellent abrasion resistance and process for producing the same 失效
标题翻译：具有优异耐磨性的耐热树脂成型体及其制造方法
公开(公告)号：US4737409A
公开(公告)日：1988-04-12
申请号：US43443
申请日：1987-04-28
申请人： Isao Sasaki , Kozi Nishida , Masaru Morimoto , Kenji Kushi
发明人： Isao Sasaki , Kozi Nishida , Masaru Morimoto , Kenji Kushi
IPC分类号： C08J7/04 , C08L33/24 , C09D4/00 , B32B27/06
CPC分类号： C08L33/24 , C08J7/047 , C09D4/00 , C08J2423/00 , C08J2433/00 , Y10T428/261 , Y10T428/264 , Y10T428/265 , Y10T428/269 , Y10T428/31721 , Y10T428/31928
摘要： A heat-resistant resin molded article excellent in abrasion resistance, surface smoothness, solvent resistance, durability and adhesiveness between base material and cured film, consisting of (1) a resin molded article composed of 2% by weight or more of a structural unit represented by the following structural formula ##STR1## (wherein R is a hydrogen atom, an alkyl group, an aryl group or an alicyclic group of 1 to 20 carbon atoms) and 98% by weight or less of an ethylenic monomer unit and (2) a cured film formed on the surface of said resin molded article by curing a crosslinking-curable resin material containing 30% by weight or more of at least one monomer having three or more (meth)acryloyloxy groups in one molecule, as well as a process for producing said heat-resistant resin molded article.

6. 发明授权

US4388345A Coating composition and process for preparing synthetic resin shaped articles by using same 失效
标题翻译：涂料组合物及其制备方法
公开(公告)号：US4388345A
公开(公告)日：1983-06-14
申请号：US343221
申请日：1982-01-27
申请人： Kazuo Kishida , Isao Sasaki , Kenji Kushi , Misao Tamura
发明人： Kazuo Kishida , Isao Sasaki , Kenji Kushi , Misao Tamura
IPC分类号： C09D5/00 , C08J7/04 , C08J7/16 , C09D4/00 , B05D3/06
CPC分类号： C08J7/16 , C09D4/00 , C08J2331/00 , Y10T428/31507
摘要： A shaped article of synthetic resins, such as polydiethylene glycol bisallylcarbonate, is coated with the following coating composition and then irradiated with ultraviolet rays, whereby the coating composition deposited on the shaped article is cured to form a coating film having an excellent abrasion resistance, surface smoothness, adhesion to the substrate resin, flexibility, heat resistance, solvent resistance and durability. The coating composition comprised of (a) a mixture of, based on the weight of the mixture, (i) 25-99.95 wt. % of at least one polyfunctional monomer having at least three acryloyloxy or methacryloyloxy groups, (ii) 0-50 wt. % of at least one mono- or bi-functional monomer having one or two polymerizable unsaturated groups and (iii) 0.05-25 wt. % of at least one organic acid which has at least one halogen substituent (fluorine, chlorine or bromine) and which is liquid at normal temperature and pressure, and (b) 0.01-10 wt. parts, based on 100 wt. parts of said mixture, of a photosensitizer. The coating composition may contain 0.05-25 wt. % of at least one compound having an acrylamide or methacrylamide group and a hydroxyl group or groups.
摘要翻译：合成树脂如聚二甘醇双烯丙基碳酸酯的成形制品用以下涂料组合物涂覆，然后用紫外线照射，由此沉积在成型制品上的涂料组合物固化以形成具有优异耐磨性，表面平滑性，与基材树脂的粘合性，柔软性，耐热性，耐溶剂性和耐久性。涂料组合物包含（a）基于混合物重量的混合物，（i）25-99.95wt。至少一种具有至少三个丙烯酰氧基或甲基丙烯酰氧基的多官能单体的％，（ii）0-50wt。％的至少一种具有一个或两个可聚合不饱和基团的单官能或双官能单体和（iii）0.05-25wt。至少一种具有至少一个卤素取代基（氟，氯或溴）并在常温常压下为液体的有机酸的％，和（b）0.01-10重量％基于100wt。所述混合物的一部分，光敏剂。涂料组合物可以含有0.05-25wt。％的至少一种具有丙烯酰胺或甲基丙烯酰胺基团和羟基或基团的化合物。

7. 发明授权

US4351881A Radiation cured acrylate coating method and coated product 失效
标题翻译：辐射固化丙烯酸酯涂层方法和涂层产品
公开(公告)号：US4351881A
公开(公告)日：1982-09-28
申请号：US206560
申请日：1980-11-13
申请人： Kazumasa Kamada , Isao Sasaki , Kenji Kushi
发明人： Kazumasa Kamada , Isao Sasaki , Kenji Kushi
IPC分类号： C08F20/00 , C08F2/44 , C08F2/46 , C08F2/50 , C08F20/10 , C08F20/26 , C08F20/38 , C08F20/52 , C08F30/00 , C08F30/02 , C08F220/20 , C08F220/28 , C08F220/38 , C08F220/58 , C08F230/02 , C08J7/04 , C09D4/00 , C09D5/00 , C09D171/00 , C08F216/20 , C08F228/04
CPC分类号： C08F2/46 , C09D4/00 , Y10T428/31507 , Y10T428/31935
摘要： A coating composition comprising a polyfunctional monomer (a) having at least 3 (meth)acryloyloxy groups, a (meth)acrylic acid mono or diester of polyethyleneglycol (b), a sulfonic acid (c), a phosphoric acid ester (d), an ethanolamine (e), organic solvent, and a photosensitizer.

8. 发明授权

US4274933A Coating composition 失效
标题翻译：涂料组成
公开(公告)号：US4274933A
公开(公告)日：1981-06-23
申请号：US103626
申请日：1979-12-14
申请人： Kazumasa Kamada , Isao Sasaki , Kenji Kushi
发明人： Kazumasa Kamada , Isao Sasaki , Kenji Kushi
IPC分类号： C08F20/00 , C08F2/44 , C08F2/46 , C08F2/50 , C08F20/10 , C08F20/26 , C08F20/38 , C08F20/52 , C08F30/00 , C08F30/02 , C08F220/20 , C08F220/28 , C08F220/38 , C08F220/58 , C08F230/02 , C08J7/04 , C09D4/00 , C09D5/00 , C09D171/00
CPC分类号： C08F2/46 , C09D4/00 , Y10T428/31507 , Y10T428/31935
摘要： A coating composition comprising a polyfunctional monomer (a) having at least 3 (meth)acryloyloxy groups, a (meth)acrylic acid mono or diester of polyethyleneglycol (b), a sulfonic acid (c), a phosphoric acid ester (d), an ethanolamine (e), organic solvent, and a photosensitizer.
摘要翻译：一种包含具有至少3个（甲基）丙烯酰氧基的多官能单体（a），聚乙二醇（b）的（甲基）丙烯酸单酯或二酯），磺酸（c），磷酸酯（d），乙醇胺（e），有机溶剂和光敏剂。

9. 发明授权

US4291097A Scratch-resistant, dyeable coating compositions for synthetic resin articles 失效
标题翻译：用于合成树脂制品的耐刮擦可染色涂料组合物
公开(公告)号：US4291097A
公开(公告)日：1981-09-22
申请号：US103625
申请日：1979-12-14
申请人： Kazumasa Kamada , Isao Sasaki , Kenji Kushi
发明人： Kazumasa Kamada , Isao Sasaki , Kenji Kushi
IPC分类号： C08F2/00 , C08F2/48 , C08F20/00 , C08F20/10 , C08F20/20 , C08F20/28 , C08F30/00 , C08F30/02 , C08F220/00 , C08F220/26 , C08F290/00 , C08F299/00 , C09D4/00 , C09D5/00 , C09D171/00 , B05D3/06
CPC分类号： C09D4/00 , Y10T428/31507 , Y10T428/31928
摘要： Coating compositions comprising a polyfunctional monomer of a mono or polypentaerythritol poly(meth)acrylate, a bifunctional (meth)acrylate having specific monomer structure, an additional (meth)acrylate containing not more than 2 (meth)acryloyloxy groups, a phosphoric acid ester and an ethanolamine all blended together in a suitable organic solvent system together with a photosensitizer are disclosed. The compositions provide a scratch-resistant, hard cross-linked film surface that is dyeable and resists static and fogging to a synthetic resin article, such as polymethyl methacrylate, to which they are applied.
摘要翻译：包含单或多季戊四醇聚（甲基）丙烯酸酯，具有特定单体结构的双官能（甲基）丙烯酸酯，另外的（甲基）丙烯酸酯含有不多于2个（甲基）丙烯酰氧基的多官能单体，磷酸酯和公开了在合适的有机溶剂系统中与光敏剂一起共混的乙醇胺。所述组合物提供耐刮擦，硬交联的膜表面，其可染色并且抵抗其所施用的合成树脂制品（例如聚甲基丙烯酸甲酯）的静电和起雾。

10. 发明授权

US4287227A Coating composition and process for producing synthetic resin moldings by using the same 失效
标题翻译：用于制造合成树脂模制品的涂料组合物和方法
公开(公告)号：US4287227A
公开(公告)日：1981-09-01
申请号：US109245
申请日：1980-01-03
申请人： Kazumasa Kamada , Isao Sasaki , Kenji Kushi
发明人： Kazumasa Kamada , Isao Sasaki , Kenji Kushi
IPC分类号： C08F2/00 , C08F2/44 , C08F2/48 , C08F2/50 , C08F20/00 , C08F20/10 , C08F20/26 , C08F220/00 , C08F220/20 , C08F283/00 , C08F290/00 , C08F299/00 , C08F299/02 , C08J3/28 , C08J7/04 , C08K5/5419 , C09D4/00 , C09D4/06 , C09D5/00 , C09D7/12 , C09D171/00 , B05D3/06
CPC分类号： C09D4/00 , C09D4/06 , Y10T428/31507 , Y10T428/31649 , Y10T428/31855
摘要： A coating composition comprising a monomer mixture of mono- or polypentaerythritol hving at least three (meth) acryloyloxy groups and at least one monofunctional acrylate or methacrylate having at least one ether bond in the molecule, a boiling point above 150.degree. C. under normal pressure and a viscosity below 20 centipoises at 20.degree. C., a photosensitizing agent, at least one silicon containing surface active agent and at least one organic solvent capable of forming a uniform solution upon mixing with the vinyl monomer mixture. Also disclosed is a process of coating surfaces with the coating compositions.
摘要翻译：一种涂料组合物，其包含具有至少三个（甲基）丙烯酰氧基的单 - 或多季戊四醇和至少一个在分子中具有至少一个醚键的单官能丙烯酸酯或甲基丙烯酸酯的单体混合物，在常压下高于150℃的沸点 20℃下的粘度低于20厘泊，光敏剂，至少一种含硅表面活性剂和至少一种能够与乙烯基单体混合物混合时形成均匀溶液的有机溶剂。还公开了用涂料组合物涂覆表面的方法。

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